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MATERIAL SAFETY DATA SHEET (MSDS)

ASAM ASETAT MURNI (ASAM ASETAT GLASIAL)


CH3COOH
A.

PENDAHULUAN
Material Safety Data Sheet (MSDS) adalah kumpulan data keselamatan dan
petunjuk dalam penggunaan bahan-bahan kimia berbahaya. Panduan ini sebagai
informasi bagi tenaga kerja laboratorium dan tim Keselamatan Kesehatan Kerja (K3)
dalam pengunaan bahan-bahan kimia berbahaya yang sering digunakan dalam
praktikum atau analisis. Informasi tersebut diharapkan berguna untuk menumbuhkan
naluri atau sikap mencegah, menghindari dan mampu menanggulangi kecelakaan kimia
yang mungkin terjadi, serta sikap kehati-hatian dalam menangani bahan kimia
berbahaya.

B.

PENGERTIAN DAN KONSEP


Asam
asetat, asam
etanoat atau asam
cuka adalah senyawa
kimia asam organik yang
dikenal
sebagai
pemberi
rasa asam dan aroma dalam makanan. Asam cuka memiliki rumus empiris C 2H4O2.
Rumus ini seringkali ditulis dalam bentuk CH3-COOH, CH3COOH, atau CH3CO2H. Asam
asetat murni (disebut asam asetat glasial) adalah cairan higroskopis tak berwarna, dan
memiliki titik beku 16.7C.
Asam asetat merupakan salah satu asam karboksilat paling sederhana,
setelah asam format. Larutan asam asetat dalam air merupakan sebuah asam lemah,
artinya hanya terdisosiasi sebagian menjadi ion H+ dan CH3COO-. Asam asetat
merupakan pereaksi kimia dan bahan baku industri yang penting. Asam asetat
digunakan
dalam produksi polimer seperti polietilena
tereftalat, selulosa
asetat,
dan polivinil asetat, maupun berbagai macam serat dan kain. Dalam industri makanan,
asam asetat digunakan sebagai pengatur keasaman. Di rumah tangga, asam asetat
encer juga sering digunakan sebagai pelunak air. Dalam setahun, kebutuhan dunia akan
asam asetat mencapai 6,5 juta ton per tahun. 1.5 juta ton per tahun diperoleh dari
hasil daur ulang, sisanya diperoleh dari industri petrokimia maupun dari sumber hayati.

C.
1.
2.
3.
4.
5.
6.
7.
8.

NAMA-NAMA ASAM ASETAT GLASIAL


Acetic Acid (glasial)
Asam metanoat
Azunzuur
Asam cuka (Vinegar)
Essigsaure
Acide acetque
Acidium aceticum
Ethanoic acid

D. PENAMAAN
Asam asetat merupakan nama trivial atau nama dagang dari senyawa ini, dan
merupakan nama yang paling dianjurkan oleh IUPAC. Nama ini berasal dari
kata Latin acetum, yang berarti cuka. Nama sistematis dari senyawa ini adalah asam

etanoat. Asam asetat glasial merupakan nama trivial yang merujuk pada asam asetat
yang tidak bercampur air. Disebut demikian karena asam asetat bebas-air
membentuk kristal mirip es pada 16.7 C, sedikit di bawah suhu ruang.
Singkatan yang paling sering digunakan, dan merupakat singkatan resmi bagi
asam asetat adalahAcOH atau HOAc dimana Ac berarti gugus asetil, CH3C(=O). Pada
konteks asam-basa, asam asetat juga sering disingkat HAc, meskipun banyak yang
menganggap singkatan ini tidak benar. Ac juga tidak boleh disalahartikan dengan
lambang unsur Aktinium (Ac).
E.

PRODUKSI
Asam asetat diproduksi secara sintetis maupun secara alami melalui fermentasi
bakteri. Sekarang hanya 10% dari produksi asam asetat dihasilkan melalui jalur alami,
namun kebanyakan hukum yang mengatur bahwa asam asetat yang terdapat dalam
cuka haruslah berasal dari proses biologis. Dari asam asetat yang diproduksi oleh industri
kimia, 75% diantaranya diproduksi melalui karbonilasi metanol. Sisanya dihasilkan
melalui metode-metode alternatif.

F. CARA PEMBUATAN ASAM ASETAT GLASIAL


A. Karbonilasi Metanol
o Dalam reaksi ini, methanol dan karbon monoksida bereaksi menghasilkan asam asetat.
o Proses ini melibatkan iodometana sebagai zat antara, reaksi ini melalui tiga tahap, dengan
katalis logam kompleks pada tahap kedua.
B. Oksidasi Asetaldehida
o Asetaldehida yang digunakan dihasilkan melalui oksidasi Butana atau Nafta ringan, ketika
dipanaskan bersama udara disertai dengan beberapa ion logam, terbentuk Peroksida
yang selanjutnya terurai menjadi Asam Asetat.
o Melalui kondisi dan katalis yang sama asetaldehida dapat dioksidasi oleh oksigen udara
menghasilkan asam asetat.
G. SIFAT FISIK DAN KIMIA
o
o
o
o
o
o
o
o
o
o
o
o
o
o
o

Bentuk: Cairan
Warna: Tidak berwarna
Bau: Tajam
Nilai pH (50g/l H2O): (20oC) 2,5
Kekentalan Dinamik: (20oC) 1,22 mm2/s
Kekentalan Kinematik: (20oC) 1,77
Titik lebur: (17oC)
Titik didih: 116-118
Suhu penyalaan: 485oC
Titik nyala: 39oC
Batas ledakan: Lebih rendah 4 Vol%, leboh tinggi 19,9 Vol%
Tekanan uap: (20oC) 1,54 hPa
Densitas uap relatif: 2,07
Densitas; (20oC) 1,05 g/cm3
Kelarutan dalam air: (20oC) Dapat larut

o Log Pow: -0,17


o Faktor Biokonsentrasi: 1
o Indeks Refraksi: (20oC) 1,37
H. PENYIMPANAN ASAM ASETAT GLASIAL
o Jauhkan bahan dari nyala api.
o Tutup wadah dengan rapat dan hati-hati bila membuka tutup wadah.
o Simpan dalam wadah yang kuat dan tahan bocor dalam ruangan yang berventilasi pada
suhu diatas 16oC (titik beku).
o Jauhkan dari bahan inkompatibel: Oksidator (Kromat, Permanganat, Perklorat, basa kuat
seperti NaOH dan logam).
o Simpan dalam area terpisah dan disetujui.
o Simpan wadah tertutup rapat dan disegel sampai siap untuk digunakan.
o Hindari semua sumber-sumber pengapian (percikan atau api)
I.
o
o
o
o
o

STABILITAS REAKTIFITAS
Kondisi yang harus dihindarkan yaitu pemanasan.
Suhu < 0oC
Bahan yang harus dihindari: Beresiko meledak dengan zat pengoksid.
Reaksi yang hebat dapat terjadi dengan logam (Besi, Zinc, Magnesium)
Dinyatakan meledak dengan udara dalam uap atu gas jika di panaskan.

J.
o
o
o
o

IDENTITAS BAHAYA
Dapat terbakar.
Mengakibatkan luka bakar yang parah.
Uap asam dapat mengakibatkan iritasi pada hidung dan tenggorokan.
Kadar yang tinggi dapat menyebabkan peradangan saluran pernafasan dan akumulasi
cairan pada paru-paru.
o Dapat menyebabkan iritasi pada mata dan kerusakan mata permanen.
o Bila tertelan dapat menyebabkan gangguan saluran usus.
K. BATAS PEMAPARAN YANG DIPERBOLEHKAN
Nilai Ambang Batas (NAB) yaitu standar faktor bahaya di tempat kerja sebagai
pedoman pengendalian agar tenaga kerja masih dapat menghadapinya tanpa
mengakibatkan penyakit atau gangguan kesehatan dalam pekerjaan sehari-hari untuk
waktu tidak lebih dari 8 jam sehari atau 40 jam seminggu
Di Indonesia, menurut SNI 19-0232-2005 NAB Nilai Ambang Batas (NAB) zat kimia
di udara tempat kerja ICS 13.040.30 Badan Standardisasi Nasional (BSN), Nilai ambang
batas untuk zat kimia Asam asetat (64-19-7) mempunyai Bilai Ambang Batas sebesar 25
mg/m3 dan 10 bds (bagian dalam sejuta).
L.
1.
2.

