Konversi Trial

Impor x y xy x2
no tahun ton
1 2012 44399.263 89331317.16 4048144
2 2013 45479.692 91550620 4052169
3 2014 45898.054 92438680.76 4056196 Tahun
4 2015 46855.36 94413550.4 4060225 2017
5 2016 47604.76 95971196.16 4064256 2018
2019
2020
Jumlah 10070 230237.129 463705364 20280990 2021
SLOPE (A) 778.6662

INTERCEPT (B) -1522186.301
MAKA KEBUTUHAN PADA TAHUN 2021

X 2021
A 778.6662
B -1522186.301
Y 51498.0892
KAPASITAS PRODUKSI 70% = 36048.66244 Di bulatkan menjadi , 36000 ton/tahun

Kapasitas (Ton)
48383.4244000001
49162.0906
49940.7568000001
JUMLAH FURFURAL
50719.423
51498.0892 (TON/TAHUN)
f(x) =
R² = 0
DATA KEBUTUHAN FURFURAL
87000
82000
77000
72000
67000
62000
57000
52000
47000
42000
2012 2012.5 2013 2013.5 2014 2014.5 2015 2015.5 2016
furfural
di , 36000 ton/tahun
015.5 2016
I. Reaksi UTAMA
Menentukan konversi reaksi utama dan samping :

Berdasarkan Literatur Coulson and Richardson diperoleh data sebagai berikut
Komponen Go298.15 (kJ/mol) Ho298.15 (kJ/mol)
CH3OH -162.51 -201.17
CO -137.28 -110.54
CH3COOH -376.69 -434.84
CH3COOCH3 -321.5 -410
H2O -228.6 -241.8
CO2 -394.38 -393.51
H2 0 0
buku TERMO J.C SMITH BAB 13
G Reaksi Asam Asetat -76.9 kJ/mol
H Reaksi Asam Asetat -123.13 kJ/mol
R 8.314 j/mol K
T 30 C
o
ln Ka 298.15 G 298 .15
Asam Asetat = (13.11B)
−RT
30.5111619472
Ka 298.15 17816782162614.2
Dimana :
T1 30 C
T2 202 C
Ho  1 1 
ln Ka2 – ln Ka1 = -    (13.15)
R  T1 T2 
PENTOSA Untuk,
T= 202 C K298
475.15 K 17.8167821626
Untuk,
T= 70 C K298
343.15 K 17816782162614.2
Untuk,
T= 120 C K298
393.15 K 17816782162614.2
Untuk,
T= 140 C K298
413.15 K 17816782162614.2
Untuk,
T= 160 C K298
433.15 K 17816782162614.2
GLUKOSA T= 160 C K298

433.15 75.5450424142
G H TC
H2O -237.129 -285.83 647.3
C5H4O2 -79.79 -202 657.1
C5H10O5 -722.9 -817.07 900.64
G FURFURAL -68276.9999999999
H FURFURAL -242420
furfural
T= 160 C K298
433.15 5.8207480941
T= 240 C K298
513.15 5.8207480941
T= 260 C K298
533.15 5.8207480941
T= 280 C K298
553.15 5.8207480941
-335544.32
agai berikut
Tc (K) Pc (Bar) Pc (Atm)
512.58 80.96 79.90128608
132.92 34.99 34.53243577
592.71 57.86 57.10336478
506.8 46.9 46.2866887
647.13 220.55 217.66586765
304.19 73.82 72.85465586
33.18 13.13 12.95829899
( Reaktan (-))
-76900 G Reaksi Samping 1 -10900
-123130 H Reaksi Samping 1 -15790
303.15 G Reaksi Samping 2 -28500

H Reaksi Samping 2 -41170
ln Reaksi Samping 2 4.3247290666

Ka 298.15 75.5450424142
ln Reaksi Samping 2 11.3077778348

Ka 298.15 81452.7058749814
303.15 K Ka1 = Ka 298,15

475.15 K Ka2 = Ka 475,15
lnKT/K298 KT/K298 KT Konversi

0.0001786318 1.0001786478 18 0.7705831792
17.9998199649

-5.6947186813 0.0033636833 59930012849.8965 0.861610987
51.2151796334
-11.1835714355 1.39006989413403E-05 247665724.945942 0.8802491401
68.7337015823

-13.0071220323 2.24428845787063E-06 39985998.5639504 0.8858853039
75.7921529781

-14.6622736359 4.28800682348551E-07 7639848.34858448 0.8907763893
82.8237220772
1.880267203 6.5552562126 495.2171086177 0.5932519736
5.0443428586
PC PC atm
220.5 217.61145
49.2 48.55548
65.8838 65.02072222
303.15 8.314

0.0002915887 1.0002916312 5.8224456059 0.7213226639
0.9866845433
0.0003975947 1.0003976738 5.823062853 0.8895214678
1.2941003969
0.0034835935 1.0034896682 5.8410605738 0.9508514548
1.4080816055
0.0004390993 1.0004391957 5.8233045418 0.9152826753
1.3418735143
% konversi
77%
% konversi
86%
% konversi
88%
% konversi
89%
% konversi
89%
% konversi
59%
% konversi
72%
% konversi
89%
% konversi
95%
% konversi
92%
Kapasitas = 18000 ton/hari
Oprasi Produksi = 300 hari/tahun
Basis Produksi = 1 jam oprasi
Kapasitas/jam = 18000 ton 1000

tahun
= 2500.0000 kg/jam
Kemurnian Furfural = 98.5 %

0.985
Produk Furfural = 2462.5000 kg/jam =
Impuritis = 2%
0.02
Produk Impuritis = 50.0000 kg/jam (Air)
Konversi Pentosa ke Furfural = 43.0 % 0.4300

8948.0378 kg/jam pentosa
Konversi pentosan ke pentosa = 32.0 %

186.4175 kmol pentosan
Massa Hemiselulosa = 28.75 %

28298.1695 kg/jam hemiselulosa
Ampas tebu = 98428.4157
1 TAHUN =
Feed Ampas Tebu = 98628.7813 kg/jam 863988124.0478
Perbandingan Bahan Baku = Ampas Tebu : As. Sulfat

1 : 8
Kemurnian Larutan As. Sulfat = 6%

0.06
Feed Larutan As. Sulfat = 789030.2503 kg/jam =
Feed Larutan As. Sulfat 36% = 131505.0417 kg/jam =

feed Air = 657525.2086 kg/jam =
Komposisi Ampas Tebu

28.75 % Hemiselulosa
0.2875
28355.7746
25 % Pentosan
0.25
24657.1953 kg/jam
40 % Selulosa
0.4
39451.5125 kg/jam
25 % Lignin
0.25
24657.1953 kg/jam
6.25 % Kadar Abu

0.0625
6164.2988 kg/jam
Pabrik Pembuatan Furfural dari Jerami Padi
kg 1 tahun 1 hari
ton 300 hari 24 jam
26.0417 kmol/jam
NOTE :
25.6510 kmol/jam
Komponen BM
H2O 18
H2SO4 98
C5H10O5 150
C5H8O4 132
C5H4O2 96
C6H10O5 162
59.6536 kmol 24690.1948
-24303.7773
24490.1948
24607.1039 kg G25*K20 24500.0000
28.7500
25.0000
0.8696
86.9565
8760.0000 JAM
kg/tahun KONVERSI :
Pentosan ke pentosa : 32 %
(Sumber : Patent, US 2017/0233362) Pentosa ke Furfural : 43 %
kg Kemurnian Furfural : 98 %
Jerami padi : AS.SULFAT
41687.9928 kmol/jam
(mol x %) + (mol x % air dlm sulfat) used
5158.8146 kmol/jam buy

(mol x %) + (mol x % air dlm sulfat)
36529.1783 kmol/jam
Komponen Kg
Hemiselulosa 28355.7746
Selulosa 39451.5125
Lignin 24657.1953
Kadar Abu 6164.2988
Pentosan 24657.1953
Total 98628.7813
Persen Total Komposisi ampas tebu

100.0000 kg/jam
sehari 2367090.7508 kg
sebulan 71012722.5245 kg
setahun 852152670.2937 kg
( Sumber : Patent , US 2017/0233362A1 )
(Sumber : Patent, US 8,901,325 B2)

REFERENSI
Tanki-01
Fungsi : Menampung As. Sulfat 36%

T= 30 °C
P= 1 atm
Input
Komponen Aliran 2
Kmol Kg
Asam Sulfat 36 % 5158.8146 131505.0417
Total 5158.8146 131505.0417
H2O (Asam) 146.1167130133 2630.1008

Total 5304.9313 134135.1425
Fraksi T-01
H2SO4 0.9725
H2O 0.0275
Rumus di D15 (x) Rumus di D16 (z)

(kg H2SO4 36% X 2)/100 kg H2SO4 36% + x
Rumus di C15 (n) Rumus di C16 (l)

x/18 mol H2SO4 36% +n
ALIRAN 2
Fungsi = Mengalirkan air menuju Mixer (MT-01)

T= 30 °C
P= 1 atm
Input
Komponen Aliran 3
Kmol Kg
Air 36529.178253331 657525.208559958
Total 36529.178253331 657525.208559958
Aliran 2 Aliran 4
Air 84163.2266956746 Air 741688.43525563
Asam sulfat 47341.8150163169 Asam sulfat 47341.815016317
Aliran 3 789030.25027195
Air 657525.208559958
789030.250271949
MIXER-01
Fungsi = Mengencerkan As. Asetat hingga 6 %

T = 30
P = 1
Aliran 1 = Air + Asam Sulfat (Asam Sulfat 36%)

Aliran 2 = Air
Feed Asam Sulfat 6 % = 789030.2503

Asam Sulfat pada Aliran 3 = 47341.8150
Air pada Aliran 3 = 741688.4353
Rumus Pengenceran = V1 N1
V1 (0,36)
V1
Feed Asam Sulfat 36% = 131505.0417

Jadi, Air yang perlu ditambahakan pada Aliran 2

Sebelum Recycle
input
Komponen Aliran 2
Kmol Kg
Air 4675.7348 84163.2267
Asam Sulfat 483.0797 47341.8150
Subtotal 5158.8146 131505.0417
Total 789030.2503
Input
Komponen Aliran 2 Aliran 3
Kg Kg
Air 84163.2267 657525.2086
Asam Sulfat 47341.8150 -
Subtotal 131505.0417 657525.2086
Total 789030.2503
Sesudah Recycle
input
Komponen Aliran 2
Kmol Kg
Air 1172.4405 21103.9297
Asam Sulfat 121.1322 11870.9605
Subtotal 1293.5728 32974.8902
Total 197849.3412
Fungsi = Mengencerkan As. Asetat hingga 6 %

T = 30
P = 1

Aliran 2 = Air
Feed Asam Sulfat 6 % = 197849.3412

Rumus Pengenceran = V1 N1
V1 (0,36)
V1
Feed Asam Sulfat 36% = 32974.8902

Jadi, Air yang perlu ditambahakan pada Aliran 3

MIXER-01
an As. Asetat hingga 6 %

Komponen
°C
atm H2O
H2SO4
Sulfat (Asam Sulfat 36%) C5H10O5
C5H8O4
C6H10O5
Kg/jam
Kg/jam As. Sulfat Murni 36 %
Kg/jam 0.36
= V2 N2 As. Sulfat di inginkan 6 %

= 135307,6047(0,6) 0.06
= 131505.0417 Kg/jam
kg/jam
kg/jam
kg/jam
= 657525.2086 kg/jam
input output
Aliran 3 Aliran 4
kmol kg Kmol Kg
36529.1783 657525.2086 41204.9131 741688.4353
- 483.0797 47341.8150
36529.1783 657525.2086 41687.9928 789030.2503
789030.2503 789030.2503
Fraksi aliran 1
Output 0.9064 air
Aliran 4 0.0936 sulfat
Kg
741688.4353
47341.8150
789030.2503
789030.2503 0.0914
131505.041711992
657525.2086
input output
Aliran 3 Aliran 4
kmol kg Kmol Kg
9159.6917 164874.4510 10332.1323 185978.3807
- 121.1322 11870.9605
9159.6917 164874.4510 10453.2645 197849.3412
197849.3412 197849.3412
an As. Asetat hingga 6 %

Komponen
°C
atm H2O
H2SO4
C5H8O4
C6H10O5
Kg/jam
Kg/jam As. Sulfat Murni 36 %
Kg/jam 0.36
= V2 N2 As. Sulfat di inginkan 6 %

= 135307,6047(0,6) 0.06
= 32974.8902 Kg/jam
kg/jam
kg/jam
kg/jam
= 164874.4510 kg/jam
BM
18
98
150
132
96
162
64% H2O
0.64
94% H2O
0.94
Fraksi
0.9884
0.0116
1.0000
0.06
BM
18
98
150
132
96
162
64% H2O
0.64
94% H2O
0.94
input
Komponen Aliran 2 Aliran 3
Kmol Kg kmol
Air 4675.7348 21103.9297 36529.1783
Asam Sulfat 483.0797 11870.9605
Subtotal 5158.8146 32974.8902 36529.1783
Total 197849.3412
Kondisi operasi
T= 30 C 303.15
T ref = 25 C 298.15
Data Cp Liquid
Komponen A B C
Air 92.053 -0.039953 -0.00021103
Asam sulfat 26.004 0.70337 -0.0013856
Komponen A.T 1/2 BT^2 1/3 CT^3

Air 460.265 -60.05934725 -95.37765253
Asam sulfat 130.02 1057.3409525 -626.2392804133
Input Aliran 2
Komponen n (kmol) n (mol) Cp dT (J/mol K)
Air 4675.7348 4675734.81642637 377.4863815882
Asam sulfat 483.0797 483079.745064459 701.6578669117
Total
Input Aliran 3
Air 36529.1783 36529178.253331 377.4864
Total
Output aliran 4
Air 41204.9131 41204913.0697574 377.4863815882
Asam sulfat 483.0797 483079.745064459 701.6578669117
Total
Neraca Panas M-01

Panas Panas masuk (KJ) Panas Keluar (KJ)
Aliran 2 2,103,983
Aliran 3 13789267.321239
Aliran 4 15893250.2418274
Total 15,893,250.24 15,893,250.24
output
Aliran 3 Aliran 4
kg Kmol Kg
164874.4510 41204.9131 185978.3807
- 483.0797 11870.9605
164874.4510 41687.9928 197849.3412
197849.3412
K
K
D
5.3469E-07
1.0342E-06
1/4 DT^4
72.6583813682
140.536194825
Q (J) Q (KJ)
1765026217.1186 1,765,026
338956703.47017 338,957
2,103,983
Q (J) Q (KJ)
13789267321.239 13,789,267
13,789,267
Q (J) Q (KJ)
15554293538.357 15,554,294
338956703.47017 338,957
15,893,250
HEAT EXCHENGER - 01
Liquid
Komponen BM A
Air 18 92.053
As. Sulfat 98 26.004
Furfural 96 66.792
Toluena 92 83.703
Xylena 106 70.916
CP Dt pada aliran 6
Komponen A.T 1/2 BT^2
Air 460.265 -60.05934725
Asam sulfat 130.02 1057.3409525
Furfural 333.96 1063.6245375
Toluena 418.515 776.669145
Xylena 354.58 1209.364625
Cp Dt GLUKOSA 2184
CP Dt pada aliran 7
Air 9455.7198852631 -1434.3855253503
Asam sulfat 2671.1409720094 25252.265085616
Furfural 6860.9001616079 25402.3347048177
Toluena 8598.004644674 18549.0357551991
Xylena 7284.5190421096 28883.0164229042
Cp dt glukosa 44868.265519678
Input (yang mau dipanaskan), dari MP-04

Aliran 6
Komponen
Kmol Mol
Air 41204.9130697574 41,204,913.0698
As. Sulfat 483.0797450645 483,079.7451
Furfural 0 0.0000
Toluena 0 0.0000
Xylena 0 0.0000
Glukosa 0 0.0000
Subtotal 41,687.9928 41,687,992.8148
Input (yg mau diambil panasnya) dari R-01

Q8
Komponen
Kmol Mol
Air 41,078.5664 41,078,566.3908
As. Sulfat 483.0797 483,079.7451
Pentosan 127.0219 127,021.9153
Selulosa 99.8464 99,846.4206
Lignin 0.0000 0.0000
Abu 0.0000 0.0000
Pentosa 34.0718 34,071.7608
Glukosa 143.6814 143,681.4345
Furfural 25.7033 25,703.2582
Toluena 0.0000 0.0000
Xylena 0.0000 0.0000
Total 41,991.9709 41,991,970.9251
41,957.8992
Kondisi Operasi
T C K
T ref 25 298.15
Tin yg mau dipanaskan 30 303.15
Tout setelah dipanaskan 127.7203880945 400.8703880945
Tin yg mau diambil panas 160 433.15
Tout setelah diambil panas 70 343
PANAS MASUK
Input yang mau dipanaskan Q6
Komponen KMol Cp.dT (J/mol.K)
Air 41,204.9131 377.4864
As.Sulfat 483.0797 701.6579
Furfural 0.0000 847.0956
Toluena 0.0000 789.9941
Xylena 0.0000 915.3755
Glukosa 0.0000 2,184.0000
Total 41,687.9928
Input yg mau diambil panasnya Q8

Komponen KMol Cp.dT (J/mol.K)
Air 41,078.5664 10,450.8423
As. Sulfat 483.0797 19,734.0790
Pentosan 127.0219 40,891.5000
Selulosa 99.8464 50,719.5000
Lignin 0.0000 0.0000
Abu 0.0000 0.0000
Pentosa 34.0718 49,140.0000
Glukosa 143.6814 58,968.0000
Furfural 25.7033 24,484.7602
Toluena 0.0000 22,918.0045
Xylena 0.0000 26,229.4395
Total 41,991.9709
Panas input yang di serap oleh fluida

443,980,011.09
NERACA PANAS HEAT EXCHANGER 01 (HE-01)
Aliran Q in Q out
Q5 15,893,250.2418 0.0000
Q6 0.0000 326,600,828.9949
Q8 459,873,261.3357 0.0000
Q9 0.0000 149,165,682.5826
Total 475,766,511.5775 475,766,511.5775
B C D
-0.039953 -0.00021103 5.3469E-07
0.70337 -0.0013856 1.0342E-06
0.70755 -0.0018082 0.000001963
0.51666 -0.001491 1.97725E-06
0.8045 -0.0021885 2.5061E-06
1/3 CT^3 1/4 DT^4

-95.37765253 72.6583813682
-626.2392804133 140.536194825
-817.2386452392 266.7497103476
-673.8761309875 268.6861257182
-989.1199950813 340.5509165065
1/3 CT^3 1/4 DT^4

-2667.0760734426 2395.6126600218
-17511.7310683886 4633.6056649545
-22852.7079372548 8794.9796173908
-18843.8156920954 8858.8249864931
-27659.0815842728 11228.2722461249
Input setelah dipanaskan

Aliran 6
Komponen
Kg fraksi mol Kmol
741688.435255632 0.9884 Air 41,204.9131
47341.815016317 0.0116 As. Sulfat 483.0797
0 0.0000 Furfural 0.0000
0 0.0000 Toluena 0.0000
0 0.0000 Xylena 0.0000
0 0.0000 Glukosa 0.0000
789,030.2503 1.0000 Subtotal 41,687.9928
Input setelah diambil panasnya

Q9
Komponen
Kg Fraksi mol Kmol
739,414.1950 0.9782481147 0.9790Air 41,078.5664
47,341.8150 0.0115040979 0.0115As. Sulfat 483.0797
16,766.8928 0.0030249096 0.003027366 Pentosan 127.0219
16,175.1201 0.0023777503 0.0023796811 Selulosa 99.8464
24,657.1953 0 Lignin 0.0000
6,164.2988 0 Abu 0.0000
5,110.7641 0.0008113875 Pentosa 34.0718
25,862.6582 0.0034216406 0.0034244192 Glukosa 143.6814
2,467.5128 0.0006120994 0.0006125964 Furfural 25.7033
0.0000 0 Toluena 0.0000
0.0000 0 Xylena 0.0000
883,960.4523 1.0000 Total 41,991.9709
848,028.1940
delta T
0
5
102.7203880945
135
45 suhu menuju RDF
PANAS KELUAR
Q = n.Cp.dT (kJ) Komponen
15,554,293.5384 Air
338,956.7035 As. Sulfat
0.0000 Furfural
0.0000 Toluena
0.0000 Xylena
0.0000 Glukosa
15,893,250.2418 Total

Q = n.Cp.dT (KJ) Komponen
429,305,619.0258 Air
9,533,133.8686 As. Sulfat
5,194,116.6491 Pentosan
5,064,160.5275 Selulosa
0.0000 Lignin
0.0000 Abu
1,674,286.3261 Pentosa
8,472,606.8274 Glukosa
629,338.1112 Furfural
0.0000 Toluena
0.0000 Xylena
459,873,261.3357 458,198,975.01 Total
ng di serap oleh fluida
475,766,511.58
475,766,511.58 Q5 + Q8 = Q6 + Q9
Q6 = (Q5 + Q8)-Q9
Q= 309,591,387.8690 Q6 =
Buat ngitung panas aliran GLUKOSA :
tabel 8.2 Heat capacities of the element, j/mol oC (Coulson hal 322)
Element Solid Liquid
c 7.5 11.7
h 9.6 18
b 11.3 19.7
si 15.9 24.3
o 16.7 25.1
f 20.9 29.3
p and s 22.6 31
all others 26 33.5

Cp glukosa 436.8
Cp pentosan 302.9
Cp pentosa 364
Cp selulosa 375.7
CP Dt pada aliran 9
Komponen A.T 1/2 BT^2 1/3 CT^3 1/4 DT^4
Air 4142.385 -576.49182525 -977.9832428704 797.1526
Asam sulfat 1170.18 10149.1015725 -6421.33147572 1541.856
Furfural 3005.64 10209.4158375 -8379.8005011525 2926.575
Toluena 3766.635 7455.016305 -6909.7901488875 2947.82
Xylena 3191.22 11608.331625 -10142.237250731 3736.266
Cp dt glukosa 19656
Cp dt pentosan 13630.5
Cp dt pentosa 16380
Cp dt selulosa 16906.5
Aliran 6
Mol Kg Fraksi mol
41,204,913.0698 741,688.4353 0.9884
483,079.7451 47,341.8150 0.0116
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
41,687,992.8148 789,030.2503 1.0000
l panasnya
Q9
Mol Kg Fraksi mol
41,078,566.3908 739,414.1950 0.9782481147
483,079.7451 47,341.8150 0.0115040979
127,021.9153 16,766.8928 0.0030249096
99,846.4206 16,175.1201 0.0023777503
0.0000 24,657.1953 0
0.0000 6,164.2988 0
34,071.7608 5,110.7641 0.0008113875
143,681.4345 25,862.6582 0.0034216406
25,703.2582 2,467.5128 0.0006120994
0.0000 0.0000 0
0.0000 0.0000 0
41,991,970.9251 883,960.4523 1.0000
etelah dipanaskan Q7
Kmol Cp.dT (J/mol.K) Q = n.Cp.dT (KJ)
41,204.9131 7,749.8709 319,332,758.6520
483.0797 15,045.2807 7,268,070.3428
0.0000 18,205.5065 0.0000
0.0000 17,162.0497 0.0000
0.0000 19,736.7261 0.0000
0.0000 44,868.2655 0.0000
326,600,828.9949
etelah diambil panasnya Q9

KMol Cp.dT (J/mol.K) Q = n.Cp.dT (KJ)
41,078.5664 3,385.0625 139,053,514.7337
483.0797 6,439.8065 3,110,940.0714
127.0219 13,630.5000 1,731,372.2164
99.8464 16,906.5000 1,688,053.5092
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
34.0718 16,380.0000 558,095.4420
143.6814 19,656.0000 2,824,202.2758
25.7033 7,761.8305 199,504.3341
0.0000 7,259.6812 0.0000
0.0000 8,393.5804 0.0000
149,165,682.5826 148,607,587.14
Panas yang di lepas oleh fluida panas

-177,435,146.41
Q8 = Q6 + Q9
Q5 + Q8)-Q9
326,600,828.99
Input dari keluaran HE-01, pada T = 127,720388094501
Komponen n Cp Q (KJ)
Air 41204.9130697574 7887.5848264713 325,007,247.1051
Asam Sulfat 483.0797450645 14864.3651227135 7,180,673.7140
Furfural
Toluena
Xylena
Glukosa - - -
total 41,687.9928 22,751.9499 332,187,920.8191
T ref 25 C 298.15
T in 127.7203880945 C 400.8703880945
Tout heater 160 C 433.15
Komponen A B C
Air 92.0530 -0.0400 -0.0002
Asam sulfat 26.0040 0.7034 -0.0014
Furfural 66.792 7.08E-01 -1.81E-03
Glukosa - - -
Toluena 83.703 5.17E-01 -1.49E-03
Xylena 70.916 8.05E-01 -2.19E-03
OUTPUT PADA T =160

Komponen kmol Cp Dt Q (KJ)
Air 41204.9131 10450.8422942923 430626048.242057
Asam sulfat 483.0797 19734.0790334387 9533133.86855546
Total
440159182.110612
Panas yang diberikan steam (Qso - Qsin)
Qs = Q keluar - Q masuk = 107,971,261.2915
Steam yang digunakan yaitu saturated steam (T = 370 C,

Sumber : steam table (Smith, van Ness, 1984) Appendix F, hal.691
H saturated vapor (Hv) = 2,342.8000 kJ/Kg

H saturated liquid (Hl) = 1,890.2000 kJ/Kg
Panas laten (λ) = Hv - Hl

= 452.6000 Kj/Kg
Massa Steam yang dibutuhkan (m) = Qs/λ

= 238,557.8022
Panas yang dibawa masuk oleh steam masuk (Qsin)

Qs in = m x Hv = 558,893,219.0758 kJ
Panas yang dibawa steam keluar heater-02 (Qso)

Qs out = m x Hl = 450,921,957.7843 kJ
Neraca Panas H-02

Panas Q in (kJ) Q out (kJ)
Q in heater 332,187,920.8191 0.0000
Q out heater 0.0000 440,159,182.1106
Qs in 558,893,219.0758 0.0000
Qs out 0.0000 450,921,957.7843
Total 891,081,139.8949 891,081,139.8949
0.988412
0.011588
K
K
input
D E Komponen A.T 1/2 BT^2
5.3469.E-07 - Air 9455.719885263 -1436.072911
1.0342.E-06 - Asam Sulfat 2671.140972009 25253.34214
1.96E-06 -
- -
1.97E-06
2.51E-06
OUTPUT
Air 12427.155 -1974.51
Asam Sulfat 3510.54 34721.75835
kJ
Kg
1/3 CT^3 1/4 DT^4
-2527.6748077928 2395.61266
-17693.7236545497 4633.605665
1/3 CT^3 1/4 DT^4

-3650.9041575 3649.101452
-25556.3291025 7058.109786
RE
PROSES PERTAMA
Fungsi = Menghidrolisis senyawa pentosan pad
T = 160
P = #VALUE!
t = 1
Konversi Pentosan to Pentosa =

