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MODUL PINTAS 2020

TINGKATAN 5 4541/2
CHEMISTRY
Kertas 2
September/Oktober
1
2 2 jam Dua jam tiga puluh minit

PERATURAN PEMARKAHAN
CHEMISTRY K2
4541/2
 Section A
Bahagian A

Question Answer Marks

Soalan Jawapan Markah
1. (a) Saponification 1
Saponifikasi

(b) Concentrated potassium hydroxide solution

1
Larutan kalium hidroksida pekat

(c) To reduce the solubility of soap

1
Untuk mengurangkan keterlarutan sabun

(d) (i) Cleaning agent A

1
Agen pencuci A

(ii) Effectiveness in cleansing action :

cleaning agent A is not effective in hard water while 1
cleaning agent B effective in hard water.
Keberkesanan tindakan pencucian :
Agen pencuci A tidak berkesan dalam air liat manakala
Agen pencuci B berkesan dalam air liat.

Effect to environment :
cleaning agent A is a biodegradable while cleaning agent B is non-
biodegradable //
cleaning agent A do not cause water pollution while cleaning agent B cause
water pollution. 1
Kesan terhadap alam sekitar:
Agen pencuci A adalah terbiodegradasi manakala agen pencuci B adalah
tidak terbiodegradasi//
Agen pencuci A tidak menyebabkan pencemaran air manakala agen
pencuci B menyebabkan pencemaran air

(e) (i) Aspirin// 1

Paracetamol/parasetamol

(ii) Q: Antibiotic
1
Antibiotik

R: Psychotherapeutic
1
Psikoterapeutik

TOTAL / JUMLAH 9
 Question Answer Marks
Soalan Jawapan Markah
2. (a) (i) Nucleon number 1
Nombor nukleon

(ii) 10 1

(iii)

• Correct number of electrons and shells 1

Bilangan elektron dan petala yang betul
• Nucleus
Nukleus

(b) (i) 80 °C 1

(ii) The heat energy absorbed by the particles

Tenaga haba diserap oleh zarah-zarah 1

is used to overcome the forces of attraction between particles

dan digunakan untuk mengatasi daya tarikan antara zarah-zarah 1

(c) 1. Potassium manganate(VII) is made up of tiny and discrete particles.

Kalium manganat (VII)terdiri daripada zarah-zarah yang halus dan
1
Diskrit

2. The particles move freely between water molecules

1
Zarah-zarah bergerak bebas di antara molekul-molekul air

3. from an area of high concentration to an area of low concentration.

1
dari kawasan yang berkepekatan tinggi ke kawasan yang berkepekatan
rendah.

TOTAL / JUMLAH 9
 Question Answer Marks
Soalan Jawapan Markah
3. (a) Empirical formula is a chemical formula that shows the simplest ratio of
number of atoms of each element in a compound.
1
Formula empirik adalah formula kimia yang menunjukkan nisbah paling
ringkas bagi bilangan atom setiap unsur yang terdapat dalam sebatian.

(b) ion 1

(c) To allow oxygen from the air flow in to react with magnesium.
Untuk membenarkan oksigen daripada udara masuk dan bertindak balas 1
dengan magnesium.

(d) The process of heating, cooling and weighing is repeated until a constant
mass is obtained.
1
Proses pemanasan, penyejukan dan penimbangan diulang beberapa kali
sehingga jisim tetap diperoleh.

(e) (i) Magnesium : 27.75 – 25.35 g // 2.4 g 1

Magnesium

Oxygen : 29.35 – 27.75 g // 1.6 g 1

Oksigen

(ii) Number of mole of magnesium : 2.4 / 24 = 0.1 mol 1

Bilangan mol magnesium

Number of mole of oxygen : 1.6 / 16 = 0.1 mol 1

Bilangan mol oksigen

(f) (i) No
1
Tidak

(ii) Lead is less reactive towards oxygen

1
Plumbum kurang reaktif terhadap oksigen

TOTAL / JUMLAH 10
 Question Answer Marks
Soalan Jawapan Markah
4. (a) Horizontal rows in periodic table of elements
Baris mendatar di dalam jadual berkala unsur 1

