V formalin 600 massa NH3 25.

7731
massa formalin 244.2 V NH3 (ml) 28.541639
mol formalin 8.1319 massa na2co3 1.2887
F/U 2 massa na2so3 31.5
mol urea 4.0659 volume h2so4 13.7
massa urea 244.2 t reaksi (menit) 12

DATA PERCOBAAN
Waktu Viskositas (s) Volume Titrasi pH
Sampel Suhu (oC)
1 2 rata-rata 1 2 rata-rata Sebelum
0 11.15 11.13 11.14 26 1.2 1.2 1.2 10
1 12.19 12.21 12.2 24 1.1 1.1 1.1 9
2 12.28 6:14 12.27 64 1.1 1 1.05 9
3 13.13 13.11 13.12 77 1.1 1 1.05 9
4 13.47 13.49 13.48 85 1 1 1 9
5 14.63 14.65 14.64 85 1 0.9 0.95 8
6 14.84 14.82 14.83 85 1 0.9 0.95 8
7 14.01 13.99 14 85 1 0.9 0.95 8
8 15.59 15.57 15.58 83 1 0.8 0.9 8
9 15.41 15.43 15.42 84 1 0.8 0.9 8
10 15.25 15.27 15.26 85 0.9 0.8 0.85 8

ANALISA DENSITAS SAMPEL

Massa
massa densitas
Sampel Piknometer + V pikno massa pikno kosong t pengambilan sampl
sample sample
Sampel (gr)
0 50.3 25.564649 22.17 28.13 1.1003 12
1 50.87 25.56 22.17 28.7 1.1226 24
2 50.75 25.56 22.17 28.58 1.1180 36
3 50.98 25.56 22.17 28.81 1.1269 48
4 50.94 25.56 22.17 28.77 1.1254 60
5 50.99 25.56 22.17 28.82 1.1273 72
6 50.76 25.56 22.17 28.59 1.1183 84
7 50.5 25.56 22.17 28.33 1.1082 96
8 51.13 25.56 22.17 28.96 1.1328 108
9 51.16 25.56 22.17 28.99 1.1340 120
10 51.97 25.56 22.17 29.8 1.1657 132

ANALISA VISKOSITAS SAMPLE

air sample
sample
densi (g/cm3) t visko (s) visko air densi sample t visko (s)
0 0.99708 6.27 0.0008937 1.1003 11.14
1 0.99708 6.27 0.0008937 1.1226 12.2
2 0.99708 6.27 0.0008937 1.1180 12.27
3 0.99708 6.27 0.0008937 1.1269 13.12
4 0.99708 6.27 0.0008937 1.1254 13.48
5 0.99708 6.27 0.0008937 1.1273 14.64
6 0.99708 6.27 0.0008937 1.1183 14.83
7 0.99708 6.27 0.0008937 1.1082 14
8 0.99708 6.27 0.0008937 1.1328 15.58
 9 0.99708 6.27 0.0008937 1.1340 15.42
10 0.99708 6.27 0.0008937 1.1657 15.26

ANALISA TITRASI SAMPLE

V titrasi (mL) N titran V sample
sample Mr Form
1 2 rata2 (mL) (H2SO4) (mL) g/ml
0 1.2 1.2 1.2 0.5 30.03 100 0.9009
1 1.1 1.1 1.1 0.5 30.03 100 0.825825
2 1.1 1 1.05 0.5 30.03 100 0.7882875
3 1.1 1 1.05 0.5 30.03 100 0.7882875
4 1 1 1 0.5 30.03 100 0.75075
5 1 0.9 0.95 0.5 30.03 100 0.7132125
6 1 0.9 0.95 0.5 30.03 100 0.7132125
7 1 0.9 0.95 0.5 30.03 100 0.7132125
8 1 0.8 0.9 0.5 30.03 100 0.675675
9 1 0.8 0.9 0.5 30.03 100 0.675675
10 0.9 0.9 0.9 0.5 30.03 100 0.675675