INFORMASI TOKSIKOLOGI (POTENSI EFEK KESEHATAN)


Rute masuk: Terserap melalui kulit. Dermal kontak. Kontak mata. Inhalasi. Konsumsi.
Efek jangka pendek (akut)
Uap asam dapat mengakibatkan iritasi pada hidung dan tenggookan. Kadar yang
tinggi dapat menyebabkan peradangan saluran pernafasan dan akumulasi cairan pada

paru-paru. Jika terkena gas tersebut dapat mengakibatkan kerusakan jaringan terutama
pada selaput lendir mata, mulut dan saluran pernapasan. Tersentuh dengan kulit dapat
menghasilkan luka bakar. Terhirup gas tersebut akan menghasilkan iritasi pada saluran
pernapasan, yang ditandai dengan batuk, tersedak, atau sesak napas. Radang pada
mata ditandai dengan mata kemerahan, penyiraman, dan gatal. Radang kulit yang
ditandai dengan gatal, merah pada kulit.
Efek Kesehatan Akut Potensi: Kulit: Sangat menjengkelkan dan korosif.
Menyebabkan gangguan pada kulit (memerah dan gatal, peradangan). Dapat
menyebabkan terik, kerusakan jaringan dan luka bakar. Mata: Sangat menjengkelkan dan
korosif. Menyebabkan iritasi mata, lakrimasi, kemerahan, dan nyeri. Dapat menyebabkan
luka bakar, penglihatan kabur, konjungtivitis, kerusakan kornea dan konjungtiva dan
permanen cedera. Penghirupan: Menyebabkan iritasi saluran pernapasan parah.
Mempengaruhi organ arti (hidung, telinga, mata, rasa), dan darah. Dapat menyebabkan
pneumonitis kimia, bronkitis, dan edema paru. Eksposur parah dapat menyebabkan
jaringan paru-paru kerusakan dan korosi (ulkus) pada selaput lendir. Inhalasi juga dapat
menyebabkan rhinitis, bersin, batuk, menindas perasaan dalam nyeri dada atau dada,
dyspnea, mengi, takipnea, sianosis, air liur, mual, pusing, otot kelemahan. Tertelan:
Cukup beracun. Korosif. Menyebabkan gangguan saluran pencernaan (pembakaran dan
rasa sakit dari mulut, tenggorokan, dan perut, batuk, ulserasi, perdarahan, mual, kejang
abdomial, muntah, hematemesis, diare. Juga dapat mempengaruhi hati (gangguan fungsi
hati), perilaku (kejang-kejang, giddines, kelemahan otot), dan saluran kemih sistem ginjal (hematuria, Albuminuria, nephrosis, gagal ginjal akut, nekrosis tubular akut). Juga
dapat menyebabkan dispnea atau asfiksia. Juga dapat menyebabkan syok, koma dan
kematian.
3.

4.

Efek Jangka panjang (kronis)


Iritasi pada hidung, tenggorokan, mata dan kulit, serta dapat menimbulkan erosi
pada gigi.Berbahaya jika terjadi terkena kulit, tertelan, terhirup. Efek mutagenik:
mutagenik untuk sel somatik mamalia, mutagenik untuk bakteri dan ragi. Substansi
mungkin beracun untuk ginjal, mukosa, selaput, kulit, gigi. Jika terkena zat ini secara
berkelanjutan dapat merusak organ saraf. Terkena dalam waktu yang lama dengan zat
tersebut dapat menghasilkan iritasi mata kronis dan iritasi kulit yang parah,
menyebabkan iritasi saluran pernapasan, menyebabkan serangan infeksi bronkus.
Efek Kesehatan kronis Potensi: Paparan kronis melalui konsumsi dapat
menyebabkan menghitam atau erosi pada gigi dan rahang nekrosis, faringitis, dan
gastritis. Ini mungkin juga perilaku (mirip dengan akut konsumsi), dan metabolisme
(berat badan). Paparan kronis melalui inhalasi dapat menyebabkan asma dan / atau
bronkitis dengan batuk, dahak, dan / atau sesak napas. Hal ini juga dapat mempengaruhi
darah (leukosit menurun count), dan sistem kemih (ginjal). Kontak kulit berulang atau
berkepanjangan dapat menyebabkan penebalan, menghitam, dan cracking kulit. Efek
mutagenik: mutagenik untuk sel somatik mamalia. Mutagenik untuk bakteri dan / atau
ragi. Dapat menyebabkan kerusakan berikut organ: ginjal, selaput lendir, kulit, gigi.
Dapat mempengaruhi materi genetik dan dapat menyebabkan efek reproduksi
berdasarkan data hewan. Tidak ada data manusia ditemukan.
Keracunan untuk Hewan:

PERINGATAN: LC50 ATAS NILAI TERTERA DI BAWAH INI ADALAH ESTIMASI BERDASARKAN
Sebuah SAMBUNGAN 4-JAM. Oral akut toksisitas (LD50): 3310 mg / kg [Tikus]. Toksisitas
kulit akut (LD50): 1060 mg / kg [Kelinci]. Toksisitas akut dari uap (LC50): 5620 1 jam
[mouse].
5.

Efek lain Beracun pada Manusia: Sangat berbahaya jika terjadi inhalasi (korosif paru).
Sangat berbahaya jika terjadi kontak kulit (iritan), menelan. Berbahaya jika terjadi kontak
kulit (korosif, permeator), kontak mata (korosif).

M. TINDAKAN PERTOLONGAN PERTAMA


1. Mata
Jika terkena mata segera siram dengan air bersih yang banyak dan mengalir
sekurang-kurangnya selama 10 menit. kemudian hubungi petugas medis segera.
2. Kulit
Jika terkena kulit, segera basuh kulit dengan air yang banyak dan mengalir
sedikitnya selama 15 menit. Olesi dengan Polyethylene Glycol atau dapat menghubungi
perawatan medis dengan segera. Jika terkena pakaian, segera lepaskan pakaian yang
terkontaminasi
3. Terhirup
Jika terhirup, segera cari tempat yang mengandung udara bersih dan segar. Jika
pingsan, berikan pernapasan buatan. Jika sulit bernapas, berikan oksigen. Dapatkan
medis perhatian segera.
4. Tertelan
Diusahakan untuk tidak memuntahkannya kecuali bila diarahkan oleh petugas
medis. Berikan air minum yang banyak. Jangan pernah memberikan apapun melalui
mulut kepada orang yang pingsan. Longgarkan pakaian yang ketat seperti kerah, dasi,
ikat pinggang atau ikat pinggang. Dapatkan bantuan medis jika gejala muncul.
N. KEBAKARAN DAN CARA PENCEGAHANNYA
o Asam asetat pekat bersifat korosif dan karena itu harus digunakan dengan penuh hatihati. Asam asetat dapat menyebabkan luka bakar, kerusakan mata permanen, serta
iritasi pada membran mukosa. Luka bakar atau lepuhan bisa jadi tidak terlihat hingga
beberapa jam setelah kontak. Sarung tangan latextidak melindungi dari asam asetat,
sehingga dalam menangani senyawa ini perlu digunakan sarung tangan berbahan karet
nitril. Asam asetat pekat juga dapat terbakar di laboratorium, namun dengan sulit. Ia
menjadi mudah terbakar jika suhu ruang melebihi 39 C (102 F), dan dapat membentuk
campuran yang mudah meledak di udara (ambang ledakan: 5.4%-16%)Resiko yang
khusus, mudah menyala, uap lebih berat dari pada udara.
o Uap asam asetat memungkinkan membentuk ledakan campuran dengan udara.
o Reaksi antara asam asetat dan bahan-bahan seperti 5-azidotetrazole, pentafluoride brom,
kromium trioksida, hydrogen peroksida, kalium permanganate, atrium peroksida dan
triklorida phorphorus.
o Tindakan pencegahan kebakaran dapat dilakukan dengan cara media yang cocok untuk
pemadaman air, CO2, busa, Powder dan apabila memadamkan dengan air, cegahlah air
pemadam kebakaran memasuki permukaan air tanah karena mengandung uap yang
keluar dari air.

O. TINDAKAN TERHADAP TUMPAHAN DAN KEBOCORAN


A. Tumpahan kecil
Encerkan dengan air dan mengepel atau menyerap dengan bahan inert dan tempat
kering dalam wadah pembuangan limbah baik. Jika diperlukan menetralisir residu dengan
larutan encer natrium karbonat.
B. Tumpahan besar
o Mudah terbakar cair, korosif cair. Jauhkan dari panas. Jauhkan dari sumber api. Hentikan
kebocoran jika tanpa resiko.
o Jika produk dalam bentuk padat, gunakan sekop untuk menaruh materi ke dalam wadah
pembuangan limbah nyaman.
o Jika produk dalam bentuk cair:
Menyerap dengan bumi kering, pasir atau non materi yang mudah terbakar.
Jangan sampai air dalam container.
Menyerap dengan bahan inert dan menempatkan bahan yang tumpah dalam pembuangan
limbah yang baik.
Jangan menyentuh bahan tumpah.
Gunakan air semprot tirai untuk menglihkan melayang uap.
Mencegah masuk ke dalam selokan, ruang bawah tanah atau daerah terbatas. Tanggul jika
diperlukan.
Memnta bantuan bila dibuang.
Menetralisir residu dengan larutan encer natrium karbonat.
Perlindungan pribadi dalm kasus tumpahan besar dapat menggunakan splash kacamata,
uap respirator, boots, sarung tangan dan sebuah alat bernafas mandiri contained harus
digunakan untuk menghindri inhalasi produk.
P. TINDAKAN PENCEGAHAN DAN PERLINDUNGAN DIRI
Jauhkan dari api dan sumber api.
Jangan ditelan. Jika tertelan, segera dapatkan saran medis dan tunjukan wadah atau label.
Pribadi perlindungan: Menggunakan APD (Alat Pelindung Diri) berupa splash kacamata,
sintetis celemek, uap respirator, masker, boots, sarung tangan dan sebuah alat bernafas
mandiri contained harus digunakan untuk menghindri inhalasi produk. Pastikan untuk
menggunakan respirator yang disetuju/bersertifikat/setara. Sarung tangan (Tahan).
Tahan nafas jika berhadapan dalam bentuk gas/asap/uap/semprotan.
Jangan pernah menambahkan air pada produk ini. Dalam hal ventilasi cukup, pakai
pernapasan yang sesuai eralatan.
Hindari kontak dengan kulit dan mata.
Jauhkan dari incompatibles seperti agen oksidasi, mengurangi agen logam, asam, alkali.
Rekayasa kontrol: sediakan ventilasi pembuangan atau kendali teknik lain.
Q. PEMBUANGAN LIMBAH
Metode pembuangan limbah:
1. Buanglah sesuai dengana semua yang berlaku federal, Negara dan peraturan local.
2. Selalu kontak pemelihara limbah diizinkan (TSP) untuk memastikan kepatuhan.
R. MANFAAT DAN KEGUNAAN

1.

