TUGAS BESAR UTS

MK : Neraca Massa dan Energi

DOSEN : Denni Kartika Sari., ST.,MT

KELOMPOK : 1. Sri Sofarini 3335210019

2. Selviana Pratiwi 3335210020

3. Yasser Baihaqy Akya 3335210042

4. Ardini Putri 3335210044

PRARANCANGAN PABRIK BUTIL OLEAT DARI n-BUTANOL DAN ASAM OLEAT KAPASITAS 210020 TON PER TAHUN

Floww diagram proses

NERACA MASSA
a. Kapasitas Pabrik per tahun
Waktu Operasi 1 tahun
Maka
Kapasitas Pabrik perjam
= 210020 ton/tahun
= 330 hari
= 26517,67592 kg/jam

b. Komponen Produk :
C17H33COOC4H9 = 26295,62644 kg/jam
Impuritas = 222,0494789 kg/jam

c. Komponen Umpan Masuk :

Komponen umpan C17H33COOH = komponen produk 22161,00237
C17H33COOH = 99% berat = 21939,39235
H2O = 1% berat = 221,6100237
= 100% Jinan ZZ Internasional TRADE Co., LTD 22161,00237
Komponen umpan H2SO4 = komponen produk 565,1241496
H2SO4 = 98,00% berat 553,8216666
H2O = 2,00% berat 11,30248299
= 100% PT Petrokimia Gresik 565,1241496
Komponen umpan C4H9OH = komponen produk 5893,086526
C4H9OH = 99,50% berat 5887,194298
H2O = 0,50% berat 5,892227778
= 100% PT Petro OXO Nusantara 5893,086526
MENGHITUNG NERACA MASSA

ARUS 1
PROSES REAKSI OVERALL
OVERALL

ARUS 1
ARUS 2

ARUS 4

A. Neraca Massa Overall

tabel 4.6 Neraca massa overall
output
komponen input (kg/jam) (kg/jam
arus 1 arus 2 arus 4 arus 11
C17H33COOH 21939,39235 0 0 0,417706444
C15H31COOH 221,6100237 0 0 221,6061033
C4H9OH 0 0 5887,194298 0,028002667
H2SO4 0 553,8216666 0 0
H2O 0 11,30248299 5,892227778 0
C17H33COOC4H9 0 0 0 26295,62644
total 22161,00237 565,1241496 5893,086526 26517,67825
jumlah 28619,21305
PROSES REAKSI DI MIXER ARUS 1 M-110 ARUS 3
30℃ 1Atm

ARUS 1

B. Neraca Massa Mixer

Fungsi : mencampur H2SO4 dengan C17H33COOH
tabel 4.1 neraca massa di sekitar mixer 1
Komponen Input (kg/jam) Output (kg/jam)
arus 1 arus 2 arus 3
H2SO4 0 553,8216666 553,8216666
C17H33COOH 21939,39235 0 21939,39235
C17H31COOH 221,6100237 0 221,6100237
H2O 0 11,30248299 11,30248299
Total 22161,00237 565,1241496 22726,12652
Jumlah 22726,12652 22726,12652

ARUS 11/13 ARUS 9

REAKSI DI REAKTOR ARUS 3 R-210 ARUS 5

100℃ 1Atm
ARUS 4
ARUS 10/12

C. Neraca Massa di Sekitar Reaktor

Fungsi : Mereaksikan hasil dari Mixer dan Butanol fungsi pengali
dengan bantuan katalis asam sulfat 23,33555556
 H2SO
C17H33COOH + C4H9OH C17H33COOC4H9 + H2O
mula-mula 233,353222 1166,777544 0,000186684 6,384608
Reaksi 196,0886733 196,0886733 196,0886733 196,0886733
Sisa 37,26454867 970,6888711 196,08886 202,4732813

Neraca Massa di Sekitar Reaktor

tabel 4.2 neraca massa di sekitar reaktor
output
komponen input (kg/jam) (kg/jam)
arus 3 arus 4 arus 9 arus 10 arus 11 arus 5
H2SO4 553,82274 0 0 0 0 553,82274
C4H9OH 0 5887,194298 28368,63818 0 0 34255,83248
C17H33COOH 21939,39393 0 0 4169,111687 0 26108,50562
C17H31COOH 221,6084369 0 0 42,11601067 0 263,7244476
C17H33COOC4H9 0 0 0,025669111 0 0 0,025669111
H2O 11,30140956 5,892227778 0 0 28,39937111 45,59300844
Total 22726,12652 5893,086526 28368,66385 4211,227698 28,39937111 61227,50397
Jumlah 61227,50397 61227,50397

MENCARI FRAKSI INPUT

arus 3 arus 4 arus 9
total umpan asli 973,883 total umpan asli 252,5369 total umpan asli 1215,6841
C17H33COOH 0,965383 C4H9OH 0,999 C4H9OH 0,9999991
C15H31COOH 0,009751 H2O 0,001 C17H33COOC4H9 9,0484E-07
H2SO4 0,024369 total 1 total 1
H2O 0,000497
total 1
 arus 10 arus 11
total umpan asli 180,464 total umpan asli 1,217
C17H33COOH 0,989999 H2O 1
C17H31COOH 0,010001
total 1

