Kondisi Awal Umpan

Parameter Pengukuran
Volume Ethanol (ml) 260.5 ml A
Volume Aquades (ml) 239.5 ml etanol 8.2133
Massa Etanol teknis (gr) 207.5 ml aquades 8.14
Massa Aquades (gr) 237 ml
Massa Total feed (gr) 444.5 ml
Fraksi feed 0.5
Suhu Umpan 28.0
Densitas 0.91

Kurva Kalibrasi
Konsentrasi (y) Densitas (x) (dimunculkan persamaannya)
10% 0.98 x pada pers. Untuk densitas
20% 0.97 hasilnya adalah fraksi (Xd)
30% 0.96
40% 0.94
50% 0.91
60% 0.91
70% 0.88
80% 0.86
90% 0.83
96% 0.81

Distilasi Batch Tanpa Refluks (Distilat)

waktu suhu destilat Volume Destilat Massa Destilat Densitas
10 menit 86 32 30.48 0.89
20 menit 86 40 32.6 0.88
30 menit 86 30 27.77 0.88
40 menit 86 32 25.31 0.89
50 menit 86 29 23.86 0.91
60 menit 86 18 15.23 0.8
70 menit 86 19 18.06 0.82
173.31

Kondisi Akhir Distilasi

Massa Labu Bulat Kosong Massa labu Bulat Suhu Suhu Koreksi Fraksi Distilat (Xd)
335.7 830.7 86 90.042 0.0928065714
Perhitungan Komposisi Distilat dan Bottom menggunakan persamaan Rayleigh
Massa (g) Xf Mr Feed (g/mol)Mol
Lo (massa awal) 444.5 13.890625

0.5 32
 D (Destilat) 173.31 5.4159375
L (akhir) 271.19 8.4746875
0.5 32
% umpan jadi D 0.3898987627
% umpan jadi L 0.6101012373
Total 1

Perhitungan Komposisi Distilat dan Bottom menggunakan Persamaan Rayleigh

T(.C) Pe (Etanol) Pa (Aquades) alfa x
221.1371801386 95.9 70.1551580041 1.3669700522 0.5
225.2066345807 99.0703731919 72.5594719462 1.3653678911 0.46
229.2760890227 102.2867735695 75.0027536747 1.3637735757 0.42
233.3455434648 105.5485334102 77.4845857686 1.3621874901 0.38
237.4149979068 108.8549780721 80.0045416329 1.3606099835 0.34
241.4844523489 112.2054268725 82.5621861901 1.3590413729 0.3
245.5539067909 115.5991939267 85.1570765474 1.3574819453 0.26
249.623361233 119.0355889491 87.7887626405 1.3559319595 0.22
253.692815675 122.5139180167 90.4567878546 1.3543916485 0.18
257.7622701171 126.0334842962 93.1606896226 1.3528612208 0.14
Rata-rata 1.359861714
T.akhir 261.8317245591 t.akhir
T.Rata 4.0694544421 t.rata

Kurva Kesetimbangan Garis Ideal

x y x y
1 1 0 0
0.880412 0.9095181646 0.1 0.1 1.2

0.765915 0.8169238532 0.2 0.2 1

0.656195 0.7222147049 0.3 0.3 0.8
0.550961 0.6253891697 0.4 0.4
0.6
0.449945 0.5264464792 0.5 0.5
0.352897 0.4253866181 0.6 0.6 0.4

0.259586 0.3222102968 0.7 0.7 0.2

0.169797 0.2169189243 0.8 0.8 0
0.083331 0.1095145824 0.9 0.9 0

1 1
 Mr Ethanol = 46
B C Mr Aquades =18
1652.05 231.48 Koefisien Antoine (A,B,C) Carl L. Yaws
1810.94 244.485 Ethanol 8 1,652 231
Aquadest

Kurva Kalibrasi
120%

100%
f(x) = 0.0978181818x + 0.008
R² = 0.9986750763
80%

60%

40%

20%

0%
0 2 4 6 8 10 12

X Destilat
0.095042
0.094064
0.094064
0.095042
0.096998
0.08624
0.088196
0.0928065714

Reyligh Percobaan
Xd
Xb

Fraksi Bottom (Xb)

0.1

(Lo/L) ln(Lo/L)

1.6390722372 0.49413
 1.6390722372 0.49413

y y-x 1/(y-x) A Aakumulasi

0.577518947 0.077519 12.90007 0 0
0.0185176347 -0.44148 -2.2651 0.21269952 0.2126995178 Xb
0.4968705792 0.076871 13.00888 0.21487564 0.4275751586 Xd
0.0172175622 -0.36278 -2.75647 0.2050481 0.632623262
0.4120829746 0.072083 13.8729 0.22232857 0.8549518298
0.0160083993 -0.28399 -3.52123 0.20703341 1.06198524
0.3229304375 0.06293 15.89056 0.24738662 1.309371856
0.0148458267 -0.20515 -4.87438 0.22032358 1.5296954314
0.2291715309 0.049172 20.33697 0.30925176 1.8389471934
0.0136234935 -0.12638 -7.91286 0.24848216 2.0874293512

0.1
0.04

KURVA KESETIMBANGAN
1.2

0.8 kurva Kes etimbanga m

ga ri s i deal
0.6

0.4

0.2

0
0 0.2 0.4 0.6 0.8 1 1.2
Interpolasi