Konversi Selulosa to Glukosa =
KOMPOSISI INPUT REAKTOR

Aliran BE-01
Komponen Bm
Kmol
Air 18
Asam Sulfat 98
Pentosan 132 186.7969
Selulosa 162 243.5279
Lignin - -
Abu - -
SUBTOTAL 430.3248
TOTAL 8
Reaksi Hidrolisis Pentosan menjadi Pentosa :
m
b
s
Reaksi Hidrolisis Selulosa menjadi Glukosa :
m
b
s
PROSES KEDUA
Fungsi = Mendehidrasi senyawa pentosa menja
T = 160
P = 3
Konversi pentosa ke furfural =
Reaksi Dehidrasi Pentosa menjadi Furfural :
m
b
s
Komponen BM kmol
Air 18 41078.5664
H2SO4 98 483.0797
C5H10O5 (Pentosa) 150 34.0718
C6H12O6 (Glukosa) 180 143.6814
C5H8O4 (Pentosan) 132 127.0219
C6H10O5 (Selulosa) 162 99.8464
Lignin
Abu
Furfural 96 25.7033
Komponen Input
Aliran BE-01 Aliran 7
Kg Kg
Air 741,688.4353
Asam Sulfat 47,341.8150
Pentosan 24,657.1953
Selulosa 39,451.5125
Lignin 24,657.1953
Abu 6,164.2988
Pentosa
Glukosa
Furfural
Subtotal 94,930.2020 789,030.2503
Total 883,960.4523
REAKTOR-01
drolisis senyawa pentosan pada ampas tebu menjadi pentosa

°C (Dari Example Patent US2017/0233362 A1)
atm
jam
32 %
59 %
SI INPUT REAKTOR
Aliran BE-01 Aliran 7
Kg Kmol Kg
41204.9131 741688.4353
483.0797 47341.8150
24657.1953
39451.5125
24657.1953
6164.2988
94930.2020 41687.9928 789030.2503

883960.4523
Pentosan Air (H2S04) Pentosa

C5H8O4 H2O >>>>>> C5H10O5
186.7969 41204.9131
59.7750 59.7750 59.7750
127.0219 41145.1381 59.7750
Selulosa Air (H2SO4) Glukosa

C6H10O5 H2O >>>>>> C6H12O6
243.5279 41145.1381
143.6814 143.6814 143.6814
99.8464 41001.4566 143.6814
idrasi senyawa pentosa menjadi furfural

°C
atm
43% 0.43
Pentosa (AS.SULFAT) Furfural Air

C5H10O5 >>>>>> C5H4O2 3 H2O
59.7750
25.7033 25.7033 77.1098
34.0718 25.7033 77.1098
kg 77.1098
739414.1950
47341.8150
5110.7641
25862.6582
16766.8928
16175.1201
24657.1953
6164.2988
2467.5128
Output
Aliran 8
Kg
739,414.1950
47,341.8150
16,766.8928
16,175.1201
24,657.1953
6,164.2988
5,110.7641
25,862.6582
2467.5128
883,960.4523 BALANCE
(BE-01) (7)
R-01
(8)
Komponen Bm
0.94 Air 18
0.06 Asam Sulfat 98
Pentosan 132
Selulosa 162
Lignin -
Abu -
Furfural 96
Glukosa 180
41391.7100
740612.484914
PROSES PERTAMA
Fungsi = Menghidrolisis senyawa pentosan pad
T = 160
P = 7.7
t = 1
Konversi Pentosan to Pentosa =

Konversi Selulosa to Glukosa =
KOMPOSISI INPUT REAKTOR

Aliran BE-01
Komponen Bm
Kmol
Air 18
Asam Sulfat 98
Pentosan 132 186.7969
Selulosa 162 243.5279
Lignin - -
Abu - -
SUBTOTAL 430.3248
TOTAL
Reaksi Hidrolisis Pentosan menjadi Pentosa :
m
b
s
Reaksi Hidrolisis Selulosa menjadi Glukosa :
m
b
s
PROSES KEDUA
Fungsi = Mendehidrasi senyawa pentosa menja
T = 160
P = 3
Konversi pentosa ke furfural =
Reaksi Dehidrasi Pentosa menjadi Furfural :
m
b
s
Komponen BM kmol
Air 18 41078.5664
H2SO4 98 483.0797
C5H10O5 (Pentosa) 150 34.0718
C6H12O6 (Glukosa) 180 143.6814
C5H8O4 (Pentosan) 132 127.0219
C6H10O5 (Selulosa) 162 99.8464
Lignin
Abu
Furfural 96 25.7033
Komponen Input
Aliran BE-01 Aliran 7 Not Recycle
Kg Kg
Air 741,688.4353
Asam Sulfat 47,341.8150
Pentosan 24,657.1953
Selulosa 39,451.5125
Lignin 24,657.1953
Abu 6,164.2988
Pentosa
Glukosa
Furfural
Toluene
Xylane
Subtotal 94,930.2020 789,030.2503
Total 883,960.4523
883,960.4523
883,960.4523
REAKTOR-01
senyawa pentosan pada ampas tebu menjadi pentosa

°C (Dari Example Patent US2017/0233362 A1)
atm
jam
32 %
59 %
INPUT REAKTOR
Aliran BE-01 Aliran 7 SEBELUM RECYCLE ALIRAN 7 SESUDAH RECYCLE
Kg Kmol Kg kmol
41204.9131 741688.4353 41204.9131
483.0797 47341.8150 483.0797
24657.1953
39451.5125
24657.1953
6164.2988
94930.2020 41687.9928 789030.2503 41687.9928

883960.4523
Pentosan Air (H2S04) Pentosa

C5H8O4 H2O >>>>>> C5H10O5
186.7969 41204.9131
59.7750 59.7750 59.7750
127.0219 41145.1381 59.7750
Selulosa Air (H2SO4) Glukosa

C6H10O5 H2O >>>>>> C6H12O6
243.5279 41145.1381
143.6814 143.6814 143.6814
99.8464 41001.4566 143.6814
senyawa pentosa menjadi furfural

°C
atm
43% 0.43
Pentosa (AS.SULFAT) Furfural Air
C5H10O5 >>>>>> C5H4O2 3 H2O
59.7750
25.7033 25.7033 77.1098
34.0718 25.7033 77.1098
kg
739414.1950
47341.8150
5110.7641
25862.6582
16766.8928
16175.1201
24657.1953
6164.2988
2467.5128
Output
Aliran 7 Recycle Aliran 8
Kg Kg Kmol Fraksi ol
741688.4353 739,414.1950 41078.5663907927 0.9782481147
47341.8150 47,341.8150 483.0797450645 0.0115040979
16,766.8928 127.02191529 0.0030249096
16,175.1201 99.8464205591 0.0023777503
24,657.1953
6,164.2988
5,110.7641 34.0717608072 0.0008113875
0.0000 25,862.6582 143.6814344631 0.0034216406
0.0000 2467.5128 25.7032581528 0.0006120994
0.0000 0.0000 41991.9709251293
0.0000 0.0000
789030.2503 883,960.4523
883,960.4523
3 BALANCE
(BE-01) (7)
R-01
(8)
AN 7 SESUDAH RECYCLE
kg Komponen Bm
741688.4353 0.94 Air 18
47341.8150 0.06 Asam Sulfat 98
Pentosan 132
Selulosa 162
Lignin -
Abu -
Pentosa 150.0000
789030.2503 Furfural 96
Glukosa 180
41391.7100
740612.484914
Input
Komponen
Kmol Kg
Air 41204.9131 741688.4353
Asam sulfat 483.0797 47341.8150
Pentosan 186.7969 24657.1953
Selulosa 243.5279 39451.5125
Lignin 24657.1953
Abu 6164.2988
Pentosa
INERT Glukosa 0.0000 0.0000
Furfural 0.0000 0.0000
Toluena 0.0000 0.0000
Xylena 0.0000 0.0000
Total 42118.3176 883960.4523
Senyawa A B
Air 92.0530 -0.0400
Asam sulfat 26.0040 0.7034
Furfural 66.7920 0.7076
Toluene 83.7030 0.5167
Xylene 70.9160 0.8045
Yaws' Handbook of Thermodynamic and Physical Properties

HEAT CAPACITY OF LIQUID
CP = A+BT+CT2+DT3
CP=J/mol K, Tdeg K
T ref = 25.0000
Tinput = 160.0000
Toutput = 160.0000
Cp dT
Komponen
Input Output
Air 10450.8423 10450.8423
Asam sulfat 19734.0790 19734.0790
Furfural 24484.7602 24484.7602
Toluena 22918.0045 22918.0045
Xylena 26229.4395 26229.4395
Pentosan 40891.5000 40891.5000
Selulosa 50719.5000 50719.5000
Pentosa 49140.0000 49140.0000
Glukosa 58968.0000 58968.0000
PANAS MASUK
Panas Sensibel reaksi pertama

Komponen Kmol Cp dT
Pentosan 186.7969 40,891.5000
Air 41,204.9131 10,450.8423
Asam sulfat 483.0797 19,734.0790
Pentosa 0.0000 49,140.0000
Total 41,874.7897
Panas Sensibel reaksi kedua

Komponen Kmol Cp dT
Selulosa 243.5279 50,719.5000
Air 41,145.1381 10,450.8423
Asam sulfat 483.0797 19,734.0790
Glukosa 0.0000 58,968.0000
Total 41,871.7457
Panas Sensibel reaksi ketiga

Komponen Kmol Cp dT
Pentosa 59.7750 49,140.0000
Asam sulfat 483.0797 19,734.0790
Furfural 0.0000 24,484.7602
Air 10,450.8423
Total 542.8548
Panas sensibel inert

Komponen Kmol Cp Dt
Toluena 0.0000 22918.0045
Xylena 0.0000 26229.4395
Total
Qin = Q1+Q2+Q3+Q4
= 912154161.1049
Panas Reaksi Qr
Panas Pembentukan Standar Reaktan Reaksi Pertama pada T =
Komponen Mol (kmol) (kJ/kmol)
Pentosan 59.7750 -648,560.0000
Air 59.7750 -241,800.0000
Pentosa 0.0000 -879,900.0000
Total
Panas Reaksi Qr
Panas Pembentukan Standar Reaktan Reaksi Kedua pada T =
Selulosa 143.6814 -691460.0000
Air 143.6814 -241800.0000
Glukosa 0.0000 -1078940.0000
Total
Panas Reaksi Qr
Panas Pembentukan Standar Reaktan Reaksi Ketiga pada T =
Pentosa 25.7033 -879900.0000
Furfural 0.0000 -151040.0000
Air 0.0000 -241800.0000
Total
Sigma n Hf Reaktan = -209929718.2569

Menghitung Panas Reaksi pada T = 160.0000
Panas Reaktan Reaksi Pertama
Komponen Mol (kmol) Cp dT (kJ/kmol K)
Pentosan 59.7750 40891.5000
Air 59.7750 10450.8423
Pentosa 0.0000 49140.0000
Total
Panas Reaktan Reaksi Kedua

Selulosa 143.6814 50719.5000
Air 143.6814 10450.8423
Glukosa 0.0000 58968.0000
Total
Panas Reaktan Reaksi Ketiga

Pentosa 25.7033 49140.0000
Furfural 0.0000 24484.7602
Air 0.0000 10450.8423
Total
Sigma Q Reaktan = 13121090.1172
Total Panas
Neraca Panas Pada R-01
Q1 + Qw-in = Q2 +Qr + Qw-out
Qs = Qin - Qout
= Q1 - Q2 - Qr
20769208.7103
Cp air = 4.1860
T1 = 28.0000
T2 = 48.0000
T ref = 25.0000
Jumlah Air Pendingin Yang Dibutuhkan
m= 248079.4160 Kg/h
Panas Sensibel Yang Dibawa Oleh Air Pendingin Masuk
= 3115381.3065 kJ/h
Panas Sensibel Yang Dibawa Oleh Air Pendingin Keluar
= 23884590.0169 kJ/h
Neraca Panas Reaktor-01 (R-01)

Komponen Panas Masuk (kJ) Panas Keluar (kJ)
Q in 912,154,161.1049 0.0000
Q out 0.0000 911,878,222.4502
Qr 0.0000 -20,493,270.0557
Qw-in 3,115,381.3065 0.0000
Qw-out 0.0000 23,884,590.0169
Total 915,269,542.4114 915,269,542.4114
Output Komponen Bm
Kmol Kg Air 18
41078.5664 739414.1950 Asam Sulfat 98
483.0797 47341.8150 Pentosan 132
127.0219 16766.8928 Selulosa 162
99.8464 16175.1201 Lignin -
24657.1953 Abu -
6164.2988 Pentosa 150.0000
34.0718 5110.7641 Furfural 96.0000
143.6814 25862.6582 Toluena 92.0000
25.7033 2467.5128 Glukosa 180.0000
0.0000 0.0000 Xylena 106.0000
0.0000 0.0000
41991.9709 883960.4523
C D
-0.0002 5.3469.E-07
-0.0014 1.0342.E-06
-0.0018 1.9630.E-06
-0.0015 1.9773.E-06
-0.0022 2.5061.E-06
C 298.1500 K
C 433.1500 K
C 433.1500 K
ANAS MASUK
Panas Sensibel reaksi pertama

Q (kJ) Komponen
7,638,406.8369 Pentosan
430,626,048.2421 Air
9,533,133.8686 Asam sulfat
0.0000 Pentosa
447,797,588.9475 Total
Panas Sensibel reaksi kedua

Q (kJ) Komponen
12,351,611.0428 Selulosa
430,001,348.9458 Air
9,533,133.8686 Asam sulfat
0.0000 Glukosa
Glukosa
451,886,093.8571 Total
Panas Sensibel reaksi ketiga

Q (kJ) Komponen
2,937,344.4317 Pentosa
9,533,133.8686 Asam sulfat
0.0000 Furfural
0.0000 Furfural
Air
12,470,478.3002 Total
Panas sensibel inert

Q (KJ) Komponen
0.0000 Toluena
0.0000 Xylena
0.0000 Total
Qout
kJ -275938.6546
25.0000 298.1500 K Panas Pembentukan Standar Produk Re

n Komponen
-38,767,686.2967 625246.6983 Pentosan
-14,453,599.5845 Air
0.0000 Pentosa
-53,221,285.8812 Total

n Komponen
-99349964.6739 Selulosa
-34742170.8532 Air
0.0000 -20931511.3726 Glukosa
-134092135.5270 Total

n Komponen
-22616296.8486 88933.2732 Pentosa
0.0000 Furfural
0.0000 Air
-22616296.8486 Total
kJ/h Signa n Hf Produk

-20217331.4011
= -20217331.4011 kJ/h
C 433.1500 K
Panas Produk Reaksi Pertama
Q (kJ) Komponen
2444290.1878 Pentosan
624699.2963 Air
0.0000 Pentosa
3068989.4841 Total
Panas Reaktan Reaksi Kedua

Q (kJ) Komponen
7287450.5153 Selulosa
1501592.0122 Air
0.0000 Glukosa
8789042.5274 Total
Panas Reaktan Reaksi Ketiga

Q (kJ) Komponen
1263058.1056 Pentosa
0.0000 Furfural
0.0000 Air
1263058.1056 Total
kJ/h Sigma Q Produk
Delta QR = -275938.6546
Delta HR = -20493270.0557 kJ/h EKSO
kJ/h
kJ/kg K
C = 301.1500 K
C = 321.1500 K
C = 298.1500 K
Buat ngitung panas aliran GLUKOSA :
tabel 8.2 Heat capacities of the element, j/mol oC (Coulson hal 322)
Element Solid Liquid
c 7.5 11.7
h 9.6 18
b 11.3 19.7
si 15.9 24.3
o 16.7 25.1
f 20.9 29.3
p and s 22.6 31
all others 26 33.5
Cp glukosa 436.8000
Cp dt glukosa 58968.0000
Cp pentosan 302.9000
Cp Dt Pentosan 40891.5000
Cp selulosa 375.7000
Cp dt selulosa 50719.5000
Cp pentosa 364.0000
Cp dt pentosa 49140.0000
PANAS KELUAR
sibel reaksi pertama

Kmol Cp dT Q (kJ)
127.0219 40,891.5000 5,194,116.6491
41,145.1381 10,450.8423 430,001,348.9458
483.0797 19,734.0790 9,533,133.8686
59.7750 49,140.0000 2,937,344.4317
41,815.0147 447,665,943.8951
sibel reaksi kedua

Kmol Cp dT Q (kJ)
99.8464 50,719.5000 5,064,160.5275
41,001.4566 10,450.8423 428,499,756.9336
483.0797 19,734.0790 9,533,133.8686
143.6814 58,968.0000 8,472,606.8274
0.0000 58,968.0000 0.0000
41,728.0642 451,569,658.1571
sibel reaksi ketiga

Kmol Cp dT Q (kJ)
34.0718 49,140.0000 1,674,286.3261
483.0797 19,734.0790 9,533,133.8686
25.7033 24,484.7602 629,338.1112
0.0000 24,484.7602 0.0000
77.1098 10,450.8423 805,862.0922
619.9645 12,642,620.3980
Kmol Cp Dt Q(KJ)
0.0000 22918.0045 0.0000
0.0000 26229.4395 0.0000
0.0000
= Q1+Q2+Q3+Q4
= 911878222.4502 kJ
mbentukan Standar Produk Reaksi Pertama pada T = 25.0000 298.1500 K

Mol (kmol) (kJ/kmol) n
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
59.7750 -879,900.0000 -52,596,039.1829
-52,596,039.1829
mbentukan Standar Produk Reaksi Kedua pada T = 25.0000 298.1500 K

0.0000 -691460.0000 0.0000
0.0000 -241800.0000 0.0000
143.6814 -1078940.0000 -155023646.8996
-155023646.8996
mbentukan Standar Produk Reaksi Ketiga pada T = 25.0000 298.1500 K

0.0000 -879900.0000 0.0000
25.7033 -151040.0000 -3882220.1114
77.1098 -241800.0000 -18645143.4640
-22527363.5754
= -230147049.6580 kJ/h
duk Reaksi Pertama
Mol (kmol) Cp dT (kJ/kmol K) Q (kJ)
0.0000 40891.5000 0.0000
0.0000 10450.8423 0.0000
59.7750 49140.0000 2937344.4317
2937344.4317
ktan Reaksi Kedua

0.0000 50719.5000 0.0000
0.0000 10450.8423 0.0000
143.6814 58968.0000 8472606.8274
8472606.8274
ktan Reaksi Ketiga

0.0000 49140.0000 0.0000
25.7033 24484.7602 629338.1112
77.1098 10450.8423 805862.0922
1435200.2034
= 12845151.4625 kJ/h
Air 12427.155 -1974.51 -3650.9041575 3649.101
Asam sulfat 3510.54 34721.75835 -25556.3291025 7058.11
Furfural 9016.92 34929.0819 -32858.1374175 13396.9
Toluena 11299.905 25505.732925 -27381.78118125 13494.15
Xylena 9573.66 39712.332375 -40159.9457325 17103.39
Komponen ∆Hf (KJ/mol) ∆Hf (KJ/Kmol)
Pentosan -648.56 -648560.0000 YAWS
Air -241.8 -241800.0000 YAWS
Pentosa -879.9 -879900.0000
Glukosa -1078.94 -1078940.0000 Nilai awal =
Selulosa -691.46 -691460.0000
furfural -151.04 -151040.0000 YAWS
sulfat -735.13 -735130.0000 YAWS
-1078.9400
Trial Tekanan Dengan Penen
Komponen ANTA ANTB

Air 18.3036 3816.44
Furfural 18.7949 5365.88
Asam Sulfat 2.0582 -4192.4
Glukosa 254.41 -31423
1 Kpa = 7.500617 mmHg
Kondisi Oprasi :
T 160 C
P 7.7054 atm
Komponen kmol kg
Air 41078.5664 739414.1950
H2SO4 483.0797 47341.8150
Furfural 25.7033 2467.5128
Glukosa 143.6814 25862.6582034
Total 41731.0308 815086.1810
Rumus Antoine Untuk Air dan Furfural (Sumber buku Coulson)

Ln (Pi) = ANTA - ANTB/(T+ANTC)
Pi = exp (ANTA - (ANTB/(T+ ANTC)))
Rumus Antoine untuk asam sulfat (Sumber buku Yaws)

log 10 P = A+B/T+C log 10 T +DT+ET^2
P= 10^(A+B/T+C log 10 T +DT+ET^2)
Rumus antoine untuk glukosa (Sumber Hysys)

ln P = a + b/(T+c) + d ln T + e*T^f
P= exp(a + b/(T+c) + d ln T + e*T^f)
Komponen Fraksi mol T (C)

Air 0.9844
H2SO4 0.0116
160
Furfural 0.0006
Glukosa 0.0034
Air 0.9844
H2SO4 0.0116
150
Furfural 0.0006
Glukosa 0.0034
Air 0.9844
H2SO4 0.0116
170
Furfural 0.0006
Glukosa 0.0034
Tbp= Temperatur saat bagian pertama cairan mulai menguap, atau s

Trial Tekanan Dengan Penentuan Temperature Bubble Point (Tbp)
ANTC ANT D ANT E ANT F

-46.13
5.4
3.2578 -0.0011224 5.5371E-07
0 -31.006 6.2417E-18 6
433.15 K
mmHg Komponen
Air
BM Fraksi mol Asam Sulfat
18 0.9844 Pentosan
98 0.0116 Selulosa
96 0.0006 Lignin
180 0.0034 Abu
1.0000 Furfural
Glukosa
T (K) Pi (mmhg) Pi (atm) P (atm)

4640.1759 6.1055
3.8610 0.0051
433 6.0107
705.8457 0.9287
0.0133 0.0000
3572.2609 4.7003
2.1449 0.0028
423.15 4.6273
530.5357 0.6981
0.0049 0.0000
5948.4459 7.8269
6.7768 0.0089
443 7.7054
927.2059 1.2200
0.0339205641 4.463232117E-05
tama cairan mulai menguap, atau saat bagian ap terakhir terembunkan

*Tmin dan Tmax dlm Celcius
*Sumber: Coulson Vol. 6, Appendix D
Note : 1 atm = 760 mmHg
Bm
18
98
132
162
-
-
96
180
Komponen B C
Furfural 18.7949 5365.88 5.4
H2O 18.303 3816.44 -46.13
Asam Sulfat 9.784 3883 0
Rumus Antoine Pi* (bar) = exp [A-(B/(T+C))]

1 atm =
1 atm =
Komponen Temperatur ( C ) Temperatur (K) Tekanan Uap (mmhg) Tekanan ATM

FURFURAL
0.0 273.2 0.6 0.0

20.0 293.2 2.3 0.0
40.0 313.2 7.0 0.0
60.0 333.2 19.0 0.0
80.0 353.2 46.0 0.1
100.0 373.2 101.5 0.1
120.0 393.2 206.7 0.3
140.0 413.2 393.4 0.5
160.0 433.2 705.8 0.9
180.0 453.2 1203.6 1.6
200.0 473.2 1962.8 2.6
220.0 493.2 3077.7 4.0
H2O
Temp (C) Temp (K) P (bar) P (atm)

0 273.15 4.4 0.0
20 293.15 17.3 0.0
40 313.15 55.2 0.1
60 333.15 149.3 0.2
80 353.15 355.1 0.5
100 373.15 759.5 1.0
120 393.15 1488.1 2.0
140 413.15 2709.6 3.6
160 433.15 4637.4 6.1
180 453.15 7528.6 9.9
Asam Sulfat
Temp (C) Temp (K) P (bar) P (atm)
0 273.15 0.0 0.0
20 293.15 0.0 0.0
40 313.15 0.1 0.0
60 333.15 0.2 0.0
80 353.15 0.3 0.0
100 373.15 0.5 0.0
120 393.15 0.9 0.0
140 413.15 1.5 0.0
160 433.15 2.3 0.0
180 453.15 3.4 0.0
200 473.15 4.8 0.0
220 493.15 6.8 0.0
240 513.15 9.2 0.0
260 533.15 12.2 0.0
280 553.15 15.9 0.0
300 573.15 20.3 0.0
320 593.15 25.5 0.0
340 613.15 31.5 0.0
360 633.15 38.5 0.1
380 653.15 46.5 0.1
400 673.15 55.5 0.1
273.15
Coulson Vol. 6, Appendix D
760 mmhg
1.01325 bar
Diagram Fasa Furfural

4.5
4.0 12; 4.0

Tekanan (atm)
3.5
3.0
2.5 11
2.0
1.5 10
1.0 9
0.5 8
7
5 6
0.0 1 2 3 4
0.0 50.0 100.0 150.0 200.0 250.0
Tempereture (C)
Diagram Fasa H2O

11.0
Tekanan (atm)
10.0 10
9.0
8.0
7.0
6.0 9
5.0
4.0
8
3.0
2.0
8.0
Te
7.0
6.0 9
5.0
4.0
8
3.0
2.0 7
1.0 6
5
0.0 1 2 3 4
0 20 40 60 80 100 120 140 160 180
Temperatur (C)
Diagram Fasa H2SO4

0.1
2
0.1
Tekanan (atm)
0.1 20
0.1 19
18
0.0
17
0.0
16
0.0 15
14
13
0.0 12
11
10
8 9
3 4 5 6 7
0.0 1 2
0 50 100 150 200 250 300 350 400
Temperetur (C)
12; 4.0
11
00.0 250.0
10
8
9
0 160 180 200
21; 0.1
20
19
18
Colum
nE
17
350 400 450

ROTARY DRUM FILTER-01
Fungsi = Memisahkan aliran keluran reaktor dari padatan

T = 70 °C
P = 1 atm
Input Output
Komponen Aliran 8 Aliran 12 (to waste treatment)
Kmol Kg Kmol Kg
Air 41078.5664 739414.1950 41.0786 739.4142
Asam Sulfat 483.0797 47341.8150 0.4831 47.3418
Pentosa 34.0718 5110.7641 34.0718 5110.7641
Glukosa 143.6814 25862.6582 0.1437 25.8627
Pentosan 127.0219 16766.8928 127.0219 16766.8928
Selulosa 99.8464 16175.1201 99.8464 16175.1201
Lignin - 24657.1953 - 24657.1953
Abu - 6164.2988 - 6164.2988
Furfural 25.7033 2467.5128 0.0257 2.4675
Subtotal 41991.9709 883960.4523 302.6711 69689.3574
Total 883960.4523 883960.4523
0.0788
1
Output Jumlah liquid loss 0.001 =

Aliran 10 (FEED EVAPORATOR 815.09 kg
Kmol Kg
41037.4878 738674.7808
482.5967 47294.4732
- -
143.5378 25836.7955
- -
- -
- -
- -
25.6776 2465.0453
41689.2998 814271.0949
883960.4523 BALANCE
% kg yg diwaste
0.1
ROTARY DRUM FILTER-01
Fungsi = Memisahkan aliran keluran reaktor dari padatan