2.

3.

4.
5.

Asam asetat memiliki banyak manfaat bagi kehidupan manusia,tidak hanya itu
asam asetat juga berperan dalam perindustrian dan kesehatan, yaitu:
Dalam industri makanan asam asetat digunakan sebagai pengatur keasaman, pemberi
rasa asam dan aroma dalam makanan, serta untuk menambah rasa sedap pada
masakan.
Asam asetat digunakan sebagai pereaksi kimia untuk menghasilkan berbagai senyawa
kimia. Sebagian besar (40-45%) dari asam asetat dunia digunakan sebagai bahan untuk
memproduksi monomer vinil asetat (vinyl acetate monomer, VAM).
Selain itu asam asetat juga digunakan dalam produksi anhidrida asetat dan juga ester.
Penggunaan asam asetat lainnya, termasuk penggunaan dalam cuka relatif kecil. Sekitar
larutan 12,5% untuk makanan.
Reagen untuk analisa.
Untuk membuat putih timbal, dll.

Material Safety Data Sheet HCl


1. IDENTIFIKASI PRODUK
Nama : Asam klorida, reagen ACS
Identifikasi perusahaan : acros organics N.V
One reagent lane
Fairlawn, NJ 07410
Untuk informasi di Amerika Utara, telp : 800-ACROS-01
Untuk informasi bahaya di US, telp : CHEMTREC:800-424-4300
2. KOMPOSISI/INFORMASI KANDUNGAN BAHAN
CAS # BAHAN % EINECS#
7647-01-0 Asam klorida 37 % 231-595-7
7732-18-5 air seimbang 231-791-2
Symbol bahaya : C
Resiko : R34 : menyebabkan luka baker
R37 : gangguan system pernafasan
3. IDENTIFIKASI BAHAYA

Tinjauan keadaan darurat


Kenampakan :
bersih, tidak berwarna sampai kuning muda
Bahaya korosif, sensitive, menyebabkan luka baker pada kulit dan mata,
dapat menyebabkan gangguan pernafasan, dan efek samping yang
berdampak buruk bagi saluran pencernaan.
Dampak kesehatan
Mata :
menyebabkan luka permanent pada mata, uap/percikan dapat
mengakibatkan iritasi dan luka baker yang parah. Kontak dengan cairan
secara langsung mengakibatkan luka baker baik pada kulit maupun mata,
menyebabkan rasa sakit dan peka terhadap cahaya
Kulit :
dalam jumlah yang banyak dapat membahayakan bagi kulit, cairan
bersifat korosif apabila kontak dengan kulit akan menyebabkan luka baker
dan koreng (borok).
Saluran pembuangan :
efek samping yang berbahaya dapat mengakibatkan kerusakan/gangguan
pada system pencernaan, seperti sakit di sekitar perut, muntah-muntah,
dan kemungkinan kematian, dapat menyebabkan kerusakan permanent
pada jaringan espagus dan system pencernaan.
Pernafasan :
menyebabkan iritasi parah pada saluran pernafasan atas, seperti batukbatuk, luka pada tenggorokan, sesak nafas, dan kemungkinan koma.
Menyebabkan penyakit paru-paru dan gangguan pernafasan.
Kronis :
Apabila sering terkena kulit dan terpapar terlalu lama dapat menyebabkan
dermatitis, apabila terlalu sering berkenaan dengan bahan dapat
menyebabkan erosi pada gigi.
4. PERTOLONGAN PERTAMA
Mata :
bilas mata dengan air mengalir krang lebih selama 15 menit, dan segera
mencari pertolongan medis, JANGAN mengedipkan mata atau
membiarkannya tertutup.
Kulit :
segera mencari pertolongan medis, bilas daerah yang terkena dengan air
yang banyak selama kurang lebih 15 menit, tanggalkan pakaian atau
sepatu yang terkena oleh bahan atau terkontaminasi
Saluran pembuangan :
JANGAN dimuntahkan, apabila korban dalam keadaan yang

membahayakan/kritis, berikan 2-4 cangkir penuh susu atau air, dan


segera mencari pertolongan medis.
Pernafasan :
segera cari udara segar dan jauhkan dari sumber bahaya. jika tidak
bernafas, berikan bantuan nafas (nafas buatan). Jika sesak nafas , berikan
oksigen. Segera cari pertolongan medis.
5. CARA MEMADAMKAN KEBAKARAN
Informasi umum
Gunakan pakaian pelindung, dan peralatan pernafasan, MSHA/NIOSH, dan
perlengkapan lainnya yang dapat melindungi. Bahan tidak mudah
terbakar akan tetapi bereaksi dengan sebagian besar logam, menjadi gas
hydrogen yang mudah terbakar. Semprotkan air untuk mencegah api
meluas
6. TINDAKAN PENYELAMATAN
Informasi umum :
gunakan APD (Alat Pelindung Diri) seperti yang disarankan pada point ke 8
Tumpahan/kebocoran :
tumpahan yang banyak dapat dinetralisir dengan cairan alkaline abu soda
encer. Untuk mengambil tumpahan gunakan bahan yang dapat menyerap
akan tetapi tidak berbahaya seperti tanah, pasir, vermiculite.
7. PENANGANAN DAN PENYIMPANAN
Penanganan :
Cuci tangan setelah menangani bahan. Tanggalkan pakaian yang diduga
terkontaminasi dan cuci sebelum digunakan kembali. Cari tempat yang
mempunyai sirkulasi udara yang memadai. Jangan sampai terkena kulit
atau mata, jangan terhirup atau tertelan.
Penyimpanan :
Jauhkan dari udara panas dan api. Jangan disimpan ditempat yang terkena
sinar matahari langsung. Simpan di tempat yang sejuk, kering, dengan
sirkulasi udara yang baik.
8. PENGAWASAN DAN PERLINDUNGAN PERSONAL
Pengawasan terhadap pekerja :
Gunakan ruangan yang mempunyai saluran pembuangan udara/uap untuk
mengurangi keadaan bahaya bagi pekerja.
Peralatan pelindung diri untuk pekerja
Mata :
gunakan kacamata yang melindungi, atau gunakan goggles seperti yang
dianjurkan oleh OSHA, atau menurut standar Eropa EN 166
Kulit :
gunakan sarung tangan pelindung untuk mencegah terjadinya luka pada

kulit
Pakaian :
gunakan pakaian yang dapat melindungi badan dengan baik
9. SIFAT-SIFAT FISIK BAHAN KIMIA
Kenampakan Bersih, tak berwarna sampai kuning muda
Bau Kuat, menyengat
Daya larut 823 g/L air pada 32 F
Kepadatan 1.16-1.19
pH 1.1 (0.1 N sol)
% penguapan dalam volume @ 21 C (70 F). Tidak tersedia
Titik didih 230 derajat F
Titik lebur -101 derajat F
Uap (udara=1) 1.257
Tekanan uap 160 mm Hg
Tingkat penguapan (butyl asetat = 1) 2.0
Rumus molekul : HCl
Berat molekul : 36.46
10. KESTABILAN DAN DAYA REAKSI
Stabilitas bahan kimia :
stabil dibawah temperature normal dan bertekanan
Dijauhkan pada kondisi :
bahan yang tidak sesuai, cahaya
Bahan-bahan yang tidak sesuai :
Asetat, asetat anhidrat, ammonium hidroksida, kalsium karbonat, kalsium
phosphate, sodium, sodium hidroksida, asam sulfat.
Bahaya dekomposisi produk :
Hydrogen klorida, klorin, karbon monoksida, gas hydrogen
11. INFORMASI KERACUNAN
Karsinigenik : asam klorida, reagen ACS
IARC : grup 3 karsinogen
Epidemiologi : informasi tidak tersedia
Efek reproduksi : informasi tidak tersedia

12. INFORMASI EKOLOGI


Bahaya lingkungan :
Ikan air tawar LC100=10 mg/L/24 jam, udang LC50=100-300 ppm,
bintang laut LC50=100-330 mg/L/48 jam, kepiting LC50=240 mg/L/48
jam

Keadaan lingkungan :
Substansi akan ternetralisir soil karbonat-berdasarkan komponennya
Fisik/Kimia :
Informasi tidak tersedia
13. PERTIMBANGAN PEMBUANGAN
Pengaturan limbah berdasarkan Negara, wilayah kesatuan, Negara bagian
yang bersangkutan

Material Saftey Data Sheet


Natrium klorida/Sodium Chlorida
(Nacl)
Nama
TSCA
Sinonim
Nama Kimia

: Natrium klorida
: TSCA 8 (b) persediaan: Natrium klorida
: Sea Salt
: Sodium chloride

