Disusun oleh
FAKULTAS TEKNIK
UNIVERSITAS DIPONEGORO
2016
KEMENTERIAN PENDIDIKAN NASIONAL
UNIVERSITAS DIPONEGORO
FAKULTAS TEKNIK
JURUSAN TEKNIK KIMIA
Jl. Prof. H. Soedarto, SH. Kampus Tembalang Semarang 50239 Tel
p. (024) 7460058, Fax. (024) 7460055
LEMBAR PENGESAHAN
Mengetahui,
Dosen Pengampu
NIP. 197509152000121001
1. Consider the introductory example,
dC A E
K1C A exp
dt RT
dT E
K 2C A exp
dt RT
where CA = 1.0 gmol/L and T = 300 K initially. Determine the concentration and temperature
after 100 seconds with ∆t = 10 seconds if E/R = 300 K; K1=-0.1/sec; K2 = 1.0 K/gmol-sec.
Jawab :
************************************
t CA T
************************************
10 0.72932 302.707
20 0.53095 304.691
30 0.38603 306.140
40 0.28041 307.196
50 0.20354 307.964
60 0.14766 308.522
70 0.10712 308.928
80 0.07768 309.222
90 0.05633 309.436
>>
2. Consider the absorbtion of A from a gas into liquid film B in which A reacts with B
according to
A+B 2C
r = kCA2
C A 2C A
DAB kC A2
t x 2
where: t = 0, CA = 0;
x = 0, CA = CA0;
x = L, dC/dx = 0
For the following data, determine the final concentration formula after dicretization if:
L = 0.3 cm
k = 1.0 liters/gmole-sec
Jawab :