T = 70 °C
P = 1 atm
Input Output
Komponen Aliran 8 Aliran 12 (to waste treatment)
Kmol Kg Kmol Kg
Air 41078.5664 739414.1950 41.0786 739.4142
Asam Sulfat 483.0797 47341.8150 0.4831 47.3418
Pentosa 34.0718 5110.7641 34.0718 5110.7641
Glukosa 143.6814 25862.6582 0.1437 25.8627
Pentosan 127.0219 16766.8928 127.0219 16766.8928
Selulosa 99.8464 16175.1201 99.8464 16175.1201
Lignin - 24657.1953 - 24657.1953
Abu - 6164.2988 - 6164.2988
Furfural 25.7033 2467.5128 0.0257 2.4675
Toluene 0.0000 0.0000 0.0000 0.0000
Xylane 0.0000 0.0000 0.0000 0.0000
Subtotal 41991.9709 883960.4523 302.6711 69689.3574
Total 883960.4523 883960.4523
0.0788
1
Output Jumlah liquid loss 0.001 =

Aliran 10 (FEED EVAPORATOR 815.09 kg
Kmol Kg Fraksi mol
41037.4878 738674.7808 0.984365 Komponen Bm
482.5967 47294.4732 0.011576 Air 18
- - Asam Sulfat 98
143.5378 25836.7955 0.003443 Pentosa 150
- - Glukosa 180
- - Pentosan 132
- - Selulosa 162
- - Lignin -
25.6776 2465.0453 0.000616 Abu -
0.0000 0.0000 Furfural 96
0.0000 0.0000 Toluene 92
41689.2998 814271.0949 Xylane 106
883960.4523 BALANCE
% kg yg diwaste
0.1
Input yang mau dipanaskan (dari RDF-01)
Output
Komponen Aliran 11 (MENUJU HE-02)
Kmol
Air 41037.4878
Asam Sulfat 482.5967
Glukosa 143.5378
Furfural 25.6776
Toluena 0.0000
Xylena 0.0000
Total 41689.2998
Senyawa A
Air 92.0530
Asam sulfat 26.0040
Furfural 66.7920
Toluene 83.7030
Xylene 70.9160
Cp glukosa = 436.8
Input yang mau diambil panasnya (dari bottom EV-01)
Komponen Aliran 14
Kmol
Air 41.0375
Glukosa 143.5378
Furfural 25.6519
Toluena 0.0000
Xylena 0.0000
Total 692.8238
CP Dt pada aliran 11
Komponen A.T
Air 4142.385
Asam sulfat 1170.18
Furfural 3005.64
Toluena 3766.635
Xylena 3191.22
Glukosa 19656
Kondisi Operasi
T C
T ref 25
Tin yg mau dipanaskan 70
Tout setelah dipanaskan 71.2311189467
Tin yg mau diambil panas 100
Tout setelah diambil panas 72
Komponen A.T
Air 6903.975
Asam sulfat 1950.3
Furfural 5009.4
Toluena 6277.725
Xylena 5318.7
Glukosa 32760
PANAS MASUK
Input yang mau dipanaskan
Komponen
Air
As.Sulfat
Glukosa
Furfural
Toluena
Xylena
Total
Input yg mau diambil panasnya

Komponen
Air
Asam Sulfat
Glukosa
Furfural
Toluena
Xylena
Total
Aliran
Q10
Q13
Q11
Q14
Total
Output
an 11 (MENUJU HE-02) Komponen
Kg mol
738674.7808 41037487.8244019 Air
47294.4732 482596.665319394 Asam Sulfat
25836.7955 143537.753028639 Glukosa
2465.0453 25677.5548946455 Furfural
0.0000 0 Toluena
0.0000 0 Xylena
814271.0949 Total
B C D
-0.0400 -0.0002 5.3469.E-07
0.7034 -0.0014 1.0342.E-06
0.7076 -0.0018 1.9630.E-06
0.5167 -0.0015 1.9773.E-06
0.8045 -0.0022 2.5061.E-06
Aliran 14 Komponen
Kg mol
738.6748 41037.487824402 Air
47294.4732 482596.665319394 Asam Sulfat
25836.7955 143537.753028639 Glukosa
2462.5802 25651.8773397509 Furfural
0.0000 0 Toluena
0.0000 0 Xylena
76332.5238 Total
1/2 BT^2 1/3 CT^3 1/4 DT^4

-576.49182525 -977.9832428704 797.1525703229
10149.1015725 -6421.33147572 1541.8563807589
10209.4158375 -8379.8005011525 2926.5752034709
7455.016305 -6909.7901488875 2947.8200820494
11608.331625 -10142.237250731 3736.2659793268
K delta T
298.15 0
343.15 45
344.3811189467 46.2311189467
373.15 75
345 47 suhu menuju KE
1/2 BT^2 1/3 CT^3 1/4 DT^4

-1005.76683375 -1790.5316090756 1535.3615242613
17706.4605375 -11756.4355662 2969.7037318652
17811.6868125 -15342.080536088 5636.751523546
13006.269675 -12650.725627313 5677.6703769391
20252.281875 -18568.821619969 7196.2623500554
Q11
KMol Cp.dT (J/mol.K) Q = n.Cp.dT (kJ)
41,037.4878 3,385.0625 138,914,461.2190
482.5967 6,439.8065 3,107,829.1314
143.5378 19,656.0000 2,821,378.0735
25.6776 7,761.8305 199,304.8298
0.0000 7,259.6812 0.0000
0.0000 8,393.5804 0.0000
41,689.2998 145,042,973.2536
Q14
KMol Cp.dT (J/mol.K) Q = n.Cp.dT (KJ)
41.0375 5,643.0381 231,576.1066
482.5967 10,870.0287 5,245,839.6041
143.5378 32,760.0000 4,702,296.7892
25.6519 13,115.7578 336,443.8103
0.0000 12,310.9394 0.0000
0.0000 14,198.4226 0.0000
10,516,156.3102
Panas input yang diserap oleh fluida

-134,526,816.94
155,559,129.5638
155,559,129.5636
Q=
Q in Q out
145,042,973.2536 0.0000
10,516,156.3102 0.0000
0.0000 149,010,278.2389
0.0000 6,548,851.3247
155,559,129.5638 155,559,129.5636
Output
Aliran 12 (FEED EVAPORATOR)
Kmol Kg mol
41037.4878 738674.7808 41037487.8244
482.5967 47294.4732 482596.6653194
143.5378 25836.7955 143537.7530286
25.6776 2465.0453 25677.55489465
0.0000 0.0000 0
0.0000 0.0000 0
41689.2998 814271.0949
diambil panasnya
Aliran 15
Kmol Kg mol
41.0375 738.6748 41037.4878244
482.5967 47294.4732 482596.6653194
143.5378 25836.7955 143537.7530286
25.6519 2462.5802 25651.87733975
0.0000 0.0000 0
0.0000 0.0000 0
692.8238 76332.5238
Air 4255.7131924 -593.4005858237 -1008.68543653 823.8943657523
Asam sulfat 1202.1940170898 10446.77921685 -6622.91873597 1593.5804916139
Furfural 3087.8688966876 10508.86252596 -8642.87071188 3024.75198708
Toluena 3869.6833491951 7673.675235194 -7126.71177492 3046.7095600886
Xylena 3278.5260312237 11948.80913311 -10460.6362974 3861.6051731132
Glukosa 20193.7527559158
Air 4326.491 -603.99147515 -1027.97184181 840.7417851308
Asam sulfat 1222.188 10633.2311435 -6749.55117285 1626.1668521616
Furfural 3139.224 10696.4225025 -8808.12531087 3086.603684774
Toluena 3934.041 7810.633383 -7262.97690438 3109.0102576258
Xylena 3333.052 12162.068975 -10660.6471866 3940.5692788651
Glukosa 20529.6
PANAS KELUAR
Input setelah dipanaskan Q12
Komponen Kmol Cp.dT (J/mol.K) Q = n.Cp.dT (KJ)
Air 41,037.4878 3,477.5215 142,708,747.6845
As.Sulfat 482.5967 6,619.6350 3,194,613.7716
Glukosa 143.5378 20,193.7528 2,898,565.8958
Furfural 25.6776 8,114.1249 208,350.8869
Toluena 0.0000 7,590.7077 0.0000
Xylena 0.0000 8,775.0431 0.0000
Total 149,010,278.2389
Input setelah diambil panasnya Q15

Komponen KMol Cp.dT (J/mol.K) Q = n.Cp.dT (KJ)
Air 41.0375 3,535.2695 145,078.5778
Asam Sulfat 482.5967 6,732.0348 3,248,857.5563
Glukosa 143.5378 20,529.6000 2,946,772.6546
Furfural 25.6519 8,114.1249 208,142.5360
Toluena 0.0000 7,590.7077 0.0000
Xylena 0.0000 8,775.0431 0.0000
Total 6,548,851.3247
Panas yang dilepas oleh fluida panas

-142,461,426.91
3,967,304.99
KESETIMBANGAN VA
Input (11)
komponen BM
xi kmol kg
air 18.0000 0.9844 41037.4878 738674.7808

Asam sulfat 98.0000 0.0116 482.5967 47294.4732
Glukosa 180.0000 0.0034 143.5378 25836.7955
Furfural 96.0000 0.0006 25.6776 2465.0453
1.0000 41689.2998 814271.0949
TOTAL 814271.0949
Komponen ANTA ANTB ANTC ANT D

Air 18.3036 3816.4400 -46.1300
Furfural 18.7949 5365.8800 5.4000
Asam sulfat 2.0582 -4192.4000 3.2578 -0.0011
Glukosa 254.4100 -31423.0000 0.0000 -31.0060
1 atm = 101.325 kPa
Kondisi Operasi : T 100 C 373.15

P 1 atm 101.325
760 mmHg
Asam Sulfat ( mmHg) : Sumber buku Yaws Glukosa (kPa) : Sumber dari hys
log 10 P = A+B/T+C log 10 T +DT+ET^2 ln P =
P = 10^(A+B/T+C log 10 T +DT+ET^2) P=
Komponen Pi (mmHg) kmol BM ki (Pisat/P)

Air 759.9430 41037.4878 18.0000 0.9999
Asam sulfat 0.0724 482.5967 98.0000 0.0001
Glukosa 0.0000 143.5378 180.0000 0.0000
Furfural 101.5016 25.6776 96.0000 0.1336
41689.2998
Light key = Air
Heavy key = Furfural
ref = Furfural Kref =
komponen Ki α = Ki/Kref Log α

Air 0.9999 7.4870 0.8743
Asam sulfat 0.0001 0.0007 -3.1465
Glukosa 0.0000 0.0000 -6.9510
Furfural 0.1336 1.0000 0.0000
Diinginkan distribusi LK = 0.999 Diinginkan distribusi HK =

0.001
Komponen LK (air) Komponen HK ( Furfural)

LK (D) = 40996.4503 HK (D) = 0.0257
LK (B) = 41.0375 HK (B) = 25.6519
Log (D/B) = 2.9996 Log (D/B) = -2.9996
komponen X = Log α Y = Log Di/Bi XY X^2

air 0.8743 2.9996 2.6225 0.7644
Furfural 0.0000 -2.9996 0.0000 0.0000
total 0.8743 0.0000 2.6225 0.7644
slope = 6.8616
intersept = -2.9996
komponen X = Log α Y = Log Di/Bi Di/Bi D (kmol)

Air 0.8743 2.9996 999.0000 40996.4503
Asam sulfat -3.1465 -24.5894 0.0000 0.0000
Glukosa -6.9510 -50.6944 0.0000 0.0000
Furfural 0.0000 -2.9996 0.0010 0.0257
total -9.2232 40996.4760
KESETIMBANGAN VAPOR-LIQUID PADA EVAPORATOR
ouput
top (Utilitas) bottom (13)
xi kmol kg xi kmol
1.0000 40996.4503 737936.1061 0.0592 41.0375

0.0000 0.0000 0.0000 0.6966 482.5967
0.0000 0.0000 0.0000 0.2072 143.5378
0.0000 0.0257 2.4650 0.0370 25.6519
1.0000 40996.4760 737938.5711 1.0000 692.8238
814271.0949
ANT E ANT F
0.0000
0.0000 6.0000
1 Kpa = 7.500617 mmHg
K
kPa
(kPa) : Sumber dari hysys

a + b/(T+c) + d ln T + e*T^f furfural
exp(a + b/(T+c) + d ln T + e*T^f) 1.88E+01
5.37E+03
Fraksi (xf) Yi 4.62E+00 3.79E+02
0.9844 0.9843 101.501645473
0.0116 0.0000 4.62E+00
0.0034 0.0000 GLUKOSA
0.0006 0.0001 2.54E+02
0.9844 -8.42E+01
-1.84E+02
1.69E-02 3.73E+02
-1.34E+01 5.9219804836
0.1335547967 1.51487155E-06 2.70E+15
1.13624713E-05
0.999
0.001
B (kmol)
41.0375
482.5967
143.5378
25.6519
692.8238
ttom (13)
kg
738.6748
47294.4732
25836.7955
2462.5802
76332.5238
kemurnian furfural = 3.702511
Air dan Furfural (mmHg) : Sumber dari Coulson and Richardson

ln P = ANT A -(ANTB/(T+ANTC))
P= EXP(ANT A -(ANTB/(T+ANTC)))
Input (11)
komponen BM
xi kmol kg
air 18.0000 0.9844 41037.4878 738674.7808

Asam sulfat 98.0000 0.0116 482.5967 47294.4732
Glukosa 180.0000 0.0034 143.5378 25836.7955
Furfural 96.0000 0.0006 25.6776 2465.0453
Toluene 92.0000 0.0000 0.0000 0.0000
Xylene 106.0000 0.0000 0.0000 0.0000
1.0000 41689.2998 814271.0949
TOTAL 814271.0949
Komponen ANTA ANTB ANTC ANT D

Air 18.3036 3816.4400 -46.1300
Furfural 18.7949 5365.8800 5.4000
Asam sulfat 2.0582 -4192.4000 3.2578 -0.0011
Glukosa 254.4100 -31423.0000 0.0000 -31.0060
Toluene 16.0137 3096.52 -53.67
Xylene 16.1169 3369.74 -58.45
1 atm = 101.325 kPa
Kondisi Operasi : T 100.442297328 C 373.592297328

P 1 atm 101.325
760 mmHg
Asam Sulfat ( mmHg) : Sumber buku Yaws Glu

log 10 P = A+B/T+C log 10 T +DT+ET^2 ln P =
P = 10^(A+B/T+C log 10 T +DT+ET^2) P=
Komponen Pi (mmHg) kmol BM ki (Pisat/P)

Air 772.0169 41037.4878 18.0000 1.0158
Asam sulfat 0.0749 482.5967 98.0000 0.0001
Glukosa 0.0000 143.5378 180.0000 0.0000
Furfural 103.1947 25.6776 96.0000 0.1358
Toluene 563.8142 0.0000 92.0000 0.7419
Xylene 226.8169 0.0000 106.0000 0.2984
41689.2998
Light key = Air

Heavy key = Furfural
ref = Furfural Kref =
komponen Ki α = Ki/Kref Log α

Air 1.0158 7.4812 0.8740
Asam sulfat 0.0001 0.0007 -3.1390
Glukosa 0.0000 0.0000 -6.9308
Furfural 0.1358 1.0000 0.0000
Toluene 0.7419 5.4636 0.7375
Xylene 0.2984 2.1980 0.3420
Diinginkan distribusi LK = 0.999 Diinginkan distribusi HK =

0.001
Komponen LK (air) Komponen HK ( Furfural)

LK (D) = 40996.4503 HK (D) = 0.0257
LK (B) = 41.0375 HK (B) = 25.6519
Log (D/B) = 2.9996 Log (D/B) = -2.9996
komponen X = Log α Y = Log Di/Bi XY X^2

air 0.8740 2.9996 2.6215 0.7638
Furfural 0.0000 -2.9996 0.0000 0.0000
total 0.8740 0.0000 2.6215 0.7638
slope = 6.8642
intersept = -2.9996
komponen X = Log α Y = Log Di/Bi Di/Bi D (kmol)

Air 0.8740 2.9996 999.0000 40996.4503
Asam sulfat -3.1390 -24.5464 0.0000 0.0000
Glukosa -6.9308 -50.5741 0.0000 0.0000
Furfural 0.0000 -2.9996 0.0010 0.0257
Toluene 0.7375 2.0627 115.5209 0.0000
Xylene 0.3420 -0.6519 0.2229 0.0000
total -8.1163 40996.4760
KESETIMBANGAN VAPOR-LIQUID PADA EVAPORATOR
ouput
top (Utilitas)
xi kmol
1.0000 40996.4503
0.0000 0.0000
0.0000 0.0000
0.0000 0.0257
0.0000 0.0000
0.0000 0.0000
1.0000 40996.4760
814271.0949
0.9990
0.001
ANT E ANT F
0.0000
0.0000 6.0000
K Di lampiran, tulis temperatur 132,5 C

kPa Di lampiran, tulis tekanan 1 atm,
Glukosa (kPa) : Sumber dari hysys

a + b/(T+c) + d ln T + e*T^f
exp(a + b/(T+c) + d ln T + e*T^f)
Fraksi (xf) Yi
0.9844 0.9999
0.0116 0.0000
0.0034 0.0000
0.0006 0.0001
0.0000 0.0000
0.0000 0.0000
1.0000
0.1358
0.999
0.001
B (kmol)
41.0375
482.5967
143.5378
25.6519
0.0000
0.0000
692.8238
ut
bottom (13)
kg xi kmol kg
737936.1061 0.0592 41.0375 738.6748

0.0000 0.6966 482.5967 47294.4732
0.0000 0.2072 143.5378 25836.7955
2.4650 0.0370 25.6519 2462.5802
0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000
737938.5711 1.0000 692.8238 76332.5238
0949
1 Kpa = 7.500617 mmHg
Air dan Furfural (mmHg) : Sumber dari Coulson

ln P = ANT A -(ANTB/(T+ANTC))
furfural P= EXP(ANT A -(ANTB/(T+ANTC)))
1.88E+01
5.37E+03
4.64E+00 3.79E+02
103.194703468
4.64E+00
GLUKOSA
2.54E+02
-8.41E+01
-1.84E+02
1.70E-02 3.74E+02
-1.33E+01 5.9231650887
1.6135192E-06 2.72E+15
1.21023896E-05
3.23%
kemurnian furfural = 3.702511
(mmHg) : Sumber dari Coulson and Richardson

NTB/(T+ANTC))
-(ANTB/(T+ANTC)))
Kondisi operasi :
T in = 70 C 343.15
T out = 132.5 C 405.65
T ref = 25 C 298.15
Panas Sensibel Masuk EV-01 (Q12)

Komponen Kmol Cp. Dt (KJ/Kmol K) Q (KJ)
Air 41,037.4878 3,385.0625 138,914,461.2190
Asam sulfat 482.5967 6,439.8065 3,107,829.1314
Glukosa 143.5378 19,656.0000 2,821,378.0735
Furfural 25.6776 7,761.8305 199,304.8298
0.0000 7,259.6812 0.0000
0.0000 8,393.5804 0.0000
Total 145,042,973.2536
Panas Sensibel Keluar EV-01 (top)

Komponen Kmol Cp. Dt Q (kJ)
Air 40,996.4503 8,116.4130 332,744,122.4162
Asam sulfat 0.0000 15,772.4542 0.0000
Glukosa 0.0000 0.0000 0.0000
Furfural 0.0257 19,098.3454 490.3988
Toluene 0.0000 18,018.8047 0.0000
Xylene 0.0000 20,710.7797 0.0000
Total 332,744,612.8150
Panas Sensibel Keluar EV-01 (bottom)

Komponen Kmol Cp. Dt Q (KJ)
Air 41.0375 8,116.4130 333,077.1996
Asam sulfat 482.5967 15,772.4542 7,611,733.8223
Glukosa 143.5378 46,956.0000 6,739,958.7312
Furfural 25.6519 19,098.3454 489,908.4132
Toluene 0.0000 18,018.8047 0.0000
Xylene 0.0000 20,710.7797 0.0000
Total 15,174,678.1662
Menghitung panas laten keluar EV-01

Rumus : Hv = A*(1-T/Tc)^n
Data dari buku Yaws :

Komponen A Tc n
Air 52.053 647.13 0.321
Furfural 59.186 657 0.313
Toluene 50.139 591.79 0.383
Xylene 60.216 617.05 0.458
Panas laten keluar EV-01

Komponen Kmol Hv (KJ/mol) Q (4) (KJ)
Air 40,996.4503 37.9334 1,555,136,777.0467
Asam sulfat 0.0000 0.0000 0.0000
Glukosa 0.0000 0.0000 0.0000
Furfural 0.0257 43.8135 1,125.0245
Toluene 0.0000 32.1947 0.0000
Xylene 0.0000 36.8675 0.0000
Total 1,555,137,902.0712
Panas yang diberikan steam :

Qsteam = Q keluar - Q masuk
= 1,758,014,219.7988 kJ
Steam yang digunakan yaitu saturated steam (T = 370)



= 452.6000 kJ/kg
Jadi jumlah steam yang dibutuhkan :

m = Qs / panas laten
= 3,884,255.8988 kg
Qs in = m . Hv = 9,100,034,719.7184
Qs o = m . HI = 7,342,020,499.9196
Neraca panas Evaporator -01

Panas Q in Q out
Q1 145,042,973.2536
Q2 332,744,612.8150
Q3 15,174,678.1662
Q4 1,555,137,902.0712
Qs in 9,100,034,719.7184
Qs out 7,342,020,499.9196
Total 9,245,077,692.9720 9,245,077,692.9720
C
K Senyawa
K Air
K Asam sulfat
Furfural
Toluene
Xylene
Buat ngitung panas aliran output

tabel 8.2 Heat capacities of the element, j/m
Element
c
h
b
si
o
f
p and s
all others
Cp glukosa
Cp dt glukosa
Cp dT pada aliran input T= 70 C

Komponen
Air
Asam sulfat
Furfural
Toluene
Xylene
,Kj/mol T, K Cp dT pada aliran input T= 132,5 C

Komponen
Air
Asam sulfat
Furfural
Toluene
Xylene
MOL Opsional Q (4) (KJ) PAKE YANG INI

40996450.34 1,555,136.7770
0 0.0000
0 0.0000
25.67755489 1.1250
0 0.0000
0 0.0000
1,555,137.9021
Panas yang diberikan steam :

Q untuk ngitung spek Evaporator :
204,431,455.6297
MANIPULASI UNTUK NGITUNG SPEK EVAPORATOR

Steam yang digunakan yaitu saturated steam (T = 370)
H saturated vapor (Hv) =

H saturated liquid (Hl) =
Panas laten (λ) =

=
kJ Jadi jumlah steam yang dibutuhkan :

kJ m =
=
Qs in =
Qs o =
Neraca panas Evaporator -01

Panas Q in
Q1 145,042,973.2536
Q2
Q3
Q4
Qs in 1,058,201,533.9133
Qs out
Total 1,203,244,507.1670
Liquid
A B C D
9.21E+01 -4.00E-02 -2.11E-04 5.35E-07
2.60E+01 7.03E-01 -1.39E-03 1.03E-06
6.68E+01 7.08E-01 -1.81E-03 1.96E-06
8.37E+01 5.17E-01 -1.49E-03 1.98E-06
7.09E+01 8.05E-01 -2.19E-03 2.51E-06
ung panas aliran output

Heat capacities of the element, j/mol oC (Coulson hal 322)
Solid Liquid
7.5 11.7
9.6 18
11.3 19.7
15.9 24.3
16.7 25.1
20.9 29.3
22.6 31
26 33.5
436.8
19656
46956
a aliran input T= 70 C
A.T 1/2 BT^2 1/3 CT^3 1/4 DT^4
4142.385 -576.49182525 -977.98324 797.1525703229
1170.18 10149.1015725 -6421.3315 1541.856380759
3005.64 10209.4158375 -8379.8005 2926.575203471

3766.635 7455.016305 -6909.7901 2947.820082049
3191.22 11608.331625 -10142.237 3736.265979327
a aliran input T= 132,5 C

A.T 1/2 BT^2 1/3 CT^3 1/4 DT^4
9895.6975 -1511.39202525 -2831.102 2563.209572055
2795.43 26607.9595725 -18588.708 4957.772427797
7180.14 26766.0858375 -24258.156 9410.27584197
8998.0725 19544.860305 -20002.716 9478.587829106
7623.47 30433.631625 -29360.123 12013.80147099
PAKE YANG INI
K EVAPORATOR
ed steam (T = 370)
ess, 1984) Appendix F, hal.691
2,342.8000 kJ/Kg
1,890.2000 kJ/Kg
Hv - Hl
452.6000 kJ/kg
kJ
Qs / panas laten kJ
451,682.4031 kg
m . Hv = 1,058,201,533.9133
m . HI = 853,770,078.2837
Q out
332,744,612.8150
15,174,678.1662
1,555,137.9021
853,770,078.2837
1,203,244,507.1670
Input : Keluaran Reboiler-01 (dari bottom RB-01)
Komponen Mol (kmol)

Air 41.0375
Asam sulfat 482.5967
Glukosa 143.5378
Furfural 25.6519
Total 667.1719
T in chiller -03 = 132.5 C 405.65

T out chiller-03 = 30 C 303.15
Tref 25 C 298.15
Panas sensibel masuk chiller-03 405.6500 K

Komponen Mol (kmol) Cp dT (kJ/kmol K) Q1 (kJ)
Air 41.0375 8,116.4130 333,077.1996
Asam sulfat 482.5967 15,772.4542 7,611,733.8223
Glukosa 143.5378 46,956.0000 6,739,958.7312
Furfural 25.6519 19,098.3454 489,908.4132
Total 667.1719 15,174,678.1662
Panas sensibel keluaran Chiller-03

Air 41.0375 377.4864 15,491.0928
Asam sulfat 482.5967 701.6579 338,617.7468
Glukosa 143.5378 2,184.0000 313,486.4526
Furfural 25.6519 847.0956 21,729.5925
Total 667.1719 689,324.8847
Qs = 14,485,353.2816 KJ
Cp Air 4.186 kJ/kg.K

T1 28 C 301.15
T2 48 C 321.15
Tref 25 C 298.15
Jumlah AMMONIA (Pendingin) Yang Dibutuhkan
Qs
m
Cp air x ( T 2  T1 )
= 173021.4200 kg/jam
Panas Sensibel Yang Dibawa Oleh Pendingin Masuk
Qwin  m x Cp air x (T1  Tref )

= 2172802.9922 kJ/jam
Panas Sensibel Yang Dibawa Oleh Pendingin Keluar

Q wout  m x Cp air x (T2  Tref )
= 16658156.2738 kJ/jam

Q1 15,174,678.1662 0.0000
Q2 0.0000 689,324.8847
Qw-in 2,172,802.9922 0.0000
Qw-out 0.0000 16,658,156.2738
0.0000
Total 17,347,481.1585 17,347,481.1585
Senyawa A
Air 9.21E+01
Asam sulfat 2.60E+01
Furfural 6.68E+01
Toluene 8.37E+01
Xylene 7.09E+01

K tabel 8.2 Heat capacities of the element, j/mol oC (Coulson
K Element Solid
K c 7.5
h 9.6
b 11.3
si 15.9
o 16.7
f 20.9
p and s 22.6
all others 26
Cp glukosa 436.8
Cp dt glukosa 46956
2184