Formula Kimia

: NaCl

Komposisi dan Informasi Bahan

Komposisi:
Nama CAS #% berdasar Berat
Natrium klorida 7647-14-5 100
Data toksikologi pada Bahan : Natrium klorida: LISAN (LD50): Akut:
3000 mg / kg [Rat.]. 4000 mg / kg [Tikus]. Dermal (LD50): Akut:>
10000 mg / kg [Kelinci]. DUST (LC50): Akut:> 42000 mg / m 1 jam [Rat].
Sodium Chlorida atau Natrium Chlorida (NaCl) yang dikenal
sebagai garam adalah zat yang memiliki tingkat osmotik yang tinggi.
Natrium klorida adalah senyawa kimia dengan rumus molekul NaCl.
Senyawa
ini
adalah garam yang
paling
memengaruhi salinitas laut dan cairan
ekstra selularpada
banyak
organisme multi selular. Sebagai komponen utama pada garam dapur,
natrium
klorida
sering
digunakan
sebagai bumbu dan pengawet makanan.
Natrium adalah logam putih perak yang lunak, yang melebur pada
97,5 C.Natrium teroksidasi dengan cepat dalam udara lembab, maka
harus disimpan terendam seluruhnya dalam pelarut nafta atau silena.
Logam ini bereaksi keras dengan air, membentuk Natrium Hidroksida
dan Hidrogen. Dalam garam-garamnya natrium berada sebagai kation
monovalen Na +. Garam-garam ini membentuk larutan tak berwarna,
hampir semua garam natrium larut dalam air.
0

Identifikasi Bahaya
Tanda Bahaya
Potensi Efek Kesehatan Akut : Sedikit berbahaya dalam kasus kontak
kulit (iritan), kontak mata (iritan), menelan, inhalasi.
Potensi Efek Kesehatan kronis :
Efek karsinogenik : Tidak tersedia.
Efek
mutagenik : Mutagenik
untuk
sel
somatik
mamalia.
mutagenik untukbakteri dan atau ragi.
Efek teratogenik: Tidak tersedia.
Tindakan Pertolongan Pertama
Kontak Mata : Periksa dan lepaskan lensa kontak. Dalam kasus kontak,
segera basuh mata dengan banyak air selama minimal 15 menit. Air
dingin dapat digunakan. Dapatkan perawatan medis.
Kontak Kulit : Cuci dengan sabun dan air. Tutupi kulit yang teriritasi
dengan yg melunakkan. Dapatkan bantuan medis jika terjadi iritasi. air
dingin dapat digunakan.

Terhirup : Jika terhirup, pindahkan ke udara segar. Jika tidak bernapas,


berikan pernapasan buatan. Jika sulit bernapas, berikan oksigen.
Dapatkan medis perhatian jika gejala muncul.
Tertelan : Jangan memancing
muntah
kecuali
diarahkan
untuk
melakukannyaoleh tenaga medis. Dilarang memberikan apapun melalui
mulut kepada sadarorang. Kendurkan pakaian ketat seperti kerah, dasi,
ikat pinggang atau ikat pinggang. Dapatkan bantuan medis jika gejala
muncul.
Resiko ledakan produk di hadapan dampak mekanis :
Keterangan Khusus tentang Bahaya Kebakaran : Ketika dipanaskan
untuk dekomposisi itu memancarkan asap beracun.
Keterangan Khusus tentang Bahaya Ledakan : Elektrolisis
natrium
klorida dalam adanya senyawa nitrogen untuk menghasilkan klorin
dapat menyebabkan pembentukan peledak triklorida nitrogen. Reaksi
berpotensi meledak dengan anhidrida dichloromaleic + urea. Tindakan
Release Terkadang
Tumpahan Kecil : Gunakan alat yang tepat untuk menempatkan tumpah
solid di dalam wadah pembuangan limbah nyaman. Selesai
membersihkan dengan menyebarkan air di permukaan yang
terkontaminasi dan membuang sesuai dengan kebutuhan otoritas lokal
dan regional.
Tumpahan besar : Gunakan sekop untuk menaruh materi ke dalam
wadah pembuangan limbah nyaman. Selesai membersihkan dengan
menyebarkan air di terkontaminasi permukaan dan memungkinkan
untuk mengevakuasi melalui sistem sanitasi.
Penanganan dan Penyimpanan :
Tindakan pencegahan:
Simpan dalam tempat terkunci.
Jangan menelan.
Jangan menghirup debu.
Hindari kontak dengan mata.
Pakailah pakaian pelindung yang sesuai.
Jika tertelan : Segera dapatkan saran medis dan tunjukkan wadah atau
label. Jauhkan dari incompatibles seperti oksidasi agen, asam.
Penyimpanan : Simpan wadah tertutup rapat. Simpan wadah di
tempatyang sejuk,
berventilasi baik. Hidroskopis.
Pengontrolan Pemaparan / Perlindungan Pribadi :
Kontrol Rekayasa : Gunakan lampiran proses, ventilasi pembuangan
lokal, atau rekayasa lain kontrol untuk menjaga kadar udara di bawah
yang direkomendasikan batas yang diperbolehkan. Jika operasi
pengguna menghasilkan debu, asap atau kabut, gunakan ventilasi
untuk menjaga paparan kontaminan udara di bawah batas yang
diperbolehkan .

Perlindungan
Pribadi : Splash
kacamata, Lab
mantel, Debu
respirator, Sarung tangan. Pastikan untuk menggunakan / respirator
atau setara bersertifikat disetujui.
Pribadi Perlindungan di Kasus Tumpahan Besar : Splash
kacamata, Setelan penuh, Debu respirator, Boots Sarung
tangan, Sebuah alat bernafas mandiri harus digunakan untuk
menghindari inhalasi produk, Pakaian pelindung yang disarankan
mungkin tidak cukup. berkonsultasi dengan spesialis SEBELUM
penanganan ini produk.
Informasi Toksikologi
Rute masuk : Terhirup . Tertelan .
Keracunan untuk Hewan :
PERINGATAN : NILAI LC50 DIBAWAH INI ADALAH ESTIMASI
BERDASARKAN
A SAMBUNGAN 4 - JAM . oral akut
toksisitas ( LD50 ) : 3000 mg / kg [ Rat . ] . Toksisitas kulit akut
( LD50 ) : > 10000 mg / kg [ Kelinci ] .
Toksisitas akut dari debu ( LC50 ) : > 42000 mg/m3 1 jam [ Rat ] .
Efek kronis pada Manusia :
Efek mutagenik : Mutagenik untuk sel somatik mamalia . Mutagenik
untuk bakteri dan atau ragi .
Efek beracun lainnya pada Manusia : Sedikit berbahaya dalam
kasus kontak kulit (iritan), menelan, inhalasi .
Keterangan Khusus tentang Keracunan untuk Hewan : Terendah
Published Lethal Dosis ( LDL ) [ Man ] - Rute : Oral ; Dosis : 1000 mg /
kg .

Material Safety Data Sheet


Sodium Bromide

ACC# 21060

Section 1 - Chemical Product and Company Identification


MSDS Name: Sodium Bromide
Catalog Numbers: S78369, S78369-1, NC9508240, NC9557408, S255 3, S255 500,
S255-3, S255-500, S2553, S255500, S783691, XXS25550KG
Synonyms:
Company Identification:
Fisher Scientific
1 Reagent Lane
Fair Lawn, NJ 07410
For information, call: 201-796-7100
Emergency Number: 201-796-7100
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call: 703-527-3887

Section 2 - Composition, Information on Ingredients


CAS#
7647-15-6

Chemical Name

Percent

EINECS/ELINCS

100

231-599-9

SODIUM BROMIDE

Hazard Symbols: None listed.


Risk Phrases: None listed.

Section 3 - Hazards Identification


EMERGENCY OVERVIEW
Appearance: white. Caution! May cause eye and skin irritation. May cause respiratory
and digestive tract irritation. May cause central nervous system depression. May cause
fetal effects based upon animal studies.
Target Organs: Central nervous system.
Potential Health Effects
Eye: May cause eye irritation.
Skin: May cause skin irritation.
Ingestion: May cause central nervous system depression, characterized by excitement,
followed by headache, dizziness, drowsiness, and nausea. Advanced stages may cause
collapse, unconsciousness, coma and possible death due to respiratory failure. Advanced
stages may cause collapse, unconsciousness, coma and possible death due to respiratory
failure.
Inhalation: May cause respiratory tract irritation. May cause effects similar to those
described for ingestion.
Chronic: May cause fetal effects. May cause incoordination and mental disturbances.

Section 4 - First Aid Measures


Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally
lifting the upper and lower eyelids. Get medical aid.
Skin: Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes
while removing contaminated clothing and shoes.
Ingestion: If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give
anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation: Remove from exposure to fresh air immediately. If not breathing, give
artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures


General Information: As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
During a fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion.
Extinguishing Media: Use extinguishing media most appropriate for the surrounding
fire.

Section 6 - Accidental Release Measures


General Information: Use proper personal protective equipment as indicated in Section
8.
Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container.
Clean up spills immediately, observing precautions in the Protective Equipment section.
Avoid generating dusty conditions. Provide ventilation.

Section 7 - Handling and Storage


Handling: Wash thoroughly after handling. Remove contaminated clothing and wash
before reuse. Use with adequate ventilation. Minimize dust generation and accumulation.
Avoid contact with eyes, skin, and clothing. Do not ingest or inhale.
Storage: Store in a cool, dry place. Store in a tightly closed container.

