TUGAS

PERANCANGAN REAKTOR

Disusun oleh:
Elisabeth Natalia P.

(121130334)

Ihsan Firdianto

(121130359)

PROGRAM STUDI TEKNIK KIMIA S1

JURUSAN TEKNIK KIMIA
FAKULTAS TEKNIK INDUSTRI
UNIVERSITAS PEMBANGUNAN NASIONAL VETERAN
YOGYAKARTA
2017

Tugas

: Mereaksikan asam fasetat (C3COOH) 1000kg/jam dengan butanol (C4H90H)

1500 kg/jam menjadi butil asetat (CH3COOC4H10)

Alat

: Reaktor Alir Tangki Berpengaduk (RATB) Seri 2, dengan volume standart atau

V1=V2
Kondisi operasi :
Suhu
= 100C (Kirk Othmer 1979 vol 8 hal 319)
Tekanan = 1 atm
Data Kinetika :
K1
Kc = K 2 = 4,2 (Mc Ketta, hal 640)
Dimana K1 = 17,4 x 10-3 lt/gmol mnt (Smith)
K2 = 4,14 x 10-3 lt/gmol mnt
Xa = 0,9 Xe
Persamaan reaksi kimia :
K1
C3COOH + C4H90H

CH3COOC4H10 + H2O
K2

Reaksi Elementer:
(-r)

= K1.CA.CB - K2.CC.CD

BUAT GAMBAR REAKTORNYA DISINI!

Kompone

M (kg/j)

(kg/ltr)

1000

1,0492

953,1071

1500

0,810

1851,831

50,65

0,882

57,4263

330,08

330,08

H2SO4

1,8852

1,8357

1,0269

qi (ltr/jam)

Jumlah

3193,4914

FAo

1000 kg / jam
60,02 kg /kgmol

= 16,66 kgmol/jam

FBo

1500 kg / jam
74,12 kg /kgmol

= 20,2374 kgmol/jam

CAo

F Ao
qo

16,66 kgmol/ jam

3193,4914 ltr / jam

CBo

F Bo
qo

20,2374 kgmol/ jam

3193,4914 ltr / jam

Pada saat kesetimbangan

CAe = CAo.(1-xe)
CBe = CBo.- CAo xe
CCe = CCo.+ CAo xe
CDe = CDo.+ CAo xe
C total = CAo + CBo

M =

CB0
CA 0

6,3371 x 103
5,2169 X 103

= 1,2147

= 5,2169 X 10 -3 kgmol/ltr
= 6,3371 X 10 -3 kgmol/ltr

Kc

K1
K2

Kc

CA 0 XeCA 0 Xe
C Ao . ( 1x e ) C Bo.C Ao xe

4,2

Xe 2
( 1x e ) ( M xe)

4,2

Xe 2
M XeM Xe+ Xe 2

4,2

Cce C De
CAe CBE
=

CA 0 Xe CA 0 Xe
CA 0 ( 1 x e ) CA 0 ( M xe)

Xe 2
(1,21471,2147 Xe Xe+ Xe 2)

5,102 5,102Xe 4,2Xe + 4,2Xe2 = Xe2

5,102 9,302Xe + 4,2Xe2

= Xe2

3,2Xe2 9,302Xe + 5,102

=0

Xe

= 0,734 (Trial and Error)

Xa = 0,9 Xe
= 0,9 (0,734)
= 0,66 (Konversi keluar reaktor)
Tabel Stoikiometri
Komponen

Masuk

Reaksi

Keluar

FAo

-FAo Xa

FA = FAo (1-Xa)

FBo

-FAo Xa

FB = FBo - FAo Xa

FCo

FAo Xa

FC = FAo Xa

FDo

FAo Xa

FD = FAo Xa

Fto

CA

FA
q

Ft = Fto

F A o(1 Xa)
qo

= CAo ( 1- Xa)

CB

FB
q

F B oF A o Xa
qo

CC

FC
q

F A o Xa
qo

= CAo Xa

CD

FD
q

F A o Xa
qo

= CAo Xa

= CBo - CAO ( 1- Xa)

REAKTOR 1
CA1 = CAo.(1- Xa1)
CB1 = CBo.- CAo Xa1
CC1 = CAo Xa1
CD1 = CAo Xa1
(-rA) = K1.CA1.CB1 - K2.CC1.CD1
Neraca mol (steady state)
Rin - Rout + Rgen = Racc
FA0 - FA1 + rA1.V1

=0

FA0 - FA0 (1- Xa1) + rA1 .V1

=0

FA0 Xa1

= - rA1 .V1
V1

F A 0 Xa1
rA 1

V1

F A 0 Xa1
K 1. C A 1. C B 1K 2.C C 1. C D 1

V1

F A 0 Xa1
K 1. C Ao.(1X a 1).(C BoC Ao X a 1)K 2.(C Ao X a 1).(C Ao X a 1)
V1

F A 0 Xa1
( 17. 4 x 103 )( 5,2169 ) ( 1X a 1 ) . 5,2169 ( 1,2147X a 1 )( 4,14 x 103 ) (5,2169 x 5,2169)
V1

F A 0 Xa1
0,474 ( 1X a 1 ) . ( 1,2147X a 1 )0,113 Xa12

V1

F A 0 Xa1
0,5761,05 Xa 1+0,361 Xa12

REAKTOR 2
CA2 = CAo.(1- Xa2)
CB2 = CBo.- CAo Xa2
CC2 = CAo Xa2
CD2 = CAo Xa2
(-rA) = K1.CA2.CB2 - K2.CC2.CD2
Neraca mol (steady state)
Rin - Rout + Rgen = Racc
FA1 - FA2 + rA2.V2

=0

FA0 (1- Xa1) - FA0 (1- Xa2)

= - rA2 .V2

V2

F A 0 Xa2Xa 1
rA 2

V2

F A 0( Xa2 Xa1)
K 1. C A 2. C B 2K 2. C C 2 .C D 2

V2

F A 0( Xa2Xa 1)
K 1. C Ao.(1X a 2).(C BoC Ao X a2)K 2.(C Ao X a 2).(C Ao X a 2)
V2

F A 0( 0,66 Xa1)
( 17. 4 x 103 )( 5,2169 ) ( 10,66 )( 5,2169 ) ( 1,21470,66 )4,14 x 103(5,2169 x 5,2169 x 0,66)
V2

F A 0(0,66Xa 1)
0,0890,049

V2

F A 0(0,66Xa 1)
0,04

F A 0 Xa1
0,5761,05 Xa 1+0,361 Xa12

Dimana V2 = V1
F A 0(0,66Xa 1)
0,04

0,38 0,693 Xa1 + 0,24 Xa12 0,576 Xa1 + 1,05 Xa12 - 0,361 Xa13 = 0,04 Xa1
0,38 1,269 Xa1 + 1,29 Xa12 0,361 Xa13

= 0,04 Xa1

-0,361 Xa13 + 1,29 Xa12 1,309 Xa1+ 0,38

=0
Xa1

Didapat Xa1= 0,51 dan Xa2 = 0,66

V1

F A 0 Xa1
= 0,5761,05 Xa 1+0,361 Xa12

16,66
x 0,51 x 1000
60
0,5761,05 ( 0,51 ) +0,361(0,51)2

= 1053,676 ltr
V = 0,8 VR

= 0,51

VR =

V
0,8

1053,676 ltr
0,8

Volume reaktor total

VR = VR1 + VR2
=

VR1 + VR1

=2

VR1

= 2 (1317,095 ltr)
= 2634,19 ltr

= 1317,095 ltr