Perhitungan Estimasi Ketidakpastian COD

1. Perhitungan Ketidakpastian Reprodusibilitas Duplo

No Kode Sampel X1 (mg/L) X2 (mg/L) Rerata (mg/L) d r (%)
1 256 11.16 10.89 11.026 0.263 2.387
2 257 9.97 9.18 9.579 0.789 8.242
3 258 10.63 7.47 9.053 3.158 34.884
4 259 8.13 9.05 8.592 0.921 10.720
5 260 11.09 9.64 10.368 1.447 13.959
6 261 10.37 10.76 10.566 0.395 3.736
7 262 10.57 8.59 9.579 1.974 20.604
8 263 10.37 11.09 10.730 0.724 6.744
9 264 9.84 10.50 10.171 0.658 6.468
10 265 8.39 9.32 8.855 0.921 10.401
11 266 10.04 10.30 10.171 0.263 2.587
12 267 9.45 10.57 10.007 1.118 11.177
Rata-rata 10.992
uR (%) 9.745

2. Perhitungan Ketidakpastian Bias dari Nilai CRM

CRM ERA Demand Cat. No P274-516
Certified Value 127 ± 3.21 Hasil pen
Faktor Cakupan (K) 2 No
1
bias lab 0.762 mg/L nilai rata konsentrasi lab - nilai crm 2
bias relatif 0.600 % (bias lab rata2 : nilai CRM) *100 3
bias² 0.360 4
5
sd bias 1.208 mg/L 6
sd bias relatif 0.951 % (nilai sd bias : nilai CRM)*100 7
Rata-rata
sbias relatif/√n 0.360 % Sd Bias
(sbias relatif/√n)² 0.129 n

uCref 1.605 mg/L nilai U CRM : faktor cakupan

uCref relatif 1.264 % (u(Cref) : nilai CRM)*100
uCref² 1.597

bias² + (sbias relatif/√n)² + uCref² 2.09

1.44 %

3. Perhitungan ketidakpastian gabungan uc(y)

uc(y) √uR²+ubias²
Item Nilai Nilai²
uR 9.745 94.967
ubias 1.444 2.086
9.852
uc(y) =√( 〖𝒖𝑹〗 ^𝟐+ 〖𝒖𝑩𝒊𝒂𝒔〗 ^𝟐 )

ketidakpastian diperluas (pelaporan)

U = faktor cakupan (k) x uc(y) 19.703

4. Data perhitungan hasil estimasi ketidakpastian COD

No Data - U Satuan nilai ± U didapat dari :
1 11.03 ± 2.17 mg/L nilai ketidakpastian diperluas
2 9.58 ± 1.89 mg/L
3 9.05 ± 1.78 mg/L
4 8.59 ± 1.69 mg/L
5 10.37 ± 2.04 mg/L
6 10.57 ± 2.08 mg/L
7 9.58 ± 1.89 mg/L
8 10.73 ± 2.11 mg/L
9 10.17 ± 2.00 mg/L
10 8.86 ± 1.74 mg/L
11 10.17 ± 2.00 mg/L
12 10.01 ± 1.97 mg/L
Hasil pengujian CRM di lab
Konsentrasi (mg/L) Bias (mg/L)
124.333 2.667
124.333 2.667
131.000 4.000
127.667 0.667
127.667 0.667
124.333 2.667
124.333 2.667
126.24
1.21
7

perluas (U) : 100 * data pengujian