Komponen A.T
Air 9895.6975
Asam sulfat 2795.43
Furfural 7180.14
Toluene 8998.0725
Xylene 7623.47

Komponen A.T
Air 460.265
Asam sulfat 130.02
Furfural 333.96
Toluene 418.515
K Xylene 354.58
K
K
Liquid
B C D
-4.00E-02 -2.11E-04 5.35E-07
7.03E-01 -1.39E-03 1.03E-06
7.08E-01 -1.81E-03 1.96E-06
5.17E-01 -1.49E-03 1.98E-06
8.05E-01 -2.19E-03 2.51E-06
of the element, j/mol oC (Coulson hal 322)

Liquid
11.7
18
19.7
24.3
25.1
29.3
31
33.5
1/2 BT^2 1/3 CT^3 1/4 DT^4

-1511.39202525 -2831.102048 2563.21
26607.9595725 -18588.707756 4957.772
26766.0858375 -24258.156296 9410.276

19544.860305 -20002.715982 9478.588
30433.631625 -29360.123357 12013.8
1/2 BT^2 1/3 CT^3 1/4 DT^4
-60.05934725 -95.37765253 72.65838
1057.3409525 -626.23928041 140.5362
1063.6245375 -817.23864524 266.7497

776.669145 -673.87613099 268.6861
1209.364625 -989.11999508 340.5509
Komponen Mol (kmol)

Air 41.0375
Glukosa 143.5378
Furfural 25.6519
Total 667.1719
T in chiller -03 = 132.5 C 405.65

Tref 25 C 298.15

Air 41.0375 8,116.4130 333,077.1996
Asam sulfat 482.5967 15,772.4542 7,611,733.8223
Glukosa 143.5378 46,956.0000 6,739,958.7312
Furfural 25.6519 19,098.3454 489,908.4132
Total 667.1719 15,174,678.1662

Air 41.0375 377.4864 15,491.0928
Asam sulfat 482.5967 701.6579 338,617.7468
Glukosa 143.5378 2,184.0000 313,486.4526
Furfural 25.6519 847.0956 21,729.5925
Total 667.1719 689,324.8847
Qs = 14,485,353.2816 KJ

Q1 15,174,678.1662 0.0000
Q2 0.0000 689,324.8847
Qw-in -2,647,020.1453 0.0000
Qw-out 0.0000 -1,110,937.7400
12,949,270.8763
Total 12,527,658.0209 12,527,658.0209

Senyawa A
Air 9.21E+01
Asam sulfat 2.60E+01
Furfural 6.68E+01
Toluene 8.37E+01
Xylene 7.09E+01

K tabel 8.2 Heat capacities of the element, j/mol oC (Coulson
K Element Solid
K c 7.5
h 9.6
b 11.3
si 15.9
o 16.7
f 20.9
p and s 22.6
all others 26
Cp glukosa 436.8
Cp dt glukosa 46956
2184

Komponen A.T
Air 9895.6975
Asam sulfat 2795.43
Furfural 7180.14
Toluene 8998.0725
Xylene 7623.47

Komponen A.T
Air 460.265
Asam sulfat 130.02
Furfural 333.96
Toluene 418.515
Xylene 354.58
Ammonia Cair
A B C
-1.82E+02 3.37E+00 -1.44E-02
Ammonia Keluar
T -30.0000 243.0000
Tref 25.0000 298.0000
Cp Ammonia -1,939.1048
Ammonia Masuk
T -33.0000 240.0000
Tref 25.0000 298.0000
Kebutuhan Ammonia
572.9127 Kmol
9,739.5155 Kg
Liquid
B C D
-4.00E-02 -2.11E-04 5.35E-07
7.03E-01 -1.39E-03 1.03E-06
7.08E-01 -1.81E-03 1.96E-06
5.17E-01 -1.49E-03 1.98E-06
8.05E-01 -2.19E-03 2.51E-06
of the element, j/mol oC (Coulson hal 322)

Liquid
11.7
18
19.7
24.3
25.1
29.3
31
33.5
1/2 BT^2 1/3 CT^3 1/4 DT^4

-1511.39202525 -2831.102048 2563.21
26607.9595725 -18588.707756 4957.772
26766.0858375 -24258.156296 9410.276

19544.860305 -20002.715982 9478.588
30433.631625 -29360.123357 12013.8
1/2 BT^2 1/3 CT^3 1/4 DT^4
-60.05934725 -95.37765253 72.65838
1057.3409525 -626.23928041 140.5362
1063.6245375 -817.23864524 266.7497

776.669145 -673.87613099 268.6861
1209.364625 -989.11999508 340.5509
Ammonia Gas
D A B C
2.04E-05 3.3573E+01 -1.2600E-02 8.8900E-05
Panas laten penguapan ammonia pada T =
Hv =
Komponen
Ammonia
D E
-7.1800E-08 1.8700E-11
nia pada T = -30.0000 C

243.0000 K
A*(1-T/Tc)^n ,Kj/mol T, K
A Tc n Hv (Kj/mol) Kj/Kmol
31.5230 405.6500 0.3640 22.6025 22,602.5211
0.5990 0.4010 0.7170

KOLOM EKSTRAKSI-01
Fungsi : Untuk memisahkan furfural dari air, asam sulfat dan glukosa
Komponen Masuk
Input (15)
Komponen Xi %
KMol Liquid Mass Liquid
Air 41.0375 738.6748 0.0097 0.9677
Asam Sulfat 482.5967 47294.4732 0.6196 61.9585
Glukosa 143.5378 25836.7955 0.3385 33.8477
Furfural 25.6519 2462.5802 0.0323 3.2261
Subtotal 692.8238 76332.5238 1.0000 100.0000
Total 692.8238 76332.5238 1.0000 100.0000
Banyaknya solute dan diluent yang terkandung dalam feed ekstraktor
Komponen Massa Fraksi Massa

Air 738.6748 0.0097
Asam Sulfat 47294.4732 0.6196
Glukosa 25836.7955 0.3385
Furfural 2462.5802 0.0323
Subtotal 76332.5238 1.0000
Total 76332.5238 1.0000
Diinginkan 99.9% furfural yang terekstrak dari feed, maka: =

Kadar solute dalam rafinate (XNp)
XNp = (100% - 99.9%)
XNp = 0.001 =
X 'Np = X Np/1-X Np =
RnP = (feed furfural asumsi)/(Feed Asam

Sulfat+Feed Furfural+Feed Glukosa)
RnP = 3.2576463E-05
= 0.0032576463 %
Jadi, % solute dalam ekstrak =
% solute dalam raffinate =
Jumlah solvent yang dibutuhkan (solvent : Feed = 0.4:1)

Aliran Solvent = 30533.0095
Kemurnian Toluena = 0.9900

Feed Toluena = 30227.6794
Xylena = 305.3301
Toluena yang terbawa rafinate = 30.2276794058
Toluena yang terbawa ekstrak = 30197.4517
Perhitungan Setelah Recycle

Komponen Input
Aliran 15 Aliran 32
Kmol Kg Kmol Kg
Air 41.0375 738.6748 - -
Asam Sulfat 482.5967 47294.4732 - -
Furfural 25.6519 2462.5802 0.0000 0.0000
Toluena - - 328.5617 30227.6794
Xylena - - 2.8805 305.3301
Glukosa 143.5378 25836.7955 - -
Subtotal 692.8238 76332.5238 331.4422 30533.0095
Total 106865.5333
Perhitungan Pertama
Komponen Input Output
Aliran 16 Aliran Bottom, RAFF, LIMBAH
Kmol Kg Kmol Kg
Air 41.0375 738.6748 41.0375 738.6748
Asam Sulfat 482.5967 47294.4732 482.5967 47294.4732
Furfural 25.6519 2462.5802 0.0008 0.0802
Toluena 328.5617 30227.6794 0.3286 30.2277
Xylena 2.8805 305.3301 0.0029 0.3053
Glukosa 143.5378 25836.7955 143.5378 25836.7955
Subtotal 1024.2660 106865.5333 667.5042 73900.5568
Total 106865.5333 106865.5333
KOLOM EKSTRAKSI-01
Kondisi Operasi T= 30 C
P= 1 atm 760
Solute (C) = Furfural

Solvent (S) = toluena
Diluent (D) = air
Xf (fraksi solute) = 0.0323

Fraksi diluent = 0.9677
X'f = 0.0333
0.999 99.9 % (Sumber Patent : US 2017/02333
1 Kg Furfural/kg Air 0.1 %
0.0010
99.9967423537 % Y= 0.99996742
0.0032576463 % X= 0.00003258
kg/jam
0.0100
kg/jam 328.5617 kmol/jam 30533.0095
kg/jam 106.0000 kmol/jam 0.99
0.0010 (Toluen terbawa air, Sumber Patent Utama)
Output
Aliran Bottom 34 Aliran Top 17
Kmol Kg Kmol Kg
41.0375 738.6748 - -
482.5967 47294.4732 - -
0.0008 0.0802 25.6510 2462.5000 25.9026
0.3286 30.2277 328.2332 30197.4517
0.0029 0.3053 2.8776 305.0248
143.5378 25836.7955 - -
667.5042 73900.5568 356.7618 32964.9765
106865.5333 BALANCE
Output Komponen BM
Aliran Top Toluena 92
Kmol Kg Furfural 96
- - Xylena 106
- -
25.6510 2462.5000
328.2332 30197.4517
2.8776 305.0248
- -
356.7618 32964.9765
106865.5333 BALANCE
mmHg
(Sumber Patent : US 2017/0233362 A1)

KOLOM EKSTRAKSI-01
Fungsi : Untuk memisahkan furfural dari air, asam sulfat dan glukosa
Komponen Masuk
Input (15)
Komponen Xi %
Air 41.0375 738.6748 0.0097 0.9677
Asam Sulfat 482.5967 47294.4732 0.6196 61.9585
Glukosa 143.5378 25836.7955 0.3385 33.8477
Furfural 25.6519 2462.5802 0.0323 3.2261
Toluen 0.0000 0.0000 0.0000 0.0000
Xylane 0.0000 0.0000 0.0000 0.0000
Subtotal 692.8238 76332.5238 1.0000 100.0000
Total 692.8238 76332.5238 1.0000 100.0000
Banyaknya solute dan diluent yang terkandung dalam feed ekstraktor
Komponen Massa Fraksi Massa

Air 738.6748 0.0097
Asam Sulfat 47294.4732 0.6196
Glukosa 25836.7955 0.3385
Furfural 2462.5802 0.0323
Toluen 0.0000 0.0000
Xylane 0.0000 0.0000
Subtotal 76332.5238 1.0000
Total 76332.5238 1.0000
Diinginkan 99.9% furfural yang terekstrak dari feed, maka: =

Kadar solute dalam rafinate (XNp)
XNp = (100% - 99.9%)
XNp = 0.001 =
X 'Np = X Np/1-X Np =
RnP = (feed furfural asumsi)/(Feed Asam

Sulfat+Feed Furfural+Feed Glukosa)
RnP = 3.2576463E-05
= 0.0032576463 %
Jadi, % solute dalam ekstrak =
% solute dalam raffinate =
Jumlah solvent yang dibutuhkan (solvent : Feed = 0.4:1)

Aliran Solvent = 30533.0095
Kemurnian Toluena = 0.9900
Feed Toluena = 30227.6794
Xylena = 305.3301
Toluena yang terbawa rafinate = 30.2277
Toluena yang terbawa ekstrak = 30197.4517
Perhitungan Setelah Recycle

Komponen Input
Aliran 15 Aliran 32
Kmol Kg Kmol Kg
Air 41.0375 738.6748 - -
Asam Sulfat 482.5967 47294.4732 - -
Furfural 25.6519 2462.5802 0.0000 0.0000
Toluena 0.0000 0.0000 328.5617 30227.6794
Xylena 0.0000 0.0000 2.8805 305.3301
Glukosa 143.5378 25836.7955 - -
Subtotal 692.8238 76332.5238 331.4422 30533.0095
Total 106865.5333
1024.2660
Perhitungan Pertama
Aliran 16 Aliran Bottom, RAFF, LIMBAH
Kmol Kg Kmol Kg
Air 41.0375 738.6748 41.0375 738.6748
Asam Sulfat 482.5967 47294.4732 482.5967 47294.4732
Furfural 25.6519 2462.5802 0.0008 0.0802
Toluena 328.5617 30227.6794 0.3286 30.2277
Xylena 2.8805 305.3301 0.0029 0.3053
Glukosa 143.5378 25836.7955 143.5378 25836.7955
Subtotal 1024.2660 106865.5333 667.5042 73900.5568
Total 106865.5333 106865.5333
40.9541
481.6163
0.0008
0.3279
0.0029
143.2462
KOLOM EKSTRAKSI-01
Kondisi Operasi T= 30 C
P= 1 atm 760
Solute (C) = Furfural

Solvent (S) = toluena
Diluent (D) = air
Xf (fraksi solute) = 0.0323

Fraksi diluent = 0.9677
X'f = 0.0333
0.999 99.9 % (Sumber Patent : Jurnal …………
1 Kg Furfural/kg Air 0.1 %
0.0010
99.9967423537 % Y= 0.99996742
0.0032576463 % X= 0.00003258
kg/jam
0.0100
kg/jam 328.5617 kmol/jam 30533.0095
kg/jam 2.8805 kmol/jam 0.99
0.0010 (Toluen terbawa air, Sumber Patent Utama)
Output
Aliran Bottom 34 Aliran Top 17
Kmol Kg Kmol Kg
41.0375 738.6748 - -
482.5967 47294.4732 - -
0.0008 0.0802 25.6510 2462.5000 25.5989
0.3286 30.2277 328.2332 30197.4517 327.5664
0.0029 0.3053 2.8776 305.0248 2.8717
143.5378 25836.7955 - -
667.5042 73900.5568 356.7618 32964.9765
106865.5333
0.061478997
Output 0.722986727 Komponen BM
Aliran Top 1.2519E-06 Toluena 92
Kmol Kg 0.000492224 Furfural 96
- - 4.31529E-06 Xylena 106
- - 0.215036484
25.6510 2462.5000 0.061478997
328.2332 30197.4517 0.722986727
2.8776 305.0248 1.2519E-06
- - 0.000492224
356.7618 32964.9765 4.31529E-06
106865.5333 BALANCE
0.215036484
mmHg
(Sumber Patent : Jurnal ……………..)

0.0400652646
0.4711634191
0.0250441561 0.07189963
0.3207777435 0.920034506
0.002812231 0.008065864
0.1401371857
0.061478997
0.722986727
1.2519E-06
0.000492224
4.31529E-06
0.215036484
0.0814677234
0.0520690909
73131.2687
0.0336734241
Kolom Ekstr
Tref 25.00 oC
Tin 30.00 oC
Delta T 5.0000 oC
Input (Kmol)
Komponen
Feed Solvent
Air 41.0375 -
Asam Sulfat 482.5967 -
Furfural 25.6519 0.0000
Toluena 0.0000 328.5617
Xylena 0.0000 2.8805
Glukosa 143.5378 -
692.8238 331.4422
Total
1024.2660
Cp Bm
Water - 18
Asam Sulfat - 98
Furfural - 96
Toluene - 92
Xylene - 106
Glukosa 436.8 180
Q Keluaran Ekstrasi Kebawah pada T = 303.1500
Komponen n Cp
Air 41.0375 377.4864
Asam Sulfat 482.5967 701.6579
Furfural 0.0008 847.0956
Toluena 0.3286 789.3487
Xylena 0.0029 915.3755
Glukosa 143.5378 2,184.0000
Total 667.5042
Q Keluaran Ekstraksi Keatas pada T = 303.1500
Komponen n Cp
Air - -
Asam Sulfat - -
Furfural 25.6510 847.0956
Toluena 328.2332 789.3487
Xylena 2.8776 915.3755
Glukosa - -
total 353.8842 1,636.4443
Aliran Panas Masuk (kJ) Panas Keluar (kJ)

Qfeed 689,324.8847
Qsolvent 261,986.4802
Qtop 667,857.9865
Qbottom 283,453.3783
Total 951,311.3649 951,311.3649
Kolom Ekstraksi (KE-01)
298.15 K
303.15 K
278.15 K
Output (Kmol)
top bottom
- 41.0375 Komponen A
- 482.5967 Air 9.21E+01
25.6510 0.0008 Asam Sulfat 2.60E+01
328.2332 0.3286 Furfural 6.68E+01
2.8776 0.0029 Glukosa -
- 143.5378 Toluena 83.703
356.7618 667.5042 Xylena 70.916
1024.2660 BALANCE

Air 460.265 -60.05934725 -95.37765253
Asam Sulfat 130.02 1057.3409525 -626.2392804
Furfural 333.96 1063.6245375 -817.2386452
Glukosa
Toluena 418.515 776.669145 -673.876131
Xylena 354.58 1209.364625 -989.1199951
K KEBAWAH Panas Sensibel extractive agent masuk KE-01

Dari Tangki
Q Komponen Kmol
15,491.0928 Air -
338,617.7468 Asam Sulfat -
0.7079 Furfural 0.0000
259.3498 Toluena 328.5617
2.6367 Xylena 2.8805
313,486.4526 Glukosa
667,857.9865 Total 331.4422
K KEATAS Panas masuk KE-01, pada T =

Dari Cooler-01
Q Komponen n (kmol)
- Air 41.0375
- Asam Sulfat 482.5967
21,728.8846 Furfural 25.6519
259,090.4163 Toluena 0.0000
2,634.0775 Xylena 0.0000
- Glukosa 143.5378
283,453.3783 Total 549.2860
0.0000
B C D E
-4.00E-02 -2.11E-04 5.35E-07 -
7.03E-01 -1.39E-03 1.03E-06 -
7.08E-01 -1.81E-03 1.96E-06 -
- - - -
5.17E-01 -1.49E-03 1.97E-06
8.05E-01 -2.19E-03 2.51E-06
1/4 DT^4
72.6583813682
140.536194825
266.7497103476
268.040653928
340.5509165065
gent masuk KE-01 Solvent Masuk
CpdT (Kj/kmol) Qh (j)

- -
- -
847.0956 0.0000
789.3487 259,349.7660
915.3755 2,636.7142
261,986.4802
303.1500 K
CpdT Q(J)
377.4864 15,491.0928
701.6579 338,617.7468
847.0956 21,729.5925
789.3487 0.0000
915.3755 0.0000
2,184.0000 313,486.4526
689,324.8847
Komponen Masuk
Input
Komponen
Air 41.0375 738.6748
asam Sulfat 482.5967 47294.4732
FURFURAL 0.0008 0.0802
Toluena 0.3286 30.2277
Xylena 0.0029 0.3053
Glukosa 143.5378 25836.7955
Total 667.5042 73900.5568
SUMBER BUKU COULSON :

Komponen ANTA ANTB
Air 18.3036 3816.44
Furfural 18.7949 5365.88
Toluena 16.0137 3096.52
Xylena 16.1169 3369.74
1 atm = 760
Kondisi Operasi : T 213.283

P 1.30

Komponen Pi (mmHg) Pi (atm)

Air 15303.5304 20.1362
Asam sulfat 60.0298 0.0790
Furfural 2656.9482 3.4960
Toluena 7033.6767 9.2548
Xylena 3802.2958 5.0030
Glukosa 1.0743 0.0014
Total
Komponen Pi (mmHg) Ki (Pi/P)

Air 15303.5304 15.4894
Asam sulfat 60.0298 0.0608
Furfural 2656.9482 2.6892
Toluena 7033.6767 7.1191
Xylena 3802.2958 3.8485
Glukosa 1.0743 0.0011
Total
Ditetapkan
LK : Asam Sulfat
HK : Glukosa
Komponen Ki (Pi/P) K ref

Air 15.4894 0.0011
Asam sulfat 0.0608 0.0011
Furfural 2.6892 0.0011
Toluena 7.1191 0.0011
Xylena 3.8485 0.0011
Glukosa 0.0011 0.0011
Total
Diinginkan distribusi komponen kunci
LIGHT Key
Asam Sulfat D 482.5967
Asam Sulfat B 0.0000
Log D/B 8.0000
Key Komponen X = log iK Y = log iD/iB

Glukosa 0.0000 -11.0000
Total 1.7473 -3.0000
y = aX + B
a (slope) 10.8742
b (intercept) -11.0000
Maka untuk setiap komponen

Komponen X = log iK Y = log iD/iB
Air 4.1537 34.1680
Furfural 3.3933 25.8991
Toluena 3.8161 30.4967
Xylena 3.5489 27.5918
Glukosa 0.0000 -11.0000
Kondisi Top Dew Point

Komponen Kmol Xi
Air 41.0375 0.0783
Asam sulfat 482.5967 0.9210
Furfural 0.0008 0.0000
Toluena 0.3286 0.0006
Xylena 0.0029 0.0000
Glukosa 0.0000 0.0000
Total 523.9664 1.0000
Top Distilation Trial Error Kondisi Operasi

Temperature 277.5533192785
Pressure 1.2
Komponen Kg Xi
Air 738.6748 0.0783
Asam sulfat 47294.4727 0.9210
Furfural 0.0802 0.0000
Toluena 30.2277 0.0006
Xylena 0.3053 0.0000
Glukosa 0.0000 0.0000
Total 48063.7607 1.0000
Bottom Trial Error

Temperature 353.5563
Pressure 1.40
Komponen Kg Xi
Air 0.0000 0.0000
Furfural 0.0000 0.0000
Toluena 0.0000 0.0000
Xylena 0.0000 0.0000
Glukosa 25836.7955 1.0000
Total 25836.7960 1.0000
NERACA MASSA KOLOM DETILASI 02 (KD-02)

Input
Komponen Aliran 9
Kmol Kg
Air 41.0375 738.6748
Asam sulfat 482.5967 47294.4732
Furfural 0.0008 0.0802
Toluena 0.3286 30.2277
Xylena 0.0029 0.3053
Glukosa 143.5378 25836.7955
667.5042 73900.5568
Total
73900.5568
0.0614789971 0.0004922242
0.7229867271 0.000004
0.0000013 0.2150364844
KOLOM DESTILASI-02
Xi %
0.0615 0.9996
0.7230 63.9975
0.0000 0.0001
0.0005 0.0409
0.0000 0.0004
0.2150 34.9616
1.0000 100.0000
ANTC Tmin
-46.13
5.4
-53.67 7
-58.45 28
mmHg
C 486.433
atm 988
305.6843 T ini yang buat di lampiran
kmol BM
41.0375 18
482.5967 98
0.0008 96
0.3286 92
0.0029 106
143.5378 180
667.5042
Xi Yi (Ki.Xi)
0.0615 0.9523
0.7230 0.0439
0.0000 0.0000
0.0005 0.0035
0.0000 0.0000
0.2150 0.0002
1.0000 1.0000
alpha (ki/kref) log alpha

14245.5148 4.1537
55.8796 1.7473
2473.2591 3.3933
6547.4007 3.8161
3539.4226 3.5489
1.0000 0.0000
26862.4767
LK 0.9999999900
0.0000000100
Heavy Key
Glukosa D
Glukosa B
Log D/B
X.Y X^2
13.9780 3.0529
0.0000 0.0000
13.9780 3.0529
(((2*D64)-(B64*C64))/((2*E64)-(B64^2)))
((C64-(B68*B64))/2)
iD/iB D (mol)
14722012969725700000000000000000000.0000 41.0375
99999998.4975 482.5967
79273004169425600000000000.0000 0.0008
3138583164378490000000000000000.0000 0.3286
3906926962268620000000000000.0000 0.0029
0.0000 0.0000
Massa
738.6748
47294.4727
0.0802
30.2277
0.3053
0.0000
48063.7607
Celcius 550.7033192785
atm 912
A B
18.3036 3816.4400
16.0137 3096.5200
16.1169 3369.7400
Celcius 626.7062915792
atm 1064
A B
16.0137 3096.5200
16.1169 3369.7400
Output
Aliran Top (10)
Kmol Kg
41.0375 738.6748
482.5967 47294.4727
0.0008 0.0802
0.3286 30.2277
0.0029 0.3053
0.0000 0.0000
523.9664 48063.7607
73900.5568
738.6748
TILASI-02
SUMBER BUKU YAWS :

Tmax Komponen
Asam sulfat
log 10 P =
137 P=
168
SUMBER DARI HYSYS :
Komponen
Glukosa
ln P =
P=
K
mmHg 1 Kpa =
-8.618661234
2.6870229017
236616.923514049
HK 0.0%
100.0%
0.0000
143.5378
-11.0000
B (mol)
0.0000
0.0000
0.0000
0.0000
0.0000
143.5378
Kondisi Bottom Bubble point

Komponen Kmol
Air 0.0000
Asam Sulfat 0.0000
Furfural 0.0000
Toluena 0.0000
Xylena 0.0000
Glukosa 143.5378
Total 143.5378
Kelvin
mmHg
C Pi (mmHg) Ki (Pi/P)
-46.1300 46161.5467 50.6157
840.5580 0.9217
9375.2615 10.2799
-53.6700 17742.0912 19.4540
-58.4500 10629.1932 11.6548
47.1992 0.0518
Kelvin
mmHg
C Pi (mmHg) Ki (Pi/P)
124251.4410 116.7777
9884.5908 9.2900
29911.8867 28.1127
-53.6700 40537.9311 38.0996
-58.4500 26553.9784 24.9567
1063.9886 1.0000
Aliran bottom (11)

Kmol Kg
0.0000 0.0000
0.0000 0.0005
0.0000 0.0000
0.0000 0.0000
0.0000 0.0000
143.5378 25836.7955
143.5378 25836.7960
Komponen BM
Toluena 92
Furfural 96
Xylena 106
BUKU YAWS :
A B C D E
2.0582 -4192.4 3.2578 -0.001122 5.5371E-07
A+B/T+C log 10 T +DT+ET^2
10^(A+B/T+C log 10 T +DT+ET^2)
DARI HYSYS :
A B C D E F
254.41 -31423 0 -31.006 6.2417E-18 6
a + b/(T+c) + d ln T + e*T^f
7.500617 mmHg
-6.560461234
8.7537832091
-0.5459722377
0.1310171567
1.7783668941
60.0297996805
-64.5988436114 189.8111563886
486.433
6.187098878 -191.8371878101
13247606211905700.000 0.0826875837
-1.9433438378
0.1432242296
1.0742700912
Xi Massa
0.0000 0.0000
0.0000 0.0005
0.0000 0.0000
0.0000 0.0000
0.0000 0.0000
1.0000 25836.7955
1.0000 25836.7960
Xi = Yi/Ki
0.0015
0.9993
0.0000
0.0000
0.0000
0.0000
1.0009
Yi = Xi*Ki
0.0000
0.0000
0.0000
0.0000 Ln(Pi) = ANTA - ANTB/(T+ANTC)
0.0000 Pi = exp (ANTA - (ANTB/(T+ ANTC)))
1.0000
1.0000
Kemurnian glukosa hasil destilasi :
0.9999999817
99.9999981695
Condensor-01
Fungsi : untuk mengubah fase destilate dari fase gas menjadi fase cair
Kondisi Operasi
Temp 277.5533192785 C 550.7033192785 K
Press 1.2 atm 912 mmHg
theta 1.2682407591 trial and error
Komponen Xf Xd alpha (α-θ)/α

