53800632589
Reaksi 1
Cr2O3 + 4KOH
M Massa M
awal 0.839 127.525 3.356
reaksi 0.296 44.918 1.182
setimbang 0.543 82.607 2.174
Reaksi 2
2Fe2O3.Cr2O3 + 8KOH
M Massa M
awal 0.409 127.525 1.635
reaksi 0.096 29.894 0.383
setimbang 0.313 97.631 1.252
Reaksi 3
2MgO.Cr2O3 + 8KOH
M Massa M
awal 0.664 127.525 2.657
reaksi 0.038 7.322 0.153
setimbang 0.626 120.203 2.504
Reaksi 4
Al2O3 + 2KOH
M Massa M
awal 1.250 127.525 2.500
reaksi 1.250 127.525 2.500
setimbang 0.000 0.000
Reaksi 5
SiO2 + 2KOH
M Massa M
awal 2.125 127.525 4.251
reaksi 2.125 127.525 4.251
setimbang 0.000 0.000
→ 2KAlO2 + H2O
Massa M Massa M Massa
140.028
140.028 2.500 245.049 1.250 22.504
2.500 245.049 1.250 22.504
→ K2SiO3 + H2O
Massa M Massa M Massa
238.047
238.047 2.125 327.315 2.125 38.258
2.125 327.315 2.125 38.258
→ 2KAlSiO4
Massa M Massa
245.049
245.049 2.500 395.078
2.500 395.078
→ K2Cr2O7
Massa M Massa
20.614
20.614 0.429 126.263
0.429 126.263
126.263 99.99
126.275
Massa
10.639
10.639
+ 4K2CrO4
Massa M Massa
+ 4K2CrO4
Massa M Massa
15.461
15.461
Neraca Massa
Enthalphy of Vaporization
Vapor Pressure
Boiling Point
4000
-183
3600
2977 70.093
2230
1000
CP = A + BT + CT^2 + DT^3
B C D Tmin (K)
3.64E-01 -1.22E-03 1.80E-06 1.60E+02
-6.11E+00 3.09E-01 -4.15E-03 1.40E+01
4.49E-01 -1.66E-03 2.70E-06 1.51E+02
7.28E-01 -2.15E-03 2.77E-06 1.98E+02
5.66E-01 -1.72E-03 2.28E-06 1.85E+02
-4.00E-02 -2.11E-04 5.35E-04 2.73E+02
Hvap = A (1-T/Tc)^n
B C D E
-2.86E+03 -5.05E+00 3.74E-11 2.74E-07
-4.13E+01 1.09E+00 -6.69E-10 1.46E-04
-3.68E+03 -3.15E+01 2.01E-02 5.53E-13
-3.11E+03 -9.14E+00 -4.24E-10 2.53E-06
-4.00E+03 -1.03E+01 -3.26E-10 8.67E-07
-3.15E+03 -7.30E+00 2.42E-09 1.81E-06
Hf = A + BT + CT^2
Tmax (K) CP @ 25 C
4.65E+02 1.07E+02
3.20E+01 -
4.15E+02 1.03E+02
5.14E+02 1.52E+02
5.07E+02 1.60E+02
6.15E+02 7.56E+01
TB Hvap 2 TB
3.51E+02 3.94E+01
2.04E+01 4.60E-01
2.94E+02 2.46E+01
3.77E+02 3.48E+01
3.91E+02 4.32E+01
3.73E+02 3.95E+01
Hf 298 K Hf 500 K
-2.35E+02 2.44E+02
0.00E+00
-1.66E+02 -1.73E+02
-1.04E+02 -1.10E+02
-2.74E+02 -2.89E+02
-2.42E+02
1. Vaporizer (HE-100)
Fungsi : Merubah Fasa Ethanol dari Liquid ke Gas sebelum masuk ke Reak
· Temperatur : 150° C
· Tekanan : 1 atm
· Katalis : Tandem
· Komposisi Umpan 99,99% Ethanol dan 0.01% Water
0 C2 H 6 O
0 H2O
Total
C2 H 6 O
Mula-Mula #NAME?
