Percobaan Vol O2 (ml) mol O2 (mmol)

1 0 0
2 7.5 0.3348214286
3 14 0.625
4 28.8 1.2857142857
5 41.2 1.8392857143
6 48.3 2.15625
~ 57.9 2.5848214286

laju rata - rata (M / menit) -0.0000663462

laju reaksi rata-rata antara 10 dan 25 menit -0.0000880952
laju reaksi awal -0.0001
laju reaksi sesaat pada t=15 -0.000088939
H2O2 (M) bereaksi waktu (menit) H2O2 sisa (M) laju
0 0 0.006 0
0.0006696429 5 0.0053303571 -0.0001339286
0.00125 10 0.00475 -0.000125
0.0025714286 25 0.0034285714 -0.0001028571 0.0061
0.006
0.0036785714 45 0.0023214286 -0.000081746 0.0059
0.0043125 65 0.0016875 -6.634615385E-05 0.0058
0.0057
0.0051696429 0.0008303571 0 0.0056
0.0055 f(x) = - 6.58241
0.0054 R² = 0.95240414
0.0053
0.0052
0.0051
0.005
0.0049
0.0048
0.0047
0.0046
0.0045
0.0044
0.0043
0.0042
0.0041
0.004
0.0039
0.0038
0.0037
0.0036
0.0035
0.0034
0.0033
0.0032

Konsentrasi
0.0031
0.003
0.0029
0.0028
0.0027
0.0026
0.0025
0.0024
0.0023
0.0022
0.0021
0.002
0.0019
0.0018
0.0017
0.0016
0.0015
0.0014
0.0013
0.0012
0.0011
0.001
0.0009
0.0008
0.0007
0.0006
0.0005
0.0004
0.0003
0.0002
0.0001
0
0 1 2 3 4 5
0.0004
0.0003
0.0002
0.0001
0
0 1 2 3 4 5
 Grafik Hubungan Waktu dengan Konsentrasi

0.0061
0.006
0.0059
0.0058
0.0057
0.0056
0.0055 f(x) = - 6.58241758241758E-05x + 0.0055652473
0.0054 R² = 0.9524041468
0.0053 0.0053303571
0.0052
0.0051
0.005
0.0049
0.0048
0.0047
0.00475
0.0046
0.0045
0.0044
0.0043
0.0042
0.0041
0.004
0.0039
0.0038
0.0037
0.0036
0.0035
0.0034 0.0034285714
0.0033
0.0032
Konsentrasi

0.0031
0.003
0.0029
0.0028
0.0027
0.0026
0.0025
0.0024
0.0023
0.0022
0.0021
0.002
0.0019
0.0018
0.0017
0.0016
0.0015
0.0014
0.0013
0.0012
0.0011
0.001
0.0009
0.0008
0.0007
0.0006
0.0005
0.0004
0.0003
0.0002
0.0001
0
0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45

Waktu
0.0004
0.0003
0.0002
0.0001
0
0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45

Waktu
 Col umn F
Li near (Col umn F)

0.0023214286

0.0016875

34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66
34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66
waktu (s) [NOBr} mol/ L ln A 1/ [NoBr]
0 0.01 -4.60517019 100
2 0.0071 -4.94766049 140.8451
4 0.005 -5.29831737 200
6 0.0045 -5.40367788 222.2222
8 0.0038 -5.57275421 263.1579
10 0.0033 -5.71383281 303.0303

Jika Orde Nol, maka

Grafik Orde Nol

0
0.012
0 2
0.01
-1
0.008 f(x) = - 0.0006271429x + 0.008752381
R² = 0.8682755772
Axis Title

-2
0.006 Col umn B
Li near (Col umn B)

Axis Title
0.004 -3
0.002
-4
0
0 2 4 6 8 10 12
-5 f(x) = - 0.107
Axis Title R² = 0.948980

-6

Grafik Orde dua

350

300
f(x) = 20.0616030045x + 104.567900046 Note : Sifat kelinearan bag
250 R² = 0.9900931998

200
Axis Title

Col umn D
150 Li near (Col umn D) Dari orde dua kita dapat nilai k = 20.
100 nilai dari 1/ [A0] = 104.57 , sehingga
50

0
0 2 4 6 8 10 12
Axis Title
 Jika Orde 1

Grafik Orde satu

0
0 2 4 6 8 10 12

-1

-2
Axis Title

Col umn C
-3 Li nea r (Col umn C)

