LAMPIRAN

data kurva baku

konsentrasi (ppm) Absorbansi

2.5 0.05
6.5 0.1749
13.5 0.371
25 0.8585

data kurva baku

1
0.9
y = 0.0324x
0.8
R² = 0.9901
0.7
Absorbansi

0.6
0.5
0.4
0.3
0.2
0.1
0
0 5 10 15 20 25 30
konsentrasi

40 deg C
waktu Absorbansi C ln C 1/C
0 0.8585 26.496914 3.277028 0.037740
5 0.7544 23.283951 3.147764 0.042948
10 0.712 21.975309 3.089919 0.045506
20 0.6617 20.422840 3.016654 0.048965
30 0.627 19.351852 2.962788 0.051675

50 deg C
waktu Absorbansi C ln C 1/C
0 0.8585 26.496914 3.277028 0.037740
5 0.722 22.283951 3.103867 0.044875
10 0.6472 19.975309 2.994497 0.050062
20 0.5645 17.422840 2.857782 0.057396
30 0.5298 16.351852 2.794341 0.061155

60 deg C
waktu Absorbansi C ln C 1/C
0 0.8585 26.496914 3.277028 0.037740
 5 0.6896 21.283951 3.057953 0.046984
10 0.5824 17.975309 2.888999 0.055632
20 0.4997 15.422840 2.735849 0.064839
30 0.4326 13.351852 2.591655 0.074896

orde ke 0

30.000
y = -0.215x + 25.102
R² = 0.8678
25.000
y = -0.315x + 24.602
C (konsentrasi)

20.000 R² = 0.8709
y = -0.403x + 24.145
15.000 R² = 0.8792

10.000

5.000

0.000
0 5 10 15 20 25 30 35
waktu (menit)
40 deg C 50 deg C 60 deg C
Linear (40 deg C) Linear (50 deg C) Linear (60 deg C)

orde ke 1

3.500
y = -0.0096x + 3.2237
3.000 R² = 0.8989
y = -0.0154x + 3.2052
2.500
R² = 0.9124
2.000 y = -0.0216x + 3.191
ln C

R² = 0.9365
1.500

1.000

0.500

0.000
0 5 10 15 20 25 30 35
waktu
40 deg C 50 deg C 60 deg C
Linear (40 deg C) Linear (50 deg C) Linear (60 deg C)
 orde ke 2
0.090

0.080 y = 0.0004x + 0.0398

R² = 0.9265
0.070
y = 0.0008x + 0.0403
0.060 R² = 0.946
0.050 y = 0.0012x + 0.0405
1/C

R² = 0.9761
0.040

0.030
40 deg C
0.020
50 deg C
0.010
60 deg C
0.000 Linear (40 deg C)
0 10 20 30 40
Linear (50 deg C)
waktu (menit)
Linear (60 deg C)

kesimpulan
mengikuti orde 2, karena R2 ke tiga nya paling mendekati 1

suhu (celcius) k T (kelvin) 1/T ln k

40 0.0004 313 0.003195 -7.824046
50 0.0008 323 0.003096 -7.130899
60 0.0012 333 0.003003 -6.725434

Chart Title
(6.600)
0.00295 0.00300 0.00305 0.00310 0.00315 0.00320 0.00325
(6.800)

(7.000)

(7.200)
ln k

(7.400)

(7.600)
y = -5739x + 10.552
R² = 0.9826
(7.800)

(8.000)
1/T
Dari kurva tersebut di dapatkan persamaan y= -5739 x + 10.552

30oC= 303 K
Ln k= (-5739*(1/303))+10.552
Ln k= -8.388594
k= anti Ln k
k= 0.000227

Jadi, besar k ketika suhu 30oC adalah 0.000227

Rumus t0.5 pada orde ke-2 : =1/(Co.k)

t0.5 =1/(26.496914*0.000227)
t0.5 = 165.929962

Rumus t90 pada orde ke-2: =0.11/(Co.k)

t90 =0.11/(26.496914*0.000227)
t90 =18.25229586 menit