Data Keadaan Ruang

Hari ke-1 Hari ke-2

Parameter
Awal Akhir Awal Akhir
Suhu (⁰C) 26.7 27.5 27 26.2
Tekanan (mBar) 959 958 960 959

Kalibrasi Termometer
Percobaan Literatur
Jenis Termometer
Tb (˚C) Td (˚C) Tb (˚C) Td (˚C)
Termometer Alkohol 200 ⁰C 2 96 0 98.5
Termometer Raksa 200 ⁰C 0 98 0 98.5

Kalibrasi Piknometer
Massa Massa
Massa
Piknomet Piknomet
Piknomet
Massa Piknometer kosong (g) er + er + mA (g) mM (g) mA (kg) mM (kg)
er kosong
Aquadest Metanol
(g)
(g) (g)
11.4182 21.7002 11.9455 19.0656 10.2820 7.1201 0.0103 0.0071

Kalibrasi Refraktometer
Indeks Bias Interpolasi Indeks bi
Nama Zat Rata-rata Literatur
1 2 3 Suhu
Aquadest 1.330 1.330 1.330 1.330 1.332 34.50
Benzene 1.488 1.485 1.483 1.486 1.492 35.00
54.34

Penentuan Indeks Bias Campuran dengan Fraksi mol Methanol

Massa
Massa Massa Botol
Botol Botol Kosong + Massa Massa
Botol Cuplikan Kosong Aquades+ nA (mol) nm (mol)
Kosong
+Aquades Metanol Aquadest Metanol
(gr)
(gr) (gr)
1 13.2736 18.1483 18.1483 4.8747 0.0000 0.2708 0.0000
2 13.5007 17.8667 18.1070 4.3660 0.2403 0.2426 0.0075
3 13.2311 17.1045 17.6680 3.8734 0.5635 0.2152 0.0176
4 13.4163 16.7425 17.8090 3.3262 1.0665 0.1848 0.0333
5 13.0742 15.8681 17.4184 2.7939 1.5503 0.1552 0.0484
6 13.2465 15.5066 17.3910 2.2601 1.8844 0.1256 0.0589
7 13.3563 15.0650 17.3361 1.7087 2.2711 0.0949 0.0710
8 12.7827 13.9796 16.6420 1.1969 2.6624 0.0665 0.0832
9 13.3365 14.1159 17.0515 0.7794 2.9356 0.0433 0.0917
10 13.7819 14.2131 17.5412 0.4312 3.3281 0.0240 0.1040
11 13.7052 13.7052 17.4179 0.0000 3.7127 0.0000 0.1160
 K u r v a K a l i b r a si T er m o m et er A l k o h o l 200⁰C
120

100
f(x) = 1.02559652928417 x
R² = 0.999566160520607

T literatur (ºC)
80

60

40

20

0
0 20 40 60 80 100 120
T percobaan (ºC)

ρA (g/ml) ρM (g/ml) V (ml)

KALIBRASI REFRAKT
0.9970 0.6904 10.3129 1.550

1.500
f(x) = 1.00285830519799 x
Interpolasi Indeks bias 1.450 R² = 0.999997978829022
benzene aquadest
Axis Title
1.400
1.4922 1.3318
1.4919 1.3317 1.350
1.4791 1.3287
1.300

1.250
1.320 1.340 1.360 1.380 1.400 1.42
𝜂
xm Rata-rata Koreksi Axis Title
1 2 3
0.0000 1.332 1.331 1.331 1.331 1.333
0.0300 1.333 1.333 1.332 1.332 1.334
0.0756 1.335 1.333 1.335 1.334 1.336 KURVA INDEX BIAS TER
0.1528 1.337 1.337 1.338 1.337 1.339
0.2379 1.339 1.338 1.339 1.339 1.340 1.345
0.3193 1.339 1.339 1.339 1.339 1.341
0.4278 1.338 1.338 1.338 1.338 1.340
0.5558 1.335 1.336 1.336 1.336 1.337 1.340
0.6793 1.333 1.333 1.333 1.333 1.335
0.8128 1.330 1.330 1.330 1.330 1.332
1.0000 1.326 1.327 1.326 1.326 1.328 1.335
INDEX BIAS

