1.

Masukkan Data Tc, Pc, ω, T, P

Tc 305.3 K T 323 K Tr 1.06
Pc 48.72 bar P 15 bar Pr 0.31
ω 0.1

2. Masukkan parameter - parameter EoS

EoS α(Tr) σ ϵ Ω ψ Zc
VdW 1 0 0 0.125 0.421875 0.375
RK 0.972215 1 0 0.08664 0.42748 0.333333
SRK 0.89174 1 0 0.08664 0.42748 0.333333
PR 0.904962 2.414214 -0.414214 0.07780 0.45724 0.30740

3. Hitung q dan β
𝑞=𝜓 𝛼(𝑇_𝑟 )/ 〖 Ω 𝑇 〗 _𝑟

𝛽=Ω
𝑃_𝑟/𝑇_𝑟

4. Lakukan Goal-Seek untuk Menghitung Zk+1 Satd.

*General Equation for SATURATED LIQUID Bo -0.302613
𝑍=1+Ḃ 𝑃𝑟/𝑇𝑟 B1 0.003253
B -0.302287
Ḃ=𝐵^0+𝜔𝐵^1 Z 0.912031

𝐵^0=0.083−0.422/ 〖𝑇𝑟〗 ^1.6

𝐵^1=0.139−0.172/
〖𝑇𝑟〗 ^4.2
5. Menghitung Volume Molar (V), m3/mol
𝑉_𝑠𝑎𝑡𝑑=(𝑍_(𝑘+1) Satd.
𝑅𝑇)/𝑃 V (cm3/mol 1632.79
rho (mol/c 0.0006
*Ingat: Satuan sesuaikan dengan satuan R nya !

Densitas: mol/m3
R 8.314 J/mol.K
83.14 bar.cm3/mol.K
 1. Masukkan Data Tc, Pc, ω, T, P
Tc 305.3 K T 323 K Tr
Pc 48.72 bar P 15 bar Pr
ω 0.1

2. Masukkan parameter - parameter EoS

EoS α(Tr) σ ϵ Ω ψ Zc
VdW 1 0 0 0.125 0.421875 0.375
RK 0.9722146 1 0 0.08664 0.42748 0.333333
SRK 0.89174 1 0 0.08664 0.42748 0.333333
PR 0.9049625 2.414214 -0.414214 0.07780 0.45724 0.30740

3. Hitung q dan β
𝑞=𝜓 𝛼(𝑇_𝑟 )/ 〖 Ω 𝑇 〗 _𝑟 q 4.16
β 0.03

𝛽=Ω
𝑃_𝑟/𝑇_𝑟

*initial guess = beta

4. Lakukan Goal-Seek untuk Menghitung Zk+1 Satd. Liquid
*General Equation for SATURATED LIQUID Zk 0.0382
𝑍_(𝑘+1)=𝛽+(𝑍_𝑘+𝜖𝛽)(𝑍_𝑘+𝜎𝛽) Zk+1 0.0480
((1+𝛽−𝑍_𝑘)/𝑞𝛽) Abs.Error 0.010

*General Equation for SATURATED VAPOR *initial guess = 1

𝑍_(𝑘+1)=1+𝛽−𝑞𝛽 (𝑍_𝑘−𝛽)/((𝑍_𝑘+𝜖𝛽) Satd. Vapor
(𝑍_𝑘+𝜎𝛽)) Zk 0.9170
Zk+1 0.9170
Abs.Error 0.000
𝐴𝑏𝑠.𝐸𝑟𝑟𝑜𝑟=|𝑍_(𝑘+1)−𝑍_𝑘 |

~Prosedur Goal Seek (Data --> What if analysis --> Goal Seek) :
*Set Cell = Abs.Error
*To Value = 0.00000

*By Changing Zk
Cell =
1.06
0.31

5. Menghitung Volume Molar (V), m3/mol

𝑉_𝑠𝑎𝑡𝑑=(𝑍_(𝑘+1) Satd. Liquid Satd. Vapor
𝑅𝑇)/𝑃
V (cm3/mol) 86.00 V (cm3/mol)
rho (mol/cm3) 0.0116 rho (mol/cm3)
*Ingat: Satuan sesuaikan dengan satuan R nya !