Bereaksi #NAME?
Sisa #NAME?
0 C2 H 6 O
0 H2
Magnesium Oxide C2 H 4 O
Total
Cr2O3 +
Mula-Mula 127.525
Bereaksi 44.918
Sisa 82.607
2Fe2O3.Cr2O3 +
Mula-Mula 0.409
Bereaksi 0.096
Sisa 0.313
2Fe2O3.Cr2O3 +
Mula-Mula 127.525
Bereaksi 29.894
Sisa 97.631
2MgO.Cr2O3 +
Mula-Mula 0.664
Bereaksi 0.038
Sisa 0.626
2MgO.Cr2O3 +
Mula-Mula 127.525
Bereaksi 7.322
Sisa 120.203
Al2O3 +
Mula-Mula 1.250
Bereaksi 1.250
Sisa 0.000
Al2O3 +
Mula-Mula 127.525
Bereaksi 127.525
Sisa 0.000
SiO2 +
Mula-Mula 2.125
Bereaksi 2.125
Sisa 0.000
SiO2 +
Mula-Mula 127.525
Bereaksi 127.525
Sisa 0.000
K2SiO3 +
Mula-Mula 2.125
Bereaksi 1.250
Sisa 0.875
K2SiO3 +
Mula-Mula 327.315
Bereaksi 192.538
Sisa 134.777
0 Cr2O3
4KOH
1,5 O2
2H2O
2K2CrO4
2Fe2O3.Cr2O3
8KOH
1,5 O2
4K2CrO4
2H2O
MgO.Cr2O3
8KOH
3O2
Al2O3
2KOH
SiO2
2KOH
K2SiO3
4K2CrO4
H2O
Fe2O3
MgO
2KAlO2
K2SiO3
KAlSiO4
Total
C4 H 6 O
Mula-Mula 3O2
Bereaksi M
Sisa 0.996
C4 H 6 O
Mula-Mula →
Bereaksi Massa
Sisa 31.881
0 C2 H 6 O
0 H2
0 C4 H 6 O
0 C4H10O
0 H2O
Total
0 C2 H 6 O
0 H2O
0 C4H10O
Total
0 C2 H 6 O
0 H2O
0 C4H10O
Total
as sebelum masuk ke Reaktor (CRV-100)
01% Water
de : 22.997%
C2H4O H2
#NAME? #NAME?
#NAME? #NAME?
C2H4O H2
#NAME? #NAME?
#NAME? #NAME?
#NAME? #NAME?
#NAME?
hyde : 100%
4KOH + 1,5O2 → 2K2CrO4 + 2H2O
3.356 1.258 0.000 0.000
1.182 0.443 0.591 0.591
2.174 0.815 0.591 0.591
2KAlO2 → 2KAlSiO4
2.500 0.000
2.500 2.500
0.000 2.500
2KAlO2 → 2KAlSiO4
245.049 0.000
245.049 395.078
0.000 395.078
127.525 120.203
21.254 0.000
95.644 0.000
127.525 0.000
280.055 0.000
127.525 0.000
476.094 0.000
327.315 134.777
0.000 59.188
0.000 76.223
0.000 15.330
0.000 1.525
0.000 245.049
0.000 327.315
0.000 395.078
3609.912 1954.225
1655.687
lcohol : 100%
2 H2 C4H10O
Massa M
0.000 0.000
2 H2 C4H10O
M 0.000
0.000 Massa
84.1324812753384 84.1324812753384
0
H1 + H11
#NAME? #NAME?
#NAME?
