BAB IV

NERACA MASSA DAN PANAS

4.1. Neraca Massa

Kapasitas Produksi : 51.000 ton/tahun (Kemurnian MEK 99,99%)
Operasi Pabrik : 330 hari/tahun
Produk : Metil Etil Keton (MEK)
Bahan Baku : 2-Butanol

4.1.1. Neraca Massa Mixing Point-01 (MP-01)

Neraca Massa Started MP-01

Input (kg) Output (kg)
Komponen
Aliran 31 Aliran 1 Aliran 2
2-Butanol - 6.766,812 8.717,667
Air - 0,021 4,381
TOTAL 6.766,834 8.722,048

Neraca Massa Recycle MP-01

Input (kg) Output (kg)
Komponen
Aliran 31 Aliran 1 Aliran 2
2-Butanol 1.950,800 6.766,867 8.717,667
Air 4,360 0,021 4,381
TOTAL 8.722,048 8.722,048

4.1.2. Neraca Vaporizer-01 (VP-01)

Neraca Massa Vaporizer-01 (VP-01)

Input (Kg) Output (Kg)
Komponen Aliran 30 Aliran 3
Aliran 2
(Liquid) (Vapor)

30
 2-Butanol 8.717,6668 1.742,9453 6.974,7215
Air 4,3807 0,8660 3,4947
1.743,8313 6.978,2162
TOTAL 8.722,0475
8.698,6715

4.1.3. Neraca Massa Reaktor-01 (R-01)

Input (Kg) Output (Kg)

Komponen
Aliran 6 Aliran 7
2-Butanol 6.974,7215 207,2416
MEK 0,0000 6.582,6290
Hidrogen 0,0000 182,8508
Air 3,4947 3,4947
TOTAL 6.978,2162 6.978,2162
4.1.4. Neraca Partial Condenser-01 (PC-01)

Input (Kg) Output (Kg)

Komponen Aliran 9
Aliran 8
Liquid Vapor
2-Butanol 209,2416 208,2612 0,9805
MEK 6.582,6290 6.440,6259 142,0031
Hidrogen 182,8508 2,0023 180,8485
Air 3,4947 3,4743 0,0204

6.978,2162 6.654,3637 323,8525

TOTAL
6.978,2162

4.1.5. Neraca Massa Knock Out Drum-01 (KOD-01)

Input (Kg) Output (Kg)
Komponen Aliran 10 Aliran 17
Aliran 9
Liquid Vapor

31
 2-Butanol 209,2416 208,2612 0,9805
MEK 6.582,6290 6.440,6259 142,0031
Hidrogen 182,8508 2,0023 180,8485
Air 3,4947 3,4743 0,0204

6.978,2162 6.654,3637 323,8525

TOTAL
6.978,2162

4.1.6. Neraca Massa Kolom Destilasi-01 (KD-01)

Input (Kg) Output (Kg)

Komponen Bottom (Aliran
Aliran 11 Top (Aliran 12)
18)
2-Butanol 208,2612 0,0214 208,2398
MEK 6.440,6259 6.439,9818 0,6441
Hidrogen 2,0023 2,0023 0,0000
Air 3,4743 0,0003 3,4740
6.442,0059 212,3578
TOTAL 6.654,3637
6.654,3637

4.1.7. Neraca Massa Total Condenser-01 (TC-01)

Input (Kg/jam) Output (Kg/jam)

Komponen Aliran 12 Aliran 13
Vapor Reflux Destilat
2-Butanol 0,0214 0,0000 0,0214
MEK 6.447,3685 7,3867 6.439,9818
Hidrogen 2,0046 0,0023 2,0023
Air 0,0003 0,0000 0,0003
7,3890 6.442,0059
Total 6.449,3950
6.449,3950

32
4.1.8. Neraca Massa Accumulator-01 (ACC-01)

Input (Kg/jam) Output (Kg/jam)