GRAVIMETRI/ANALISA KADAR RESIN

G G sample G sample
sample Kadar resin (%)
1 2 3 4 basah kering
0 53.14 60.66 57.11 54.9 7.52 1.76 23.40%
1 54.08 59.86 58.25 56.05 5.78 1.97 34.08%
2 50.35 55.96 54.58 52.24 5.61 1.89 33.69%
3 53.06 58.34 56.74 54.84 5.28 1.78 33.71%
4 50.24 55.48 54.22 52.13 5.24 1.89 36.07%
5 41.79 47.05 46.03 43.81 5.26 2.02 38.40%
6 39.8 45.66 44.15 41.86 5.86 2.06 35.15%
7 41.96 47.03 45.05 43.6 5.07 1.64 32.35%
8 41.42 46.96 45.39 43.46 5.54 2.04 36.82%
9 55.42 60.79 59.39 57.36 5.37 1.94 36.13%
10 39.95 45.05 44.01 41.68 5.1 1.73 33.92%
G total 61.63 20.72 33.98%

Nsp/Cr

sample Nsp Cr (g/mL) Nsp/Cr

Nsp/Cr
2
0 0.9607288845 0.2575 3.73057795 1.8 f(x) = 0.083583653959315 x + 0.987339916667676
1 1.1908081663 0.3826 3.11215594 1.6 R² = 0.896336817115194
1.4
2 1.1941656452 0.3766 3.170613
1.2
3 1.36504668 0.3799 3.59300644
Nsp/Cr

1
4 1.4265675065 0.4059 3.51448569 0.8
5 1.6399620078 0.4329 3.78803529 0.6
6 1.6528819821 0.3931 4.20434084 0.4
0.2
7 1.4816311616 0.3585 4.13330516
0
8 1.8231154226 0.4171 4.37053935 0.2575 0.3826 0.3766 0.3799 0.4059 0.4329 0.3931 0.358
9 1.7970176878 0.4097 4.38648373
Cr (g/ml)
 0.4
0.2
0
0.2575 0.3826 0.3766 0.3799 0.4059 0.4329 0.3931 0.358

Cr (g/ml)
10 1.8453351003 0.3954 4.66683968

t sample pengambilan asumsi orde 0 asumsi orde 1 asumsi orde 2

sample
(menit) Cf (mol/mL) ln Cf 1/Cf
0 12 54.054 3.98998354689736 0.0185000185000185
1 24 45.420375 3.8159607929181 0.0220165509421708
2 36 41.38509375 3.72292076164831 0.0241632894694119
3 48 41.38509375 3.72292076164831 0.0241632894694119
4 60 37.5375 3.62534043330945 0.0266400266400266
5 72 33.87759375 3.52275384453435 0.0295180350582013
6 84 33.87759375 3.52275384453435 0.0295180350582013
7 96 33.87759375 3.52275384453435 0.0295180350582013
8 108 30.405375 3.4146194019938 0.0328889217778107
9 120 30.405375 3.4146194019938 0.0328889217778107
10 132 30.405375 3.4146194019938 0.0328889217778107

t sample pengambilan asumsi orde 1

sample Cf (mol/mL)
(mnt) ln(Cf0/Cf) (a) k1 (a/menit)
0 12 54.054 0 0
1 24 45.420375 0.174022753979259 0.0072509480824691
2 36 41.3850938 0.267062785249045 0.0074184107013624
3 48 41.3850938 0.267062785249045 0.0055638080260218
4 60 37.5375 0.364643113587909 0.0060773852264652
5 72 33.8775938 0.46722970236301 0.0064893014217085
6 84 33.8775938 0.46722970236301 0.0055622583614644
7 96 33.8775938 0.46722970236301 0.0048669760662814
8 108 30.405375 0.575364144903562 0.0053274457861441
9 120 30.405375 0.575364144903562 0.0047947012075297
10 132 30.405375 0.575364144903562 0.0043588192795724