(b) 3 1

(c) Amphoteric property : Oxide of X / oksida X 1

Sifat amfoterik

Acidic property : Oxide of Y / oksida Y 1

Sifat berasid

(d) (i) Covalent compound

1
Sebatian kovalen

(ii) Correct formula of reactants and products

Formula bahan dan hasil yang betul 1

Balance equation
Persamaan seimbang 1

C + O2 → CO2

(iii)

•Correct number of electrons and shells 1

Bilangan elektron dan petala yang betul

• nucleus 1
nukleus

(iv) Low melting and boiling point// cannot conduct electricity in any state
Takat lebur dan takat didih rendah// tidak boleh mengkonduksi elektrik 1
dalam mana-mana keadaan

TOTAL / JUMLAH 10
 Question Answer Marks
Soalan Jawapan Markah
5. (a) To allow the movement of ions and complete the circuit
1
Untuk membenarkan pengaliran ion-ion dan melengkapkan litar

(b) (i) Fe2+  Fe3+ + e 1

(ii) Green colour of solution turns brown

1
Warna hijau larutan berubah ke perang

(iii) Add sodium hydroxide solution.

1
Tambah larutan natrium hidroksida

Brown precipitate formed.

1
Mendakan perang terbentuk

(c) (i) Correct formula of reactants and products

Formula bahan dan hasil yang betul 1

Balance equation
Persamaan seimbang 1

Cr2O72- + 14H+ + 6e → 2Cr3+ + 7H2O

(ii) Orange colour of solution turns green.

1
Warna jingga larutan bertukar hijau.

(iii) 2x + 7(-2) = -2
1
x = +6

(iv) Bromine water//Chlorine water// acidified potassium manganate(VII)

solution 1
Air bromin//air klorin//larutan kalium manganat(VII) berasid

(d) From carbon electrode X to carbon electrode Y through connecting wire

1
Dari elektrod karbon X ke elektrod karbon Y melalui wayar penyambung

TOTAL / JUMLAH 11
 Question Answer Marks
Soalan Jawapan Markah
6. (a) Heat released when one mole of silver is displaced from silver nitrate
solution by copper 1
Haba yang dibebaskan apabila satu mol argentum disesarkan daripada
larutan argentum nitrat oleh kuprum.

(b) Correct formula of reactants and products

1
Formula bahan dan hasil yang betul

Balance equation
1
Persamaan seimbang

Cu + 2Ag+ → Cu2+ + 2Ag

(c) (i) 50 X 4.2 X 6 // 1260 J 1

(ii) (1.0 )(50) // 0.05 mol

1
1000
1
(iii) - 1260 J mol-1 // 25200 J mol-1 // - 25.2 kJ mol-1
0.05
1
(d) 1. Energy axis correct and two energy level
1
2. Correct name/formula of reactants and products
1
3. Label ΔH with value and unit

Energy
Tenaga

Cu + 2AgNO3

ΔH = -25.2 k J mol-1

Cu(NO3)2 + 2Ag

(e) (i) Heat of displacement of silver by zinc is more than -25.2 k J mol-1
1
Haba penyesaran argentum oleh zink lebih daripada -25.2 kJ mol-1

(ii) Zinc is more electropositive than copper

1
Zink lebih elektropositif berbanding kuprum

TOTAL / JUMLAH 11
 Section B
Bahagian B

Question Answer Marks

Soalan Jawapan Markah

Compound Hydrocarbon A Hydrocarbon B

Sebatian Hidrokarbon A Hidrokarbon B
7 (a) (i) Number of carbon atom 3 3
Bilangan atom karbon
Same number of carbon atoms
Bilangan atom karbon adalah sama 1

