Perkampungan Ilmu Ting 4 2017: CheMistrY

ELECTROCHEMISTRY Name : ………………………………………….

Class : ………………………………..………

1. Diagram 1 shows substance W that can conduct electricity. What is W?

Rajah 1 menunjukkan bahan W yang boleh mengkonduksi arus elektrik.
Apakah W?

Diagram / Rajah 1

A Tetrachloromethane / Tetraklorometana

B Molten napthalene / Leburan naftalena

C Solid sodium chloride / Pepejal natrium klorida

D Aqueous sodium chloride solution / Larutan akueus natrium klorida

2. Diagram 2 shows the set up of the apparatus used to electroplate an iron key with
nickel by electrolysis
Rajah 2 menunjukkan susunan radas yang digunakan untuk menyadur kunci besi
dengan nikel melalui proses elektrolisis.

Diagram/ Rajah 2

Which of the following is true in this experiment?

Antara pernyataan berikut yang manakah benar tentang eksperimen itu?

A Nickel foil becomes thicker

Kepingan nikel semakin tebal

B Grey solid deposited at the iron key

Pepejal kelabu terenap pada kunci besi

C Gas bubble releases around iron key

Gelembung gas terbebas di sekeliling kunci besi

D Brown solid deposited at the iron key

Pepejal perang terenap pada kunci besi
Perkampungan Ilmu Ting 4 2017: CheMistrY
ELECTROCHEMISTRY

3. What are the ions present in molten sodium chloride and sodium chloride aqueous solution?
Apakah ion-ion yang wujud dalam leburan natrium klorida dan larutan akues natrium klorida?

Molten sodium chloride Sodium chloride aqueous solution

Leburan natrium klorida Larutan akues natrium klorida
A Na + , H+ , Cl− , OH− Na + , H+ , Cl−
B Na + , Cl− Cl− , OH−
C Na + , Cl− Na + , H+ , Cl− , OH−
D Na + , OH− Na + , H+ , Cl− , OH−

4. Which of the following voltaic cells produces the lowest voltage?

Antara yang berikut, yang manakah menghasilkan voltan yang paling rendah?

A Lead - copper cell

Sel plumbum - kuprum
B Zinc - copper cell
Sel Zink - kuprum
C Aluminium – lead cell
Sel Aluminium - plumbum
D Magnesium – copper cell
Sel Magnesium - kuprum

5 Which of the following is true about electrolytes?

Antara yang berikut, yang manakah benar tentang elektrolit?

A Compounds that conduct electricity in solid state

Sebatian yang boleh mengkonduksi arus elektrik dalam keadaan pepejal
B Compounds that conduct electricity in molten state or aqueous solution
Sebatian yang boleh mengkonduksi arus elektrik dalam keadaan leburan atau larutan akueus
C Elements that conduct electricity in solid or molten state
Unsur yang boleh mengkonduksi arus elektrik dalam keadaan pepejal dan leburan
D Elements that conduct electricity in molten state
Unsur yang boleh mengkonduksi arus elektrik dalam keadaan leburan

6. What is the gas produce at the anode in electrolysis of copper (II) nitrate solution?
Apakah gas yang terhasil di anod dalam electrolysis larutan kuprum (II) nitrat?

A Oxygen / Oksigen
B Hydrogen / Hidrogen
C Nitrogen / Nitrogen
D Nitrogen dioxide /Nitrogen dioksida
6 Table 6 shows information about three simple voltaic cells.
Jadual 6 menunjukkan maklumat tentang tiga sel voltan ringkas.

Pair of metals Potential difference(V) Positive terminal

Pasangan logam Beza keupayaan(V) Terminal positif
W and X
0.7 X
W dan X
X and Y
2.0 Y
X dan Y
W and Z
1.6 Z
W dan Z
Table /Jadual 6

What is the potential difference of a voltaic cell which uses Y and Z as electrodes?
Berapakah beza keupayaan sel volta yang menggunakan Y and Z sebagai elektrod?

A 0.4 V C 1.1 V
B 0.9 V D 1.3 V

7. Diagram 7 below shows a simple voltaic cell. The reading on the voltmeter is 0.3 V.
Rajah 7 di bawah menunjukkan suatu sel volta ringkas. Bacaan voltmeter ialah 0.3 V.

Diagram / Rajah 7

Which of the following will increase the reading on the voltmeter?

Antara kaedah berikut, yang manakah dapat menambahkan bacaan voltmeter?