ln K1 terhadap 1/T
0 0
0.0027 0.0028 0.0029 0.003 0.0031 0.0032 0.0033 0.0034 0.0035 0.0027 0.0028
-1
-1
-2
-2 -3
-4
ln K1

ln K2

-3 f(x) = 4826.61371871319 x − 18.7895804046086 -5 f(x) =

R² = 0.467341170766749 -6
-4 R² = 0
-7
-5 -8
-9
-6 -10
1/T

ENERGI AKTIVASI
 Persamaan Ea/R R (J/mol.K) Ea (J/mol) Ea (kJ/mol)
y = 4826,6x - 18,79 4826.6 8.314 40128.3524 40.1283524
y = 7893,4x - 31,171 7893.4 8.314 65625.7276 65.6257276
 pikno kosong 22.17 V pikno 25.56
pikno+air 47.66 densi formalin 1.1
visko air (s) 6.27 densi nh3 0.903
viskositas air 0.8937 mr urea 60.06
massa air 25.49 mr. formaldehid 30.03
densitas air 0.99708 mr nh3 17

pH
Sesudah
9
8
8
8
8
7
7
7
7
7
7

t pengambilan sample Analisa Densitas Sampel

1.1800
12
24 1.1600
36
Densitas (g/cm3)

1.1400
48
60 1.1200
72 1.1000
84
96 1.0800
108 1.0600
120 12 24 36 48 60 72 84 9
132 t (menit)

E
ample t pengambilan sample
visko (g/cm.s) (menit) Analisa Viskositas Sampel
0.0018 12
0.0027
0.0020 24
0.0020 36 0.0025
Viskositas (g/cm.s)

0.0021 48 0.0023
0.0022 60
0.0021
0.0024 72
0.0024 84 0.0019
0.0022 96 0.0017
0.0025 108
0.0015
12 24 36 48 60 72 84 9

t (menit)
 Viskosit
0.0019

0.0017

0.0015
0.0025 120 12 24 36 48 60 72 84 9
0.0025 132
t (menit)

t pengmbilan sample
Cf (mol/L)
% (menit) Kadar Formalin Bebas
90.09 54.054 12 95
82.5825 45.420375 24 90
78.82875 41.385094 36 85

Kadar CH2O (%)

78.82875 41.385094 48 80
75.075 37.5375 60 75
71.32125 33.877594 72 70
71.32125 33.877594 84 65
71.32125 33.877594 96 60
55
67.5675 30.405375 108
50
67.5675 30.405375 120 12 24 36 48 60 72 84 96
67.5675 30.405375 132
t (menit)

t pengambilan sample
Cr (g/mL)
(menit) Kadar Resin terhadap Waktu
0.2575281623999 12 23.4 45
0.3826312653989 24 34.08 40
0.3766355733925 36 33.69 35
Kadar Resin (%)

0.379917682692 48 33.71 30
0.4059107457497 60 36.07 25
20
0.4329320833489 72 38.4
15
0.3931370090392 84 35.15
10
0.3584615949171 96 32.35 5
0.4171373999006 108 36.82 0
0.4096715727276 120 36.13 12 24 36 48 60 72 84 96

0.3954142902638 132 33.92 t (menit)

Nsp/Cr intercept 0.9873

K a Mr
15 x + 0.987339916667676 Rentang 6000-20000 0.0002 0.8 41510.85154
4 Rentang 9000-17000 0.0003 0.5 10970000
Rentang 7000-70000 0.0014 0.6 56351.10166

Mr 41510.852
derajat polimerisasi 460.77091

9 0.4059 0.4329 0.3931 0.3585 0.4171 0.4097 0.3954

Cr (g/ml)
9 0.4059 0.4329 0.3931 0.3585 0.4171 0.4097 0.3954

Cr (g/ml)

60
asumsi orde 2
1/Cf 50
0.0185000185000185 f(x) = − 2.09015625 x + 50.05284375
0.0220165509421708 40 R² = 0.862272059943172