Number of hydrogen atom 6 8

Bilangan atom hidrogen 1
Number of hydrogen atoms in hydrocarbon
B is higher
Bilangan atom hidrogen dalam
hidrokarbon B lebih tinggi
1
Type of covalent bond Double bond// Single bond//
between carbon atom// Unsaturated Saturated
Type of hydrocarbon
Jenis ikatan kovalen Ikatan ganda dua// Ikatan tunggal//
antara atom karbon// Tak tepu Tepu
Jenis hidrokarbon 1

Homologous series// Alkene// Alkane//

IUPAC name Propene Propane
Siri homolog// Alkena// Alkana// 1
Nama IUPAC propena propana

General formula/Formula CnH2n// CnH2n+2//

am// n=2,3,4… n=1,2,3… Max 4
Molecular formula/ C3H6 C3H8
Formula Molekul

(ii) C3H6 + 9/2 O2 → 3 CO2 + 3 H2O

Correct formula of reactants and products 1

Formula bahan dan hasil yang betul

Balance equation 1
Persamaan seimbang

Number of mole of C3H6 = 8.4 // 0.2 mol 1

Bilangan mol C3H6 42
 From chemical equation/ Daripada persamaan kimia
1 mol of C3H6 produces 3 mol of CO2/
1
1 mol C3H6 menghasilkan 3 mol of CO2

0.2 mol of C3H6 produces 0.6 mol of CO2

1
0.2 mol of C3H6 menghasilkan 0.6 mol CO2

Volume of CO2 = 0.6 X 24 dm3 // 14.4 dm3

1
Isipadu CO2

Reaction I - Esterification 1
(b)
Tindak balas I – Pengesteran

Homologous series of compound C- Ester

1
Siri Homolog sebatian C

Structural Formula of compound C

1
Formula struktur sebatian C

H H O H H H

H C C C O C C C H

H H H H H

IUPAC Name of compound C – propyl propanoate

1
Nama IUPAC sebatian C - propil propanoat

Chemical equation for Reaction I:

Persamaan kimia Tindak balas I

C2H5COOH + C3H7OH → C2H5COO C3H7 + H2O

Correct formula of reactants and products

1
Formula bahan dan hasil yang betul

Balance equation
1
Persamaan seimbang
(c)
Set I
Methanoic acid contains hydrogen
ion.
Asid metanoik mengandungi ion
hidrogen
Hydrogen ion neutralise the
negative charges at protein
membrane
Ion hidrogen meneutralkan cas
negatif pada membran protein
Rubber particles collide with each
other causes the protein membrane
breaks
Polimer getah berlanggar antara
satu sama lain menyebabkan
membran protein pecah.
Rubber polymers combine together
and coagulate
Polimer getah bergabung dan
menggumpal.
Set II
Ammonia solution contains
1
hydroxide ion.
Larutan ammonia mengandungi
ion hidroksida
Hydroxide ion neutralise the 1
hydrogen ion in lactic acid that
produced by activities of bacteria
Ion hidroksida meneutralkan
ion hidrogen dalam asid laktik
yang terhasil daripada aktiviti
bakteria.
Rubber particles repel each other 1
prevents protein membrane break
Polimer getah menolak antara satu
sama lain menghalang membran
protein pecah.
Rubber polymers cannot combine 1
and coagulate
Polimer getah tidak dapat
bergabung dan menggumpal
TOTAL / JUMLAH 20
 Question Answer Marks
Soalan Jawapan Markah
8 (a) Gas X : oxygen/oksigen 1
Gas Y : hydrogen/ hidrogen 1

(b) Electrode Cathode Anode

Elektrod Katod Anod

Ions attracted to 1+1

H+ NO3- , OH-
Ion tertarik ke

ions selectively
discharged 1+1
H+ OH-
ion yang terpilih
untuk dinyahcas
-
Reason Position of OH- ion is lower
penjelasan than NO3- ion in the 1
electrochemical series.
Kedudukan ion OH- lebih
rendah daripada ion NO3-
dalam siri elektrokimia.