1.330

1.325
INDEX BIA
1.330

1.325

1.320
0.0000 0.2000 0.4000

FR
o l 200⁰C Kur va Kal i br as i Te r mome t e r A i r R aks a
200⁰C
120

100
f(x) = 1.00510204081633 x
T literatur (ºC)
80 R² = 1

60

40

20

0
100 120 0 20 40 60 80 100 120
T percobaan (ºC)

ALIBRASI REFRAKTOMETER

) = 1.00285830519799 x
= 0.999997978829022

40 1.360 1.380 1.400 1.420 1.440 1.460 1.480 1.500

Axis Title

KURVA INDEX BIAS TERHADAP FRAKSI METANOL

0.2000 0.4000 0.6000 0.8000 1.0000 1.2000

FRAKSI METANOL
Penentuan Indeks Bias Metanol Teknis
Indeks bias
Zat
1 2
Metanol teknis 1.329 1.328
Umpan 1.339 1.339

Kondisi Awal Umpan

Parameter Pengukuran
Volume Metanol (ml) 383
Volume Aquadest (ml) 206
Massa metanol teknis (gram) 282
Massa aquadest (gram) 208
Massa umpan (gram) 470
Fraksi umpan 0.4
Suhu Umpan (⁰C) 34
Suhu Umpan Terkoreksi (⁰C) 34.884

Distilasi Batch Refluks Parsial (Distilat) Suhu

Distilat
Waktu (menit) Suhu Distilat (⁰C)
koreksi(⁰
10 62 C)
63.61
20 62 63.61
30 62 63.61
40 62 63.61
50 62 63.61
60 63 64.64
70 63 64.64
80 63 64.64
90 63 64.64

Distilasi Batch Refluks Parsial (Bottom) Suhu

Bottom
Waktu (menit) Suhu Bottom (⁰C)
Koreksi(
10 74 ⁰C)
75.92
20 74 75.92
30 74 75.92
40 74 75.92
50 74 75.92
60 74 75.92
70 74 75.92
80 74 75.92
90 74 75.92

Penentuan Jumlah Tetesan

 Tetesan Jumlah Tetesan Waktu (s)
Distilat 11 0.1
Refluks 14 0.1

Pengamatan Kondisi Akhir Distilasi

Massa Labu Bulat +

Massa Labu Bulat Kosong (gram)
Bottom (gram) Suhu (⁰C)

394 627 74

Pengukuran Tinggi Kolom Vigreux

Pengukuran Tinggi (cm)
Kolom Vigreux 162

Perhitungan Komposisi Distilat dan Bottom menggunakan Persamaan Rayleigh

Massa (g) xF
Lo 470.0000
D 8.6325 0.40
L 233.0000
% umpan jadi D 1.84%
% umpan jadi L 49.57%
Total 51.41%

Perhitungan Komposisi Distilat dan Bottom menggunakan Persamaan Rayleigh

T (˚C) PM˚ P A˚
63.31 95.9000 23.2644
66.82 110.0792 27.2118
70.34 125.9601 31.7125
73.85 143.6969 36.8271
77.37 163.4527 42.6205
80.88 185.3998 49.1627
84.40 209.7193 56.5284
87.91 236.6019 64.7974
91.43 266.2472 74.0546
94.95 298.8644 84.3903
98.46 334.6718 95.9000
Rata-rata

Penentuan Jumlah Tahap

 Kurva Kesetimbangan
X Y
1.0000 1.0000
0.8289 0.9514
0.6811 0.8945
0.5528 0.8283
0.4409 0.7515
0.3431 0.6632
0.2570 0.5620
0.1810 0.4466
0.1137 0.3156
0.0537 0.1672
0.0000 0.0000