Komponen Aliran 13 Aliran 14 Aliran 15
Vapor Reflux Destilat
2-Butanol 0,0214 0,0000 0,0214
MEK 6.447,3685 7,3867 6.439,9818
Hidrogen 2,0046 0,0023 2,0023
Air 0,0003 0,0000 0,0003
7,3890 6.442,0059
Total 6.449,3950
6.449,3950

4.1.9. Neraca Massa Reboiler-01 (RB-01)

Input (Kg/jam) Output (Kg/jam)

Komponen
Aliran 18 Aliran 19 Aliran 20
2-Butanol 6.460,2375 6.251,9977 208,2398
MEK 19,9808 19,3367 0,6441
Hidrogen 0,0000 0,0000 0,0000
Air 107,7730 104,2991 3,4740
6.375,6335 212,3578
Total 6.587,9913
6.587,9913

4.1.10. Neraca Massa Mixing Point-02 (MP-02)

Input (kg) Output (kg)

Komponen
Aliran 29 Aliran 30 Aliran 31
2-Butanol 207,855 1.742,945 1.950,800
Air 3,474 0,886 4,360
TOTAL 1.955,160 1.955,160

33
4.1.11. Neraca Massa Kolom Destilasi-02 (KD-02)

Input (Kg) Output (Kg)

Komponen Bottom (Aliran
Aliran 20 Top (Aliran 21)
26)
2-Butanol 208,240 0,331 207,909
MEK 0,644 0,644 0,000
Air 3,474 0,000 3,474
0,975 211,383
TOTAL 212,358
212,358

4.1.12. Neraca Massa Total Condenser-02 (TC-02)

Input (Kg/jam) Output (Kg/jam)

Komponen Aliran 21 Aliran 22
Vapor Reflux Destilat
2-Butanol 0,331 0,000 0,331
MEK 0,644 0,000 0,644
Air 0,000 0,000 0,000
0,000 0,975
Total 0,975
0,975

4.1.13. Neraca Massa Accumulator-02 (ACC-02)

Input (Kg/jam) Output (Kg/jam)

Komponen Aliran 22 Aliran 23 Aliran 24
Vapor Reflux Destilat
2-Butanol 0,331 0,000 0,331
MEK 0,644 0,000 0,644
Air 0,000 0,000 0,000
0,000 0,975
Total 0,975
0,975

34
4.1.14. Neraca Massa Reboiler-02 (RB-02)

Input (Kg/jam) Output (Kg/jam)

Komponen
Aliran 26 Aliran 27 Aliran 28
2-Butanol 208,839 0,930 207,909
MEK 0,000 0,000 0,000
Air 3,489 0,016 3,474
0,946 211,383
Total 212,329
212,326

35
36

4.2 Neraca Panas

Kapasitas Produksi : 51.000 ton/tahun (Kemurnian Metil Etil Keton 99,99%)
Operasi Pabrik : 330 hari/tahun
Satuan : Kilo Joule (kJ)
Temperatur referensi : 25oC

4.2.1. Neraca Panas Mixing Point-01 (MP-01)

Neraca Panas Started Mixing Point-01 (MP-01)
Panas Panas Masuk (kJ) Panas Keluar (kJ)
Q1 101.794,0381 0,0000
Q32 0,0000 0,0000
Q2 0,0000 101.794,0381
Total 101.794,0381 101.794,0381

Neraca Panas Recycle Mixing Point-01 (MP-01)

Panas Panas Masuk (kJ) Panas Keluar (kJ)
Q1 78.962,5381 0,0000
Q32 22.831,5000 0,0000
Q2 0,0000 101.794,0381
Total 101.794,0381 101.794,0381

4.2.2. Neraca Panas Vaporizer-01 (VP-01)

Komponen Panas masuk (kJ) Panas keluar (kJ)