Air 0.0615 0.0783 14245.5148 0.9999
Asam sulfat 0.7230 0.9210 55.8796 0.9773
Furfural 0.0000 0.0000 2473.2591 0.9995
Toluena 0.0005 0.0006 6547.4007 0.9998
Xylena 0.0000 0.0000 3539.4226 0.9996
Glukosa 0.2150 0.0000 1.0000 -0.2682
Total 1.0000 1.0000
L/D + 1 1.0214
L/D min 0.0213965
L/D aktual = 1,5 x L/D min 0.0320948
V = L+D = (R+1).D 540.7830
L = RxD 16.8166
Komposisi Feed Condenser-01 (V)

Komponen Kmol Kg Xi BM
Air 42.3546 762.3824 0.0783 18
Asam sulfat 498.0855 48812.3798 0.9210 98
Furfural 0.0009 0.0828 0.0000 96
Toluena 0.3391 31.1978 0.0006 92
Xylena 0.0030 0.3151 0.0000 106
Glukosa 0.0000 0.0000 0.0000 180
Total 540.7830 49606.3580 1.0000
Komposisi Reflux
Air 1.3171 23.7076 0.0783 18
Asam sulfat 15.4888 1517.9071 0.9210 98
Furfrual 0.0000 0.0026 0.0000 96
Toluena 0.0105 0.9702 0.0006 92
Xylena 0.0001 0.0098 0.0000 106
Glukosa 0.0000 0.0000 0.0000 180
Total 16.8166 1542.5972 1.0000
Komposisi Destilat
Air 41.0375 738.6748 0.0783 18
Asam sulfat 482.5967 47294.4727 0.9210 98
Furfural 0.0008 0.0802 0.0000 96
Toluena 0.3286 30.2277 0.0006 92
Xylena 0.0029 0.3053 0.0000 106
Glukosa 0.0000 0.0000 0.0000 180
Total 523.9664 48063.7607 1.0000
NERACA CONDENSOR 01 (CD-01)

Input Output
Komponen Aliran 10 Aliran Reflux (12)
Kmol Kg Kmol Kg
Air 42.3546 762.3824068158 1.3171 23.7076
Asam sulfar 498.0855 48812.3797955599 15.4888 1517.9071
Furfural 0.0009 0.0827968683 0.0000 0.0026
Toluena 0.3391 31.1978 0.0105 0.9702
Xylena 0.0030 0.3151 0.0001 0.0098
Glukosa 0.0000 0.0000 0.0000 0.0000
540.7830 49606.3580 16.8166 1542.5972
Total
49606.3580 49606.3580
Input Output
Komponen Aliran 20 Aliran Reflux Aliran Destilat (21)
Kg Kg Kg
Air 762.3824068158 23.7076 738.6748
Asam slfat 48812.37979556 1517.9071 47294.4727
Furfural 0.0827968683 0.0026 0.0802
Toluena 31.1978310017 0.9702 30.2277
Xylena 0.3151296061 0.0098 0.3053
Glukosa 2.6666098E-07 0.0000 0.0000
Sub Total 49606.3580 1542.5972 48063.7607
Total 49606.3580 49606.3580
Xf/(α-θ)/α XD/(α-θ)/α
0.0615 0.0783
0.7398 0.9424
0.0000 0.0000
0.0005 0.0006
0.0000 0.0000
-0.8017 0.0000
0.0001 1.0213965
ditulis 0 di lampiran
1,2-1,5
Output
Aliran Destilat (13)
Kmol Kg
41.0375 738.6748 0.0783208346
482.5967 47294.4727 0.9210450067
0.0008 0.0802 1.594849E-06
0.3286 30.2277 0.0006270664
0.0029 0.3053 5.497437E-06
0.0000 0.0000
523.9664 48063.7607
9606.3580
ACCUMULATOR-01
fungsi : untuk memisahakan destilat keluaran kolom destilasi dari impuritis
Input Output
Komponen Aliran (12,13) Aliran Reflux (14)
Kmol Kg Kmol Kg
Air 42.3546 762.3824068158 1.3171 23.7076259765
Asam sulfat 498.0855 48812.3797955599 15.4888 1517.907067204
Furfural 0.0009 0.0827968683 0.0000 0.0025747147
Toluena 0.3391 31.1978310017 0.0105 0.9701515959
Xylena 0.0030 0.3151296061 0.0001 0.0097995111
Glukosa 0.0000 2.66660980078853E-07 0.0000 8.29229363E-09
540.7830 49606.3580 16.8166 1542.5972
Total
49606.3580 49606.3580
Input OUTPUT
Komponen Aliran 21 Aliran Reflux Aliran Destilat 22
Kg Kg Kg
Air 762.3824 23.7076 738.6748
Asam sulfat 48812.3798 1517.9071 47294.4727
Furfural 0.0828 0.0026 0.0802
Toluena 31.1978 0.9702 30.2277
Xylena 0.3151 0.0098 0.3053
Glukosa 0.0000 0.0000 0.0000
Sub Total 49606.3580 1542.5972 48063.7607
Total 49606.3580 49606.3580
CCUMULATOR-01
Output Komponen BM
Aliran Destilat (15) Toluena 92
Kmol Kg Xylena 106
41.0375 738.67478084
482.5967 47294.472728
0.0008 0.0802221536
0.3286 30.227679406 Furfural 96
0.0029 0.305330095
0.0000 2.583687E-07
523.9664 48063.7607
49606.3580
0.0006289079
0.0628907912
5.37554E-12
30533.009501
-17530.7512
Reboiler 01 (RB-01)
Fungsi : Untuk memanaskan kembali feed keluaran bottom dengan tujuan mempertahank
kondisi operasi di dalam kolom destilasi.
Temp 353.5562915792 C 626.7062915792

Press 1.4000 atm 1064
L* = F + L 684.3208
V* = V + (q - 1) F 540.7830 v/L condensor
B* = L* - V* 143.5378
Komposisi Feed Reboiler (L)

Komponen XL kmol kg
Air 0.0000 0.0000 0.0000
Asam sulfat 0.0000 0.0000 0.0023
Furfural 0.0000 0.0000 0.0000
TOLUENA 0.0000 0.0000 0.0000
XYLENA 0.0000 0.0000 0.0000
Glukosa 1.0000 684.3208 123177.7374
Total 1.0000 684.3208 123177.7397
684.3208
Komposisi Boil-UP Reboiler (V)
Komponen YV kmol kg
aIR 0.0000 0.0000 0.0000
Asam sulfat 0.0000 0.0000 0.0018
Furfural 0.0000 0.0000 0.0000
TOLUENA 0.0000 0.0000 0.0000
XYLENA 0.0000 0.0000 0.0000
Glukosa 1.0000 540.7830 97,340.9419
Total 1.0000 540.7830 97,340.9436
540.7830
Komposisi Produk Reboiler (B)
Komponen XB kmol kg
Air 0.0000 0.0000 0.0000
Asam sulfat 0.0000 0.0000 0.0005
Furfural 0.0000 0.0000 0.0000
TOLUENA 0.0000 0.0000 0.0000
XYLENA 0.0000 0.0000 0.0000
Glukosa 1.0000 143.5378 25,836.7955
Total 1.0000 143.5378 25,836.7960
143.5378
Neraca Massa Reboiler RB-01
Input Outpu
Komponen
L (kg) L(kmol) V(kg) TOP
Air 0.0000 0.0000 0.0000
Asam sulfat 0.0023 0.0000 0.0018
Furfural 0.0000 0.0000 0.0000
Toluena 0.0000 0.0000 0.0000
Xylena 0.0000 0.0000 0.0000
Glukosa 123177.7374 684.3208 97340.9419
97340.9436
TOTAL 123177.7397 684.3208
123177.7397
123177.7397 0.9999999664
3.3621583265777E-08
0.9999999664
01 (RB-01)
n tujuan mempertahankan Fungsi : Untuk menguapkan light key yang m
K
mmHg
Keterangan :
BM aliran V* = aliran komponen vapo
18
98
96
92 aliran L* = aliran komponen feed
106 aliran B = aliran komponen botto
180
L∗−L
q=
F
BM
18.0000
98.0000
96.0000
92.0000 Feed masuk pada kondisi bubble p
106.0000 sehingga :
180.0000 L*=F+L
V* = V + (1-q) x F
B = L* - V*
BM dimana :
18.0000
98.0000
96.0000
92.0000 L* = komponen trap o
106.0000 V* = komponen vapor
180.0000 F = komponen feed K
L = komponen refluk
V = komponen feed C
Output
V(kmol) B(kg) B(kmol)
0.0000 0.0000 0.0000 B = OUT R
0.0000 0.0005 0.0000 V = REFLUX
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
0.0000 0.0000 0.0000
540.7830 25836.7955 143.5378
540.7830 25836.7960 143.5378
123177.7397 684.3208
0.9999999817
uapkan light key yang masih ada dalam produk bottom KD-01
aliran komponen vapor menuju KD-01
aliran komponen feed trap out reboiler (YG MASUK REBOILER)

aliran komponen bottom KD-01
L∗− L
q=
F
k pada kondisi bubble point atau saturated liquid feed, q = 1
V* = V + (1-q) x F winkle 6.45 6.46

B = L* - V*
L* = komponen trap out

V* = komponen vapor RB-01
F = komponen feed KD-01
L = komponen refluks
V = komponen feed CD-01
Input dari keluaran KE-01, pada T = 30 C
T ref 25 C 298.15
T in 30 C 303.15 K
Tout heater 80 C 353.15 K
Komponen A B C D
Air 92.053 -4.00E-02 -2.11E-04 5.35E-07
Asam Sulfat 26.004 7.03E-01 -1.39E-03 1.03E-06
Furfural 66.792 7.08E-01 -1.81E-03 1.96E-06
Glukosa - - - -
Toluena 83.703 5.17E-01 -1.49E-03 1.97E-06
Xylena 70.916 8.05E-01 -2.19E-03 2.51E-06

Air 5062.915 -715.58819475 -1233.786962705 1022.83140317
Asam Sulfat 1430.22 12597.8842275 -8100.910844547 1978.36547748
Furfural 3673.56 12672.7511625 -10571.64188013 3755.1067804
Glukosa
Toluena 4603.665 9253.768095 -8717.131978363 3773.27973731
Xylena 3900.38 14409.198375 -12795.06595214 4794.02603279
Output dari keluaran heater-05 pada T = 112,78 C

Komponen kmol Cp Dt Q (KJ)
Air 41.0375 4,136.3712 169,746.2846
Asam Sulfat 482.5967 7,905.5589 3,815,196.3435
Furfural 0.0008 9,529.7761 7.9635
Glukosa 143.5378 24,024.0000 3,448,350.9788
Toluena 0.3286 8,913.5809 2,928.6616
Xylena 0.0029 10,308.5385 29.6935
7,436,259.9255
Qs = Q keluar - Q masuk = 6,768,401.9390 kJ



= 452.6000 Kj/Kg
= 14,954.4895 Kg

Qs in = m x Hv = 35,035,377.9554 kJ

Qs out = m x Hl = 28,266,976.0164 kJ
Neraca Panas H-06

Q in heater 667,857.9865 0.0000
Q out heater 0.0000 7,436,259.9255
Qs in 35,035,377.9554 0.0000
Qs out 0.0000 28,266,976.0164
Total 35,703,235.9419 35,703,235.9419
Input dari keluaran KE-01, pada T = 30C
Komponen kmol Cp Dt Q (Kj)
Air 41.0375 377.4864 15,491.0928
Asam Sulfat 482.5967 701.6579 338,617.7468
Furfural 0.0008 847.0956 0.7079
Toluena 0.3286 789.3487 259.3498
Xylena 0.0029 915.3755 2.6367
Glukosa 143.5378 2,184.0000 313,486.4526
667,857.9865
Cp Glukosa 436.8
Cp dT Glukosa 24024
O
Komponen Input Top
Kmol Kg Kmol
Air 41.0375 738.6748 41.0375
Asam sulfat 482.5967 47294.4732 482.5967
Furfural 0.0008 0.0802 0.0008
Toluena 0.3286 30.2277 0.3286
Xylena 0.0029 0.3053 0.0029
Glukosa 143.5378 25836.7955 0.0000
667.5042 73900.5568 523.9664
Total
667.5042
Heat Capacity Coefficient of LiquidsCp liq =A+B*T+C*(T^2)+D*(T^3)
Komponen A B C
Air 92.0530 -0.0400 -0.0002
Asam sulfat 26.0040 0.7034 -0.0014
Furfural 66.7920 0.7076 -0.0018
Toluena 83.7030 0.5167 -0.0015
Xylena 70.9160 0.8045 -0.0022
Glukosa
T Operasi
T ref = 25.0000 C
Input Outp
H-03 Top CD-01
C K C K
80.0000 353.1500 277.5533 550.7033
Panas masuk KD-01

Komponen Kmol Cp dT Q (kJ)
Air 41.0375 4,136.3712 169,746.2846
Asam sulfat 482.5967 7,905.5589 3,815,196.3435
Furfural 0.0008 9,529.7761 7.9635
Toluena 0.3286 8,913.5809 2,928.6616
Xylena 0.0029 10,308.5385 29.6935
Glukosa 143.5378 24,024.0000 3,448,350.9788
Total 667.5042 7,436,259.9255
Panas masuk CD-02 keluaran Top KD-02

Air 42.3546 20,320.0073 860,645.3379
Asam sulfat 498.0855 38,801.8800 19,326,654.1275
Furfural 0.0009 49,279.6234 42.5021
Toluena 0.3391 48,145.3023 16,326.4022
Xylena 0.0030 54,316.2448 161.4779
Glukosa 0.0000 110,315.2899 0.0002
Total 540.7830 20,203,829.8477
Panas Destilat yg keluar CD-01

Air 41.0375 6,028.6555 247,400.8764
Asam sulfat 482.5967 11,632.6082 5,613,857.8579
Furfural 0.0008 14,041.3540 11.7336
Toluena 0.3286 13,174.2984 4,328.5703
Xylena 0.0029 15,203.9348 43.7945
Glukosa 0.0000 34,987.6800 0.0001
Total 523.9664 5,865,642.8329
Panas Reflux yang keluar dari bottom KD

Air 1.3171 6,028.6555 7,940.2839
Asam sulfat 15.4888 11,632.6082 180,175.6955
Furfural 0.0000 14,041.3540 0.3766
Toluena 0.0105 13,174.2984 138.9246
Xylena 0.0001 15,203.9348 1.4056
Glukosa 0.0000 34,987.6800 0.0000
Total 16.8166 188,256.6862
Panas latent Condensor CD-01

Lvc = Lvb (((Tc-T)/(Tc-Tb))^0,38) T= 378.2500
Komponen Tc (K) Tb (K) Lvb (KJ/Kmol)

Air 647.1300 373.1500 40.6500
Asam sulfat 925.0000 613.1500 33.2800
Furfural 657.0000 434.8500 43.2000
Toluena 591.7900 383.7800 33.1800
Xylena 617.0500 412.2700 35.6600
Glukosa 1307.1700 693.1500 117.5100
Total
Panas liquid yang keluar dari bottom KD-01 pada T =

Air 0.0000 28288.2020 0.0000
Asam sulfat 0.0000 51805.1307 0.2500
Furfural 0.0000 68885.6772 0.0000
Toluena 0.0000 69010.3644 0.0000
Xylena 0.0000 76999.2109 0.0000
Glukosa 143.5378 143,513.3882 20,599,589.2661
Total 143.5378 20,599,589.5161
Beban Panas CD-01, Q CD-01

Q CD-01 = Qin CD-01 + QL CD-01 - Qd CD-01 - Qr CD-01
Q CD-01 = 14172169.9032 kJ
Beban Panas RB-01, Q RB-01
Q RB-01 = Q bottom KD-01 + Qd + Q CD-01 - Qin KD-01

Q RB-01 = 33201142.3266 kJ
Neraca Panas KD-01
Komponen Q input (KJ) Q output (Kj)

Qin KD-01 7,436,259.9255
Q RB-01 33,201,142.3266
Qd CD-01 5,865,642.8329
Qbottom 20,599,589.5161
Q CD-01 14,172,169.9032
Total 40,637,402.2521 40,637,402.2521
CONDENSER-01
Kondisi Operasi
T ref = 25.0000 C
Tinput = 277.5533 C
Toutput = 105.1000 C
Panas masuk Condensor, Qv pada T= 550.7033

Qv = 20203829.8477
Panas latent kondensor, QLv pada T= 378.2500
QLv = 22239.5745
Panas destilat, Qd = Q destilat pada T= 378.2500

Qd = 5865642.8329
Panas refluks, Ql pada T= 378.2500

Ql = 188256.6862
Beban panas kondensor, Q CD-01 = Qv + Qlv - Qd - Ql

Q CD-01 = 14172169.9032 kJ
Kebutuhan refrigerant:
Cp air = 4.1840 kj/kg K

Twin = 28.0000 C 301.1500
Twout = 45.0000 C 318.1500
Tref = 25.0000 C 298.1500
jumlah air pendingin
= 199248.8177 Kg
= 2500971.1594 kJ
= 16673141.0625
Neraca Panas Condensor-01 (CD-01)

Qv 20,203,829.8477
Qlv 22,239.5745
Qw-in -2,589,789.7350 REFRIGERANT YANG DIPAKAI A
Qd 5,865,642.8329 PERHITUNGAN REFRIGERANT D
Ql 188,256.6862
Qw-out -1086918.4960
Q Latent 12669298.6642 11582380.1682
Total 17,636,279.6872 17,636,279.6872
REBOILER -01 (RB-01)
Kondisi Operasi
T ref = 25.0000 C
Tinput = 353.5563 C
Panas keluar dari bottom KD-01, Q = 20599589.5161
Panas Sensibel Vapor yang keluar, Qv

Air 0.0000 43502.6748 0.0000
Asam sulfat 0.0000 72879.1132 1.3251
Furfural 0.0000 105850.2052 0.0000
Toluena 0.0000 110149.8897 0.0000
Xylena 0.0000 121329.3215 0.0000
Glukosa 540.7830 191,942.2552 103,799,110.5929
Total 540.7830 103,799,110.5929
Panas masuk RB-01,

(Ql = feed RB)
Air 0.0000 43502.6748 0.0000
Asam sulfat 0.0000 72879.1132 1.6768
Furfural 0.0000 105850.2052 0.0000
Toluena 0.0000 110149.8897 0.0000
Xylena 0.0000 121329.3215 0.0000
Glukosa 684.3208 143,513.3882 98,209,191.3404
Total 684.3208 98,209,191.3404
Panas bottom keluar reboiler (Qb)

Air 0.0000 43502.6748 0.0000
Asam sulfat 0.0000 72879.1132 0.3517
Furfural 0.0000 105850.2052 0.0000
Toluena 0.0000 110149.8897 0.0000
Xylena 0.0000 121329.3215 0.0000
Glukosa 143.5378 191,942.2552 27,550,960.0262
Total 143.5378 27,550,960.0262
Beban Panas Reboiler, Q RB-01 :

Q RB-01 = QLv = 33,201,142.3266 kJ
Dari Tabel Steam, Untuk Saturated Steam pada T = 370 C Diperoleh Data:
Entalpi Liquid Jenuh, HL = 1890.2000
Entalpi Uap Jenuh, Hv = 2342.8000
Panas Laten, L = 452.6000
Jumlah Steam Yang Dibutuhkan

m = Q Lv / L
= 73356.4788 Kg
Panas Yang Dibawa Masuk Oleh Steam Masuk

Qs-in = m x Hv
= 171859558.6453 kJ
Panas Yang Dibawa Keluar Oleh Steam

Qc-out = m x HL
= 138658416.3186 kJ
Neraca Panas Reboiler-01 (RB-01)

Ql 98,209,191.3404
Qs-in 171,859,558.6453
Qv 103,799,110.5929
Panas latent 60,263.0481
Qlv
Qb 27,550,960.0262
Qc-out 138,658,416.3186
Total 270,068,749.9857 270,068,749.9857
Output
Top bot
Kg Kmol Kg
738.6748 0.0000 0.0000
47294.4727 0.0000 0.0005
0.0802 0.0000 0.0000
30.2277 0.0000 0.0000
0.3053 0.0000 0.0000
0.0000 143.5378 25836.7955
48063.7607 143.5378 25836.7960
667.5042 73900.5568
Cp (J/(mol K))
D
0.0000
0.0000
0.0000
0.0000
0.0000
Cp Glukosa 436.8000
T Operasi
= 298.1500 K
Output
Out CD-01 Bottom
C K C K
105.1000 378.2500 353.5563 626.7063
K
Lvc n (kmol) QLv

40.3608 42.3546 1709.4641
41.1949 498.0855 20518.5931
47.0912 0.0009 0.0406
33.5125 0.3391 11.3643
37.8046 0.0030 0.1124
137.5299 0.0000 0.0000
540.7830 22239.5745
626.7063
Operasi
= 298.1500 K
= 550.7033 K
= 378.2500 K
K
kJ
K
k/J
K
k/J
K
k/J
Ammonia Cair
K A B C D
K -1.82E+02 3.37E+00 -1.44E-02 2.04E-05
K
Ammonia Keluar
T -30.0000 243.0000
Tref 25.0000 298.0000
Ammonia Masuk
T -33.0000 240.0000
Tref 25.0000 298.0000
Kebutuhan Ammonia
560.5259 Kmol
9,528.9404 Kg
RANT YANG DIPAKAI AMMONIA

NGAN REFRIGERANT DI AIR TIDAK DIPAKAI
Operasi
= 298.1500 K
= 626.7063 K
= 737.5782 K NOTE !!!!
TULIS DI LAMPIRAN SUHU OUTPUT REBOILER 366
Di HYSYS, pada suhu 360 C glukosa juga sudah jadi fase u
Panas latent
Panas latent Reboiler RB-01
Lvc = Lvb (((Tc-T)/(Tc-Tb))^0,38) T= 737.5782 K
Komponen Tc (K) Tb (K) Lvb (KJ/Kmol) Lvc

GLUKOSA 1034.0200 693.1500 117.5100 111.4367
Total
(Sumber: Buku Thermo, Appendix F Hal: 669)
kJ/kg
kJ/kg
kJ/kg
Ammonia Gas
A B C D E
### ### ### ### 1.8700E-11
Panas laten penguapan ammonia pada -30.0000

243.0000
Hv = A*(1-T/Tc)^n
Komponen A Tc
Ammonia 31.5230 405.6500
T/Tc
0.5990
UTPUT REBOILER 366,4125
osa juga sudah jadi fase uap pada tekanan 1,4 atm
639.5625
n (kmol) QLv
540.7830 60263.0481
540.7830 60263.0481
C
K
,Kj/mol T, K
n Hv (Kj/mol) Kj/Kmol
0.3640 22.6025 22,602.5211
(1-T/Tc)
0.4010 0.7170
KOLOM
Komponen Masuk
Input
Komponen Xi
Air 41.0375 738.6748 0.0783
asam Sulfat 482.5967 47294.4727 0.9210
FURFURAL 0.0008 0.0802 0.0000
Toluena 0.3286 30.2277 0.0006
Xylena 0.0029 0.3053 0.0000
Total 523.9664 48063.7607 1.0000

Komponen ANTA ANTB ANTC
Air 18.3036 3816.44 -46.13
Furfural 18.7949 5365.88 5.4
Toluena 16.0137 3096.52 -53.67
Xylena 16.1169 3369.74 -58.45
1 atm = 760 mmHg
Kondisi Operasi : T 208.115 C

P 1.50 atm
282.6274 TULIS DI LAMPIRAN

Komponen Pi (mmHg) Pi (atm) kmol

Air 13806.5943 18.1666 41.0375
Asam sulfat 47.1785 0.0621 482.5967
Furfural 2366.3098 3.1136 0.0008
Toluena 6451.0087 8.4882 0.3286
Xylena 3453.4555 4.5440 0.0029
Total 523.9664
Komponen Pi (mmHg) Ki (Pi/P) Xi

Air 13806.5943 12.1110 0.0783
Asam sulfat 47.1785 0.0414 0.9210
Furfural 2366.3098 2.0757 0.0000
Toluena 6451.0087 5.6588 0.0006
Xylena 3453.4555 3.0293 0.0000
Total 1.0000
Ditetapkan
LK : Furfural
HK : Asam Sulfat
Komponen Ki (Pi/P) K ref alpha (ki/kref)

Air 12.1110 0.0414 292.6461
Asam sulfat 0.0414 0.0414 1.0000
Furfural 2.0757 0.0414 50.1566
Toluena 5.6588 0.0414 136.7363
Xylena 3.0293 0.0414 73.1998
Total 553.7388
Diinginkan distribusi komponen kunci LK
LIGHT Key
Furfural D 0.0008
Furfural B 0.0000
Log D/B 2.9996
Key Komponen X = log iK Y = log iD/iB X.Y

Furfural 1.7003 2.9996 5.1002
Asam sulfat 0.0000 -0.4771 0.0000
Total 1.7003 2.5224 5.1002
y = aX + B
a (slope) 2.0447 (((2*D64)-(B64*C64))/((2*E64)-(B64^2)))

b (intercept) -0.4771 ((C64-(B68*B64))/2)

Komponen X = log iK Y = log iD/iB iD/iB
Air 2.4663 4.5658 36800.0312
Asam sulfat 0.0000 -0.4771 0.3333
Furfural 1.7003 2.9996 999.0000
Toluena 2.1359 3.8902 7765.2182
Xylena 1.8645 3.3353 2164.0711

Komponen Kmol Xi Massa
Air 41.0364 0.2533 738.6547
Asam sulfat 120.6492 0.7447 11823.6182
Furfural 0.0008 0.0000 0.0801
Toluena 0.3285 0.0020 30.2238
Xylena 0.0029 0.0000 0.3052
Total 162.0178 1.0000 12592.8820

Temperature 276.09993892 Celcius
Pressure 1.4 atm
Komponen Kg Xi A
Air 738.6547 0.2533 18.3036
Asam sulfat 11823.6182 0.7447
Furfural 0.0801 0.0000
Toluena 30.2238 0.0020 16.0137
Xylena 0.3052 0.0000 16.1169
Glukosa 0.0000 0.0000
Total 12592.8820 1.0000
Bottom Trial Error

Pressure 1.60 atm
Komponen Kg Xi A
Air 0.0201 0.0000
Asam sulfat 35470.8545 1.0000
Furfural 0.0001 0.0000
Toluena 0.0039 0.0000 16.0137
Xylena 0.0001 0.0000 16.1169
Glukosa 0.0000 0.0000
Total 35470.8787 1.0000

Input Output
Komponen Aliran 9 Aliran Top (10)
Kmol Kg Kmol
Air 41.0375 738.6748 41.0364
Asam sulfat 482.5967 47294.4727 120.6492
Furfural 0.0008 0.0802 0.0008
Toluena 0.3286 30.2277 0.3285
Xylena 0.0029 0.3053 0.0029
Glukosa 0.0000 0.0000 0.0000
523.9664 48063.7607 162.0178
Total
48063.7607 48063.7607
0.2532831578
0.7446662438
5.15259393811441E-06
0.0020276753
1.77705330979578E-05
KOLOM DESTILASI-04
%
1.5369
98.3994
0.0002
0.0629
0.0006
100.0000
SUMBER BUKU YAWS :