Cp DT
Alcohol dari Stream 1 yang berasal dari tangki penyimpanan dengan suhu 30 °C dan tekanan 1 atm (fasa liquid)
n suhu 80, 53 °C (fasa gas) sebelum masuk Vaporizer (HE-100) stream 2 dengan Neraca Energi
= H2
m2 Cp2 DT2
1.69548571429
1.64549343E-05
-1.1615309E-10
4.08241788E-16
Cp 1.696
DT 35
59.343
m (fasa liquid)
K
K
K
K
1. Vaporizer (HE-100)
Fungsi : Merubah Fasa Ethanol dari Liquid ke Gas sebelum masuk ke Reak
· Temperatur : 150° C
· Tekanan : 1 atm
· Katalis : Tandem
· Komposisi Umpan 99,99% Ethanol dan 0.01% Water
Aliran Masuk
Stream 1
Temperature 30.0000
Pressure 101.3000
Molar Flow 370.4000
Master Comp Mass Flow (Ethanol) 16995.3862
Master Comp Mass Flow (H2O) 67.1298
Sub Total Master Comp Mass Flow 17062.5160
Total
Aliran Keluar
Stream 7
Temperature 150.0000
Pressure 101.3000
Molar Flow 372.6000
Master Comp Mass Flow (Ethanol) 8358.9751
Master Comp Mass Flow (H2O) 1755.7140
Master Comp Mass Flow(n-Butanol) 6947.8269
Aliran Masuk
Stream 9
Temperature 79.4700
Pressure 101.3000
Molar Flow 285.4000
Master Comp Mass Flow (Ethanol) 8318.7681
Master Comp Mass Flow (H2O) 1733.6751
Master Comp Mass Flow(n-Butanol) 634.5367
Aliran Masuk
Stream 13
Temperature 92.5700
Pressure 152.0000
Molar Flow 148.6000
Master Comp Mass Flow (Ethanol) 2818.6032
Master Comp Mass Flow (H2O) 1420.7512
Master Comp Mass Flow(n-Butanol) 634.5245
0.0000
Sub Total Master Comp Mass Flow 4873.8789
Total
Aliran Masuk
Stream 12
Temperature 78.1100
Pressure 101.3000
Molar Flow 136.8000
Master Comp Mass Flow (Ethanol) 5500.1649
Master Comp Mass Flow (H2O) 312.9239
Master Comp Mass Flow(n-Butanol) 0.0122
0.0000
Sub Total Master Comp Mass Flow 5813.1010
Total
7. Cooler
Fungsi : Untuk mendinginkan Buhyl Alcohol
· Tekanan : 1 atm
· Keluaran Buthyl Alcohol 97. 59 %
Aliran Masuk
Stream 10
Temperature 126.6000
Pressure 152.0000
Molar Flow 87.2800
Master Comp Mass Flow (Ethanol) 40.2075
Master Comp Mass Flow (H2O) 22.1981
Master Comp Mass Flow(n-Butanol) 6313.1310
8. Cooler
Fungsi : Untuk mendinginkan Ethyl Alcohol
· Tekanan : 1 atm
· Keluaran Buthyl Alcohol 70 %
Aliran Masuk
Stream 16
Temperature 73.6000
Pressure 101.3000
Molar Flow 254.4000
Master Comp Mass Flow (Ethanol) 7957.8374
Master Comp Mass Flow (H2O) 1309.4849
Master Comp Mass Flow(n-Butanol) 0.9998
% Water
Aliran Keluar
Stream 2
C Temperature 150.0000 C
kPa Pressure 101.3000 kPa
kgmole/h Molar Flow 370.4000 kgmole/h
kg/h Master Comp Mass Flow (Ethanol) 16995.3862 kg/h
kg/h Master Comp Mass Flow (H2O) 67.1298 kg/h
kg/h Sub Total Master Comp Mass Flow 17062.5160 kg/h