Q2 56.916,1479 -
Q3 - 197.124,4615
Qout bottom 640.023,8555
Q-lv - 3.868.271,5746
Qs-in 6.882.343,2923 -
Qs-out - 2.233.839,5485
 37

Total 6.939.259,4402 6.939.259,4402

4.2.3. Neraca Panas Kompressor-01 (K-01)

Panas Panas Masuk (kJ) Panas Keluar (kJ)

Qin 1.103.760,3783 0,0000
Qout 0,0000 1.606.890,3941
Qkompresi 1.006.260,0317 0,0000
Qcw, in 75.469,5024 0,0000
Qcw, out 0,0000 578.599,5182
Total 2.185.489,9124 2.185.489,9124

4.2.4. Neraca Panas Heater-01 (H-01)

Komponen Panas Masuk (kJ) Panas Keluar (kJ)
Q4 1.285.618,6899 -
Q5 - 3.884.286,1783
Qs,in 3.847.457,7506 -
Qs,out - 1.248.790,2622
Total 5.133.076,4405 5.133.076,4405

4.2.5. Neraca Panas Reaktor-01 (R-01)

Panas Panas Masuk (kJ) Panas Keluar (kJ)
Q5 3.765.962,0901 0,0000
Q6 0,0000 11.388.307,3185
Qr 0,0000 152.870.412,1698
Qs, in 237.617.589,0625 0,0000
Qs,-out 0,0000 77.124.831,6643
Total 241.383.551,1526 241.383.551,1526
38

4.2.6. Neraca Panas Kompresor-02 (K-02)

Panas Panas Masuk (kJ) Panas Keluar (kJ)
Qin 11.388.307,3185 0,0000
Qout 0,0000 12.286.580,8088
Qkompresi 1.796.546,9808 0,0000
Qcw, in 134.741,0236 0,0000
Qcw, out 0,0000 1.033.014,5139
Total 13.319.595,3228 13.319.595,3228

4.2.7. Neraca Panas Chiller-01 (CH-01)

Komponen Qin (kJ/jam) Qout (kJ/jam)
Q7 12.286.580,8088 -
Q8 - 101.559,1357
Qam,in 314.539,1004 -
Qam,out - 12.499.560,7736
Total 12.601.119,9093 12.601.119,9093
4.2.8. Neraca Panas Partical Condenser (PC-01)
Komponen Panas Masuk (kJ) Panas Keluar (kJ)
Q8 102.046,8171 0,0000
Q9(Liquid) - 74.740,7407
Q9(Vapor) - 52.833,8557
Qlv 3.043.896,8383 0,0000
Qcw, in 452.755,3589 0,0000
Qcw,out 0,0000 3.471.124,4179
Total 3.598.699,0142 3.598.699,0142
 39

4.2.9. Neraca Panas Knock Out Drum-KOD-01 (KOD-01)

Komponen Panas masuk (kJ) Panas keluar (kJ)

Q9 127.574,5963 -
Q10 - 74.740,7407
Q17 - 52.833,8557
Total 127.574,5963 127.574,5963

4.2.10. Neraca Panas Heater-02 (H-02)

Komponen Panas Masuk (kJ) Panas Keluar (kJ)

Q10 74.740,7407 -
Q11 - 1.013.802,3826
Qs,in 1.390.327,9310 -
Qs,out - 451.266,2891
Total 1.465.068,6717 1.465.068,6717

4.2.11. Neraca Panas Kolom Destilasi-01 (KD-01)

Komponen Q input (kJ) Q output (kJ)

Q11 1.013.802,3826 
Q12 - 550.233,0644
Q18 - 87.058,9436
Qrb 2.824.436,0457 
Qkd - 3.200.946,4203
Total 3.822.455,0566 3.822.455,0566

4.2.12. Neraca Panas Total Condenser-01 (TC-01)

Komponen Panas Masuk (kJ) Panas Keluar (kJ)