(c) (i) Example of solution Z :

Sodium nitrate solution// sodium sulphate solution// potassium nitrate 1
solution// potassium sulphate solution//
Any suitable answer

Contoh larutan Z :
Larutan natrium nitrat// larutan natrium sulfat//Larutan kalium nitrat//
larutan kalium sulfat//
Sebarang jawapan yang sesuai

(ii) Half equation at cathode/ Persamaan setengah di katod :

2H+ + 2e → H2
Correct chemical formula of reactants and product
Formula kimia bagi bahan dan hasil tindak balas yang betul 1

Balanced chemical equation

Persamaan kimia seimbang 1
(d) (i) Positive terminal : Copper 1
Terminal positif : Kuprum

Negative terminal : Zinc 1

Terminal negatif : Zink
(ii) Half equation / Persamaan setengah:
Correct chemical formula of reactants and product
Formula kimia bagi bahan dan hasil tindak balas yang betul

Balanced chemical equation

Persamaan kimia seimbang

Positive terminal : 2H+ + 2e → H2 1+1

Terminal positif

Negative terminal : Zn → Zn2+ + 2e 1+1

Terminal negatif

(e) (i) P, Q, R, Cu 1

(ii) Negative terminal/ Terminal negatif : R 1

Voltage value / Nilai voltan = 0.6V 1

R is more electropositive than Cu // R is above Cu in Electrochemical 1

Series
R lebih elektropositif berbanding Cu // R di atas Cu dalam Siri
Elektrokimia

TOTAL / JUMLAH 20
 Section C
Bahagian C

Question Answer Marks

Soalan Jawapan Markah
9 (a) (i) Correct chemical formula of reactants and product
Formula kimia bagi bahan dan hasil tindak balas yang betul 1
PbCO3 → PbO + CO2

(ii) Residue is brown when hot turns yellow when cold 1

Baki berwarna perang apabila panas dan bertukar kuning bila sejuk

(b) Confirmatory test for zinc ion, Zn2+

Ujian pengesahan ion zink, Zn2+

1. Salt Y is added into a test tube that contain distilled water to dissolve it. 1
The salt solution is poured into 3 three difference test tubes.
Garam Y ditambah ke dalam tabung uji yang mengandungi air suling
untuk melarutkannya. Larutan garam tersebut dituang ke dalam tiga
tabung uji yangberbeza.

2. Sodium hydroxide solution is added into the first test tube until in excess 1
Larutan natrium hidroksida di tambah sehingga berlebihan ke dalam
tabung uji yang pertama

3. White precipitate formed dissolves in excess sodium hydroxide solution 1

zinc ion , lead(II) ion dan aluminium ion may be present in salt Y.
Mendakan putih yang larut dalam larutan natrium hidroksida
berlebihan terbentuk.. Ion zink, ion plumbum(II) dan ion aluminium
mungkin hadir dalam garam Y.

4. Ammonia solution is added to the second test tube until in excess 1

Larutan ammonia di tambah sehingga berlebihan ke dalam tabung uji
yang kedua.

5. White precipitate dissolves confirms the presence of ion zinc in salt Y. 1

Mendakan putih yang larut dalam larutan natrium hidroksida
berlebihan terbentuk.. Ion zink disahkan hadir dalam garam Y.

Confirmatory test for nitrate ion, NO3-

Ujian pengesahan ion nitrat , NO3-

1. 2cm3 of dilute sulphuric acid is added to the third test tube 1

2cm3asid sulfurik cair ditambah ke tabung uji yang ketiga.

2. 2cm3 iron (II) sulphate solution is added into the test tube 1
2cm3 larutan ferum(II) sulfat ditambah ke tabung uji tersebut
 3. A few drops of concentrated sulphuric acid is added slowly 1
Beberapa titis asid sulfurik pekat ditambah secara perlahan-lahan
1
-
4. Brown ring formed shows the presence of nitrate,NO3 ion
Cincin perang terbentuk menunjukkan kehadiran ion nitrat,NO3-
Max 8
(c) Procedure /Prosedur:

1. 20 cm3 of 1.0 mol dm-3 lead(II) nitrate solution is measured and pour 1
into a beaker.
20 cm3 larutan plumbum(II) nitrat 1.0 mol dm-3 disukat dan dituang ke
dalam sebuah bikar.

