Rini Kristiyanti Sabelau - 2213031012 Kimia Dasar2
Rini Kristiyanti Sabelau - 2213031012 Kimia Dasar2
Dalam unit ini kami masih membantu mengenali butir-butir soal penguasaan konsep dan
pengayaan konsep yang mendukung kajian unit topik ini (LR-1).
Unit LR-1
a. Soal-soal penguasaan konsep: PROBLEM 9.2
SAMPLE PROBLEM 16.1 Because it has a nonpolluting combustion product (water vapor), hydrogen
gas
is used for fuel aboard the space shuttle and in prototype cars with Earth-bound engines:
2H2(g) O2(g) 2H2O(g)
(a) Express the rate in terms of changes in [H2], [O2], and [H2O] with time.
(b) When [O2] is decreasing at 0.23 mol/Ls, at what rate is [H2O] increasing?
16.7 Define reaction rate. Assuming constant temperature and a closed reaction vessel, why does
the rate change with time?
16.8 (a) What is the difference between an average rate and an instantaneous rate?
(b) What is the difference between an initial rate and an instantaneous rate?
16.9 Give two reasons to measure initial rates in a kinetics study
16.10 For the reaction A(g) B(g), sketch two curves on the same set of axes that show
(a) The formation of product as a function of time
(b) The consumption of reactant as a function of time
2021 IBN Sudria, scientific learning module: observing – asking – collecting data – associating – communicating
16.11 For the reaction C(g) D(g), [C] vs. time is plotted:
16.13 (a) Use the data from Problem 16.12 to calculate the average rate from 8.0 to 20.0 s.
(b) Is the rate at exactly 5.0 s higher or lower than the rate in part (a)? Use graphical methods
to estimate the rate at 5.0 s.
16.14 Express the rate of reaction in terms of the change in concentration of each of the reactants
and products:
A(g) + 2B(g) C(g)
When [B] is decreasing at 0.5 mol/Ls, how fast is [A] decreasing?
16.15 Express the rate of reaction in terms of the change in concentration of each of the reactants
and products:
2D(g) + 3E(g) + F(g) 2G(g) + H(g)
When [D] is decreasing at 0.1 mol/Ls, how fast is [H] increasing?
16.16 Reaction rate is expressed in terms of changes in concentration of reactants and products.
Write a balanced equation for
2021 IBN Sudria, scientific learning module: observing – asking – collecting data – associating – communicating
16.17 Reaction rate is expressed in terms of changes in concentration of reactants and products.
Write a balanced equation for
16.18 The decomposition of nitrosyl bromide is followed by measuring total pressure because the
number of moles of gas changes; it cannot be followed colorimetrically because both NOBr
and Br2 are reddish brown:
2NOBr(g) 2NO(g) Br2(g)
Use the data in the table to answer the following:
(a) Determine the average rate over the entire experiment.
(b) Determine the average rate between 2.00 and 4.00 s.
(c) Use graphical methods to estimate the initial reaction rate.
(d) Use graphical methods to estimate the rate at 7.00 s.
(e) At what time does the instantaneous rate equal the average rate over the entire
experiment?
16.19 Although the depletion of stratospheric ozone threatens life on Earth today, its accumulation
was one of the crucial processes that allowed life to develop in prehistoric times:
3O2(g) 2O3(g)
(a) Express the reaction rate in terms of [O2] and [O3].
(b) At a given instant, the reaction rate in terms of [O2] is 2.17105 mol/Ls. What is it in terms
of [O3]?