EXAMPLE 6.

9
Estimate V, U, H and S for 1-butane vapor at 200°C and 70 bar if H and S are et equal to zero for saturated liquid at 0°C
Assume that the only data available are :
Tc = 420 K T= 200 °C
TR = 266.9 K (normal boiling point) P= 70 bar
Pc = 40.43 bar ꞷ= 0.191
Cig,P/R = 1.967 + 31.630x10^-3 T - 9.837x10^-6 T^2

PENYELESAIAN
Volume 1-butane dihitung dari persamaan V = ZRT/P, dengan Z mengikuti Eq. (3.57) dimana nilai Z0 dan Z1 diinterpolasi da
Tr = T/Tc = 1.1265
Pr = P/Pc = 1.7314
Z= Z^0 + ꞷZ^1 = 0.5121
V= ZRT/P = 287.7957

Tahapan a : Vaporisasi pada T1 dan P1=Psat

Normal boiling point
Tn = 266.9 K
Psn = 1.0013 bar
Critical point
Tc = 420.0 K
Psc = 40.430 bar
Mencari A dan B dengan : ln P^sat = A-(B/T)
Didapat : A= 10.126
B= 2,699.110
Mencari Panas Laten
Trn 1.092*(Ln Pc - 1.013) 0.930 - Trn ΔH(lv,n)/RTn ΔH(lv,n)
0.6355 2.9337 0.2940 9.9787 22,142.8
T= 273.15 K
Tr = 0.65
ΔH(lv,n) (1-Tr)/(1-Trn) (1-Tr)/(1-Trn)^0.38 ΔH(lv) ΔS(lv)
22,142.8 0.9592 0.9843 21,794.85 79.79

Tahapan b : Transisi pada gas ideal (T1, P1)

HRB SRB Tc R H(R,1) S(R,1)
-0.0985 -0.1063 420 8.314 -343.95 -0.88

Tahapan c : Diubah menjadi (T2, P2) pada gas ideal

T1 = 273.15 K
P1 = 1.2771 bar
T2 = 473.15 K
P2 = 70 bar
R ICPH ICPS R x ICPH R x ICPS R x ln (P2/P1) ΔH(ig) ΔS(ig)
8.314 2,473.42 6.67 20,564.01 55.47 33.2885 20,564.01 22.19

Tahapan d : Transisi ke kondisi akhir(T2, P2)

ꞷ H(R,2)/RTc S(R,2)/R Tc R H(R,2) S(R,2)
0.191 -2.430 -1.705 420 8.314 -8,485.91 -14.17

Sehingga :
H1 H2 H3 H4 H = ΔH
21,794.85 -343.95 20,564.01 -8,485.91 33,529.01

S1 S2 S3 S4 S = ΔS
79.79 -0.88 22.19 -14.17 86.92

H P V PV U = H - PV
33,529.01 70 287.80 2014.60 31,514.41
ero for saturated liquid at 0°C

473.15 K

630x10^-3 T - 9.837x10^-6 T^2 (T/K)

nilai Z0 dan Z1 diinterpolasi dari Tabel E.3 dan E.4.