Cf (mol/ml)
0.0241632894694119
30
0.0241632894694119
0.0266400266400266
20
0.0295180350582013
0.0295180350582013 10
0.0295180350582013
0.0328889217778107 0
12 24 36 48 60 72 84 96 108 120 132
0.0328889217778107
0.0328889217778107 t (menit)

asumsi orde 2
T (K) 1/T LN K1
1/Cf (1/Cf)-(1/Cf0) k2 (l/mol.mnt)
0.0185000185 0 0 299 0.0033445 0
0.022016550942 0.0035165324421523 0.0001465221850897 297 0.003367 -4.926623049
0.024163289469 0.0056632709693934 0.0001573130824832 337 0.0029674 -4.903790436
0.024163289469 0.0056632709693934 0.0001179848118624 350 0.0028571 -5.191472508
0.02664002664 0.0081400081400081 0.0001356668023335 358 0.0027933 -5.103180737
0.029518035058 0.0110180165581828 0.0001530280077525 358 0.0027933 -5.037600393
0.029518035058 0.0110180165581828 0.0001311668637879 358 0.0027933 -5.191751073
0.029518035058 0.0110180165581828 0.0001147710058144 358 0.0027933 -5.325282466
0.032888921778 0.0143889032777922 0.0001332305859055 356 0.002809 -5.23488337
0.032888921778 0.0143889032777922 0.0001199075273149 357 0.0028011 -5.340243886
0.032888921778 0.0143889032777922 0.0001090068430136 358 0.0027933 -5.435554066

ln K2 terhadap 1/T
0
0.0027
-1 0.0028 0.0029 0.003 0.0031 0.0032 0.0033 0.0034 0.0035
-2
-3
-4
ln K2

-5 f(x) = 7893.37195001136 x − 31.1713818963835

-6 R² = 0.42177452998981
-7
-8
-9
-10

1/T
 mr na2co3 106
mr na2so3 126

Analisa Densitas Sampel

36 48 60 72 84 96 108 120 132

t (menit)

Analisa Viskositas Sampel

36 48 60 72 84 96 108 120 132

t (menit)
 36 48 60 72 84 96 108 120 132

t (menit)

Kadar Formalin Bebas

36 48 60 72 84 96 108 120 132

t (menit)

Kadar Resin terhadap Waktu

36 48 60 72 84 96 108 120 132

t (menit)

BIKIN KURVA SAJA SOALNYA YANG DI SIMPEN

HANYA DI UNTUK
DATA YANG
BIKINSEBENARNYA
KURVA SAJA SOALNYA
EROR TERUS
YANG
PADAHAL
DI SIMPEN
ANGKANYA
DI DATASAM
YA
asumsi orde 1 asumsi orde 2
t ln Cf 1/Cf
12 3.9899835 0.0185
24 3.8159608 0.0220166
36 3.7229208 0.0241633
48 3.7229208 0.0241633
60 3.6253404 0.02664
72 3.5227538 0.029518
84 3.5227538 0.029518
96 3.5227538 0.029518
108 3.4146194 0.0328889
120 3.4146194 0.0328889
 132 3.3003026 0.0328889

4.2

3.8 f(x) = − 0.0589235902598282 x + 3.95126237867952

R² = 0.940729348381563

ln Cf
3.6

3.4

3.2

3
6 108 120 132 12 24 36 48 60 72 84 96 108 120 132

t (menit)

LN K2

0
-8.828334
-8.757273
-9.044955
-8.905309
-8.78489
-8.93904
-9.072572
-8.923429
-9.02879
-9.1241
ANG DI SIMPEN DI DATA YANG SEBENARNYA EROR TERUS PADAHAL ANGKANYA SAMA
 0.035
f(x) = 0.00141089451138609 x + 0.0190531825252358
0.03 R² = 0.938129454025148

7952 0.025

0.02
1/Cf
0.015

0.01

0.005

0
96 108 120 132 12 24 36 48 60 72 84 96 108 120 132

t (menit)
 Massa Pikno Kosong 22.17 gram
Massa Pikno + Air 47.66 gram
t viskositas air 6.27 detik
Waktu larut urea 8.25 menit
waktu refluks 15.05 menit
massa air 25.49 gram