Densitas: mol/m3
R 8.314 J/mol.K
83.14 bar.cm3/mol.K
Satd. Vapor
1641.66
0.0006
 1. Masukkan Data Tc, Pc, ω, T, P
Tc 369.8 K T 323 K Tr 0.87
Pc 42.48 bar P 17.16 bar Pr 0.40
ω 0.152

2. Masukkan parameter - parameter EoS

EoS α(Tr) σ ϵ Ω ψ Zc
VdW 1 0 0 0.125 0.421875 0.375
RK 1.069996 1 0 0.08664 0.42748 0.333333
SRK 1.237772 1 0 0.08664 0.42748 0.333333
PR 1.208151 2.414214 -0.414214 0.07780 0.45724 0.30740

3. Hitung q dan β
𝑞=𝜓 𝛼(𝑇_𝑟 )/ 〖 Ω 𝑇 〗 _𝑟q 6.04
β 0.04

𝛽=Ω
𝑃_𝑟/𝑇_𝑟

*initial guess = beta

4. Lakukan Goal-Seek untuk Menghitung Zk+1 Satd. Liquid
*General Equation for SATURATED LIQUID Zk 0.0716
𝑍_(𝑘+1)=𝛽+(𝑍_𝑘+𝜖𝛽)(𝑍_𝑘+𝜎𝛽) Zk+1 0.0720
((1+𝛽−𝑍_𝑘)/𝑞𝛽) Abs.Error 0.000

*General Equation for SATURATED VAPOR *initial guess = 1

𝑍_(𝑘+1)=1+𝛽−𝑞𝛽 (𝑍_𝑘−𝛽)/((𝑍_𝑘+𝜖𝛽) Satd. Vapor
(𝑍_𝑘+𝜎𝛽)) Zk 0.7500
Zk+1 0.7499
Abs.Error 0.000
𝐴𝑏𝑠.𝐸𝑟𝑟𝑜𝑟=|𝑍_(𝑘+1)−𝑍_𝑘 |

~Prosedur Goal Seek (Data --> What if analysis --> Goal Seek) :
*Set Cell = Abs.Error
*To Value 0.00000
*By
Changing Zk
Cell =
5. Menghitung Volume Molar (V), m3/mol
𝑉_𝑠𝑎𝑡𝑑=(𝑍_(𝑘+1) Satd. Liquid Satd. Vapor
𝑅𝑇)/𝑃
V (cm3/mol 112.72 V (cm3/mol 1173.53
rho (mol/c 0.0089 rho (mol/c 0.0009
*Ingat: Satuan sesuaikan dengan satuan R nya !

Densitas: mol/m3
R 8.314 J/mol.K
83.14 bar.cm3/mol.K
 1. Masukkan Data Tc, Pc, ω, T, P
Tc 425.1 K T 403 K Tr 0.95
Pc 37.96 bar P 26.59 bar Pr 0.70
ω 0.2

2. Masukkan parameter - parameter EoS

EoS α(Tr) σ ϵ Ω ψ Zc
VdW 1 0 0 0.125 0.421875 0.375
RK 1.027053 1 0 0.08664 0.42748 0.333333
SRK 1.097847 1 0 0.08664 0.42748 0.333333
PR 1.085745 2.414214 -0.414214 0.07780 0.45724 0.30740

3. Hitung q dan β
𝑞=𝜓 𝛼(𝑇_𝑟 )/ 〖 Ω 𝑇 〗 _𝑟q 5.35
β 0.06

𝛽=Ω
𝑃_𝑟/𝑇_𝑟

*initial guess = beta

4. Lakukan Goal-Seek untuk Menghitung Zk+1 Satd. Liquid
*General Equation for SATURATED LIQUID Zk 0.1418
𝑍_(𝑘+1)=𝛽+(𝑍_𝑘+𝜖𝛽)(𝑍_𝑘+𝜎𝛽) Zk+1 0.1426
((1+𝛽−𝑍_𝑘)/𝑞𝛽) Abs.Error 0.001

*General Equation for SATURATED VAPOR *initial guess = 1

𝑍_(𝑘+1)=1+𝛽−𝑞𝛽 (𝑍_𝑘−𝛽)/((𝑍_𝑘+𝜖𝛽) Satd. Vapor
(𝑍_𝑘+𝜎𝛽)) Zk 0.6111
Zk+1 0.6103
Abs.Error 0.001
𝐴𝑏𝑠.𝐸𝑟𝑟𝑜𝑟=|𝑍_(𝑘+1)−𝑍_𝑘 |

~Prosedur Goal Seek (Data --> What if analysis --> Goal Seek) :
*Set Cell = Abs.Error
*To Value 0.00000
*By
Changing Zk
Cell =
5. Menghitung Volume Molar (V), m3/mol
𝑉_𝑠𝑎𝑡𝑑=(𝑍_(𝑘+1) Satd. Liquid Satd. Vapor
𝑅𝑇)/𝑃
V (cm3/mol 179.74 V (cm3/mol 768.96
rho (mol/c 0.0056 rho (mol/c 0.0013
*Ingat: Satuan sesuaikan dengan satuan R nya !

Densitas: mol/m3
R 8.314 J/mol.K
83.14 bar.cm3/mol.K