Section 8 - Exposure Controls, Personal Protection


Engineering Controls: Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or local exhaust
ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits
Chemical Name
SODIUM BROMIDE

ACGIH
none listed

NIOSH

OSHA - Final PELs

none listed

none listed

OSHA Vacated PELs: SODIUM BROMIDE: No OSHA Vacated PELs are listed for this
chemical.
Personal Protective Equipment

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by


OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard
EN166.
Skin: Wear appropriate protective gloves and clothing to prevent skin exposure.
Clothing: Wear appropriate protective clothing to minimize contact with skin.
Respirators: Follow the OSHA respirator regulations found in 29CFR 1910.134 or
European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved
respirator when necessary.

Section 9 - Physical and Chemical Properties


Physical State: Solid
Appearance: white
Odor: none reported
pH: 6.5-8 (solution)
Vapor Pressure: Not applicable.
Vapor Density: Not available.
Evaporation Rate:Not applicable.
Viscosity: Not applicable.
Boiling Point: 1390 deg C
Freezing/Melting Point:1377 deg F
Autoignition Temperature: Not available.
Flash Point: Not available.
Decomposition Temperature:800 deg C
NFPA Rating: (estimated) Health: 1; Flammability: 0; Reactivity: 0
Explosion Limits, Lower:Not available.
Upper: Not available.
Solubility: 95 g/100ml (25 C)
Specific Gravity/Density:3.203 @ 25C
Molecular Formula:BrNa
Molecular Weight:102.8938

Section 10 - Stability and Reactivity


Chemical Stability: Stable under normal temperatures and pressures.
Conditions to Avoid: Incompatible materials, dust generation, moisture.
Incompatibilities with Other Materials: Strong oxidizing agents, strong acids.
Hazardous Decomposition Products: Hydrogen bromide.
Hazardous Polymerization: Has not been reported.

Section 11 - Toxicological Information


RTECS#:
CAS# 7647-15-6: VZ3150000
LD50/LC50:
CAS# 7647-15-6:
Oral, mouse: LD50 = 7 gm/kg;
Oral, rat: LD50 = 3500 mg/kg;<br.
Carcinogenicity:
CAS# 7647-15-6: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Epidemiology: No data available.
Teratogenicity: Effects on newborn (behavioral).

Reproductive Effects: No data available.


Neurotoxicity: No data available.
Mutagenicity: No data available.
Other Studies: No data available.</br.

Section 12 - Ecological Information


No information available.

Section 13 - Disposal Considerations


Chemical waste generators must determine whether a discarded chemical is classified as
a hazardous waste. US EPA guidelines for the classification determination are listed in 40
CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous
waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information


US DOT

IATA

RID/ADR

IMO

No
Shipping Name: information
available.
Hazard Class:
UN Number:
Packing Group:

Section 15 - Regulatory Information


US FEDERAL
TSCA
CAS# 7647-15-6 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
SARA
Section 302 (RQ)
None of the chemicals in this material have an RQ.
Section 302 (TPQ)
None of the chemicals in this product have a TPQ.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:

Canada
TDG
No
informatio
n
available.

This material does not contain any hazardous air pollutants. This material does not
contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone
depletors.
Clean Water Act:
None of the chemicals in this product are listed as Hazardous Substances under the
CWA. None of the chemicals in this product are listed as Priority Pollutants under the
CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
CAS# 7647-15-6 is not present on state lists from CA, PA, MN, MA, FL, or NJ.
California No Significant Risk Level: None of the chemicals in this product are
listed. European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
Not available.
Risk Phrases:
Safety Phrases:
WGK (Water Danger/Protection)
CAS# 7647-15-6: 1
Canada
CAS# 7647-15-6 is listed on Canada's DSL List. CAS# 7647-15-6 is listed on Canada's
DSL List.
This product has a WHMIS classification of D2B.
CAS# 7647-15-6 is listed on Canada's Ingredient Disclosure List.
Exposure Limits

Section 16 - Additional Information


MSDS Creation Date: 12/12/1997
Revision #1 Date: 8/02/2000

The information above is believed to be accurate and represents the best information currently available to us.
However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such
information, and we assume no liability resulting from its use. Users should make their own investigations to
determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any
claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or
exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages

Material Safety Data Sheet


Ammonium Hydroxide

ACC# 01260

Section 1 - Chemical Product and Company Identification


MSDS Name: Ammonium Hydroxide
Catalog Numbers: A470-250, A512-500, A564-200L, A564-20L, A564-212L, A564-500,
A667-212, A669-212, A669-385LB, A669-500, A669-612GAL, A669C-2.5, A669C-212,
A669FP500, A669S-2.5, A669S-212, A669S-500, A669S212E, A669S212EA,
A669S212LC, A699P500, S70663MF, S70665, S70665-1, S70665MF, S75029, SCH1143
Synonyms: Ammonium Hydrate; Ammonia Solution; Ammonia Water; Aqueous
Ammonia.
Company Identification:
Fisher Scientific
1 Reagent Lane
Fair Lawn, NJ 07410
For information, call: 201-796-7100
Emergency Number: 201-796-7100
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call: 703-527-3887

Section 2 - Composition, Information on Ingredients


CAS#

Chemical Name

1336-21-6

Ammonium hydroxide

7664-41-7

Ammonia

7732-18-5

Water

Percent

EINECS/ELINCS

57.0

215-647-6

22-30

231-635-3

43.0

231-791-2

Hazard Symbols: T C
Risk Phrases: 25 34

Section 3 - Hazards Identification


EMERGENCY OVERVIEW
Appearance: colourless. Danger! Corrosive. Causes eye and skin burns. Causes
digestive and respiratory tract burns. Toxic. Lachrymator (substance which increases the
flow of tears). Harmful if swallowed.
Target Organs: Eyes, skin, mucous membranes.
Potential Health Effects
Eye: Contact with liquid or vapor causes severe burns and possible irreversible eye
damage.
Skin: Causes severe skin irritation. Causes skin burns. May cause deep, penetrating
ulcers of the skin. Contact with the skin may cause staining, inflammation, and
thickening of the skin.
Ingestion: Harmful if swallowed. May cause severe and permanent damage to the
digestive tract. Causes gastrointestinal tract burns. Causes throat constriction, vomiting,
convulsions, and shock.
Inhalation: Effects may be delayed. Causes severe irritation of upper respiratory tract
with coughing, burns, breathing difficulty, and possible coma.
Chronic: Chronic ingestion may cause effects similar to those of acute ingestion.

Prolonged or repeated exposure may cause corneal damage and the development of
cataracts and glaucoma.

Section 4 - First Aid Measures


Eyes: Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed.
Extensive irrigation with water is required (at least 30 minutes).
Skin: In case of contact, immediately flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Get medical aid immediately.
Wash clothing before reuse.
Ingestion: If swallowed, do NOT induce vomiting. Get medical aid immediately. If victim
is fully conscious, give a cupful of water. Never give anything by mouth to an
unconscious person.
Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Get medical aid.
Notes to Physician: After inhalation exposure, observe for 24 to 72 hours as
pulmonary edema may be delayed.

Section 5 - Fire Fighting Measures


General Information: As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
During a fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion. Use water spray to keep fire-exposed containers cool.
Vapors may be heavier than air. They can spread along the ground and collect in low or
confined areas. Contact with metals may evolve flammable hydrogen gas. Containers
may explode when heated. Non-combustible, substance itself does not burn but may
decompose upon heating to produce corrosive and/or toxic fumes.
Extinguishing Media: For small fires, use water spray, dry chemical, carbon dioxide or
chemical foam. Do NOT get water inside containers. For large fires, use dry chemical,
carbon dioxide, alcohol-resistant foam, or water spray. Cool containers with flooding
quantities of water until well after fire is out.

Section 6 - Accidental Release Measures


General Information: Use proper personal protective equipment as indicated in Section
8.
Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then
place in suitable container. Neutralize spill with a weak acid such as vinegar or acetic
acid. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills
immediately, observing precautions in the Protective Equipment section. Provide
ventilation.

Section 7 - Handling and Storage


Handling: Wash thoroughly after handling. Remove contaminated clothing and wash
before reuse. Use only in a well-ventilated area. Do not get in eyes, on skin, or on
clothing. Keep container tightly closed. Do not ingest or inhale. Discard contaminated
shoes.

Storage: Do not store in direct sunlight. Store in a tightly closed container. Store in a
cool, dry, well-ventilated area away from incompatible substances. Corrosives area.

Section 8 - Exposure Controls, Personal Protection


Engineering Controls: Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne
concentrations low.
Exposure Limits
Chemical Name

ACGIH

Ammonium hydroxide none listed


Ammonia
Water

25 ppm TWA; 35 ppm


STEL
none listed

NIOSH

OSHA - Final PELs

none listed

none listed

25 ppm TWA; 18
mg/m3 TWA 300 ppm
IDLH

50 ppm TWA; 35
mg/m3 TWA

none listed

none listed

OSHA Vacated PELs: Ammonium hydroxide: No OSHA Vacated PELs are listed for this
chemical. Ammonia: 35 ppm STEL; 27 mg/m3 STEL Water: No OSHA Vacated PELs are
listed for this chemical.
Personal Protective Equipment
Eyes: Wear chemical goggles.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: Follow the OSHA respirator regulations found in 29CFR 1910.134 or
European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved
respirator when necessary.