-4

-5 f(x) = - 0.1074850684x - 4.7194768166

R² = 0.948980187

-6

Axis Title

Note : Sifat kelinearan bagus jika nilai R mencapai 1

dua kita dapat nilai k = 20.062 M-1 S-1

1/ [A0] = 104.57 , sehingga [A0] = 0.0095 = 0.01
orde nol waktu paruh t=0
At= Ao-K.t t1/2 = [Ao]/2K
orde satu waktu paruh t=1
lnAt=lnAo-Kt t1/2 = ln 2/ K
orde dua waktu paruh t=2
1/At = 1/Ao+ kt t1/2 = 1/[Ao]K

Persamaan Arhenius
ln k = ln A -Ea/R (1/T)
y=c+mX
waktu (s) [NO2] [M] ln [NO2] 1 [NO2]
0 0.5 -0.69315 2
Ord
1200 0.444 -0.81193 2.252252
3000 0.381 -0.96496 2.624672 0.6

4500 0.34 -1.07881 2.941176

9000 0.25 -1.38629 4 0.5
18000 0.174 -1.7487 5.747126
f(x) = - 1.72063598701153E-05x + 0.4505445079
0.4 R² = 0.9011585514
a. Laju Awal reaksi

Axis Title
b. Tentukan laju pada t = 6 x 10^3 detik 0.3
c.
d. 0.2

0.1

0
0 2000 4000 6000 8000 10000 12000

waktu

Orde 1
0
-0.2 0 00 000 000 000 000 000 000 000 000 000
20 4 6 8 10 12 14 16 18 20
-0.4 7
-0.6 6
-0.8
Axis Title

f(x) = - 5.78131989891781E-05x - 0.7699844332 f(x)

Col umn C 5 R² =
-1 R² = 0.9706856708 Li near (Col umn C)
4

Axis Title
-1.2
-1.4 3
-1.6
2
-1.8
1
-2
waktu 0
0
 Orde nol

8701153E-05x + 0.4505445079
4

Col umn B
Li near (Col umn B)

6000 8000 10000 12000 14000 16000 18000 20000

waktu

orde 2
7

6
f(x) = 0.0002098183x + 2.0124521238
5 R² = 0.9987359526
4
Axis Title

Col umn D
3 Li near (Col umn D)
2

0
0 5000 10000 15000 20000
waktu
No Konsentrasi t1/2 k orde adalah 2
1 0.00972 328 0.313660544
2 0.00456 572 0.3833885413

Chart Title
0.012

0.01
f(x) = - 2.11475409836066E-05x + 0.0166
0.008 R² = 1

Axis Title
0.006

0.004

0.002

0
300 350 400 450 500 550 600
Axis Title
 Chart Title

2.11475409836066E-05x + 0.0166563934

Col umn B
Linear (Col umn B)

0 450 500 550 600

xis Title
reaksi A + B ⇾C + D, experimen dengan :

maka hukum laju

V = k [A]2 [B]

Percobaan 1
[A0] = 400 mmol dapat diabaikan dianggap sebagai konstanta Maka pada percobaan 1 merupa
Konsentrasi C (mmol/L) t (s) Konsentrasi B ln B 1/[B] [A]
0 0 4 1.3862943611 0.25 4
2 120 2 0.6931471806 0.5 2
3 240 1 0 1 1
3.5 360 0.5 -0.6931471806 2 0.5
4 ~ 0

Percobaan 2
[A0] = 4 mmol sedangkan [B0] = 400 mmol dan dianggap sebagai konstanta Maka pada percobaan 2 merupa
konsentrasi [C] t(s) Konsentrasi A ln [A] 1/[A]
0 0 4 1.3862943611 0.25
2 69 2 0.6931471806 0.5
3 206 1 0 1
3.5 485 0.5 -0.6931471806 2
4 ~ 0

Orde nol
4.5
4
3.5
3
f(x) = - 0.0060751185x + 3.0292725073
2.5 Column C
R² = 0.7087286022
Axis Title 2 Linear (Column C)
1.5
1
0.5
0
orde
0 100 200 300 400 500 600
2.5
Axis Title
2
f(x) = 0.0036081204x + 0.251
1.5 R² = 0.9999827375

orde 1 Axis Title

1
2
0.5
1.5
0
1 f(x) = - 0.003997516x + 1.1061016335 0 100 200 300
R² = 0.9181376882 Column D
Axis Title 0.5 Linear (Column D) Axis Title