Tmin Tmax Komponen
Asam sulfat
log 10 P =
7 137 P=
28 168
SUMBER DARI HYSYS :
Komponen
Glukosa
ln P =
P=
481.265 K
1140 mmHg 1 Kpa =
-8.7112045556
2.6823845004
231616.236632883
BM
18
98
96
92
106
Yi (Ki.Xi)
0.9485
0.0381
0.0000
0.0035
0.0000
0.9902
log alpha
2.4663
0.0000
1.7003
2.1359
1.8645
0.9990000000 HK 25.0%
0.0010000000 75.0%
Heavy Key
Asam sulfat D 120.6492
Asam sulfat B 361.9475
Log D/B -0.4771
X^2
2.8911
0.0000
2.8911
)/((2*E64)-(B64^2)))
D (mol) B (mol)
41.0364 0.0011
120.6492 361.9475
0.0008 0.0000
0.3285 0.0000
0.0029 0.0000

Komponen Kmol
Air 0.0011
Furfural 0.0000
Toluena 0.0000
Xylena 0.0000
Total 361.9487
549.2499389189 Kelvin
1064 mmHg
B C Pi (mmHg) Ki (Pi/P)
3816.4400 -46.1300 45163.8780 42.4473
796.9489 0.7490
9141.1890 8.5913
3096.5200 -53.6700 17420.8750 16.3730
3369.7400 -58.4500 10415.8944 9.7894
43.9296 0.0413
NOTE !!!!!
563.6637 Kelvin SUHU BOTTOM DI LAMPIRAN TULIS 320,5137 C
1216 mmHg
B C Pi (mmHg) Ki (Pi/P)
55788.1597 45.8784
1336.5084 1.0991
11679.4545 9.6048
3096.52 -53.67 20785.6298 17.0934
3369.74 -58.45 12669.7182 10.4192
87.4606 0.0719
Output
ran Top (10) Aliran bottom (11)
Kg Kmol Kg
738.6547 0.0011 0.0201
11823.6182 361.9475 35470.8545
0.0801 0.0000 0.0001
30.2238 0.0000 0.0039
0.3052 0.0000 0.0001
0.0000 0.0000 0.0000
12592.8820 361.9487 35470.8787
48063.7607
3.0808731117084E-06 0.9999993182
0.9999967963 0.9999993182
Komponen BM
Toluena 92
Furfural 96
Xylena 106
BUKU YAWS :
A B C D E
2.0582 -4192.4 3.2578 -0.001122 5.5371E-07
A+B/T+C log 10 T +DT+ET^2
10^(A+B/T+C log 10 T +DT+ET^2)
DARI HYSYS :
A B C D E F
254.41 -31423 0 -31.006 6.2417E-18 6
a + b/(T+c) + d ln T + e*T^f
7.500617 mmHg
-6.6530045556
8.7386722254
-0.5401721117
0.1282482264
1.6737437845
47.1784626079
-65.2924770417 189.1175229583
481.265
6.1764185643 -191.5060340044
12425303407994500.000 0.0775550163
-2.3109560298
0.0991664002
0.7438091871
Xi Massa
0.0000 0.0201
1.0000 35470.8545
0.0000 0.0001
0.0000 0.0039
0.0000 0.0001
1.0000 35470.8787
Xi = Yi/Ki
0.0060
0.9942
0.0000
0.0001
0.0000
0.0000
1.0003
PIRAN TULIS 320,5137 C

Yi = Xi*Ki
0.0001
1.0991
0.0000
0.0000 Ln(Pi) = ANTA - ANTB/(T+ANTC)
0.0000 Pi = exp (ANTA - (ANTB/(T+ ANTC)))
0.0000
1.0992
Kemurnian Asam Sulfat hasil destilasi :
0.9999967963
99.9996796257
Condensor-01
Kondisi Operasi
Temp 276.0999389189 C 549.2499389189 K
Press 1.4 atm 1064 mmHg

Air 0.0783 0.2533 292.6461 0.2491
Asam sulfat 0.9210 0.7447 1.0000 -218.7606
Furfural 0.0000 0.0000 50.1566 -3.3815
Toluena 0.0006 0.0020 136.7363 -0.6072
Xylena 0.0000 0.0000 73.1998 -2.0022
Total 1.0000 1.0000
L/D + 1 1.0102
L/D min 0.0102158
L/D aktual = 1,5 x L/D min 0.0153237
V = L+D = (R+1).D 164.5005
L = RxD 2.4827

Air 41.6652 749.9737 0.2533 18
Asam sulfat 122.4980 12004.8001 0.7447 98
Furfural 0.0008 0.0814 0.0000 96
Toluena 0.3336 30.6869 0.0020 92
Xylena 0.0029 0.3099 0.0000 106
Glukosa 0.0000 0.0000 0.0000 180
Total 164.5005 12785.8519 1.0000
Komposisi Reflux
Air 0.6288 11.3189 0.2533 18
Asam sulfat 1.8488 181.1819 0.7447 98
Furfrual 0.0000 0.0012 0.0000 96
Toluena 0.0050 0.4631 0.0020 92
Xylena 0.0000 0.0047 0.0000 106
Glukosa 0.0000 0.0000 0.0000 180
Total 2.4827 192.9699 1.0000
Komposisi Destilat
Air 41.0364 738.6547 0.2533 18
Asam sulfat 120.6492 11823.6182 0.7447 98
Furfural 0.0008 0.0801 0.0000 96
Toluena 0.3285 30.2238 0.0020 92
Xylena 0.0029 0.3052 0.0000 106
Glukosa 0.0000 0.0000 0.0000 180
Total 162.0178 12592.8820 1.0000

Input Output
Kmol Kg Kmol Kg
Air 41.6652 749.9736520258 0.6288 11.3189
Asam sulfar 122.4980 12004.8000825413 1.8488 181.1819
Furfural 0.0008 0.0813700045 0.0000 0.0012
Toluena 0.3336 30.6869 0.0050 0.4631
Xylena 0.0029 0.3099 0.0000 0.0047
Glukosa 0.0000 0.0000 0.0000 0.0000
164.5005 12785.8519 2.4827 192.9699
Total
12785.8519 12785.8519
Input Output
Kg Kg Kg
Air 749.9737 11.3189 738.6547
Asam slfat 12004.8001 181.1819 11823.6182
Furfural 0.0814 0.0012 0.0801
Toluena 30.6869 0.4631 30.2238
Xylena 0.3099 0.0047 0.3052
Glukosa 0.0000 0.0000 0.0000
Sub Total 12785.8519 192.9699 12592.8820
Total 12785.8519 12785.8519
0.3145 1.0170
-0.0042 -0.0034
0.0000 0.0000
-0.0010 -0.0033
0.0000 0.0000
0.3092 1.0102158 SUSAH NIAN TRIAL NILAI TETHA UNTUK DAPETI 0

ditulis 0 di lampiran
1,2-1,5
Output
Kmol Kg
41.0364 738.6547 0.2532831578 0.2532831578
120.6492 11823.6182 0.7446662438 0.7446662438
0.0008 0.0801 5.152594E-06 5.152594E-06
0.3285 30.2238 0.0020276753 0.0020276753
0.0029 0.3052 1.777053E-05 1.777053E-05
0.0000 0.0000
162.0178 12592.8820
2785.8519 0.2532831578
0.7446662438
5.152594E-06
0.0020276753
1.77705331E-05
K DAPETI 0
ACCUMULATOR-01
Input Output
Kmol Kg Kmol Kg
Air 41.6652 749.9737 0.6288 11.3189
Asam sulfat 122.4980 12004.8001 1.8488 181.1819
Furfural 0.0008 0.0814 0.0000 0.0012
Toluena 0.3336 30.6869 0.0050 0.4631
Xylena 0.0029 0.3099 0.0000 0.0047
Glukosa 0.0000 0.0000 0.0000 0.0000
164.5005 12785.8519 2.4827 192.9699
Total
12785.8519 12785.8519
Input OUTPUT
Kg Kg Kg
Air 749.9737 11.3189 738.6547
Asam sulfat 12004.8001 181.1819 11823.6182
Furfural 0.0814 0.0012 0.0801
Toluena 30.6869 0.4631 30.2238
Xylena 0.3099 0.0047 0.3052
Glukosa 0.0000 0.0000 0.0000
Sub Total 12785.8519 192.9699 12592.8820
Total 12785.8519 12785.8519
CCUMULATOR-01
Output Komponen BM
Kmol Kg Xylena 106
41.0364 738.6547
120.6492 11823.6182
0.0008 0.0801
0.3285 30.2238 Furfural 96
0.0029 0.3052
0.0000 0.0000
162.0178 12592.8820
12785.8519
0.0024000691
0.2400069117
0.00%
Reboiler 01 (RB-01)
Temp 290.5137 C 563.6637

Press 1.6000 atm 1216
L* = F + L 526.4491
B* = L* - V* 361.9487

Komponen XL kmol kg
Air 0.0000 0.0016 0.0292
Asam sulfat 1.0000 526.4475 51591.8507
Furfural 0.0000 0.0000 0.0001
TOLUENA 0.0000 0.0001 0.0057
XYLENA 0.0000 0.0000 0.0002
Glukosa 0.0000 0.0000 0.0000
Total 1.0000 526.4491 51591.8858
526.4491
Komponen YV kmol kg
aIR 0.0000 0.0005 0.0091
Asam sulfat 1.0000 164.5000 16,120.9961
Furfural 0.0000 0.0000 0.0000
TOLUENA 0.0000 0.0000 0.0018
XYLENA 0.0000 0.0000 0.0001
Glukosa 0.0000 0.0000 0.0000
Total 1.0000 164.5005 16,121.0071
164.5005
Komponen XB kmol kg
Air 0.0000 0.0011 0.0201
Asam sulfat 1.0000 361.9475 35,470.8545
Furfural 0.0000 0.0000 0.0001
TOLUENA 0.0000 0.0000 0.0039
XYLENA 0.0000 0.0000 0.0001
Glukosa 0.0000 0.0000 0.0000
Total 1.0000 361.9487 35,470.8787
361.9487
Input Outpu
Komponen
Air 0.0292 0.0016 0.0091
Asam sulfat 51591.8507 526.4475 16120.9961
Furfural 0.0001 0.0000 0.0000
Toluena 0.0057 0.0001 0.0018
Xylena 0.0002 0.0000 0.0001
Glukosa 0.0000 0.0000 0.0000
16121.0071
TOTAL 51591.8858 526.4491
51591.8858
51591.8858 3.080873111708E-06
0.9999967963
r 01 (RB-01)
n tujuan mempertahankan Fungsi : Untuk menguapkan light key yan
K
mmHg
Keterangan :
BM aliran V* =
18
98
96
92 aliran L* =
106 aliran B =
180
L∗−L
q=
F
BM
18.0000
98.0000
96.0000
92.0000 Feed masuk pada kondisi bubbl
106.0000 sehingga :
180.0000
BM dimana :
18.0000
98.0000
96.0000
92.0000
106.0000
180.0000
Output
0.0005 0.0201 0.0011 3.080873E-06 B = OUT R
164.5000 35470.8545 361.9475 0.999996796 V = REFLUX
0.0000 0.0001 0.0000
0.0000 0.0039 0.0000
0.0000 0.0001 0.0000
0.0000 0.0000 0.0000
164.5005 35470.8787 361.9487
51591.8858 526.4491
0
ntuk menguapkan light key yang masih ada dalam produk bottom KD-01

L∗−L
q=
F
Feed masuk pada kondisi bubble point atau saturated liquid feed, q = 1
L*=F+L
V* = V + (1-q) x F winkle 6.45 6.46
B = L* - V*

O
Komponen Input Top
Kmol Kg Kmol
Air 41.0375 738.6748 41.0364
Asam sulfat 482.5967 47294.4727 120.6492
Furfural 0.0008 0.0802 0.0008
Toluena 0.3286 30.2277 0.3285
Xylena 0.0029 0.3053 0.0029
Glukosa 0.0000 0.0000 0.0000
523.9664 48063.7607 162.0178
Total
523.9664
Komponen A B C
Air 92.0530 -0.0400 -0.0002
Asam sulfat 26.0040 0.7034 -0.0014
Furfural 66.7920 0.7076 -0.0018
Toluena 83.7030 0.5167 -0.0015
Xylena 70.9160 0.8045 -0.0022
Glukosa
T Operasi
T ref = 25.0000 C
Input Ou
CD-02 Top CD-04
C K C K
105.1000 378.2500 276.0999 549.2499
Panas masuk KD-04

Air 41.0375 6,028.6555 247,400.8764
Asam sulfat 482.5967 11,632.6082 5,613,857.8579
Furfural 0.0008 14,041.3540 11.7336
Toluena 0.3286 13,174.2984 4,328.5703
Xylena 0.0029 15,203.9348 43.7945
Glukosa 0.0000 34987.6800 0.0000
Total 523.9664 5,865,642.8328

Air 41.6652 20,181.6506 840,872.5688
Asam sulfat 122.4980 38,560.9447 4,723,637.0610
Furfural 0.0008 48,937.2845 41.4794
Toluena 0.3336 47,789.2271 15,940.2672
Xylena 0.0029 53,926.2930 157.6406
Glukosa 0.0000 109680.4533 0.0000
Total 164.5005 5,580,649.0172

Air 41.0364 5,929.7125 243,333.8905
Asam sulfat 120.6492 11,436.8334 1,379,844.3996
Furfural 0.0008 13,803.5819 11.5234
Toluena 0.3285 12,948.8585 4,253.9516
Xylena 0.0029 14,945.5696 43.0304
Glukosa 0.0000 34,416.4985 0.0000
Total 162.0178 1,627,486.7955

Air 0.6288 5,929.7125 3,728.7822
Asam sulfat 1.8488 11,436.8334 21,144.3593
Furfural 0.0000 13,803.5819 0.1766
Toluena 0.0050 12,948.8585 65.1864
Xylena 0.0000 14,945.5696 0.6594
Glukosa 0.0000 34,416.4985 0.0000
Total 2.4827 24,939.1638

Lvc = Lvb (((Tc-T)/(Tc-Tb))^0,38) T= 376.9424

Air 647.1300 373.1500 40.6500
Asam sulfat 925.0000 613.1500 33.2800
Furfural 657.0000 434.8500 43.2000
Toluena 591.7900 383.7800 33.1800
Xylena 617.0500 412.2700 35.6600
Glukosa 1,307.1700 693.1500 117.5100
Total

Air 0.0011 24,632.1332 27.4677
Asam sulfat 361.9475 46,045.8447 16,666,178.1668
Furfural 0.0000 59,917.2358 0.0501
Toluena 0.0000 59,357.1738 2.5112
Xylena 0.0000 66,539.6438 0.0885
Glukosa 0.0000 129,080.3842 0.0000
Total 361.9487 16,666,208.2843

Q CD-01 = 3934970.0329 kJ

Q RB-01 = 16363022.2798 kJ
Neraca Panas KD-01

Qin KD-01 5,865,642.8328
Q RB-01 16,363,022.2798
Qd CD-01 1,627,486.7955
Qbottom 16,666,208.2843
Q CD-01 3,934,970.0329
Total 22,228,665.1127 22,228,665.1127
CONDENSER-01
Kondisi Operasi
T ref = 25.0000 C
Tinput = 276.0999 C

Qv = 5580649.0172
QLv = 6746.9750

Qd = 1627486.7955

Ql = 24939.1638

Q CD-01 = 3934970.0329 kJ

Twin = 28.0000 C 301.1500
Twout = 45.0000 C 318.1500
Tref = 25.0000 C 298.1500
= 55322.3770 Kg
= 694406.4764 kJ
= 4629376.5093

Qv 5,580,649.0172
Qlv 6,746.9750
Qw-in -719,067.3742
Qd 1,627,486.7955 REFRIGERANT YANG DIPAKAI A
Ql 24,939.1638 PERHITUNGAN REFRIGERANT D
Qw-out -301,788.0635 3215902.6587
Q Latent 3,517,690.7222
Total 4,868,328.6180 4,868,328.6180
Kondisi Operasi
T ref = 25.0000 C
Tinput = 320.5137 C

Air 0.0005 24,625.5958 12.4804
Asam sulfat 164.5000 46,035.2432 7,572,795.6756
Furfural 0.0000 59,917.2358 0.0228
Toluena 0.0000 59,357.1738 1.1413
Xylena 0.0000 66,539.6438 0.0402
Glukosa 0.0000 129,080.3842 0.0000
Total 164.5005 7,572,809.3603
Panas masuk RB-01,

(Ql = feed RB)
Air 0.0016 24,632.1332 39.9514
Asam sulfat 526.4475 46,045.8447 24,240,717.7959
Furfural 0.0000 59,917.2358 0.0728
Toluena 0.0001 59,357.1738 3.6525
Xylena 0.0000 66,539.6438 0.1288
Glukosa 0.0000 129,080.3842 0.0000
Total 526.4491 24,240,761.6014

Air 0.0011 24,625.5958 27.4604
Asam sulfat 361.9475 46,035.2432 16,662,340.9646
Furfural 0.0000 59,917.2358 0.0501
Toluena 0.0000 59,357.1738 2.5112
Xylena 0.0000 66,539.6438 0.0885
Glukosa 0.0000 129,080.3842 0.0000
Total 361.9487 16,662,371.0749

Q RB-01 = QLv = 16363022.2798 kJ

m = Q Lv / L
= 36153.3855 Kg

Qs-in = m x Hv
= 84700151.5626 kJ

Qc-out = m x HL
= 68337129.2827 kJ

Ql 24,240,761.6014
Qs-in 84,700,151.5626
Qv 7,572,809.3603
Panas laten 5,581.1663
Qlv 16,363,022.2798 16368603.4461
Qb 16,662,371.0749
Qc-out 68,337,129.2827
Total 108,940,913.1640 108,940,913.1640
Output
Top bot
Kg Kmol Kg
738.6547 0.0011 0.0201
11823.6182 361.9475 35470.8545
0.0801 0.0000 0.0001
30.2238 0.0000 0.0039
0.3052 0.0000 0.0001
0.0000 0.0000 0.0000
12592.8820 361.9487 35470.8787
523.9664 48063.7607
Cp (J/(mol K))
D
0.0000
0.0000
0.0000
0.0000
0.0000
Cp Glukosa 436.8000
T Operasi
= 298.1500 K
Output
Out CD-04 Bottom
C K C K
103.7924 376.9424 320.5137 593.6637
K
Lvc n (kmol) QLv

40.4353 41.6652 1,684.7434
41.2323 122.4980 5,050.8766
47.1750 0.0008 0.0400
33.5903 0.3336 11.2042
37.8832 0.0029 0.1107
137.6035 0.0000 0.0000
164.5005 6,746.9750
593.6637
Operasi
= 298.1500 K
= 549.2499 K
= 376.9424 K
K
kJ
K
k/J
K
k/J
K
k/J
Ammonia Cair
A B C
-1.82E+02 3.37E+00 -1.44E-02
K
K
K Ammonia Keluar
T -30.0000 243.0000
Tref 25.0000 298.0000
Cp Ammonia -1,939.1048 KJ/Kmol K
Ammonia Masuk
T -33.0000 240.0000
Tref 25.0000 298.0000
Cp Ammonia -4,620.2855 KJ/Kmol K
Kebutuhan Ammonia
155.6327 Kmol
2,645.7554 Kg
RANT YANG DIPAKAI AMMONIA

NGAN REFRIGERANT DI AIR TIDAK DIPAKAI
Operasi
= 298.1500 K
= 593.6637 K
= 593.6019 K NOTE !!!!!
TULIS DI LAMPIRAN SUHU OUT 340,4519
613.6019

Lvc = Lvb (((Tc-T)/(Tc-Tb))^0,38) T=
Komponen Tc (K) Tb (K)

Air 647.3000 373.1500
ASAM SULFAT 925.0000 610.0000
Total
kJ/kg
kJ/kg
kJ/kg
Ammonia Gas
D A B
2.04E-05 3.3573E+01 -1.2600E-02

UHU OUT 340,4519
593.6019 K
Lvb (KJ/Kmol) Lvc n (kmol) QLv

40.6500 21.8781 0.0005 0.0111
33.2800 33.9280 164.5000 5,581.1552
164.5005 5,581.1663
C D E
8.8900E-05 -7.1800E-08 1.8700E-11
pan ammonia pada T = -30.0000 C

243.0000 K
Hv = A*(1-T/Tc)^n ,Kj/mol T, K
Komponen A Tc n Hv (Kj/mol) Kj/Kmol

Ammonia 31.5230 405.6500 0.3640 22.6025 22,602.5211
T/Tc (1-T/Tc)
0.5990 0.4010 0.7170
Input : Keluaran Acc-04 (dari bottom RB-04)
Komponen Mol (kmol)

Air 0.0011
Furfural 0.0000
TOLUENA 0.0000
XYLENA 0.0000
Glukosa 0.0000
Total 361.9487
T in chiller -03 = 320.5137 C 593.6637

Tref 25 C 298.15

Air 0.0011 24,632.1332 27.4677
Asam sulfat 361.9475 46,045.8447 16,666,178.1668
Furfural 0.0000 59,917.2358 0.0501
TOLUENA 0.0000 59,495.2913 2.5170
XYLENA 0.0000 66,539.6438 0.0885
Glukosa 0.0000 129,080.3842 0.0000
Total 361.9487 16,666,208.2902
Heat Capacity Coefficient of Liquids Cp liq =A+B*T+C*(T^2)+D*(T^3)

Komponen A B C
Air 92.0530 -0.0400 -0.0002
Asam sulfat 26.0040 0.7034 -0.0014
Furfural 66.7920 0.7076 -0.0018
TOLUENA 83.7030 0.5167 -0.0015
XYLENA 70.9160 0.8045 -0.0022
Glukosa
Cp dT pada aliran output T= 30

Air 460.265 -60.05934725 -95.37765253
Asam sulfat 130.02 1057.3409525 -626.2392804133
Furfural 333.96 1063.6245375 -817.2386452392
TOLUENA 418.515 776.669145 -673.8761309875
XYLENA 354.58 1209.364625 -989.1199950813
Glukosa 0 0 0
Air 0.0011 377.4864 0.4209
Asam sulfat 361.9475 701.6579 253,963.3075
Furfural 0.0000 847.0956 0.0007
TOLUENA 0.0000 789.9941 0.0334
XYLENA 0.0000 915.3755 0.0012
Glukosa 0.0000 2,184.0000 0.0000
Total 361.9487 253,963.7638
Qs = 16,412,244.5263 KJ
Cp ammonia 1.042 kJ/kg.K

T1 -33 C 240.15
T2 50 C 323.15
Tref 25 C 298.15
Qs
m
Cp air x ( T 2  T1 )
= 189767.6448 kg/jam

= -11468797.3799 kJ/jam

= 4943447.1465 kJ/jam

Q1 16,666,208.2902 0.0000
Q2 0.0000 253,963.7638
Qw-in -2,999,135.8199 0.0000
Qw-out 0.0000 -1,258,718.4784 13,413,108.7064
14,671,827.1849
Total 13,667,072.4702 13,667,072.4702
K Cp dT pada aliran output RB-3
K Komponen A.T 1/2 BT^2 1/3 CT^3 1/4 DT^4
K Air 27202.9226261 -5264.6700595482 -12853.5 15547.38
Asam sulfat 7684.5382548 92684.1784042346 -84394.7 30071.82
Furfural 19737.9510504 93234.9836215878 -110135 57078.89
TOLUENA 24735.3832311 68081.1061238492 -90814.44 57493.24
XYLENA 20956.6495492 106010.238603021 -133298 72870.81
Cp (J/(mol K))
D
0.0000
0.0000
0.0000
0.0000
0.0000
Cp glukosa 436.8000
1/4 DT^4
72.6583813682
140.536194825
266.7497103476
268.6861257182
340.5509165065
0
Ammonia Cair
A B C D
-1.82E+02 3.37E+00 -1.44E-02 2.04E-05
Ammonia Keluar
T -30.0000 243.0000
Tref 25.0000 298.0000
Ammonia Masuk
T -33.0000 240.0000
Tref 25.0000 298.0000
K
K Kebutuhan Ammonia
K
649.1235 Kmol
11,035.0992 Kg
Ammonia Gas
A B C D E
3.3573E+01 -1.2600E-02 8.8900E-05 -7.1800E-08 1.8700E-11
Panas laten penguapan ammonia pada T = -30.0000

243.0000
Hv = A*(1-T/Tc)^n
Komponen A Tc
Ammonia 31.5230 405.6500
T/Tc
0.5990
C
K
,Kj/mol T, K
n Hv (Kj/mol) Kj/Kmol
0.3640 22.6025 22,602.5211
(1-T/Tc)
0.4010 0.7170
MIXING POINT 02
Input
Komponen Aliran RB 03 Utilitas
Kmol Kg Kmol Kg
Air 0.0011 0.0201 30872.7797 555710.0345
Asam sulfat 361.9475 35470.8545 0.0000 0.0000
Furfural 0.0000 0.0000 0.0000 0.0000
Toluena 0.0000 0.0000 0.0000 0.0000
Xylena 0.0000 0.0000 0.0000 0.0000
Glukosa 0.0000 0.0000 0.0000 0.0000
361.9487 35470.8746 30872.7797 555710.0345
Total
591180.9091
total masa untuk mencapai 6% Asam Sulfat 591180.9091

Air yang harus di tambahkan 555710.0345
30872.7797
0.999999434 1
Output
Aliran MP 03
Kmol Kg
30872.7808 555710.0546 0.06
361.9475 35470.8545 6.0
0.0000 0.0000
0.0000 0.0000
0.0000 0.0000
0.0000 0.0000
31234.7283 591180.9091
591180.9091
Komponen
Air
kg 0.9884120172 Asam Sulfat
kg 0.0115879828 Pentosan
kmol Selulosa
0.94 Lignin
0.06 Abu
Furfural
Glukosa
Toluena
Xylena
Bm
18
98
132
162
-
-
96
180
92
106
MIXING POINT 02
Input
Komponen Aliran RB 02 Utilitas
Kmol Kg Kmol Kg
Air 0.0000 0.0000 29.2934 527.2811
Asam sulfat 0.0000 0.0005 0.0000 0.0000
Furfural 0.0000 0.0000 0.0000 0.0000
Toluena 0.0000 0.0000 0.0000 0.0000
Xylena 0.0000 0.0000 0.0000 0.0000
Glukosa 143.5378 25836.7955 0.0000 0.0000
143.5378 25836.7960 29.2934 527.2811
Total
26364.0771
total masa untuk mencapai 98% glukosa 26364.0771