Section 9 - Physical and Chemical Properties


Physical State: Liquid
Appearance: colourless
Odor: strong odor - ammonia-like
pH: 13.6 at 32F.
Vapor Pressure: 115 mm Hg @20C
Vapor Density: 1.2 (Air=1)
Evaporation Rate:1 (Water=1)
Viscosity: Not available.
Boiling Point: 36 deg C
Freezing/Melting Point:-77 deg C
Autoignition Temperature: 1202 deg F ( 650.00 deg C)
Flash Point: Not available.
Decomposition Temperature:Not available.
NFPA Rating: (estimated) Health: 3; Flammability: 1; Reactivity: 0
Explosion Limits, Lower:16.0
Upper: 27.0
Solubility: Completely soluble in water.
Specific Gravity/Density:0.9
Molecular Formula:Not applicable.
Molecular Weight:Not available.

Section 10 - Stability and Reactivity

Chemical Stability: Stable under normal temperatures and pressures.


Conditions to Avoid: High temperatures, incompatible materials.
Incompatibilities with Other Materials: Acrolein, acrylic acid, chlorosulfonic acid,
dimethyl sulfate, fluorine, gold + aqua regia, hydrochloric acid, hydrofluoric acid, iodine,
nitric acid, oleum, propiolactone, propylene oxide, silver nitrate, silver oxide, silver oxide
+ ethyl alcohol, nitromethane, silver permanganate, sulfuric acid, halogens. Forms
explosive compounds with many heavy metals and halide salts.
Hazardous Decomposition Products: Nitrogen oxides (NOx) and ammonia (NH3).
Hazardous Polymerization: Has not been reported.

Section 11 - Toxicological Information


RTECS#:
CAS# 1336-21-6: BQ9625000
CAS# 7664-41-7: BO0875000
CAS# 7732-18-5: ZC0110000
LD50/LC50:
CAS# 1336-21-6:
Draize test, rabbit, eye: 250 ug Severe;
Draize test, rabbit, eye: 44 ug Severe;
Oral, rat: LD50 = 350 mg/kg;<br.
CAS# 7664-41-7:
Inhalation, mouse: LC50 = 4230 ppm/1H;
Inhalation, rabbit: LC50 = 7 gm/m3/1H;
Inhalation, rat: LC50 = 2000 ppm/4H;<br.
CAS# 7732-18-5:
Oral, rat: LD50 = >90 mL/kg;<br.
Carcinogenicity:
CAS# 1336-21-6: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA. CAS# 7664-41-7:
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA. CAS# 7732-18-5: Not listed by
ACGIH, IARC, NIOSH, NTP, or OSHA.
Epidemiology: No information available.
Teratogenicity: No information available.
Reproductive Effects: No information available.
Neurotoxicity: No information available.
Mutagenicity: No information available.
Other Studies: Standard Draize Test: Administration into the eye (rabbit) = 250 ug
(Severe).</br.
</br.
</br.

Section 12 - Ecological Information


Ecotoxicity: Fish: Rainbow trout: LC50 = 0.008 mg/L; 24 Hr.; Unspecified Fathead
Minnow: LC50 = 8.2 mg/L; 96 Hr.; Unspecified Bluegill/Sunfish: LC50 = 0.024-0.093
mg/L; 48 Hr.; Unspecified flea Daphnia: EC50 =0.66 mg/L; 48 Hr.; 22 degrees C Bluegill
LC50=0.024 to 0.093 mg/L/48H Goldfish TLm=2.0 to 2.5 mg/L/24-96H
Environmental: No information reported.

Physical: No information available.


Other: None.

Section 13 - Disposal Considerations


Chemical waste generators must determine whether a discarded chemical is classified as
a hazardous waste. US EPA guidelines for the classification determination are listed in 40
CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous
waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information


US DOT
Shipping Name:
Hazard Class:
UN Number:

IATA

RID/ADR

IMO

AMMONIA
SOLUTIONS
8

Canada
TDG
AMMONIUM
HYDROXID
E
8(9.2)

UN2672

Packing Group: III

UN2672
III

Section 15 - Regulatory Information


US FEDERAL
TSCA
CAS# 1336-21-6 is listed on the TSCA inventory.
CAS# 7664-41-7 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
SARA
Section 302 (RQ)
CAS# 1336-21-6: final RQ = 1000 pounds (454 kg) CAS# 7664-41-7: final RQ = 100
pounds (45.4 kg)
Section 302 (TPQ)
CAS# 7664-41-7: TPQ = 500 pounds; RQ = 100 pounds (does not meet toxi city criteria
but because of high production volume and recognized tox icity is considered a chemical
of concern)
SARA Codes
CAS # 1336-21-6: acute, chronic.
Section 313
This material contains Ammonia (CAS# 7664-41-7, 22 30%),which is subject to the
reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373.

Clean Air Act:


This material does not contain any hazardous air pollutants. This material does not
contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone
depletors.
Clean Water Act:
CAS# 1336-21-6 is listed as a Hazardous Substance under the CWA. CAS# 7664-41-7 is
listed as a Hazardous Substance under the CWA. None of the chemicals in this product
are listed as Priority Pollutants under the CWA. None of the chemicals in this product are
listed as Toxic Pollutants under the CWA.
OSHA:
CAS# 7664-41-7 is considered highly hazardous by OSHA.
STATE
CAS# 1336-21-6 can be found on the following state right to know lists: California, New
Jersey, Pennsylvania, Massachusetts.
CAS# 7664-41-7 can be found on the following state right to know lists: California, New
Jersey, Florida, Pennsylvania, Minnesota, Massachusetts.
CAS# 7732-18-5 is not present on state lists from CA, PA, MN, MA, FL, or NJ.
California No Significant Risk Level: None of the chemicals in this product are
listed. European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
TC
Risk Phrases:
R 25 Toxic if swallowed.
R 34 Causes burns.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 1336-21-6: 2
CAS# 7664-41-7: 2
CAS# 7732-18-5: No information available.
Canada
CAS# 1336-21-6 is listed on Canada's DSL List. CAS# 1336-21-6 is listed on Canada's
DSL List. CAS# 7664-41-7 is listed on Canada's DSL List. CAS# 7664-41-7 is listed on
Canada's DSL List. CAS# 7732-18-5 is listed on Canada's DSL List. CAS# 7732-18-5 is
listed on Canada's DSL List.
This product has a WHMIS classification of D1B, E.
CAS# 1336-21-6 is listed on Canada's Ingredient Disclosure List.
CAS# 7664-41-7 is listed on Canada's Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 7664-41-7: OEL-ARAB Republic of Egypt:TWA 25 ppm (18 mg/m3) OE
L-AUSTRALIA:TWA 25 ppm (18 mg/m3);STEL 35 ppm (27 mg/m3) OEL-AUSTRIA:
TWA 50 ppm (35 mg/m3) OEL-BELGIUM:TWA 25 ppm (17 mg/m3);STEL 35 ppm (
24 mg/m3) OEL-CZECHOSLOVAKIA:TWA 20 mg/m3;STEL 40 mg/m3 OEL-DENMARK:
TWA 25 ppm (18 mg/m3) OEL-FINLAND:TWA 25 ppm (18 mg/m3);STEL 40 ppm (
30 mg/m3) OEL-FRANCE:TWA 25 ppm (18 mg/m3);STEL 50 ppm (36 mg/m3) OE
L-GERMANY:TWA 50 ppm (35 mg/m3) OEL-HUNGARY:TWA 18 mg/m3;STEL 27 mg/m

3 OEL-INDIA:TWA 25 ppm (18 mg/m3);STEL 35 ppm (27 mg/m3) OEL-JAPAN:T


WA 25 ppm (17 mg/m3) OEL-THE NETHERLANDS:TWA 25 ppm (18 mg/m3) OEL-T
HE PHILIPPINES:TWA 50 ppm (30 mg/m3) OEL-POLAND:TWA 20 mg/m3;STEL 20
mg/m3 OEL-RUSSIA:TWA 25 ppm;STEL 20 mg/m3 OEL-SWEDEN:TWA 25 ppm (18
mg/m3);STEL 50 ppm (35 mg/m3) OEL-SWITZERLAND:TWA 25 ppm (18 mg/m3);S
TEL 50 ppm (36 mg/m3) OEL-THAILAND:TWA 50 ppm (35 mg/m3) OEL-TURKEY:
TWA 25 ppm (35 mg/m3) OEL-UNITED KINGDOM:TWA 25 ppm (18 mg/m3);STEL 3
5 ppm (27 mg/m3) OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH
TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV

Section 16 - Additional Information


MSDS Creation Date: 6/22/1999
Revision #4 Date: 7/20/2001

The information above is believed to be accurate and represents the best information currently available to us.
However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such
information, and we assume no liability resulting from its use. Users should make their own investigations to
determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any
claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or
exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.