I Increase the volume of iron(II) sulphate solution

Tambahkan isi padu larutan ferum(II) sulfat

II Substitute the iron plate with a silver plate

Gantikan kepingan ferum dengan kepingan argentum

III Use a more dilute iron(II) sulphate solution

gunakan larutan ferum(II) sulfat yang lebih cair

IV Substitute the zinc plate with a magnesium plate

Gantikan kepingan zink dengan kepingan magnesium

A I and II only C II and IV only

I dan II sahaja II dan IV sahaja

B I and III only D II, III and IV

I dan III sahaja II, III dan IV
8. Which of the following factors influence the products of electrolysis?
Antara faktor berikut, yang manakah mempengaruhi hasil elektrolisis?

I Position of ions in the Electrochemical Series

Kedudukan ion dalam Siri Elektrokimia

II Concentration of ion in the electrolyte

Kepekatan ion dalam elektrolit

III Type of electrode

Jenis elektrod

IV Volume of the solution

Isipadu larutan

A IV only
IV sahaja
B I and III I
dan III
C II and IV II
dan IV
D I, II and III I, II
dan III

-3
9 Silver nitrate solution of 1.0 mol dm is electrolysed by using silver electrodes. Which of the
following half equations represent the reaction occurred at anode and cathode respectively?
Larutan argentum nitrat 1.0 mol dm-3 dielektroliskan dengan menggunakan elektrod
argentum. Antara persamaan setengah berikut yang manakah mewakili tindak balas yang
berlaku di anod dan katod?

Anode / Anod Cathode / Katod

A Ag → Ag+ + e 2H+ + 2e → H2
B Ag → Ag+ + e Ag+ + e → Ag
C 4OH- → O2 + 2H2O + 4e 2H+ + 2e → H2
D - +
4OH → O2 + 2H2O + 4e Ag + e → Ag

10 Which of the following substance conducts electricity in molten and aqueous state?
Di antara bahan berikut, yang manakah mengkonduksi elektrik dalam keadaan lebur dan
akueus?

A Potassium sulphate /Kalium sulfat

B Naphthalene / Naftalena

C Copper /Kuprum

D Lead(II) Chloride / Plumbum(II) chloride

11 Diagram 11 shows the electrolysis of a concentrated solution Y.
Rajah 11 menunjukkan electrolysis satu larutan pekat, Y.

Diagram / Rajah 11

Which of the following is Y?

Antara berikut, yang manakah Y?
A Sodium nitrate solution
Larutan natrium nitrat
B Copper(II) sulphate solution
Larutan kuprum(II) sulfat
C Silver nitrate solution
Larutan argentum nitrat
D Potassium chloride solution
Larutan kalium klorida

12 When aqueous copper(II) sulphate solution is electrolysed using copper electrodes, the
half equation of the reaction that occurs at the anode is
Apabila larutan kuprum(II) sulfat dilektrolisiskan menggunakan elektrod-elektrod kuprum,
setengah persamaan bagi tindak balas yang berlaku di anod ialah

A 2H+ + 2e- → H2
B 4OH- → O2 + 2H2O + 4e-
C Cu2+ + 2e- → Cu
D Cu → Cu2+ + 2e-

13 Cryolite, Na3AlF6 is used in the extraction process of aluminium in industry.

What is the use of this substance?
Kriolit, Na3AlF6 digunakan dalam proses pengekstrakan aluminium dalam industri.
Apakah kegunaan bahan ini?

A Eliminate impurities
Menyingkirkan bendasing

B Increase the rate of reaction

Meningkatkan kadar tindak balas

C Hamper electrode from being oxidized

Menghalang elektrod daripada dioksidakan

D Lower the melting points of aluminium oxide

Merendahkan takat lebur aluminium oksid
 14 Rajah 14 menunjukkan elektrolisis larutan kuprum(II) nitrat menggunakan elektrod kuprum.
Diagram 14 shows the electrolysis of copper(II) nitrate solution by using copper electrodes.

Elektrod kuprum
Copper electrode
Larutan kuprum(II) nitrat
Copper(II) nitrate solution

Rajah /Diagram 14

Apakah pemerhatian di anod dan katod?

What is the observation at anode and cathode?

Anod /Anode Katod /Cathode

A Saiz bertambah Semakin menipis
Increase in size Become thinner
B Semakin menipis Saiz bertambah
Become thinner Increase in size
C Gelembung gas terbebas Gelembung gas terbebas
Gas bubbles released Gas bubbles released
D Gas bubbles released Become thinner
Gelembung gas terbebas Semakin menipis

15. Jadual 15 menunjukkan maklumat tentang tiga sel kimia.

Table 15 shows information about three chemical cells.

Sel kimia Terminal negatif Terminal positif Voltan (V)

Chemical cell Negative terminal Positive terminal Voltage (V)
I X Y 3.0
II Z Y 1.2
III X Z 1.8
Jadual /Table 15

Antara yang berikut, yang manakah susunan secara menaik bagi logam-logam ini dalam Siri
Elektrokimia?
Which of the following is the arrangement in ascending order of these metals in the
Electrochemical Series?