0
0 100 200 300 400 500 600
-0.5

-1
 0
1 f(x) = - 0.003997516x + 1.1061016335 0 100 200 300
R² = 0.9181376882 Column D
Axis Title 0.5 Linear (Column D) Axis Title

0
0 100 200 300 400 500 600
-0.5

-1
Axis Title
 konstanta lajunya semu jadi tidak usah dihitung anggap saja sebagai K
Chart Title
4.5
4 4
da percobaan 1 merupakan orde 1 3.5
f(x) = - 0.0095833333x + 3.6
v (K') 3 R² = 0.92
64 64 K 2.5
8 8K Axis Title 2 2
1 1K 1.5
1 1
0.125 0.125 K
0.5
0
0 50 100 150 200 250 300
Axis Title

da percobaan 2 merupakan orde 2

Orde 1
2

1.5
f(x) = - 0.0057762265x + 1.3862943611
1 R² = 1
Axis Title 0.5

0
0 50 100 150 200 250 300
-0.5

-1
Axis Title

orde 2 Orde dua

2.5

2
f(x) = 0.0047916667x + 0.075
= 0.0036081204x + 0.2519571155 1.5 R² = 0.92
= 0.9999827375
Axis Title
Column E 1
Linear (Column E)
0.5

0
0 50 100 150 200 250 300
100 200 300 400 500 600 Axis Title
Axis Title
100 200 300 400 500 600
Axis Title
 Chart Title

3333x + 3.6

Column C
2 Linear (Column C)

1
0.5

150 200 250 300 350 400

Axis Title

Orde 1

62265x + 1.3862943611
Column D
Linear (Column D)

0 150 200 250 300 350 400

Axis Title

Orde dua

7916667x + 0.075
Column E
Linear (Column E)

100 150 200 250 300 350 400

Axis Title
Tentukan A dan Ea dari data berikut :
Harga T harus ubah ke Kelvin
T/K 300 350 400 450 500
k/M-1S-1 7900000 30000000 79000000 170000000 320000000

T (K) k (M-1S-1) 1/T lnK

300 7900000 15.88237
350 30000000 0.002857 17.21671 20
400 79000000 0.0025 18.18496 19.5
f(x) = - 2758.352615409x +
450 170000000 0.002222 18.95131 19 R² = 0.9998924942
500 320000000 0.002 19.58383 18.5

Axis Title
18
17.5
Jadi hubungan A dan Ea adalah liner 17
maka harga A adalah 16.5
16
-2767.2 = -EA / R 0.0018 0.002 0.0022 0.0024
EA 23006.5008 Axis Title
23 Kj/ mol

ln A 25.11
A 80377490095.9
80377490095.9
 Chart Title

f(x) = - 2758.352615409x + 25.0900184049

R² = 0.9998924942

Col umn D
Li near (Col umn D)

0.002 0.0022 0.0024 0.0026 0.0028 0.003

Axis Title
The activation energy of one of the reactions in the krebs citric acids cycle is 87 kJ/ mol.
What is the change in the rate constant when the temperature falls from 37oC to 15 oC

Dik Ea 87000 J/mol

K1 = ln A - EA/R (1/T1)
K2 = ln A- EA/R (1/T2)

ln k1/k2 2.578563 lnk2/k1 -2.57856

k1/k2 13.17819 k2/k1 0.075883
K1 13.17819 K2 K2 0.075883 K1
K2 0.075883 K1 K1 13.17818
∆K -12.1782
Tentukan A dan Ea dari data berikut ini!
T(K) K 1/T lnK 2
319 0.522 0.003135 -0.65009 0.693147
329 0.755 0.00304 -0.28104
352 1.7 0.002841 0.530628
381 4.02 0.002625 1.391282
389 5.03 0.002571 1.61542 Chart Title
2
m -4020.6
1.5 f(x) = - 4020.5642472031x + 11.9481549
ln A 11.948
R² = 0.9999621004
A 154507.8 1

Axis Title
m = - Ea/R
0.5
-4020.6 Ea/R
Ea 33427.27 J/mol 0
33.427 kJ/mol 0.0024 0.0026 0.0028 0.003 0.0032
-0.5

-1
Axis Title
 Chart Title

x) = - 4020.5642472031x + 11.9481549883
² = 0.9999621004

Col umn D
Li near (Col umn D)

6 0.0028 0.003 0.0032

Axis Title