0.0000
aldehyde : 51.09 %
Aliran Keluar
Stream 3
C Temperature 150.0000 C
kPa Pressure 101.3000 kPa
kgmole/h Molar Flow 560.1000 kgmole/h
kg/h Master Comp Mass Flow (Ethanol) 8358.9751 kg/h
kg/h Master Comp Mass Flow (H2O) 67.1298 kg/h
Master Comp Mass Flow (Hydrogen) 377.9070 kg/h
Master Comp Mass Flow (Acetaldehyde) 8258.5041 kg/h
kg/h Sub Total Master Comp Mass Flow 17062.5160 kg/h
0.0000
naldehyde : 100%
Aliran Keluar
Stream 5
C Temperature 150.0000 C
kPa Pressure 101.3000 kPa
kgmole/h Molar Flow 561.1000 kgmole/h
kg/h Master Comp Mass Flow (Ethanol) 8358.9751 kg/h
kg/h Master Comp Mass Flow (H2O) 1755.7140 kg/h
kg/h Master Comp Mass Flow (Hydrogen) 377.9070 kg/h
kg/h Master Comp Mass Flow(tr-Crotonal) 6569.9199 kg/h
kg/h Sub Total Master Comp Mass Flow 17062.5160 kg/h
0.0000
Aliran Keluar
Stream 9
C Temperature 79.4700 C
kPa Pressure 101.3000 kPa
kgmole/h Molar Flow 285.4000 kgmole/h
kg/h Master Comp Mass Flow (Ethanol) 8318.7681 kg/h
kg/h Master Comp Mass Flow (H2O) 1733.6751 kg/h
kg/h Master Comp Mass Flow(n-Butanol) 634.5367 kg/h
Aliran Keluar
Stream 12
C Temperature 78.1100 C
kPa Pressure 101.3000 kPa
kgmole/h Molar Flow 136.8000 kgmole/h
kg/h Master Comp Mass Flow (Ethanol) 5500.1649 kg/h
kg/h Master Comp Mass Flow (H2O) 312.9239 kg/h
kg/h Master Comp Mass Flow(n-Butanol) 0.0122 kg/h
Aliran Keluar
Stream 14
C Temperature 78.2500 C
kPa Pressure 101.3000 kPa
kgmole/h Molar Flow 66.6800 kgmole/h
kg/h Master Comp Mass Flow (Ethanol) 2457.6726 kg/h
kg/h Master Comp Mass Flow (H2O) 239.9265 kg/h
kg/h Master Comp Mass Flow(n-Butanol) 0.9876 kg/h
Aliran Keluar
Stream 18
C Temperature 30.0000 C
kPa Pressure 101.3000 kPa
kgmole/h Molar Flow 245.4000 kgmole/h
kg/h Master Comp Mass Flow (Ethanol) 7957.8374 kg/h
kg/h Master Comp Mass Flow (H2O) 1309.4849 kg/h
kg/h Master Comp Mass Flow(n-Butanol) 0.9998 kg/h
Aliran Keluar
Stream 10
Temperature 126.6000 C
Pressure 152.0000 kPa
Molar Flow 87.2800 kgmole/h
Master Comp Mass Flow (Ethanol) 40.2070 kg/h
Master Comp Mass Flow (H2O) 22.1981 kg/h
Master Comp Mass Flow(n-Butanol) 6313.1310 kg/h
Aliran Keluar
Stream 13
Temperature 92.5700 C
Pressure 152.0000 kPa
Molar Flow 148.6000 kgmole/h
Master Comp Mass Flow (Ethanol) 2818.6032 kg/h
Master Comp Mass Flow (H2O) 1420.7512 kg/h
Master Comp Mass Flow(n-Butanol) 634.5245 kg/h
Aliran Keluar
Stream 15
Temperature 100.4000 C
Pressure 152.0000 kPa
Molar Flow 81.9200 kgmole/h
Master Comp Mass Flow (Ethanol) 360.9304 kg/h
Master Comp Mass Flow (H2O) 1180.8248 kg/h
Master Comp Mass Flow(n-Butanol) 633.5370 kg/h