Material Safety Data Sheet


Ammonium Chloride

ACC# 01170

Section 1 - Chemical Product and Company Identification

MSDS Name: Ammonium Chloride


Catalog Numbers: AC9470862, S70609, S70609-1, S70609-2, S70609-3, A649 3,
A649 500, A649-3, A649-500, A64910KG, A6493, A649500, A661 10, A661 3, A661
500, A661-10, A661-3, A661-500, A66110, A6613, A661500, NC9483471, NC9483488,
NC9528216, NC9570959, S706091, S706092, S706093, XXA649EP10KG
Synonyms: Ammonium Chloratum, Ammonium Chloridum, Ammonium Muriate, Sal
Ammonia, Salmiac.
Company Identification:
Fisher Scientific
1 Reagent Lane
Fair Lawn, NJ 07410
For information, call: 201-796-7100
Emergency Number: 201-796-7100
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call: 703-527-3887

Section 2 - Composition, Information on Ingredients


CAS#
12125-02-9

Chemical Name
Ammonium chloride

Percent

EINECS/ELINCS

>99.0

235-186-4

Hazard Symbols: XN
Risk Phrases: 22 36

Section 3 - Hazards Identification


EMERGENCY OVERVIEW
Appearance: colorless or white. Caution! May cause respiratory and digestive tract
irritation. May be harmful if swallowed. Causes eye irritation. May cause skin irritation.
Target Organs: None.
Potential Health Effects
Eye: Causes eye irritation.
Skin: May cause skin irritation.
Ingestion: May cause irritation of the digestive tract. May cause systemic toxicity with
acidosis. May be harmful if swallowed.
Inhalation: If heated, dust or fume may cause respiratory tract irritation.
Chronic: Prolonged or repeated skin contact may cause dermatitis.

Section 4 - First Aid Measures


Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the
upper and lower eyelids. Get medical aid immediately.
Skin: Flush skin with plenty of soap and water for at least 15 minutes while removing
contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash
clothing before reuse.
Ingestion: Induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or
water. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation: Remove from exposure to fresh air immediately. If not breathing, give

artificial respiration. If breathing is difficult, give oxygen. Get medical aid.


Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures


General Information: As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
During a fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion. Use water spray to keep fire-exposed containers cool.
Substance is noncombustible. Containers may explode in the heat of a fire. May
polymerize explosively when involved in a fire.
Extinguishing Media: For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. Substance is noncombustible; use agent most appropriate to
extinguish surrounding fire. For large fires, use water spray, fog or alcohol-resistant
foam. Cool containers with flooding quantities of water until well after fire is out.

Section 6 - Accidental Release Measures


General Information: Use proper personal protective equipment as indicated in Section
8.
Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container.
Clean up spills immediately, observing precautions in the Protective Equipment section.
Avoid generating dusty conditions. Provide ventilation.

Section 7 - Handling and Storage


Handling: Wash thoroughly after handling. Use with adequate ventilation. Minimize dust
generation and accumulation. Do not get in eyes, on skin, or on clothing. Keep container
tightly closed. Avoid ingestion and inhalation.
Storage: Store in a cool, dry, well-ventilated area away from incompatible substances.
Store below 40C.

Section 8 - Exposure Controls, Personal Protection


Engineering Controls: Use adequate general or local exhaust ventilation to keep
airborne concentrations below the permissible exposure limits.
Exposure Limits
Chemical Name
Ammonium chloride

ACGIH
10 mg/m3 TWA; 20
mg/m3 STEL

NIOSH

OSHA - Final PELs

10 mg/m3 TWA

none listed

OSHA Vacated PELs: Ammonium chloride: 10 mg/m3 TWA; 20 mg/m3 STEL


Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by
OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard
EN166.
Skin: Wear impervious gloves.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: Follow the OSHA respirator regulations found in 29CFR 1910.134 or

European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved
respirator when necessary.

Section 9 - Physical and Chemical Properties


Physical State: Solid
Appearance: colorless or white
Odor: odorless
pH: 5.0 (10% sol at 25C)
Vapor Pressure: 1 mm Hg @ 160.4C
Vapor Density: Not available.
Evaporation Rate:Negligible.
Viscosity: Not available.
Boiling Point: 520 deg C(sublimes)
Freezing/Melting Point:328 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Decomposition Temperature:Not available.
NFPA Rating: (estimated) Health: 1; Flammability: 0; Reactivity: 0
Explosion Limits, Lower:Not available.
Upper: Not available.
Solubility: 39.6% at 176F.
Specific Gravity/Density:1.53 (Water=1)
Molecular Formula:NH4Cl
Molecular Weight:53.4877

Section 10 - Stability and Reactivity


Chemical Stability: Stable at room temperature in closed containers under normal
storage and handling conditions.
Conditions to Avoid: Incompatible materials, excess heat.
Incompatibilities with Other Materials: Acids, alkalis, and their associated
carbonates. Substance reacts with lead and silver salts to form a fulminating compound.
Substance reacts with ammonium compounds, bromine pentafluoride, bromine
trifluoride, hydrogen cyanide, iodine heptafluoride, nitrates, and potassium chlorate.
Hazardous Decomposition Products: Irritating and toxic fumes and gases, ammonia
and hydrochloric acid fumes.
Hazardous Polymerization: May occur.

Section 11 - Toxicological Information


RTECS#:
CAS# 12125-02-9: BP4550000
LD50/LC50:
CAS# 12125-02-9:
Draize test, rabbit, eye: 500 mg/24H Mild;
Draize test, rabbit, eye: 100 mg Severe;
Oral, mouse: LD50 = 1300 mg/kg;
Oral, rat: LD50 = 1650 mg/kg;<br.
Carcinogenicity:
CAS# 12125-02-9: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Epidemiology: No information available.

Teratogenicity: No information available.


Reproductive Effects: No information available.
Neurotoxicity: No information available.
Mutagenicity: Cytogenetic analysis: hamster fibroblast, 400 mg/L.
Other Studies: None.</br.

Section 12 - Ecological Information


Ecotoxicity: Fish: LC50 = 109.0 mg/L; 48 Hr.; Static conditions Sunfish (fresh water)
TLm=6 ppm/96H
Environmental: No information reported.
Physical: No information available.
Other: None.

Section 13 - Disposal Considerations


Chemical waste generators must determine whether a discarded chemical is classified as
a hazardous waste. US EPA guidelines for the classification determination are listed in 40
CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous
waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information


US DOT

IATA

RID/ADR

IMO

No
Shipping Name: information
available.

Canada
TDG
AMMONIUM
CHLORIDE

Hazard Class:

9.2

UN Number:

UN9085

Packing Group:

III

Additional Info:

REGULATED
LIMIT
230KG

Section 15 - Regulatory Information


US FEDERAL
TSCA
CAS# 12125-02-9 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
SARA

Section 302 (RQ)


CAS# 12125-02-9: final RQ = 5000 pounds (2270 kg)
Section 302 (TPQ)
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 12125-02-9: acute, chronic.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants. This material does not
contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone
depletors.
Clean Water Act:
CAS# 12125-02-9 is listed as a Hazardous Substance under the CWA. None of the
chemicals in this product are listed as Priority Pollutants under the CWA. None of the
chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
CAS# 12125-02-9 can be found on the following state right to know lists: California, New
Jersey, Florida, Pennsylvania, Minnesota, Massachusetts.
California No Significant Risk Level: None of the chemicals in this product are
listed. European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
XN
Risk Phrases:
R 22 Harmful if swallowed.
R 36 Irritating to eyes.
Safety Phrases:
S 22 Do not breathe dust.
WGK (Water Danger/Protection)
CAS# 12125-02-9: 1
Canada
CAS# 12125-02-9 is listed on Canada's DSL List. CAS# 12125-02-9 is listed on Canada's
DSL List.
This product has a WHMIS classification of D2B.
CAS# 12125-02-9 is listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 12125-02-9: OEL-ARAB Republic of Egypt:TWA 10 mg/m3 (fume) OEL
-AUSTRALIA:TWA 10 mg/m3;STEL 20 mg/m3 (fume) OEL-BELGIUM:TWA 10 mg/m3
;STEL 20 mg/m3 (fume) OEL-DENMARK:TWA 10 mg/m3 (fume) OEL-FRANCE:TWA
10 mg/m3 (fume) OEL-THE NETHERLANDS:TWA 10 mg/m3 (fume) OEL-RUSSIA:
STEL 10 mg/m3 (fume) OEL-SWITZERLAND:TWA 6 mg/m3 (fume) OEL-UNITED K
INGDOM:TWA 10 mg/m3;STEL 20 mg/m3 (fume) OEL IN BULGARIA, COLOMBIA, J
ORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM c
heck ACGI TLV

Section 16 - Additional Information


MSDS Creation Date: 6/15/1999
Revision #1 Date: 8/02/2000

The information above is believed to be accurate and represents the best information currently available to us.
However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such

information, and we assume no liability resulting from its use. Users should make their own investigations to
determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any
claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or
exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages

Material Safety Data Sheet


Sodium hydroxide, solid, pellets or beads

ACC# 21300

Section 1 - Chemical Product and Company Identification


MSDS Name: Sodium hydroxide, solid, pellets or beads
Catalog Numbers: S71990, S71990-1, S71991, S71992, S71993, S71993-1, S71993-

2, S71993-3, S71993-4, S78605, BP359-212, BP359-500, BW13580500, BW1358350,


BW13583500, S318-1, S318-10, S318-100, S318-3, S318-3LC, S318-5, S318-50, S318500, S318-50LC, S320-1, S320-10, S320-3, S320-50, S320-500, S612-3, S612-50,
S612-500LB, S613-10, S613-3, S613-50, S613-500LB
Synonyms: Caustic soda; Soda lye; Sodium hydrate; Lye.
Company Identification:
Fisher Scientific
1 Reagent Lane
Fair Lawn, NJ 07410
For information, call: 201-796-7100
Emergency Number: 201-796-7100
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call: 703-527-3887

Section 2 - Composition, Information on Ingredients


CAS#

Chemical Name

Percent

EINECS/ELINCS

497-19-8

Sodium carbonate

<3

207-838-8

1310-73-2

Sodium hydroxide

95-100

215-185-5

Hazard Symbols: C
Risk Phrases: 35

Section 3 - Hazards Identification


EMERGENCY OVERVIEW
Appearance: white. Danger! Corrosive. Causes eye and skin burns. Hygroscopic. May
cause severe respiratory tract irritation with possible burns. May cause severe digestive
tract irritation with possible burns.
Target Organs: Eyes, skin, mucous membranes.
Potential Health Effects
Eye: Causes eye burns. May cause chemical conjunctivitis and corneal damage.
Skin: Causes skin burns. May cause deep, penetrating ulcers of the skin. May cause skin
rash (in milder cases), and cold and clammy skin with cyanosis or pale color.
Ingestion: May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns. May cause perforation of the digestive tract. Causes severe
pain, nausea, vomiting, diarrhea, and shock. May cause corrosion and permanent tissue
destruction of the esophagus and digestive tract. May cause systemic effects.
Inhalation: Irritation may lead to chemical pneumonitis and pulmonary edema. Causes
severe irritation of upper respiratory tract with coughing, burns, breathing difficulty, and
possible coma. Causes chemical burns to the respiratory tract.
Chronic: Prolonged or repeated skin contact may cause dermatitis. Effects may be
delayed.