Air yang harus di tambahkan 527.2811
29.2934
1.83051E-08 1
Output
Aliran t 04
Kmol Kg
29.2934 527.2811 1.794E-08
0.0000 0.0005 0.0
0.0000 0.0000
0.0000 0.0000
0.0000 0.0000
143.5378 25836.7955
172.8312 26364.0771
26364.0771
Komponen
Air
kg 0.1694913944 Asam Sulfat
kg 2.79230142E-08 Pentosan
kmol Selulosa
0.0199999821 Lignin
1.79389831E-08 Abu
Furfural
Glukosa
Toluena
Xylena
Bm
18
98
132
162
-
-
96
180
92
106
Neraca panas MP-01
input
BM Komponen aliran rb-02
kmol kg
92 Air 0.0000 0.0000
106 Asam sulfat 0.0000 0.0005
Furfural 0.0000 0.0000
Toluena 0.0000 0.0000
Xylena 0.0000 0.0000
96 Glukosa 143.5378 25836.7955
Subtotal 25836.7960
Total 26364.0771
neraca panas MP-04 1.8305084503E-08
komponen input (kJ) output (kJ)
panas sensibel masuk (Q17) 62,697.2939 0.0000
panas sensibel keluar (Q3) 0.0000 73,755.1507
TOTAL 73,755.1507 73,755.1507

Heat Capacity Coefficient of Liquids
Cp liq =A+B*T+C*(T^2)+D*(T^3) Cp (J/(mol K))
Komponen A B
Air 9.21E+01 -4.00E-02
Asam sulfat 2.60E+01 7.03E-01
Furfural 6.68E+01 7.08E-01
Toluena 8.37E+01 5.17E-01
Xylena 7.09E+01 8.05E-01
Glukosa
Tref = 25 C 298.15
PANAS MASUK
dari tangki-01 30 C 303.15
komponen kmol CpdT Q

Air 0.0000 377.4864 0.0000
Asam sulfat 0.0000 701.6579 0.0034
Furfural 0.0000 847.0956 0.0000
Toluena 0.0000 789.9941 0.0000
Xylena 0.0000 915.3755 0.0000
Glukosa 143.5378 436.8000 62,697.2905
TOTAL 62,697.2939
dari KD-01 30 C 303.15
Air 29.2934 377.4864 11,057.8568
Asam sulfat 0.0000 701.6579 0.0000
Furfural 0.0000 847.0956 0.0000
Toluena 0.0000 789.9941 0.0000
Xylena 0.0000 915.3755 0.0000
Glukosa 0.0000 436.8000 0.0000
total 11,057.8568
PANAS KELUAR
Ke KE-01 30 C 303.15
Air 29.2934 377.4864 11,057.8568
Asam sulfat 0.0000 701.6579 0.0034
Furfural 0.0000 847.0956 0.0000
Toluena 0.0000 789.9941 0.0000
Xylena 0.0000 915.3755 0.0000
Glukosa 143.5378 436.8000 62,697.2905
total 73,755.1507
input
Aliran T-04
UTL
kmol kg kmol kg
29.2934 527.2811 29.2934 527.2811
0.0000 0.0000 0.0000 0.0005
0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 143.5378 25836.7955
527.2811
26364.0771 26364.0771
1 1.7938983141E-08
29.2934 172.8312
(T=K)
C D Tmin Tmax T Cp at T
-2.11E-04 5.35E-07 179 533 298.15 157.48
-1.39E-03 1.03E-06 226 555 298.15 75.55
-1.81E-03 1.96E-06
-1.49E-03 1.98E-06
-2.19E-03 2.51E-06
K Cp Glukosa 436.8
5
K
K
K
Neraca panas MP-01
input
BM Komponen aliran ACC
kmol kg
92 Air 0.0011 0.0201
106 Asam sulfat 361.9475 35470.8545
Furfural 0.0000 0.0001
Toluena 0.0000 0.0039
Xylena 0.0000 0.0001
96 Glukosa 0.0000 0.0000
Subtotal 35470.8787
Total 591180.9132
neraca panas MP-04 0.9999993182
panas sensibel masuk (Q26) 11,654,053.8961 0.0000
panas sensibel keluar (Q3) 0.0000 11,908,017.6246
TOTAL 11,908,017.6600 11,908,017.6246

Komponen A B
Air 92.053 -0.039953
Asam sulfat 26.004 0.70337
Furfural 66.792 0.70755
Toluena 83.703 0.51666
Xylena 70.916 0.8045
Glukosa
Tref = 25 C 298.15
PANAS MASUK

Air 0.0011 377.4864 0.4209
Asam sulfat 361.9475 701.6579 253,963.3075
Furfural 0.0000 847.0956 0.0007
Toluena 0.0000 789.9941 0.0334
Xylena 0.0000 915.3755 0.0012
Glukosa 0.0000 436.8000 0.0000
TOTAL 253,963.7638
dari KD-01 30 C 303.15
Air 30,872.7797 377.4864 11,654,053.8961
Asam sulfat 0.0000 701.6579 0.0000
Furfural 0.0000 847.0956 0.0000
Toluena 0.0000 789.9941 0.0000
Xylena 0.0000 915.3755 0.0000
Glukosa 0.0000 436.8000 0.0000
total 11,654,053.8961
PANAS KELUAR
Ke KE-01 30 C 303.15
Air 30,872.7808 377.4864 11,654,054.3171
Asam sulfat 361.9475 701.6579 253,963.3075
Furfural 0.0000 847.0956 0.0000
Toluena 0.0000 789.9941 0.0000
Xylena 0.0000 915.3755 0.0000
Glukosa 0.0000 436.8000 0.0000
total 11,908,017.6246
input
Aliran MP-03
UTL
kmol kg kmol kg
30872.7797 555710.0345 30872.7808 555710.0546
0.0000 0.0000 361.9475 35470.8545
0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000
555710.0345
591180.9132 591180.9091
1 0.06
31234.7283 31234.7283
(T=K)
-0.00021103 5.3469E-07 179 533 298.15 157.48
-0.0013856 1.0342E-06 226 555 298.15 75.55
-0.0018082 0.000001963
-0.001491 1.97725E-06
-0.0021885 2.5061E-06
K Cp Glukosa 436.8
5
K
K
K
MIXING POINT 02
0.0600 0.0600
Input
Komponen Aliran MP 2 Aliran MT 01
Kmol Kg Kmol Kg
Air 30872.7808 555710.0546 10332.1323 185978.3807
Asam sulfat 361.9475 35470.8545 121.1322 11870.9605
Furfural 0.0000 0.0000 0.0000 0.0000
Toluena 0.0000 0.0000 0.0000 0.0000
Xylena 0.0000 0.0000 0.0000 0.0000
Glukosa 0.0000 0.0000 0.0000 0.0000
31234.7283 591180.9091 10453.2645 197849.3412
Total
789030.2503
Kebutuhan Reaktor
mol kg fraksi
air 41204.9131 741688.4353 0.94
asam sulfat 483.0797 47341.8150 0.06
41687.9928 789030.2503
0.94 0.94
0.06 0.06
0.0600
Output
Aliran R-01
Kmol Kg
41204.9131 741688.4353 0.06
483.0797 47341.8150 6.0
0.0000 0.0000
0.0000 0.0000
0.0000 0.0000
0.0000 0.0000 Komponen Bm
41687.9928 789030.2503 Air 18
789030.2503 Asam Sulfat 98
Pentosan 132
0.9884120172 Selulosa 162
0.0116 Lignin -
197849.3412 Abu -
Furfural 96
Glukosa 180
Toluena 92
Xylena 106
0.94
0.06
Neraca panas MP-01
input
BM Komponen aliran MP-2
kmol kg
92 Air 30872.7808 555710.0546
106 Asam sulfat 361.9475 35470.8545
Furfural 0.0000 0.0000
Toluena 0.0000 0.0000
Xylena 0.0000 0.0000
96 Glukosa 0.0000 0.0000
Subtotal 591180.9091
Total 789030.2503
panas sensibel keluar (Q3) 0.0000 15,893,250.2418
TOTAL 15,893,250.2418 15,893,250.2418

Komponen A B
Air 92.053 -0.039953
Asam sulfat 26.004 0.70337
Furfural 66.792 0.70755
Toluena 83.703 0.51666
Xylena 70.916 0.8045
Glukosa
Tref = 25 C 298.15
PANAS MASUK

Air 30,872.7808 377.4864 11,654,054.3171
Asam sulfat 361.9475 701.6579 253,963.3075
Furfural 0.0000 847.0956 0.0000
Toluena 0.0000 789.9941 0.0000
Xylena 0.0000 915.3755 0.0000
Glukosa 0.0000 436.8000 0.0000
TOTAL 11,908,017.6246
dari KD-01 30 C 303.15
Air 10,332.1323 377.4864 3,900,239.2213
Asam sulfat 121.1322 701.6579 84,993.3959
Furfural 0.0000 847.0956 0.0000
Toluena 0.0000 789.9941 0.0000
Xylena 0.0000 915.3755 0.0000
Glukosa 0.0000 436.8000 0.0000
total 3,985,232.6172
PANAS KELUAR
Ke KE-01 30 C 303.15
Air 41,204.9131 377.4864 15,554,293.5384
Asam sulfat 483.0797 701.6579 338,956.7035
Furfural 0.0000 847.0956 0.0000
Toluena 0.0000 789.9941 0.0000
Xylena 0.0000 915.3755 0.0000
Glukosa 0.0000 436.8000 0.0000
total 15,893,250.2418
input
Aliran R-01
Aliran MT-1
kmol kg kmol kg
10332.1323 185978.3807 41204.9131 741688.4353
121.1322 11870.9605 483.0797 47341.8150
0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000
197849.3412
789030.2503 789030.2503
0.94 0.06
41687.9928 41687.9928
(T=K)
-0.00021103 5.3469E-07 179 533 298.15 157.48
-0.0013856 1.0342E-06 226 555 298.15 75.55
-0.0018082 0.000001963
-0.001491 1.97725E-06
-0.0021885 2.5061E-06
K Cp Glukosa 436.8
5
K
K
K
STORAGE TANK
Fungsi = Menampung Produk Glukosa

T= 30 °C
P= 1 atm
Input
Komponen Aliran 18
Kmol Kg 143.5378
Air 29.2934 527.2811 3.362E-08
Asam sulfat 0.0000 0.0005 1
Furfural 0.0000 0.0000
Toluena 0.0000 0.0000
Xylena 0.0000 0.0000 98.00%
Glukosa 143.5378 25836.7955
Total 26364.0771
26364.0771
0.00%
Komponen Mol (kmol)

Air 0.0000
Asam sulfat 0.0000
Furfural 0.0000
TOLUENA 0.0000
XYLENA 0.0000
Glukosa 143.5378
Total 143.5378
T in chiller -03 = 353.5562915792 C 626.7062915792

Tref 25 C 298.15

Air 0.0000 28,288.2020 0.0000
Asam sulfat 0.0000 51,805.1307 0.2500
Furfural 0.0000 68,885.6772 0.0000
TOLUENA 0.0000 69,184.1657 0.0000
XYLENA 0.0000 76,999.2109 0.0000
Glukosa 143.5378 143,513.3882 20,599,589.2661
Total 143.5378 20,599,589.5161
Heat Capacity Coefficient of Liquids Cp liq =A+B*T+C*(T^2)+D*(T^3)

Komponen A B C
Air 92.0530 -0.0400 -0.0002
Asam sulfat 26.0040 0.7034 -0.0014
Furfural 66.7920 0.7076 -0.0018
TOLUENA 83.7030 0.5167 -0.0015
XYLENA 70.9160 0.8045 -0.0022
Glukosa

Air 460.265 -60.05934725 -95.37765253
Asam sulfat 130.02 1057.3409525 -626.2392804133
Furfural 333.96 1063.6245375 -817.2386452392
TOLUENA 418.515 776.669145 -673.8761309875
XYLENA 354.58 1209.364625 -989.1199950813
Glukosa 0 0 0
Air 0.0000 377.4864 0.0000
Asam sulfat 0.0000 701.6579 0.0034
Furfural 0.0000 847.0956 0.0000
TOLUENA 0.0000 789.9941 0.0000
XYLENA 0.0000 915.3755 0.0000
Glukosa 143.5378 2,184.0000 313,486.4526
Total 143.5378 313,486.4560
Qs = 20,286,103.0601 KJ

T1 -33 C 240.15
T2 50 C 323.15
Tref 25 C 298.15
Qs
m
Cp air x ( T 2  T1 )
= 234559.3860 kg/jam

= -14175831.0540 kJ/jam

= 6110272.0060 kJ/jam

Q1 20,599,589.5161 0.0000
Q2 0.0000 313,486.4560
Qw-in -3,707,035.8193 0.0000
Qw-out 0.0000 -1,555,819.6648 16,579,067.2408
18,134,886.9056
Total 16,892,553.6968 16,892,553.6968
K Cp dT pada aliran output RB-3
K Komponen A.T 1/2 BT^2 1/3 CT^3 1/4 DT^4
K Air 30244.5923087404 -6070.2061852942 -15450.36 19564.17
Asam sulfat 8543.7778062256 106865.590182223 -101445 37841.12
Furfural 21944.9318271582 107500.672950839 -132386 71825.67
TOLUENA 27501.1472740541 78498.0534051028 -109162 72347.08
XYLENA 23299.8979736308 122230.642907144 -160229 91697.56
Cp (J/(mol K))
D
0.0000
0.0000
0.0000
0.0000
0.0000
Cp glukosa 436.8000
1/4 DT^4
72.6583813682
140.536194825
266.7497103476
268.6861257182
340.5509165065
0
Ammonia Cair
A B C D
-1.82E+02 3.37E+00 -1.44E-02 2.04E-05
Ammonia Keluar
T -30.0000 243.0000
Tref 25.0000 298.0000
Ammonia Masuk
T -33.0000 240.0000
Tref 25.0000 298.0000
K
K Kebutuhan Ammonia
K
802.3391 Kmol
13,639.7650 Kg
Ammonia Gas
A B C D E
### ### ### ### 1.8700E-11
Panas laten penguapan ammonia pada -30.0000 C

243.0000 K
Hv = A*(1-T/Tc)^n ,Kj/mol
Komponen A Tc n
Ammonia 31.5230 405.6500 0.3640
0.5990 0.4010
T, K
Hv (Kj/mol) Kj/Kmol
22.6025 22,602.5211
0.7170
Input dari keluaran atas Kolom Ekstraktor, pada T = 30 C
Komponen n Cp Q (KJ) Q
Air - - -
Asam Sulfat - - -
Furfural 25.6510 847.0956 21,728.8846 21.7289
Toluena 328.2332 789.3487 259,090.4163 259.0904
Xylena 2.8776 915.3755 2,634.0775 2.6341
Glukosa - - -
total 353.8842 1,636.4443 283,453.3783 283.4534
T ref 25 C 298.15
T in 30 C 303.15 K
Tout heater 80 C 353.15 K
Komponen A B C D E
Air 92.053 -4.00E-02 -2.11E-04 5.35E-07 -
Asam Sulfat 26.004 7.03E-01 -1.39E-03 1.03E-06 -
Furfural 66.792 7.08E-01 -1.81E-03 1.96E-06 -
Glukosa - - - - -
Toluena 83.703 5.17E-01 -1.49E-03 1.97E-06
Xylena 70.916 8.05E-01 -2.19E-03 2.51E-06

Furfural 3673.56 12672.7511625 -10571.64188013 3755.1067804
Toluena 4603.665 9253.768095 -8717.131978363 3773.27973731
Xylena 3900.38 14409.198375 -12795.06595214 4794.02603279
Komponen mol Cp Dt Q (KJ) Q

Furfural 25.6510 9529.7760627716 244448.6831046 244.448683105
Toluena 328.2332 8913.5808539496 2925732.9081095 2925.73290811
Xylena 2.8776 10308.5384556461 29663.769047418 29.6637690474
3199845.3602615 3199.84536026
Qs = Q keluar - Q masuk = 2,916,391.9819 kJ



= 452.6000 Kj/Kg
= 6,443.6411 Kg

Qs in = m x Hv = 15,096,162.4730 kJ

Qs out = m x Hl = 12,179,770.4910 kJ
Neraca Panas H-02

Q in heater 283,453.3783 0.0000
Q out heater 0.0000 3,199,845.3603
Qs in 15,096,162.4730 0.0000
Qs out 0.0000 12,179,770.4910
Total 15,379,615.8513 15,379,615.8513
KOLOM DESTILASI-01
Fungsi : Untuk memisahkan furfural dan air dari TOLUENA
Komponen Masuk
Input
Komponen Xi
TOLUENA 327.5664 30197.4517 0.9199
XYLENA 2.8717 305.0248 0.0081
FURFURAL 25.6510 2462.5000 0.0720
Total 356.0891 32964.9765 1.0000
Komponen ANTA ANTB ANTC

Toluena 16.0137 3096.52 -53.67
Xylena 16.1169 3369.74 -58.45
Furfural 18.7949 5365.88 5.4
1 atm = 760 mmHg
Kondisi Operasi : T 116.3255 C

P 1.10 atm

Komponen Pi (mmHg) Pi (atm) kmol

Toluena 891.1653 1.1726 327.5664
Xylena 378.8734 0.4985 2.8717
Furfural 182.3836 0.2400 25.6510
Total 356.0891
Komponen Pi (mmHg) Ki (Pi/P) Xi

Toluena 891.1653 1.0660 0.9199
Xylena 378.8734 0.4532 0.0081
Furfural 182.3836 0.2182 0.0720
Total 1.0000
Ditetapkan
LK : TOLUENA
HK : FURFURAL
Komponen Ki (Pi/P) K ref alpha (ki/kref)

Toluena 1.0660 0.2182 4.8862
Xylena 0.4532 0.2182 2.0773
Furfural 0.2182 0.2182 1.0000
Total 7.9636
Diinginkan distribusi komponen kunci LK
LIGHT Key
TOLUENA D 327.5664
TOLUENA B 0.0000
Log D/B 12.3102
Key Komponen X = log iK Y = log iD/iB X.Y

Toluena 0.6890 12.3102 8.4814
Furfural 0.0000 -9.0000 0.0000
Total 0.6890 3.3102 8.4814
y = aX + B
a (slope) 30.9305 (((2*D64)-(B64*C64))/((2*E64)-(B64^2)))

b (intercept) -9.0000 ((C64-(B68*B64))/2)

Komponen X = log iK Y = log iD/iB iD/iB
Toluena 0.6890 12.3102 2042912055962.0200
Xylena 0.3175 0.8207 6.6174
Furfural 0.0000 -9.0000 0.0000

Toluena 327.5664 0.9924 30136.1088
Xylena 2.4947 0.0076 229.5130
Furfural 0.0000 0.0000 0.0000
Total 330.0611 1.0000 30365.6218

Pressure 1.05 atm
Komponen Kg Xi A
Toluena 30136.1088 0.9924 16.0137
Xylena 229.5130 0.0076 16.1169
Furfural 0.0000 0.0000 18.7949
Total 30365.6218 1.0000
Bottom Trial Error

Pressure 1.15 atm
Komponen Kg Xi A
Toluena 0.0000 0.0000 16.0137
Xylena 39.9613 0.0145 16.1169
Furfural 2462.5000 0.9855 18.7949
Total 2502.4613 1.0000

Input Output
Komponen Aliran 9 Aliran Top (10)
Kmol Kg Kmol
Toluena 327.5664 30136.1088 327.5664
Xylena 2.8717 304.4002 2.4947
Furfural 25.6510 2462.5000 0.0000
356.0891 32903.0090 330.0611
Total
32903.0090 32903.0090
0.9924416819
0.007558318
KOLOM DESTILASI-01
Komponen BM
%
Toluena 92
91.6047 Furfural 96
0.9253 Xylena 106
7.4700
100.0000
Tmin Tmax
7 137
28 168
77 277
389.476 K
836 mmHg
BM
92
106
96
Yi (Ki.Xi)
0.9806
0.0037
0.0157
1.0000
log alpha
0.6890
0.3175
0.0000
1.0000000000 HK 0.0%
0.0000000000 100.0%
Heavy Key
FURFURAL D 0.0000
FURFURAL B 25.6510
Log D/B -9.0000
X^2
0.4747
0.0000
0.4747
4*C64))/((2*E64)-(B64^2)))
D (mol) B (mol)
327.5664 0.0000
2.4947 0.3770
0.0000 25.6510

0.9924 Toluena 0.0000 0.0000 0.0000
0.0076 Xylena 0.3770 0.0145 39.9613
0.0000 Furfural 25.6510 0.9855 2462.5000
Total 26.0280 1.0000 2502.4613
385.8719530432 Kelvin
798 mmHg
B C Pi (mmHg) Ki (Pi/P) Xi = Yi/Ki

3096.52 -53.67 806.3376 1.0104 0.9822
3369.74 -58.45 338.7170 0.4245 0.0178
5365.88 5.4 160.9285 0.2017 0.0000
1.0000
NOTE !!!!!!!!!!
440.5673388207 Kelvin TULIS DI LAMPIRAN 147,4173 C KARENA KALAU 167,417338
874 mmHg
B C Pi (mmHg) Ki (Pi/P) Yi = Xi*Ki Ln(Pi) =

3096.52 -53.67 3011.6194 3.4458 0.0000 Pi =
3369.74 -58.45 1477.7854 1.6908 0.0245
5365.88 5.4 865.1456 0.9899 0.9755
1.0000
Output
Aliran Top (10) Aliran bottom (11) Kemurnian furfural hasil destilasi :
Kg Kmol Kg 0.9840 98.4
30136.1088 0.0000 0.0000
264.4389 0.3770 39.9613
0.0000 25.6510 2462.5000 0.98551588
30400.5477 26.0280 2502.4613 0.01448412 18017.72121
32903.0090
0.014484121
0.9913015079 0.985515879 DI LAMPIRAN MASSA TULIS 30400,5497
5.894814E-12
RENA KALAU 167,4173388 FURFURAL SUDAH NGUAP
ANTA - ANTB/(T+ANTC)
exp (ANTA - (ANTB/(T+ ANTC)))
hasil destilasi :
%
Condensor-01
Kondisi Operasi
Temp 112.7219530432 C 385.8719530432 K
Press 1 atm 760 mmHg

Toluena 0.9199 0.9924 4.8862 0.7830
Xylena 0.0081 0.0076 2.0773 0.4895
Furfural 0.0720 0.0000 1.0000 -0.0605
Total 1.0000 1.0000
L/D + 1 1.2830
L/D min 0.2829869
L/D aktual = 1,5 x L/D min 0.4244804
V = L+D = (R+1).D 470.1656
L = RxD 140.1045

Toluena 466.6119 42928.2960 0.9924 92
Xylena 3.5537 376.6881 0.0076 106
Furfural 0.0000 0.0000 0.0000 96
Total 470.1656 43304.9840 1.0000
Komposisi Reflux
Toluena 139.0455 12792.1872 0.9924 92
Xylena 1.0590 112.2491 0.0076 106
Furfural 0.0000 0.0000 0.0000 96
Total 140.1045 12904.4363 1.0000
Komposisi Destilat
Toluena 327.5664 30136.1088 0.9924 92
Xylena 2.4947 264.4389 0.0076 106
Furfural 0.0000 0.0000 0.0000 96
Total 330.0611 30400.5477 1.0000
Input Output
Kmol Kg Kmol Kg
Toluena 466.6119 42928.2960 139.0455 12792.1872
Xylena 3.5537 376.6881 1.0590 112.2491
Furfural 0.0000 0.0000 0.0000 0.0000
470.1656 43304.9840 140.1045 12904.4363
Total
43304.9840 43304.9840
Input Output
Kg Kg Kg
Toluena 42928.2960 12792.1872 30136.1088
Xylena 376.6881 112.2491 264.4389
Furfural 0.0000 0.0000 0.0000
Sub Total 43304.9840 12904.4363 30400.5477
Total 43304.9840 43304.9840
1.1749 1.2675
0.0165 0.0154
-1.1909 0.0000
0.0005 1.2829869
1,2-1,5
Output
Kmol Kg
327.5664 30136.1088 0.9924416819 0.992442
2.4947 264.4389 0.007558318 0.007558
0.0000 0.0000
330.0611 30400.5477 0.9924416819
3304.9840 0.007558318
ACCUMULATOR-01
Input Output
Kmol Kg Kmol Kg
Toluena 466.6119 42928.2960 139.0455 12792.1872
Xylena 3.5537 376.6881 1.0590 112.2491
Furfural 0.0000 0.0000 0.0000 0.0000
470.1656 43304.9840 140.1045 12904.4363
Total
43304.9840 43304.9840
Input OUTPUT
Kg Kg Kg
Toluena 42928.2960 12792.1872 30136.1088
Xylena 376.6881 112.2491 264.4389
Furfural 0.0000 0.0000 0.0000
Sub Total 43304.9840 12904.4363 30400.5477
Total 43304.9840 43304.9840
CCUMULATOR-01
Output Komponen BM
Kmol Kg Xylena 106
327.5664 30136.1088 0.992441682 Furfural 96
2.4947 264.4389 0.007558318
0.0000 0.0000
330.0611 30400.5477
43304.9840
0.9913015079
99.130150794
8.100184E-11
30533.009501
132.4618
Reboiler 01 (RB-01)
Temp 167.4173388207 C 440.5673388207

Press 1.1500 atm 874
L* = F + L 496.1936
B* = L* - V* 26.0280

Komponen XL kmol kg
TOLUENA 0.0000 0.0000 0.0000
XYLENA 0.0145 7.1869 761.8144
Furfural 0.9855 489.0067 46,944.6413
Total 1.0000 496.1936 47,706.4557
496.1936
Komponen YV kmol kg
TOLUENA 0.0000 0.0000 0.0000
XYLENA 0.0145 6.8099 721.8531
Furfural 0.9855 463.3556 44,482.1413
Total 1.0000 470.1656 45,203.9944
470.1656
Komponen XB kmol kg
TOLUENA 0.0000 0.0000 0.0000
XYLENA 0.0145 0.3770 39.9613
Furfural 0.9855 25.6510 2,462.5000
Total 1.0000 26.0280 2,502.4613
26.0280
Input Outpu
Komponen
TOLUENA 0.0000 0.0000 0.0000
XYLENA 761.8144 7.1869 721.8531
Furfural 46,944.6413 489.0067 44,482.1413
45,203.9944
TOTAL 47,706.4557 496.1936
TOTAL 47,706.4557 496.1936
47,706.4557
47,706.4557 0.0144841209
0.9855158791
01 (RB-01)
n tujuan mempertahankan Fungsi : Untuk menguapkan light key yang m
K NOTE !!!!!!!!!!
mmHg TULIS DI LAMPIRAN 147,4173 C
KARENA KALAU 167,4173388 FURFURAL SUDAH NGUAP
142.4173
Keterangan :
BM aliran V* = aliran komponen vapo
92.0000 aliran L* = aliran komponen feed
106.0000 aliran B = aliran komponen botto
96.0000
L∗−L
q=
F
BM
92.0000 Feed masuk pada kondisi bubble p
106.0000 sehingga :
96.0000 L*=F+L
V* = V + (1-q) x F
B = L* - V*
BM dimana :
92.0000 L* = komponen trap o
106.0000 V* = komponen vapor
96.0000 F = komponen feed K
L = komponen refluk
V = komponen feed C
Output
0.0000 0.0000 0.0000
6.8099 39.9613 0.3770 0.014484
463.3556 2,462.5000 25.6510 0.985516
470.1656 2,502.4613 26.0280
47,706.4557 496.1936
0.9840312096
uapkan light key yang masih ada dalam produk bottom KD-01

