HALOGEN

GOLONGAN VII A
Kelompok 4 :
AISYAH NUR AULIA AKBAR
GINA RIVALDO
HAFIDZ M.R OWEN
Apa yang akan
dibahas?
01 SIFAT FISIK UNSUR

02 SIFAT KIMIA UNSUR

03 PEMBUATAN UNSUR

KEGUNAAN DAN DAMPAK

04 PENGGUNAAN
SIFAT FISIK UNSUR
By Gina Rivaldo
TABEL
SIFAT
FISIK
UNSUR
SIFAT KIMIA UNSUR
By Gina Rivaldo and Hafidz M.R Owen
 Sifat-sifatnya

KELARUTAN DAYA OKSIDASI SIFAT ASAM

Reaksi Pertama : F            + 2e-   →  2F-            Eo= +2,87 Volt 

2F2(g) + 2H2O(l)   → 4HF(aq) + O2(g) Cl2        + 2e-   →2Cl-         Eo= +1,36 Volt a. Asam Halida
b. Asam Oksihalida
Br2       + 2e-    →2Br-            Eo= +1,06 Volt
Reaksi Kedua :
I2       + 2e-   →2I-          Eo= +0,54 Volt
I2(s) + KI(aq)→  KI3(aq)

F > Cl >Br> I ? Semua halogen titik didih dan F2      + 2KCl        → 2KF + Cl2
titik leburnya rendah. 2 Br-  + Cl2         → Br2 + 2 Cl
F < Cl <Br< I ? Semakin ke bawah, titik didih Br2    + 2I-          →  Br- + I2
dan lebur meningkat
Br2    + Cl-           → (tidak bereaksi)
F < Cl <Br< I ?
I2    + Br-         → (tidak bereaksi)

TITIK DIDIH DAN REAKSI

KEREAKTIFAN
TITIK LEBUR PENDESAKKAN
PEMBUATAN UNSUR
z

By Hafidz M.R Owen

Halogen dibuat dari senyawa-senyawa yang ada di alam.
Dengan mengoksidasi ion-ion halida.

Cara Reaksi Redoks :

PEMBUATAN
2HF(aq)              → 2HF+(aq) + 2F-(aq) PEMBUATAN MnO2(s) + 2H2SO4(l) + 2NaCl(s)   → Na2SO4(aq) + MnSO4(aq) + 2H2O(l) + Cl2(g)
FLUORIN KLORIN (Cl2) CaOCl2(aq) + H2SO4(l)                 → CaSO4(aq) + H2O(l) + Cl2(g)
Katode (−) : 2F+(aq) + 2e → H2(g)
CaOCl2(aq) + 2HCl(l)                  →  CaCl2(s) + H2O(l) + Cl2(g)
Anode  (+) : 2F-(aq)           → F2(g) + 2e (F2) 2KMnO4(s) + 16HCl(l)               → 2KCl(aq) + 2MnCl2(aq) + 8H2O(l) + 5Cl2(g)

Cara Elektrolisis :

PEMBUATAN 2NaCl(aq)             → 2Na+(aq) +  2Cl¯(aq)

Cara Reaksi Redoks :
Katode (-): 2NH2O(l) + 2e¯           → H2(g) + 2OH¯(aq)
BROMIN Anode (+): 2Cl¯(aq)                   → Cl2(g) + 2e¯.
a. Cl2(g) + 2Br¯(aq)      → Br(l) + 2Cl¯(aq) (Br2)
b. MnO2(s) + 2H2SO4(l) + 2NaBr(s) → MnSO4(aq) +                2NaCl(aq) + 2H2O(l)   → 2Na+(aq) + 2OH¯(aq)+ Cl2(g) + H2(g)
Na2SO4(aq)  + Br2(g)  + 2H2O(l)                                                                    2NaOH(aq)

Cara Elektrolisis : Cara Reaksi Redoks :

a. Cl2(g) + I¯(aq) → I2(s) + 2Cl¯(aq)
MgBr2(aq)               → Mg2+(aq) + 2Br¯(aq) b. IO3¯(aq) + 3HSO3¯(aq)   → I¯(aq) + 3H+(aq) + 3SO42¯
PEMBUATAN
Katode(-): 2H2O(l) + 2e¯          → H2(g) + 2OH¯(aq) I¯(aq) + IO3¯(aq) + 6H+(aq)    → I2(s) + 3H2O(l)
Anode(+): 2Br¯(aq)                   → Br2(l) + 2e¯. IODIN
MgBr2(aq)+2H2O(l) → Mg2+(aq) + 2OH¯(aq)+ Br2(l) + H2(g) (I2) c. KI(s) + MnO2(s) + H2SO4(l) → K2SO4(aq) + MnSO4(aq) + H2O(l) + I2(s)
                                       Mg(OH)2(aq)
Cara Elektrolisis :
. 2NaI(aq)                  → 2Na+(aq) + 2I¯(aq)
          Katode(-):   2H2O(l) + 2e¯        → H2(g) + 2OH¯(aq)
          Anode(+):   2I¯                     → I  + 2e¯.
KEGUNAAN UNSUR
z

By Aisyah Nur Aulia Akbar

 Apa saja kegunaannya?

FLUORIN KLORIN
-Membuat senyawa klorofluoro karbon (CFC), yang -Untuk klorinasi hidrokarbon sebagai bahan baku industri
dikenal dengan nama Freon. serta karet sintesis.
-Membuat Teflon -Untuk industri sebagai jenis pestisida .
-Memisahkan isotop U-235 dari U-238 melalui proses -Sebagai bahan desinfektans dalam air minum dan kolam
difusi gas. renang.

BROMIN IODIN

-Untuk membuat etil bromida (C2H4Br2). -Iodin Banyak digunakan untuk obat luka (larutan iodin dalam
-Untuk pembuatan AgBr. alkohol yang dikenal dengan iodium tingtur)
-Untuk pembuatan senyawa organik misalnya zat warna, -Sebagai bahan untuk membuat perak iodida (AgI)
obat-obatan dan pestisida -Untuk menguji adanya amilum dalam tepung tapioka.
DAMPAK KEGUNAAN
z

UNSUR
By Aisyah Nur Aulia Akbar
 Beberapa Dampak Penggunaan

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FLUORIN
-Membuat senyawa klorofluoro
karbon (CFC), yang dikenal
dengan nama Freon.
-Membuat Teflon
-Memisahkan isotop U-235 dari U-
238 melalui proses difusi gas.
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 Fully Editable Icon Sets: A

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 Fully Editable Icon Sets: B

You can Resize without

losing quality
You can Change Fill
Color &
Line Color

FREE
PPT
TEMPLATES
www.allppt.com
 Fully Editable Icon Sets: C

You can Resize without

losing quality
You can Change Fill
Color &
Line Color

FREE
PPT
TEMPLATES
www.allppt.com