Ketidakpastian Pengujian

I. Ketidakpastian intra-reprodusibilitas (u R)
Menghitung dari data duplikat hasil uji sampel.

Sample X1 X2 `X d r(%)
1 47.1 44.3 45.7 2.8 6.127
2 64.5 68.5 66.5 -4.0 6.015
3 58.0 56.0 57.0 2.0 3.509
4 50.0 55.3 52.65 -5.3 10.066
5 45.7 47.1 46.4 -1.4 3.017
6 24.6 25.5 25.05 -0.9 3.593
7 23.6 25.5 24.55 -1.9 7.739
8 28.8 30.4 29.6 -1.6 5.405
9 57.5 58.8 58.15 -1.3 2.236
10 166 170 168 -4.0 2.381
11 41.7 44.3 43 -2.6 6.047
12 41.7 43.3 42.5 -1.6 3.765
13 52.9 50 51.45 2.9 5.637
14 76.00 72.0 74.0 4.0 5.405
15 50.6 56.5 53.55 -5.9 11.018
16 77.0 86.0 81.5 -9.0 11.043
17 81.9 79.4 80.65 2.5 3.100
18 136 148 142 -12 8.451
19 63.6 69.1 66.35 -5.5 8.289
20 392 390 391 2.0 0.512
21 766.7 870 818.35 -103.3 12.623
22 840 905 872.5 -65 7.450
23 219 231 225 -12 5.333
24 304 334 319 -30 9.404
25 576.7 583.3 580 -6.6 1.138
26 208 198 203 10.0 4.926
27 87.1 87.9 87.5 -0.8 0.914
28 179 196.7 187.85 -17.7 9.422
29 102 94.0 98.0 8.0 8.163
30 168 160 164 8.0 4.878

rata-rata = 5.920
uR (%) = 5.25

II. Ketidakpastian baku asal (ubias)

Menghitung dari data pengujian 1 CRM
 a. Menghitung uC-ref dari 1 CRM
Nilai CRM = 51.5 + 0.9991 mg/L dgn faktor coverag

u(Cref) = 0.50974 mg/L

u(Cref) = 0.99 % 0.98

b. Menghitung Bias dari 1 CRM.

Nilai CRM = 51.5 + 0.9991 mg/L dgn faktor coverag
`X analisis Lab terhadap CRM = 46.6 mg/L, s = 3.30 mg/L, diperoleh dari

bias = -4.863 mg/L

bias = -9.44 % 89.15

c. Menghitung standar deviasi bias

sbias = 3.30 mg/L
sbias = 6.41 %
n= 8
Ön = 2.83

sbias/Ön = 2.27 % 5.13

95.26
uBias (%)= 9.8

Ketidakpastian gabungan

uc(y) = 11.08 %

Ketidakpastian diperluas

U= 22.16 %
 Tanggal
20221102
20221102
20221018
20221018
20221005
20221005
20221005
20221005
20220823
20220815
20220801
20220801
20220725
20220712
20220703
20220703
20220703
20220613
20220613
20220613
20220628
20220628
20220519
20220406
20220323
20220323
20220302
20220128
20220204
20220202
dgn faktor coverage k = 1.96

Data S251-5152
47.1
dgn faktor coverage k = 1.96 44.3
8 kali ulangan 45.7
41.7
44.3
52.9
50.0
47.1
rata2 46.6
sd 3.30