2. 20 cm3 of 1.0 mol dm-3 potassium chromate(VI) solution is measured 1

20 cm3 larutan kalium kromat(VI) 1.0 mol dm-3disukat

3. Potassium chromate(VI) solution is added into the beaker containing 1

lead(II) nitrate solution.
Larutan kalium kromat(VI) ditambah ke dalam bikar yang mengandungi
larutan plumbum(II) nitrat.

4. The mixture is stirred with a glass rod. 1

Campuran itu dikacau dengan rod kaca

5. Filter the mixture to get the yellow precipitate. 1

Turaskan campuran itu untuk mendapatkan mendakan kuning.

6. Rinse the precipitate with distilled water. 1

Bilas mendakan itu dengan air suling

7. Dry by pressing between filter papers. 1

Keringkan dengan menekan antara kertas turas.

Observation/ Pemerhatian :
Yellow precipitate is formed 1
Mendakan kuning terbentuk

Chemical equation /Persamaan kimia :

Pb(NO3)2 + K2CrO4 → Pb CrO4 + 2KNO3

Correct chemical formula of reactants and product 1

Formula kimia bagi bahan dan hasil tindak balas yang betul

Balanced chemical equation 1

Persamaan kimia seimbang

TOTAL / JUMLAH 20
 Question Answer Marks
Soalan Jawapan Markah
10 (a) The smaller the size of potatoes, the larger the total surface area exposed. 1
Semakin kecil saiz kentang, semakin besar jumlah luas permukaan

Smaller size of potatoes can absorbs heat faster than bigger size of potatoes 1
Kentang bersaiz kecil lebih cepat menyerap haba berbanding kentang
bersaiz besar.

(b) (i) Volume of H2 gas, cm3

Isi padu gas H2, cm3

II

Labelled axes with correct unit 1

Paksi berlabel dan berunit yang betul

Correct curves with label 1

Lengkung yang betul dan berlabel

Same maximum volume 1

Isipadu maksimum sama

(ii) 1.Rate of reaction in Experiment II is higher than I 1

Kadar tindak balas eksperimen II lebih tinggi daripada eksperimen I.

2.The temperature of reaction in Experiment II is higher than Experiment I 1

Suhu bahan tindak balas dalam eksperimen II lebih tinggi daripada
eksperimen I.

3.The particle of reactant in Experiment II absorbs heat and gains more 1

kinetic energy /that causes they moves faster
Zarah-zarah bahan tindak balas dalam eksperimen II menyerap haba
dan memperoleh lebih tenaga kinetik/menyebabkan zarah-zarah
bergerak lebih laju.

4.Frequency of collision between zinc atom and H+ ion in Experiment II is 1

higher than Experiment I
Frekuensi perlanggaran di antara atom zink dan ion H+ dalam
eksperimen II lebih tinggi daripada eksperimen I.
 5.Frequency of effective collision between zinc atom and H+ ion in 1
Experiment II is higher than Experiment I
Frekuensi perlanggaran berkesan di antara atom zink dan ion H+ dalam
eksperimen II lebih tinggi daripada eksperimen I.

(c) Materials:
Sodium thiosulphate solution 0.2 moldm-3, sulphuric acid 1.0 moldm-3, a
piece of white paper marked ‘X’ at the centre.
Bahan :
Larutan natrium tiosulfat 0.2 moldm-3, asid sulfurik 1.0 moldm-3, sekeping
kertas putih bertanda ‘X’di bahagian tengah

Apparatus:
150 cm3 conical flask, stopwatch, 50 cm3 measuring cylinder, 10 cm3 1
measuring cylinder.
Kelalang kon 150 cm3, jam randik, silinder penyukat 50 cm3, silinder
penyukat 10 cm3.

Procedure/ Prosedur :

1. Measure and pour 50 cm3 of 0.2 mol dm-3 sodium thiosulphate solution 1
into a conical flask.
Sukat dan tuang 50 cm3 larutan natrium tiosulfat 0.2 mol dm-3 ke
kelalang kon.