MENCARI FRAKSI OUTPUT ARUS 5

total umpan
keluar 2623,785
H2SO4 0,00904533
C4H9OH 0,46545769
C17H33COOH 0,06809895
C17H31COOH 0,00430725
C17H33COOC4H9 0,42947467
H2O 0,02361607
Total 1

ARUS 6

REAKSI DI DEKANTER
ARUS 5 R-210 ARUS 8
100℃ 1Atm

ARUS 7
 D. Neraca Massa Dekanter
Fungsi: memisahkan produk dengan air dan asam sulfat
berdasarkan density/massa jenis
tabel 4.3 neraca massa di sekitar decanter
input (kg/jam) output (kg/jam)
Komponen arus 5 arus 6 arus 7 arus 8
H2O 1445,952697 553,82274 1999,775437 0
C4H9OH 28498,80158 0 130,1353927 28368,66619
C17H33COOC4H9 26295,65211 0 0 26295,65211
C17H31COOH 263,722114 0 0 263,722114
C17H33COOH 4169,52706 0 0 4169,52706
H2SO4 553,82274 0 553,82274 0
Total 61227,4783 553,82274 2683,733569 59097,56747
Jumlah 61781,30104 61781,30104

MENCARI FRAKSI INPUT MENCARI FRAKSI OUTPUT

arus 5 arus 6 arus 7 arus 8
total umpan asli 2623,785 total umpan asli 23,733 total umpan asli 115,0062 total umpan asli 2532,512
H2O 0,023616 H2O 1 H2O 0,74514678 C4H9OH 0,480031
C4H9OH 0,465458 C4H9OH 0,04849043 C17H33COOC4H9 0,444953
C17H33COOC4H9 0,429475 H2SO4 0,20636279 C17H31COOH 0,004462
C17H31COOH 0,004307 Total 1 C17H33COOH 0,070553
C17H33COOH 0,068099 total 1
H2SO4 0,009045
Total 1
 ARUS 7/9
REAKSI DI DESTILASI 01
ARUS 6/8
D-320
ARUS 8/10

E. Neraca Massa Destilasi 01

tabel 4.4 Neraca massa di sekitar destilasi 01
input (kg/jam) output (kg/jam)
komponen arus 6/8 arus 7/9 arus8/10
C17H33COOC4H9 26295,65211 0,025669111 26295,62644
C17H31COOH 263,722114 0 263,722114
C4H9OH 28368,66619 28368,63818 0,028002667
H2O 0 0 0
C17H33COOH9 4169,52706 0 4169,52706
H2SO4 0 0 0
Total 59097,56747 28368,66385 30728,90362
Jumlah 59097,56747 59097,56747

MENCARI FRAKSI INPUT MENCARI FRAKSI OUTPUT

arus 6 arus 7 arus 8
total umpan asli 2532,5118 total umpan asli 1215,6841 total umpan asli 1316,8276
C17H33COOC4H9 0,4449532 C17H33COOC4H9 9,048E-07 C17H33COOC4H9 0,85572941
C17H31COOH 0,0044625 C4H9OH 0,9999991 C17H31COOH 0,00858222
C4H9OH 0,480031 total 1 C4H9OH 9,1128E-07
C17H33COOH 0,0705533 C17H33COOH 0,13568747
Total 1 total 1
 Arus 12

Arus 10
REAKSI DI DISTILASI 02 D-320

Arus 11

F. Neraca Massa Destilasi 02

tabel 4.5 Neraca massa di sekitar destilasi 02
input (kg/jam) output (kg/jam)
komponen arus 10 arus 11 arus 12
H2O 0 0 0
C4H9OH 0,028002667 0,028002667 0
C17H33COOC4H9 26295,62644 26295,62644 0
C17H31COOH 263,722114 221,6061033 42,11601067
C17H33COOH 4169,52706 0,417706444 4169,111687
H2SO4 0 0 0
Total 30728,90595 26517,67825 4211,227698
Jumlah 30728,90595 30728,90595

MENCARI FRAKSI INPUT MENCARI FRAKSI OUTPUT

arus 10 arus 11 arus 12
total umpan asli 1316,8276 total umpan asli 1136,3636 total umpan asli 180,464
C4H9OH 9,113E-07 C4H9OH 1,056E-06 C17H31COOH 0,01000089
C17H33COOC4H9 0,8557294 C17H33COOC4H9 0,9916264 C17H33COOH 0,98999911
C17H31COOH 0,0085822 C17H31COOH 0,0083569 total 1
C17H33COOH 0,1356875 C17H33COOH 1,575E-05
Total 1 total 1
SUMBER: PRARANCANGAN PABRIK BUTIL OLEAT DARI n-BUTANOL DAN ASAM OLEAT KAPASITAS 9000 PER TAHUN

OLEH: NURILA FIRDAUS – UNIVERSITAS SETIA BUDI - 2018

Link file skripsi: Nurila Firdaus (19130255D).pdf (setiabudi.ac.id)