1.2

0.8

0.6
Y

0.4

0.2

0
0
Indeks bias
3 Rata-rata Koreksi
1.328 1.328 1.330
1.337 1.338 1.340

Massa
Massa Labu Kosong Labu + Massa 𝜂
(g) Distilat Distilat (g) 1 2 3 rata-rata koreksi
60.5231 (g)
81.8558 21.3327 1.336 1.337 1.336 1.336 1.338
74.8472 87.5022 12.655 1.336 1.335 1.336 1.336 1.337
54.5007 72.664 18.1633 1.334 1.334 1.334 1.334 1.336
63.9692 78.336 14.3668 1.334 1.334 1.334 1.334 1.336
60.5231 75.8863 15.3632 1.330 1.331 1.330 1.330 1.332
74.8472 89.6652 14.818 1.330 1.331 1.331 1.331 1.332
54.5007 64.7639 10.2632 1.331 1.331 1.329 1.330 1.332
63.9692 73.4922 9.523 1.329 1.328 1.328 1.328 1.330
61 69.1556 9 1.329 1.329 1.329 1.329 1.331
Jumlah 125.1177 Rata-rata
Massa
Massa Botol Kosong Botol + Massa 𝜂
(g) Bottom Bottom (g) 1 2 3 rata-rata koreksi
13.0484 (g)
14.3112 1.2628 1.338 1.339 1.338 1.338 1.340
12.0443 13.3825 1.3382 1.338 1.337 1.337 1.337 1.339
13.4131 13.3825 -0.0306 1.337 1.339 1.339 1.338 1.340
13.0484 13.9217 0.8733 1.337 1.337 1.337 1.337 1.339
12.0443 14.9627 2.9184 1.337 1.338 1.338 1.338 1.339
13.4131 13.4136 0.0005 1.337 1.336 1.336 1.336 1.338
13.0484 14.0116 0.9632 1.338 1.338 1.338 1.338 1.340
12.0443 13.0318 0.9875 1.337 1.336 1.336 1.336 1.338
13.4131 13.9127 0.500 1.336 1.336 1.336 1.336 1.338
Jumlah 8.8129 akhir
Waktu (s)

Suhu Koreksi (⁰C) 𝜂 rata-rata koreksi Fraksi

Bottom

1 2 3 rata-rata koreksi
75.92 1.335 1.336 1.336 1.336 1.337 0.34

an Persamaan Rayleigh
MrF (g/mol) Mol (Lo/L) ln(Lo/L)
19.9153 Mr Methanol 32
23.6 0.3658 2.0172 0.7017 Mr Aquadest 18
9.8729
mol hilang 9.6766 2.0172
fraksi mol hilang 0.4859 0.4957
massa yang hilang 228.3675 0.5043

an Persamaan Rayleigh
α x y y-x 1 /(y-x) A AAkumulasi
4.1222 0.4000 0.7162 0.3162 3.1628
4.0453 0.3940 0.7111 0.3171 3.1540 0.0190 0.0190
3.9719 0.3880 0.7059 0.3179 3.1461 0.0189 0.0379
3.9019 0.3820 0.7006 0.3186 3.1391 0.0189 0.0567
3.8351 0.3760 0.6952 0.3192 3.1329 0.0188 0.0755
3.7711 0.3700 0.6897 0.3197 3.1277 0.0188 0.0943
3.7100 0.3640 0.6842 0.3202 3.1233 0.0188 0.1131
3.6514 0.3580 0.6785 0.3205 3.1199 0.0187 0.1318
3.5953 0.3520 0.6728 0.3208 3.1174 0.0187 0.1505
3.5415 0.3460 0.6669 0.3209 3.1158 0.0187 0.1692
3.4898 0.3400 0.6610 0.3210 3.1152 0.0187 0.1879
3.7850
 Garis Ideal
X Y R 1.2727
0 0 Intercept 0.3183
0.1 0.1 tahap 1
0.2 0.2
0.3 0.3
0.4 0.4
0.5 0.5
0.6 0.6
0.7 0.7
0.8 0.8
0.9 0.9
1 1

KURVA KESETIMBANGAN METANOL-AIR

1.2

0.8

0.6
Y

0.4

0.2

0
0 0.2 0.4 0.6 0.8

x
 Fraksi Distilat
0.41
0.41
0.57
0.69
0.81
0.89
0.85
0.94
0.94
0.723333333333

Fraksi Bottom

0.34

0.3400
g/mol Recovery
g/mol Lo(mol) L(mol) L/Lo 1-L/Lo XD XB
19.9153 9.8729 0.4957 0.5043 0.940 0.3400

P (mbar) 959 Nilai Tetapan A B C

P (kPa) 95.9 Metanol 16.5785 3638.27 239.5000
H2O 16.3872 3885.70 230.1700

Interpolasi Reyligh Percobaan

0.0000 0.7017 0.0190 Xb 0.1778 0.3400
0.4000 0.1778 0.3940 Xd 1.692177 0.7233
AN METANOL-AIR

6 0.8 1 1.2
% Recovery
1.8367%

T 3.51554
x 0.006