Waktu Viskositas (s)

Massa Piknometer Suhu
Sampel
+ Sampel (gr) (oC)
1 2 rata-rata
0 50.3 11.15 11.13 11.14 26
1 50.87 12.19 12.21 12.2 24
2 50.75 12.28 12:26 6.40 64
3 50.98 13.13 13.11 13.12 77
4 50.94 13.47 13.49 13.48 85
5 50.99 14.63 14.65 14.64 85
6 50.76 14.84 14.82 14.83 85
7 50.5 14.01 13.99 14 85
8 51.13 15.59 15.57 15.58 83
9 51.16 15.41 15.43 15.42 84
10 51.97 15.25 15.27 15.26 85

analisis densitas
Densitas Air (25 ˚C) 0.99708 g/cm3
Volume Piknometer 25.5646

Sampel waktu massa Sampel Densitas

0 12 28.13 1.1003 1.1800
1 24 28.7 1.1226
1.1600
Densitas Sampel (g/ml)

2 36 28.58 1.1180
3 48 28.81 1.1269 1.1400
4 60 28.77 1.1254 1.1200
5 72 28.82 1.1273
6 84 28.59 1.1183 1.1000

7 96 28.33 1.1082 1.0800

8 108 28.96 1.1328
1.0600
9 120 28.99 1.1340 0 20
10 132 29.8 1.1657

analisis viskositas
Viskositas Air (25 ˚C) 0.008937 kg/ms
Sampel t viskos sampel (s) Densitas Viskositas Nsp (Viskos Intrinsik)
0 11.14 1.1003 0.01752 0.9607
1 12.2 1.1226 0.01958 1.1908
2 6.40 1.1180 0.01023 0.1443
3 13.12 1.1269 0.02114 1.3650
4 13.48 1.1254 0.02169 1.4266
5 14.64 1.1273 0.02359 1.6400
6 14.83 1.1183 0.02371 1.6529
7 14 1.1082 0.02218 1.4816
8 15.58 1.1328 0.02523 1.8231
9 15.42 1.1340 0.02500 1.7970
10 15.26 1.1657 0.02543 1.8453
 Berat Cawan + Sampel (Gr)
Cawan
Volume Titrasi pH Sampel Kosong Sampel Sampel Kering
(gr) [G1] Basah
[G2] 15 Menit 60 Menit
1 2 rata-rata Sebelum Sesudah
[G3] [G4]
1.2 1.2 1.2 10 9 0 53.14 58.08 57.11 54.9
1.1 1.1 1.1 9 8 1 54.08 59.86 58.25 56.05
1.1 1 1.05 9 8 2 50.35 55.96 54.58 52.24
1.1 1 1.05 9 8 3 53.06 58.34 56.74 54.84
1 1 1 9 8 4 50.24 55.48 54.22 52.13
1 0.9 0.95 8 7 5 41.79 47.05 46.03 43.81
1 0.9 0.95 8 7 6 39.8 45.66 44.15 41.86
1 0.9 0.95 8 7 7 40.96 47.03 45.05 41.25
1 0.8 0.9 8 7 8 41.42 46.96 45.39 43.46
1 0.8 0.9 8 7 9 55.42 60.79 59.39 57.36
0.9 0.8 0.85 8 7 10 39.95 45.05 44.01 41.68

analisis densitas

Chart Title
1.1800

1.1600
Densitas Sampel (g/ml)

1.1400

1.1200

1.1000

1.0800

1.0600
0 20 40 60 80 100 120 140
Waktu (s)

analisis viskositas

Chart Title
0,000

0,000
 Chart Title
0,000

0,000

0,000

0,000

0,000

0,000

0,000
0 20 40 60 80 100 120 140
+ Sampel (Gr)

1.76
1.97
1.89
1.78
1.89
2.02
2.06
0.29
2.04
1.94
1.73