A X, Y, Z
B X, Z, Y
C Y, Z, X
D Z, X, Y
16 Diagram 16 shows a simple cell made up of magnesium plate and copper plate as electrodes and
copper(II) sulphate solution as the electrolyte.
Rajah 16 menunjukkan sebuah sel ringkas terdiri daripada kepingan magnesium dan kepingan
kuprum sebagai elektrod dan larutan kuprum(II) sulfat sebagai elektrolit.

Magnesium

Diagram 16

Rajah
Which of the following statements is true for the 2 reaction ?
above
Yang manakah pernyataan berikut adalah benar bagi tindak balas di atas ?

A The blue colour of the copper(II) sulphate solution remains unchanged

Warna biru larutan kuprum(II) sulfat tidak berubah

B Copper electrode is the positive terminal

Elektrod kuprum adalah terminal positif
C Magnesium electrode becomes larger in size
Saiz elektrod magnesium bertambah besar
D Colourless gas bubbles are produced at the copper electrode
Gelembung gas tanpa warna terhasil di elektrod kuprum

17 Diagram 17 shows a chemical cell.

Rajah 17 menunjukkan satu sel kimia.

Diagram/ Rajah 17

What is the chemical reaction that takes place at the negative terminal of the chemical cell?
Apakah persamaan tindak balas yang berlaku di terminal negatif sel kimia itu?

A Zn → Zn2+ + 2e-
B Cu2+ + 2e- → Cu
C Zn + Cu2+ → Zn2+ + Cu
D Zn2+ + Cu → Zn + Cu2+
18 Lead(II) bromide is not able to conduct electricity in solid state but can conduct electricity in
molten state because
Plumbum(II) bromida tidak boleh mengalirkan arus elektrik dalam keadaan pepejal tetapi boleh
mengalirkan arus elektrik dalam keadaan lebur kerana

A bromide ions and lead(II) ions are able to move freely in the molten state
ion bromida dan ion plumbum(II) bebas bergerak dalam keadaan lebur

B the molecules in lead (II) bromide are able to move freely in the molten state
molekul plumbum(II) bromida bebas bergerak dalam keadaan lebur

C bromine and lead atoms are free to move

atom bromin dan plumbum bebas bergerak

D the bromide and lead(II) ions are held strongly together in the molten state
ion bromida dan ion plumbum(II) terikat kuat dalam keadaan leburan

19 Table 15 shows the voltage produced by different type of cells. Based on this table , the cell that
can produce 2.00 V can be set up using
Jadual 15 menunjukkan bacaan voltan beberapa jenis sel. Berpandukan jadual ini, sel yang boleh
membekalkan 2.00V boleh dibina dengan menggunakan

Voltage / V
Cell / Sel
Voltan / V
Magnesium // Copper 2.70
Magnesium // kuprum
Zinc // Copper 1.15
Zink // kuprum
Lead // Copper 0.45
Plumbum // Kuprum
Iron // Copper 0.70
Ferum // Kuprum

Table / Jadual 15

A Magnesium // zinc
Magnesium // zink

B Iron // lead
Ferum // plumbum

C Magnesium // iron
Magnesium // ferum

D Magnesium // lead
Magnesium // Plumbum
20 Table 20 shows the result of an experiment to construct the electrochemical series by
displacement of metals from their salt solutions by a more elektropositive metal.
Jadual 20 menunjukkan keputusan bagi suatu eksperimen untuk membina Siri Elektrokimia
melalui tindak balas penyesaran logam daripada larutan garamnya oleh logam yang lebih
elektropositif.

Solution
Larutan
P(NO3)2 Q(NO3)2 R(NO3)2
Metal
Logam
√ √
P

√
Q X

R X X

√ - displacement reaction occurs X - no displacement reaction

penyesaran berlaku penyesaran tidak berlaku

Table / Jadual 18

Which of the following metals could be X, Y and Z ?

Yang manakah antara logam-logam berikut mungkin X,Y dan Z ?

P Q R

A Mg Ag Sn

B Mg Zn Cu

C Ag Sn Mg

D Zn Cu Mg
 Copper plate
Terminal : _____________
Reason : Magnesium plate
_______________________________ Terminal : _____________
_______________________________
Salt bridge State observation for magnesium
_______________________________ State the function:
Half equation : plate:
________________________
_______________________________ ________________________ ____________________________
________________________ ___
________________________

State the colour change of copper(II) sulphate: Magnesium nitrate solution

________________________________________________________________ State cation presents:

_____________________
Explain your answer :
_______________________________________________________________
_______________________________________________________________
_______________________________________________________________
_____________________