2. The conical flask is placed on top of a piece of white paper marked ‘X’ 1
at the centre.
Kelalang kon tersebut diletakkan di atas sekeping kertas putih bertanda
‘X’di bahagian tengah

3. 5 cm3 of 1.0 mol dm-3 sulphuric acid is measured using another 1

measuring cylinder.
5 cm3 asid sulfurik 1.0 moldm-3 disukat dengan menggunakan silinder
penyukat yang lain.

4. The sulphuric acid is poured immediately and carefully into the conical 1
flask. At the same time, the stop watch is started
Asid sulfurik dituang dengan cepat dan cermat. Pada masa yang sama
jam randik dimulakan.

5. The mixture in a conical flask is swirled. 1

Campuran dalam kelalang kon digoncang

6. The ‘X’ mark is observed vertically from the top of the conical flask 1
through the solution.
Tanda ‘X’ diperhatikan secara menegak dari bahagian atas kelalang
Kon menerusi larutan.

7. The stopwatch is stopped once the ‘X’ mark disappears from view. 1
Jam randik diberhentikan sebaik tanda ‘X’hilang dari penglihatan
8. Step 1 – 7 are repeated using 50 cm3 of sodium thiosulphate solution 1
with different concentration.
Langkah 1-7 diulang dengan menggunakan 50 cm3 larutan natrium
tiosulfat dengan kepekatan yang berbeza.

Conclusion/ Kesimpulan :
The higher the concentration of sodium thiosulphate solution, the higher, 1
the rate of reaction.
Semakin tinggi kepekatan larutan natrium tiosulfat , semakin tinggi kadar
tindak balas.

TOTAL / JUMLAH 20

END OF ANSWER PAPER

JAWAPAN TAMAT
 2

Proton number He
Helium
10 4
Symbol
3 4 Ne 5 6 7 8 9 10
Li Be Neon B C N O F Ne
Lithium Beryllium 20 Name of element Boron Carbon Nitrogen Oxygen Fluorine Neon
7 9 11 12 14 16 19 20
11 12 Relative atomic mass 13 14 15 16 17 18
Na Mg Al Si P S Cl Ar
Sodium Magnesium Aluminium Silicon Phosphorus Sulphur Chlorine Argon
23 24 27 28 31 32 35 40
32
19 20 21 22 23 24 25 26 27 28 29 30 31 33 34 35 36
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
Germa-
Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Arsenic Selenium Bromine Krypton
nium
39 40 45 48 51 52 55 56 59 59 64 65 70 75 79 80 84
73
42
37 38 39 40 41 43 44 45 46 47 48 49 50 51 52 53 54
Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
Molyb-
Rubidium Strontium Yttrium Zirconium Niobium Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
denum 101
86 88 89 91 93 98 103 106 108 112 115 119 122 128 127 131
96
55 56 57 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86
Cs Ba La Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
Caesium Barium Lanthanum Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury Thallium Lead Bismuth Polonium Astatine Radon
133 137 139 179 181 184 186 190 192 195 197 201 204 207 209 210 210 222
104 105 106 107 108 109
87 88 89
Fr Ra Ac Unq Unp Unh Uns Uno Une
Unnil Unnil Unnil- Unni- Unni- Unni-
Francium Radium Actinium
quadium pentium hexium lseptium loctium lennium
223 226 227
257 260 263 262 265 266

64
58 59 60 61 62 63 65 66 67 68 69 70 71
Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
Praseo
Gadoliniu
Cerium dymium Neodymium Promethium Samarium Europium Terbium Dyprosium Holmium Erbium Thulium Ytterbium Lutetium
144 m
140 141 147 150 152 167 163 165 167 169 173 175
157
98 101 103
90 91 92 93 94 95 96 97 99 100 102
Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr
Califor- Mendele- Lawren-
Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Einsteinium Fermium Nobelium
nium vium cium
232 231 238 237 244 243 247 247 254 253 254
249 256 257