L∗− L
q=
F
k pada kondisi bubble point atau saturated liquid feed, q = 1
V* = V + (1-q) x F winkle 6.45 6.46

B = L* - V*

VAPORIZER-01
Fungsi: untuk menguapkan asam sulfat
Output
Input
Komponen W (liquid)
kmol kg kmol
Toluena 327.5664 30136.1088 #REF!
Xylena 2.4947 264.4389 9.2583
Furfural 0.0000 0.0000 0.1630
Total 330.0611 30400.5477 #REF!
30400.5477 #REF!
Kondisi Operasi:
T 110 C = 383.1500 K
P 1 atm = 760.0000 mmHg
Diketahui Persamaan,
Pi* (mmHg) = exp[A-(B/(T+C)]
1 atm = 760 mmHg
Diketahui data konstanta tekanan uap komponen murni:
Komponen A B C Pi (mmHg) BM
Toluena 16.0137 3096.5200 -53.6700 746.5755 92
Xylena 16.1169 3369.7400 -58.4500 310.7192 106
Furfural 18.7949 5,365.8800 5.4000 146.1873 96
Persamaan: pers. 9.37 Treyball
(W/D)= 0.029 Ki=Pi*/P xW=yD/Ki
komponen kmol zF Ki yD xW
Toluena 327.5664 0.9924 0.9823 0.9919 1.0098

Xylena 2.4947 0.0076 0.4088 0.0073 0.0178
Furfural 0.0000 0.0000 0.1924 0.0000 0.0000
Total 330.0611 1.0000 1.5835 0.9992 1.0276
F=W+D 330.0611 Total Mol Input = F

D (VAPOR) 320.89247 (W+D)/(W/D)+1)
W (LIQUID) 9.1686 (W+D)-D
VAPORIZER-01 (VP-01)
Kondisi Operasi
T = 110.9564 C = 384.1064
P = 1.0000 atm = 760.0000
Ln (Pi) = A - B / (T + C)
Pi = exp (A - (B / (T + C)))
V = 0.8000
Effisiensi Penguapan Alat
Komposisi Massa (kg) Mol (kmol) BM

Toluena 30136.1088 327.5664 96
Xylena 264.4389 2.4947 92
Furfural 0.0000 0.0000 106
Total 30400.5477 330.0611
Komponen Massa (kg) Mol (kmol) zi Pi (kPa)

Toluena 30136.1088 327.5664 0.9924 767.1626
Xylena 264.4389 2.4947 0.0076 320.3353
Furfural 0.0000 0.0000 0.0000 151.2294
Total 30400.5477 330.0611 1.0000 1238.7273
Neraca Massa Vaporizer-01 (VP-01)

Aliran 45 Aliran 46
Massa (kg) Mol (kmol) Massa Vapor Mol Vapor
Toluena 31446.3744 327.5664 25204.1629 262.5434
Xylena 229.5130 2.4947 144.0644 1.5659
Furfural 0.0000 0.0000 0.0000 0.0000
Subtotal 31675.8874 330.0611 25348.2272 264.1093
Total 31675.8874 31675.8874
rasio mol 1,5:1
basis: 328.782 kmol formaldehida
Output kemurnian asam asetat

W (liquid) D (Vapor)
kg kmol kg
#REF! #REF! #REF!
851.7665 318.3081 29284.3423 328.782
17.2734 2.3317 247.1655
#REF! #REF! #REF!
#REF!
CARO NENTUIN KEK MANO??? Komponen ANTA ANTB ANTC
Air 18.3036 3816.44 -46.13
Furfural 18.7949 5365.88 5.4
Toluena 16.0137 3096.52 -53.67
Xylena 16.1169 3369.74 -58.45
keterangan:
Ki=m
W (liquid) D(vapor)
kmol kg kmol kg
9.2583 851.7665 318.3081 29284.3423
0.1630 17.2734 2.3317 247.1655
0.0000 0.0000 0.0000 0.0000
9.4213 869.0400 320.6398 29531.5078
K
mmHg
(Sumber: Buku Perry Hal: 686)
Ki = Pi / P Xi Yi
1.0094 0.9850 0.9943
0.4215 0.0141 0.0059
0.1990 0.0000 0.0000
1.6299 0.9991 1.0002
Output
Aliran 49
Massa Liquid Mol Liquid
6242.2115 65.0230
85.4487 0.9288
0.0000 0.0000
6327.6602 65.9518
31675.8874
formaldehida
99.80% 0.998
0.001 asam format
0.001 aasetaldehida
Tmin Tmax
0 0
0 0
7 137
28 168
O
Komponen Input Top
Kmol Kg Kmol
Toluene 327.5664 30136.1088 327.5664
Xylane 2.8717 304.4002 2.4947
Furfural 25.6510 2462.5000 0.0000
356.0891 32903.0090 330.0611
Total
356.0891
Komponen A B C
TOLUENA 83.7030 0.5167 -0.0015
XYLENA 70.9160 0.8045 -0.0022
FURFURAL 66.7920 0.7076 -0.0018
T Operasi
T ref = 25.0000 C
Input Output
H-03 Top CD-01
C K C K
80.0000 353.1500 112.7220 385.8720
Panas masuk KD-01

TOLUENA 327.5664 8913.5809 2919789.5914
XYLENA 2.8717 10308.5385 29603.0299
FURFURAL 25.6510 9529.7761 244448.6831
Total 356.0891 3193841.3044

TOLUENA 466.6119 14496.4471 6764214.9266
XYLENA 3.5537 16717.6173 59408.7431
FURFURAL 0.0000 15433.5283 0.0006
Total 470.1656 6823623.6703

TOLUENA 327.5664 11055.6514 3621459.9203
XYLENA 2.4947 12772.8924 31864.6215
FURFURAL 0.0000 11802.5158 0.0003
Total 330.0611 3653324.5421

TOLUENA 139.0455 11055.6514 1537238.7149
XYLENA 1.0590 12772.8924 13525.9069
FURFURAL 0.0000 11802.5158 0.0001
Total 140.1045 1550764.6219

Lvc = Lvb (((Tc-T)/(Tc-Tb))^0,38) T= 365.8700

TOLUENA 591.7900 383.7800 33.1800
XYLENA 617.0500 412.2700 35.6600
FURFURAL 657.0000 434.8500 43.2000
Total

TOLUENA 0.0000 20707.5164 0.0000
XYLENA 0.3770 23790.8115 8968.9742
FURFURAL 25.6510 21916.3149 562176.3073
Total 26.0280 571145.2815

Q CD-01 = 1635647.2699 kJ

Q RB-01 = 2666275.7890 kJ
Neraca Panas KD-01

Qin KD-01 3,193,841.3044
Q RB-01 2,666,275.7890
Qd CD-01 3,653,324.5421
Qbottom 571,145.2815
Q CD-01 1,635,647.2699
Total 5,860,117.0934 5,860,117.0934
CONDENSER-01
Kondisi Operasi
T ref = 25.0000 C
Tinput = 112.7220 C
Toutput = 92.7200 C

Qv = 6823623.6703

QLv = 16112.7636

Qd = 3653324.5421

Ql = 1550764.6219

Q CD-01 = 1635647.2699 kJ

Twin = 28.0000 C 301.1500
Twout = 45.0000 C 318.1500
Tref = 25.0000 C 298.1500
= 22995.8282 Kg
= 288643.6359 kJ
= 1924290.9057

Qv 6,823,623.6703
Qlv 16,112.7636
Qw-in -298,894.4204 REFRIGERANT YANG DIPAK
Qd 3,653,324.5421 PERHITUNGAN REFRIGERA
Ql 1,550,764.6219
Qw-out -125,444.1121 1336752.8494
q LATENT 1,462,196.9616
Total 6,540,842.0134 6,540,842.0134
Kondisi Operasi
T ref = 25.0000 C
Tinput = 147.4173 C
T output = 174.8889 C

TOLUENA 0.0000 25,886.1808 0.0001
XYLENA 6.8099 29,639.0184 201,839.7888
FURFURAL 463.3556 27,242.3416 12,622,892.5719
Total 470.1656 12,824,732.3608
Panas masuk RB-01,

(Ql = feed RB)
TOLUENA 0.0000 20,707.5164 0.0001
XYLENA 7.1869 23,790.8115 170,982.8540
FURFURAL 489.0067 21,916.3149 10,717,224.4077
Total 496.1936 10,888,207.2617

TOLUENA 0.0000 25,886.1808 0.0000
XYLENA 0.3770 29,639.0184 11,173.7085
FURFURAL 25.6510 27,242.3416 698,794.4383
Total 26.0280 709,968.1468

Q RB-01 = QLv = 2666275.7890 kJ

m = Q Lv / L
= 5891.0203 Kg

Qs-in = m x Hv
= 13801482.3651 kJ

Qc-out = m x HL
= 11135206.5761 kJ
Ql 10,888,207.2617
Qs-in 13,801,482.3651
Qv 12,824,732.3608
Panas latent 19,782.5431
Qlv
Qb 709,968.1468
Qc-out 11,135,206.5761
Total 24,689,689.6269 24,689,689.6269 Tulks output Q sama dengan inp
Output
Top bot
Kg Kmol Kg
30136.1088 0.0000 0.0000
264.4389 0.3770 39.9613
0.0000 25.6510 2462.5000
30400.5477 26.0280 2502.4613
356.0891 32903.0090
Cp (J/(mol K))
D
0.0000
0.0000
0.0000
Operasi
= 298.1500 K
Output
Out CD-01 Bottom
C K C K
92.7200 365.8700 147.4173 420.5673
K
Lvc n (kmol) QLv

34.2379 466.6119 15975.8135
38.5378 3.5537 136.9501
47.8753 0.0000 0.0000
470.1656 16112.7636
420.5673
ENSER-01
erasi
= 298.1500 K
= 385.8720 K
= 365.8700 K
K
kJ
K Ammonia Cair
k/J A B C D
-1.82E+02 3.37E+00 -1.44E-02 2.04E-05
K
k/J
Ammonia Keluar
K T -30.0000 243.0000
k/J Tref 25.0000 298.0000
lv - Qd - Ql
Ammonia Masuk
T -33.0000 240.0000
Tref 25.0000 298.0000
K
K
K Kebutuhan Ammonia
64.6918 Kmol
1,099.7600 Kg
GERANT YANG DIPAKAI AMMONIA
TUNGAN REFRIGERANT DI AIR TIDAK DIPAKAI
erasi SUHU INPUT

= 298.1500 K NOTE !!!!!!!!!!
= 420.5673 K TULIS DI LAMPIRAN 147,4173 C
= 448.0389 K
SUHU OUTPUT
NOTE !!!!!!!!!!
TULIS DI LAMPIRAN 174.8889 C

Lvc = Lvb (((Tc-T)/(Tc-Tb))^0,38) T= 448.0389 K
Komponen Tc (K) Tb (K) Lvb (KJ/Kmol) Lvc n (kmol)
TOLUENA 591.7900 383.7800 33.1800 28.8335 0.0000
XYLENA 617.0500 412.2700 35.6600 33.1512 6.8099
FURFURAL 657.0000 434.8500 43.2000 42.2069 463.3556
Total 470.1656

kJ/kg
kJ/kg
kJ/kg
utput Q sama dengan input
Ammonia Gas
A B C D
3.3573E+01 -1.2600E-02 8.8900E-05 -7.1800E-08
Hv = A*(1-T/Tc)^n
Komponen A
Ammonia 31.5230
QLv
0.0000
225.7578
19556.7853
19782.5431
E
1.8700E-11
-30.0000 C
243.0000 K
,Kj/mol T, K
Tc n Hv (Kj/mol) Kj/Kmol
405.6500 0.3640 22.6025 22,602.5211
T/Tc (1-T/Tc)
0.5990 0.4010 0.7170
MIXING POINT -01 (MP-01)
ACC-01
MP-01
KE-01
T-02
0.9913015079 0.988709736
Input
Komponen Aliran Acc-01 Aliran T-01
Kmol Kg Kmol Kg
Toluena 163.7832 15068.0544 164.7785 15159.6250
Xylena 1.2474 132.2195 1.6331 173.1106
Furfural 0.0000 0.0000 - -
165.0306 15200.2739 166.4117 15332.7356
Total
30533.0095 30533.0095
Kemurnian Toluene 0.9913015079 0.990186269

99.1301507943
Xylena 0.008698492
0.8698491976
Furfural 8.1001837E-11
8.1001837E-09
Tanki 5
Komponen kmol kg %mol %kg
Toluena 327.5664 30136.1088 0.9924 0.9913
Xylena 2.4947 264.4389 0.0076 0.0087
Furfural 0.0000 0.0000 0.0000 0.0000
Total 330.0611 30400.5477
163.7832 15068.0544 0.992442

1.247353 132.21946 0.007558
0.9900 1.283E-08 1.2313E-06 7.772E-11
Output 165.0306
Aliran feed KE-01 15008.03
Kmol Kg
328.5617 30227.6794 151.5963
2.8805 305.3301
0.0000 0.0000
331.4422 30533.0095
30533.0095 216.3962 2.04147358
0.988709736
0.0000
1.2473533983 0.7941201866
bm
92.0000
106.0000
96.0000
MIXING POINT -01 (MP-01)
ACC-01
MP-01
KE-01
T-02
0.9913015079 0.9887097359
Input
Komponen Aliran Acc-01 Aliran T-01
Kmol Kg Kmol Kg
Toluena 163.7832 15068.0544 164.7785 15159.6250
Xylena 1.2474 132.2195 1.6331 173.1106
Furfural 0.0000 0.0000 - -
165.0306 15200.2739 166.4117 15332.7356
Total
30533.0095 30533.0095
Kemurnian Toluene 0.9913015079 0.9887097359

99.1301507943 98.8709735898
Xylena 0.008698492 0.0112902641

0.8698491976 1.1290264102
Furfural 0.0000
0.0000
Tanki
Komponen kmol kg %mol
Toluena 327.5664 30136.1088 0.9924
Xylena 2.4947 264.4389 0.0076
Furfural 0.0000 0.0000 0.0000
Total 330.0611 30400.5477
163.7832 15068.0544 0.9924

1.2474 132.2195 0.0076
0.9900 0.0000 0.0000 0.0000
Output 165.0306
Aliran feed KE-01 15008.0288
Kmol Kg
328.5617 30227.6794 151.5963
2.8805 305.3301
0.0000 0.0000
331.4422 30533.0095
30533.0095 216.3962 2.0415
0.99
99 0.0000
0.01
1
%kg bm
0.9913 92
0.0087 106
0.0000 96
Input : Keluaran Acc-01 (dari top ACC-01)
Komponen Mol (kmol)

TOLUENA 327.5664
XYLENA 2.4947
FURFURAL 0.0000
Total 330.0611
T in chiller -03 = 92.72 C 365.87 K

T out chiller-03 = 30 C 303.15 K
Tref 25 C 298.15 K

TOLUENA 327.5664 11,055.6514 3,621,459.9203
XYLENA 2.4947 12,772.8924 31,864.6215
FURFURAL 0.0000 11,802.5158 0.0003
Total 330.0611 3,653,324.5421
Heat Capacity Coefficient of Liquids Cp liq =A+B*T+C*(T^2)+D*(T^3) Cp (J/(mol K))

Komponen A B C D
TOLUENA 83.7030 0.5167 -0.0015 0.0000
XYLENA 70.9160 0.8045 -0.0022 0.0000
FURFURAL 66.7920 0.7076 -0.0018 0.0000

TOLUENA 418.515 776.669145 -673.8761309875 268.040653928
XYLENA 354.58 1209.364625 -989.1199950813 340.5509165065
FURFURAL 333.96 1063.6245375 -817.2386452392 266.7497103476

TOLUENA 327.5664 789.3487 258,564.1015
XYLENA 2.4947 915.3755 2,283.5936
FURFURAL 0.0000 847.0956 0.0000
Total 330.0611 260,847.6951
Qs = 3,392,476.8469 KJ
T1 -33 C 240.15 K
T2 50 C 323.15 K
Tref 25 C 298.15 K
Qs
m
Cp air x ( T 2  T1 )
= 39225.7342 kg/jam

= -2370646.4714 kJ/jam

= 1021830.3756 kJ/jam

Q1 3,653,324.5421 0.0000
Q2 0.0000 260,847.6951
Qw-in -619,933.4170 0.0000
Qw-out 0.0000 -260,182.1639 2,772,543.4299
3,032,725.5938
Total 3,033,391.1251 3,033,391.1251
TOLUENA 5668.36716 11616.437328552 -11168.63 4939.479
XYLENA 4802.43152 18088.1504874 -16393.4 6275.706
FURFURAL 4523.15424 15908.35410486 -13544.68 4915.69
Ammonia Cair
A B C D
-1.82E+02 3.37E+00 -1.44E-02 2.04E-05
Ammonia Keluar
T -30.0000 243.0000
Tref 25.0000 298.0000
Ammonia Masuk
T -33.0000 240.0000
Tref 25.0000 298.0000
Kebutuhan Ammonia
134.1764 Kmol
2,280.9993 Kg
Ammonia Gas
A B C D E
3.3573E+01 -1.2600E-02 8.8900E-05 -7.1800E-08 1.8700E-11
Panas laten penguapan ammonia pada T = -30.0000 C

243.0000 K
Komponen A Tc n
Ammonia 31.5230 405.6500 0.3640
0.5990 0.4010
T, K
Hv (Kj/mol) Kj/Kmol
22.6025 22,602.5211
0.7170
Neraca panas MP-01
input
BM Komponen tangki toluena
kmol kg
92 toluena 164.7785 15159.6250
106 xylane 1.6331 173.1106
96 furfural - -
Subtotal 15332.7356
Total 30533.0095
panas sensibel keluar (Q3) 0.0000 261,986.4802
TOTAL 261,986.4802 261,986.4802

Name A B
toluene 83.703 0.51666
Xylene 70.916 0.8045
Furfural 66.792 0.70755
Tref = 25 C 298.15
PANAS MASUK

toluena 164.7785 789.3487 130,067.7153
xylane 1.6331 915.3755 1,494.9174
furfural - 847.0956 #VALUE!
TOTAL 131,562.6326
dari KD-01 30 C 303.15

toluena 163.7832 789.3487 129,282.0508
xylane 1.2474 915.3755 1,141.7968
furfural 0.0000 847.0956 0.0000
total 130,423.8476
PANAS KELUAR
Ke KE-01 30 C 303.15
toluena 328.5617 789.3487 259,349.7660
xylane 2.8805 915.3755 2,636.7142
furfural 0.0000 847.0956 0.0000
total 261,986.4802
input
output ke KE-01
recycle KD-01
kmol kg kmol kg
163.7832 15068.0544 328.5617 30227.6794
1.2474 132.2195 2.8805 305.3301
0.0000 0.0000 0.0000 0.0000
15200.2739
30533.0095 30533.0095
0.991301508 0.99
331.4422 331.4422
(T=K)
-0.001491 1.9725E-06 179 533 298.15 157.48
-0.0021885 2.5061E-06 226 555 298.15 75.55
-0.0018082 0.000001963
K
5
K
424.911125
K
2.6199E+05
K
Komponen Mol (kmol)

TOLUENA 0.0000
XYLENA 0.3770
FURFURAL 25.6510
Total 26.0280
TULIS DI LAMPIRAN SUHU 147,4173 C
T in chiller -03 = 147.4173 C 420.5673 K
T out chiller-03 = 30 C 303.15 K
Tref 25 C 298.15 K

TOLUENA 0.0000 20,707.5164 0.0000
XYLENA 0.3770 23,790.8115 8,968.9742
FURFURAL 25.6510 21,916.3149 562,176.3073
Total 26.0280 571,145.2815
Heat Capacity Coefficient of Liquids Cp liq =A+B*T+C*(T^2)+D*(T^3) Cp (J/(mol K))

Komponen A B C D
TOLUENA 83.7030 0.5167 -0.0015 0.0000
XYLENA 70.9160 0.8045 -0.0022 0.0000
FURFURAL 66.7920 0.7076 -0.0018 0.0000

TOLUENA 418.515 776.669145 -673.8761309875 268.040653928
XYLENA 354.58 1209.364625 -989.1199950813 340.5509165065
FURFURAL 333.96 1063.6245375 -817.2386452392 266.7497103476

TOLUENA 0.0000 789.3487 0.0000
XYLENA 0.3770 915.3755 345.0904
FURFURAL 25.6510 847.0956 21,728.8846
Total 26.0280 22,073.9750
Qs = 549,071.3065 KJ
T1 -33 C 240.15 K
T2 50 C 323.15 K
Tref 25 C 298.15 K
Qs
m
Cp air x ( T 2  T1 )
= 6348.6727 kg/jam

= -383688.3829 kJ/jam

= 165382.9237 kJ/jam

Q1 571,145.2815 0.0000
Q2 0.0000 22,073.9750
Qw-in -100,336.0278 0.0000
Qw-out 0.0000 -42,110.4011 448,735.2787
490,845.6798
Total 470,809.2537 470,809.2537
TOLUENA 10246.6952619 22728.7598152955 -23798.87 11530.93
XYLENA 8681.3452468 35391.3352522069 -34932.14 14650.27
FURFURAL 8176.4963016 31126.3384185196 -28861.91 11475.39
Ammonia Cair
A B C D
-1.82E+02 3.37E+00 -1.44E-02 2.04E-05
Ammonia Keluar
T -30.0000 243.0000
Tref 25.0000 298.0000
Ammonia Masuk
T -33.0000 240.0000
Tref 25.0000 298.0000
Kebutuhan Ammonia
21.7164 Kmol
369.1790 Kg
Ammonia Gas
A B C D E
3.3573E+01 -1.2600E-02 8.8900E-05 -7.1800E-08 1.8700E-11
Panas laten penguapan ammonia pada T = -30.0000 C

243.0000 K
Komponen A Tc n
Ammonia 31.5230 405.6500 0.3640
0.5990 0.4010
T, K
Hv (Kj/mol) Kj/Kmol
22.6025 22,602.5211
0.7170
STORAGE TANK
Fungsi = Menampung Produk Furfural

T= 30 °C
P= 1 atm
Input
Komponen Aliran 18
Kmol Kg
Toluena 0.0000 0.0000 0.00000
Xylena 0.3770 39.9613 0.0159688
Furfural 25.6510 2462.5000 0.9840
Total 2502.4613 98.4031
2502.4613
0.98403121
TANK-01
Fungsi = Menampung SOLVENT KE (Toluena)

T= 30 °C
P= 1 atm
Sebelum Recycle
Input
Komponen Aliran 18
Kmol Kg
Toluena 328.5617 30227.6794 Kemurnian Toluena =
Xylena 2.8805 305.3301
Total 30533.0095 0.99 =
Sesudah Recycle
Input
Komponen Aliran 18
Kmol Kg
Toluena 164.7785 15159.6250 Kemurnian Toluena =
Xylena 1.6331 173.1106
Total 15332.7356 0.98871 =
166.4117 15332.7356 pake massa
0.9901862689 0.990186 =
pake mol
Komponen BM
H2O 18
H2SO4 98
C5H10O5 150
C5H8O4 132
C5H4O2 96
C6H10O5 162
Toluena 92
99 % Xylena 106
0.99
99.00%
98.870974
99%
0.9901863

Konversi Trial

Diunggah oleh

Informasi Dokumen

Hak Cipta

Format Tersedia

Bagikan dokumen Ini

Bagikan atau Tanam Dokumen

Opsi Berbagi

Apakah menurut Anda dokumen ini bermanfaat?

Apakah konten ini tidak pantas?

Hak Cipta:

Format Tersedia

Konversi Trial

Diunggah oleh

Hak Cipta:

Format Tersedia

Impor x y xy x2

SLOPE (A) 778.6662

MAKA KEBUTUHAN PADA TAHUN 2021

KAPASITAS PRODUKSI 70% = 36048.66244 Di bulatkan menjadi , 36000 ton/tahun

Menentukan konversi reaksi utama dan samping :

GLUKOSA T= 160 C K298

303.15 G Reaksi Samping 2 -28500

ln Reaksi Samping 2 4.3247290666

ln Reaksi Samping 2 11.3077778348

303.15 K Ka1 = Ka 298,15

lnKT/K298 KT/K298 KT Konversi

lnKT/K298 KT/K298 KT Konversi

lnKT/K298 KT/K298 KT Konversi

lnKT/K298 KT/K298 KT Konversi

lnKT/K298 KT/K298 KT Konversi

Kapasitas/jam = 18000 ton 1000

Kemurnian Furfural = 98.5 %

Produk Furfural = 2462.5000 kg/jam =

Produk Impuritis = 50.0000 kg/jam (Air)

Konversi Pentosa ke Furfural = 43.0 % 0.4300

Konversi pentosan ke pentosa = 32.0 %

Massa Hemiselulosa = 28.75 %

Ampas tebu = 98428.4157

Perbandingan Bahan Baku = Ampas Tebu : As. Sulfat

Kemurnian Larutan As. Sulfat = 6%

Feed Larutan As. Sulfat = 789030.2503 kg/jam =

Feed Larutan As. Sulfat 36% = 131505.0417 kg/jam =

Komposisi Ampas Tebu

6.25 % Kadar Abu

Jerami padi : AS.SULFAT

5158.8146 kmol/jam buy

Persen Total Komposisi ampas tebu

(Sumber : Patent, US 8,901,325 B2)

Fungsi : Menampung As. Sulfat 36%

H2O (Asam) 146.1167130133 2630.1008

Rumus di D15 (x) Rumus di D16 (z)

Rumus di C15 (n) Rumus di C16 (l)

Fungsi = Mengalirkan air menuju Mixer (MT-01)

Fungsi = Mengencerkan As. Asetat hingga 6 %

Aliran 1 = Air + Asam Sulfat (Asam Sulfat 36%)

Feed Asam Sulfat 6 % = 789030.2503

Feed Asam Sulfat 36% = 131505.0417

Jadi, Air yang perlu ditambahakan pada Aliran 2

Fungsi = Mengencerkan As. Asetat hingga 6 %

Aliran 1 = Air + Asam Sulfat (Asam Sulfat 36%)

Feed Asam Sulfat 6 % = 197849.3412

Feed Asam Sulfat 36% = 32974.8902

Jadi, Air yang perlu ditambahakan pada Aliran 3

an As. Asetat hingga 6 %

= V2 N2 As. Sulfat di inginkan 6 %

an As. Asetat hingga 6 %

= V2 N2 As. Sulfat di inginkan 6 %

Komponen A.T 1/2 BT^2 1/3 CT^3

Neraca Panas M-01

Input (yang mau dipanaskan), dari MP-04

Input (yg mau diambil panasnya) dari R-01

Input yg mau diambil panasnya Q8

Panas input yang di serap oleh fluida

1/3 CT^3 1/4 DT^4

1/3 CT^3 1/4 DT^4

Input setelah dipanaskan

Input setelah diambil panasnya

Input setelah diambil panasnya

ng di serap oleh fluida