ISOTHERMAL REACTOR DESIGN:

CONVERSION
Struktur desain reaktor isothermal

1. General mol balance

2. Rate law

3. Stoikiometry

4. Kombinasi

5. Evaluasi
REAKTOR BATCH
 Desain equation for batch reactor
 Di sebagian besar reaktor batch, semakin lama reaktan tinggal di dalam reaktor, semakin banyak
reaktan yang terkonversi menjadi produk (batasnya adalah kesetimbangan atau re-aktan terbatas)
 Konversi di reaktor batch adalah fungsi waktu

Mol balance:
 Tidak ada variasi spasial laju reaksi

Untuk komponen A (reaktan)

Diferensiasi persamaan 2-4 terhadap waktu

Kombinasi dengan persamaan 2-5

Design eq for batch reactor

 Design eq for batch reactor

Design eq for batch reactor

Ingat bahwa

Waktu bergantung kepada

reaction rate constant dan
konsentrasi
CONTOH 2 𝐴→ 𝐵+𝐶 Batch reaction times
CONTOH 2 𝐴→ 𝐵+𝐶 Batch reaction times
Determining k (reaction rate constant) from batch data
1. General mol balance 2. Rate law

4. Kombinasi

3. Stoikiometry
5. Evaluasi

Kondisi batas, pada t=0, CA0=1 mol/dm3

 Excell solver
CA0 = 1 mol/dm3 TRIAL k1 0.309272
CB0 = 55.5 mol/dm3
‫ܣ‬൅‫ܤ‬՜ ‫ܥ‬
CC0 = 0 mol/dm3
dt = 0.1 menit validasi

t CA CC dCA/dt dCC/dt A sisa t CC CC CALC SSE

0 1 0 -0.309272071 0.3092721 100 0 0 0 0
0.1 0.969073 0.030927 -0.299707149 0.2997071 96.90727929 0.5 0.145 0.1453624 1.31E-07
0.2 0.939102 0.060898 -0.290438044 0.290438 93.9102078 1 0.27 0.2695945 1.64E-07
0.3 0.910058 0.089942 -0.281455607 0.2814556 91.00582735 1.5 0.376 0.375768 5.38E-08
0.4 0.881913 0.118087 -0.272750971 0.272751 88.19127128 2 0.467 0.4665079 2.42E-07
0.5 0.854638 0.145362 -0.264315545 0.2643155 85.46376157 3 0.61 0.6103344 1.12E-07
0.6 0.828206 0.171794 -0.256141004 0.256141 82.82060612 4 0.715 0.7153861 1.49E-07
0.7 0.802592 0.197408 -0.248219278 0.2482193 80.25919608 6 0.848 0.8481608 2.58E-08
0.8 0.77777 0.22223 -0.240542549 0.2405425 77.77700331 10 0.957 0.9567844 4.65E-08
0.9 0.753716 0.246284 -0.23310324 0.2331032 75.37157782 SSE TOTAL 9.25E-07
1 0.730405 0.269595 -0.225894007 0.225894 73.04054542
1.1 0.707816 0.292184 -0.218907737 0.2189077 70.78160535
1.2 0.685925 0.314075 -0.212137532 0.2121375 68.59252798
1.3 0.664712 0.335288 -0.20557671 0.2055767 66.47115267
 Contoh
CA0 = 0.03 TRIAL k1 = 0.118139
CB0 = 0.05
CC0 = 0 ‫ܣ‬൅‫ ܤ‬՜ ‫ܥ‬൅ ‫ܦ‬
CD0 = 0
dt = 0.5 menit
validasi
t CA CB CC CD dCA/dt dCB/dt dCC/dt dCD/dt A sisa (%) XA(calc) (%) t XA (exp)(%)Xa (calc) SSE
0 0.03 0.05 0 0 -0.00018 -0.00018 0.000177208 0.0001772 100 0 0 0 0 0
0.5 0.029911 0.049911 8.86042E-05 8.86042E-05 -0.00018 -0.00018 0.000176372 0.0001764 99.70465276 0.295347 25 11.3 13.23019 3.725635
1 0.029823 0.049823 0.00017679 0.00017679 -0.00018 -0.00018 0.000175541 0.0001755 99.41069965 0.5893 50 17.9 23.908852 36.1063
1.5 0.029735 0.049735 0.000264561 0.000264561 -0.00017 -0.00017 0.000174716 0.0001747 99.11813103 0.881869 75 21.8 32.695459 118.711
2 0.029648 0.049648 0.000351919 0.000351919 -0.00017 -0.00017 0.000173897 0.0001739 98.82693733 1.173063 100 33.1 40.040324 48.1681
2.5 0.029561 0.049561 0.000438867 0.000438867 -0.00017 -0.00017 0.000173083 0.0001731 98.53710907 1.462891 125 37.12 46.261454 83.56619
3 0.029475 0.049475 0.000525409 0.000525409 -0.00017 -0.00017 0.000172275 0.0001723 98.24863688 1.751363 150 41.2 51.589836 107.9487
3.5 0.029388 0.049388 0.000611547 0.000611547 -0.00017 -0.00017 0.000171473 0.0001715 97.96151145 2.038489 175 53.4 56.19731 7.824941
4 0.029303 0.049303 0.000697283 0.000697283 -0.00017 -0.00017 0.000170676 0.0001707 97.67572356 2.324276 200 69.9 60.214367 93.81149
4.5 0.029217 0.049217 0.000782621 0.000782621 -0.00017 -0.00017 0.000169884 0.0001699 97.39126409 2.608736 225 74.3 63.741893 111.4736
5 0.029132 0.049132 0.000867563 0.000867563 -0.00017 -0.00017 0.000169098 0.0001691 97.10812397 2.891876 250 78.1 66.859114 126.3575
5.5 0.029048 0.049048 0.000952112 0.000952112 -0.00017 -0.00017 0.000168317 0.0001683 96.82629426 3.173706 275 80.3 69.629123 113.8676
6 0.028964 0.048964 0.00103627 0.00103627 -0.00017 -0.00017 0.000167541 0.0001675 96.54576605 3.454234 SSE TOTAL 851.5612
6.5 0.02888 0.04888 0.001120041 0.001120041 -0.00017 -0.00017 0.000166771 0.0001668 96.26653054 3.733469
7 0.028797 0.048797 0.001203426 0.001203426 -0.00017 -0.00017 0.000166006 0.000166 95.98857901 4.011421 0 0
7.5 0.028714 0.048714 0.001286429 0.001286429 -0.00017 -0.00017 0.000165246 0.0001652 95.71190281 4.288097 50 50
8 0.028631 0.048631 0.001369052 0.001369052 -0.00016 -0.00016 0.000164491 0.0001645 95.43649337 4.563507 100 100
8.5 0.028549 0.048549 0.001451297 0.001451297 -0.00016 -0.00016 0.000163741 0.0001637 95.16234218 4.837658
9 0.028467 0.048467 0.001533168 0.001533168 -0.00016 -0.00016 0.000162996 0.000163 94.88944084 5.110559
9.5 0.028385 0.048385 0.001614666 0.001614666 -0.00016 -0.00016 0.000162256 0.0001623 94.61778101 5.382219
CSTR
Thank you