1.

Turunkan hukum laju dan reaksi keseluruhan bagi reaksi antara H2 dan I2
yang memiliki mekanisme reaksi :
I2  2I …. K1
2I  I2 …. K2
I + H2  HI + H … K3
H + I2  HI + I … K4

Jawaban :
 Reaksi Keseluruhan
I2  2I …. K1
2I  I2 …. K2
I + H2  HI + H … K3
H + I2  HI + I … K4
I2 + H2  2HI

 Hukum Laju =
[𝐼]
= K1 [I2] – K2[I2] – K3 [I] [H2] + K4 [H] [I2]
𝑑𝑡
[𝐻]
= K3 [I] [H2] – K4 [H] [I2]
𝑑𝑡
0 = K3 [I] [H2] – K4 [H] [I2]
K3 [I] [H2] = K4 [H] [I2]
𝐾3 [𝐼][𝐻2 ]
[H] =
[𝐼2 ]
0 = (K1-K2) [I2] – K3 [I] [H2] + K4 [H] [I2]
(K2-K1) [I2] + K3 [I] [H2] = K4 [H] [I2]
𝐾3 [𝐼][𝐻2 ]
(K2-K1) [I2] + K3 [I] [H2] = K4 [I2]
[𝐼2]
(K2-K1) [I2] = K4 K3[I] [H2] – K3 [I] [H2]
[I] = (k2-K1) [I2] / k4 K3 [H2] – K3[H2] =
[𝐻2 ] 𝐾3 (𝐾2 −𝐾1 )[𝐼2 ][𝐻2 ]
= – K4 [H] [I2]
𝑑𝑡 𝐾4 𝐾3 [𝐻2 ]− 𝐾3 [𝐻2 ]
𝐾3 (𝐾2 −𝐾1 )[𝐼2 ][𝐻2 ] 𝐾42 𝐾3 [𝐻2 ][𝐻][𝐼2 ]− 𝐾3 𝐾4 [𝐻2 ][𝐻][𝐼2 ]
–
𝐾4 𝐾3 [𝐻2 ]− 𝐾3 [𝐻2 ] 𝐾4 𝐾3 [𝐻2 ]− 𝐾3 [𝐻2 ]
𝑗𝑎𝑑𝑖 𝑡𝑢𝑟𝑢𝑛𝑎𝑛 ℎ𝑢𝑘𝑢𝑚 𝑙𝑎𝑗𝑢 𝑟𝑒𝑎𝑘𝑠𝑖 𝑦𝑎𝑖𝑡𝑢 𝑟 = 𝑘 [𝐻2 ][𝐼2 ]