Q12 550.233,0644 0,0000
Q13 0,0000 822.738,6930
40

Qlv 2.647.988,6554 0,0000

Qcw, in 356.322,4540 0,0000
Qcw,out 0,0000 2.731.805,4808
Total 3.554.544,1738 3.554.544,1738

4.2.13. Neraca Panas Accumulator-01 (ACC-01)

Panas Panas Masuk (kJ) Panas Keluar (kJ)

Q13 823.682,3817 0,0000
Q14 0,0000 943,6887
Q15 0,0000 822.738,6930
Total 823.682,3817 823.682,3817

4.2.14. Neraca Panas Cooler-01 (C-01)

Komponen Qin (kJ/jam) Qout (kJ/jam)

Q15 822.738,6930 -
Q16 - 72.231,3505
Qs, in 112.576,1014 -
Qs, out - 863.083,4438
Total 935.314,7943 935.314,7943

4.2.15. Neraca Panas Reboiler-01 (RB-01)

Komponen Panas masuk (kJ) Panas keluar (kJ)

Q18 87.058,9436 0,0000
Q19 0,0000 2.824.436,0457
Q20 0,0000 87.058,9436
Qs,in 4.066.401,1142 0,0000
Qs-out 0,0000 1.241.965,0685
Total 4.153.460,0579 4.153.460,0579
 41

4.2.16. Neraca Panas Kolom Destilasi-02 (KD-02)

Komponen Q input (kJ) Q output (kJ)

Q20 87.058,9436 
Q21  619,5430
Q26  92.513,3300
Qkd - 1.743,3611
Qrb 7.817,2905 
Total 94.876,2341 94.876,2341

4.2.17. Neraca Panas Total Condenser-02 (TC-02)

Komponen Panas Masuk (kJ) Panas Keluar (kJ)

Q21 619,6927 0,0000
Q22 0,0000 894,2904
Qlv 1.123,6130 0,0000
Qcw, in 127,3523 0,0000
Qcw,out 0,0000 976,3676
Total 1.870,6580 1.870,6580

4.2.18. Neraca Panas Accumulator-02 (ACC-02)

Panas Panas Masuk (kJ) Panas Keluar (kJ)

Q22 894,5065 0,0000
Q23 0,0000 0,2161
Q34 0,0000 894,2904
Total 894,5065 894,5065
42

4.2.19. Neraca Panas Cooler-02 (C-02)

Komponen Qin (kJ/jam) Qout (kJ/jam)

Q24 329,5029 -
Q25 - 11,0311
Qcw,in 47,7708 -
Qcw,out - 366,2425
Total 377,2736 377,2736

4.2.20. Neraca Panas Reboiler-02 (RB-02)

Komponen Panas masuk (kJ) Panas keluar (kJ)

Q26 619,5430 0,0000
Q27 0,0000 7.817,2905
Q28 0,0000 619,5430
Qs,in 11.254,7206 0,0000
Qs-out 0,0000 3.437,4302
Total 11.874,2637 11.874,2637

4.2.21. Neraca Panas Cooler-03 (C-03)

Komponen Qin (kJ/jam) Qout (kJ/jam)

Q28 76.548,0701 -
Q29 - 38.571,8541
Qcw,in 5.696,4324 -
Qcw,out - 43.672,6484
Total 82.244,5025 82.244,5025

4.2.22. Neraca Panas Mixing Point-02 (MP-02)

Panas Panas Masuk (kJ) Panas Keluar (kJ)

 43

Q30 38.631,8019 0,0000

Q29 317.540,1947 0,0000
Q31 0,0000 356.171,9966
Total 356.171,9966 356.171,9966

4.2.23. Neraca Panas Cooler-04 (C-04)

Komponen Qin (kJ/jam) Qout (kJ/jam)

Q31 26.276.906,2479 -
Q32 - 1.684.411,0452
Qcw,in 3.688.874,2804 -
Qcw,out - 28.281.369,4832
Total 29.965.780,5283 29.965.780,5283