Section 4 - First Aid Measures


Eyes: In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Get medical aid immediately.
Skin: In case of contact, immediately flush skin with plenty of water for at least 15

minutes while removing contaminated clothing and shoes. Get medical aid immediately.
Wash clothing before reuse.
Ingestion: If swallowed, do NOT induce vomiting. Get medical aid immediately. If victim
is fully conscious, give a cupful of water. Never give anything by mouth to an
unconscious person.
Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Get medical aid.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures


General Information: As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Use
water spray to keep fire-exposed containers cool. Use water with caution and in flooding
amounts. Contact with moisture or water may generate sufficient heat to ignite nearby
combustible materials. Contact with metals may evolve flammable hydrogen gas.
Extinguishing Media: Substance is noncombustible; use agent most appropriate to
extinguish surrounding fire. Do NOT get water inside containers.

Section 6 - Accidental Release Measures


General Information: Use proper personal protective equipment as indicated in Section
8.
Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container.
Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills
immediately, observing precautions in the Protective Equipment section. Avoid
generating dusty conditions. Provide ventilation. Do not get water on spilled substances
or inside containers.

Section 7 - Handling and Storage


Handling: Wash thoroughly after handling. Do not allow water to get into the container
because of violent reaction. Minimize dust generation and accumulation. Do not get in
eyes, on skin, or on clothing. Keep container tightly closed. Avoid ingestion and
inhalation. Discard contaminated shoes. Use only with adequate ventilation.
Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area
away from incompatible substances. Keep away from metals. Corrosives area. Keep
away from acids. Store protected from moisture. Containers must be tightly closed to
prevent the conversion of NaOH to sodium carbonate by the CO2 in air.

Section 8 - Exposure Controls, Personal Protection


Engineering Controls: Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or local exhaust
ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits
Chemical Name

ACGIH

NIOSH

OSHA - Final PELs

Sodium carbonate

none listed

none listed

none listed

Sodium hydroxide

C 2 mg/m3

10 mg/m3 IDLH

2 mg/m3 TWA

OSHA Vacated PELs: Sodium carbonate: No OSHA Vacated PELs are listed for this
chemical. Sodium hydroxide: C 2 mg/m3
Personal Protective Equipment
Eyes: Wear chemical goggles.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134
and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever
workplace conditions warrant a respirator's use.

Section 9 - Physical and Chemical Properties


Physical State: Solid
Appearance: white
Odor: Odorless
pH: 14 (5% aq soln)
Vapor Pressure: 1 mm Hg @739 deg C
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: 1390 deg C @ 760 mm Hg
Freezing/Melting Point:318 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Decomposition Temperature:Not available.
NFPA Rating: (estimated) Health: 3; Flammability: 0; Reactivity: 1
Explosion Limits, Lower:Not available.
Upper: Not available.
Solubility: Soluble.
Specific Gravity/Density:2.13 g/cm3
Molecular Formula:NaOH
Molecular Weight:40.00

Section 10 - Stability and Reactivity


Chemical Stability: Stable at room temperature in closed containers under normal
storage and handling conditions.
Conditions to Avoid: Moisture, contact with water, exposure to moist air or water,
prolonged exposure to air.
Incompatibilities with Other Materials: Acids, water, flammable liquids, organic
halogens, metals, aluminum, zinc, tin, leather, wool, nitromethane.
Hazardous Decomposition Products: Toxic fumes of sodium oxide.
Hazardous Polymerization: Will not occur.

Section 11 - Toxicological Information


RTECS#:
CAS# 497-19-8: VZ4050000
CAS# 1310-73-2: WB4900000
LD50/LC50:
CAS# 497-19-8:
Draize test, rabbit, eye: 100 mg/24H Moderate;

Draize test, rabbit, eye: 50 mg Severe;


Draize test, rabbit, skin: 500 mg/24H Mild;
Inhalation, mouse: LC50 = 1200 mg/m3/2H;
Inhalation, rat: LC50 = 2300 mg/m3/2H;
Oral, mouse: LD50 = 6600 mg/kg;
Oral, rat: LD50 = 4090 mg/kg;<br.
CAS# 1310-73-2:
Draize test, rabbit,
Draize test, rabbit,
Draize test, rabbit,
Draize test, rabbit,
Draize test, rabbit,

eye: 400 ug Mild;


eye: 1% Severe;
eye: 50 ug/24H Severe;
eye: 1 mg/24H Severe;
skin: 500 mg/24H Severe;<br.

Carcinogenicity:
CAS# 497-19-8: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA. CAS# 1310-73-2:
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Epidemiology: No information available.
Teratogenicity: No information available.
Reproductive Effects: No information available.
Neurotoxicity: No information available.
Mutagenicity: No information available.
Other Studies: See actual entry in RTECS for complete information.</br.
</br.

Section 12 - Ecological Information


No information available.

Section 13 - Disposal Considerations


Chemical waste generators must determine whether a discarded chemical is classified as
a hazardous waste. US EPA guidelines for the classification determination are listed in 40
CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous
waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information


US DOT

IATA

RID/ADR

IMO

SODIUM
Shipping Name: HYDROXIDE,
SOLID
Hazard Class:
UN Number:

SODIUM
HYDROXID
E
8(9.2)

UN1823

Packing Group: II

UN1823
II

Section 15 - Regulatory Information


US FEDERAL

Canada
TDG

TSCA
CAS# 497-19-8 is listed on the TSCA inventory.
CAS# 1310-73-2 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
SARA
Section 302 (RQ)
CAS# 1310-73-2: final RQ = 1000 pounds (454 kg)
Section 302 (TPQ)
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 497-19-8: acute. CAS # 1310-73-2: acute, reactive.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants. This material does not
contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone
depletors.
Clean Water Act:
CAS# 1310-73-2 is listed as a Hazardous Substance under the CWA. None of the
chemicals in this product are listed as Priority Pollutants under the CWA. None of the
chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
CAS# 497-19-8 is not present on state lists from CA, PA, MN, MA, FL, or NJ.
CAS# 1310-73-2 can be found on the following state right to know lists: California, New
Jersey, Florida, Pennsylvania, Minnesota, Massachusetts.
California No Significant Risk Level: None of the chemicals in this product are
listed. European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
C
Risk Phrases:
R 35 Causes severe burns.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 497-19-8: 1
CAS# 1310-73-2: 1
Canada
CAS# 497-19-8 is listed on Canada's DSL List. CAS# 497-19-8 is listed on Canada's DSL

List. CAS# 1310-73-2 is listed on Canada's DSL List. CAS# 1310-73-2 is listed on
Canada's DSL List.
This product has a WHMIS classification of E.
CAS# 497-19-8 is listed on Canada's Ingredient Disclosure List.
CAS# 1310-73-2 is listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 1310-73-2: OEL-AUSTRALIA:TWA 2 mg/m3 OEL-BELGIUM:STEL 2 mg/m3
OEL-DENMARK:TWA 2 mg/m3 OEL-FINLAND:TWA 2 mg/m3 OEL-FRANCE:TWA 2 mg
/m3 OEL-GERMANY:TWA 2 mg/m3 OEL-JAPAN:STEL 2 mg/m3 OEL-THE NETHERLA
NDS:TWA 2 mg/m3 OEL-THE PHILIPPINES:TWA 2 mg/m3 OEL-SWEDEN:TWA 2 mg/
m3 OEL-SWITZERLAND:TWA 2 mg/m3;STEL 4 mg/m3 OEL-THAILAND:TWA 2 mg/m3
OEL-TURKEY:TWA 2 mg/m3 OEL-UNITED KINGDOM:TWA 2 mg/m3;STEL 2 mg/m3
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW
ZEALAND, SINGAPORE, VIETNAM check ACGI TLV

Section 16 - Additional Information


MSDS Creation Date: 12/12/1997
Revision #4 Date: 8/01/2001

The information above is believed to be accurate and represents the best information currently available to us.
However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such
information, and we assume no liability resulting from its use. Users should make their own investigations to
determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any
claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or
exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages

DAFTAR PUSTAKA
Handout pribadi mata kuliah K3 praktek semester I oleh Ibu Sutiyami, ST,M.Kes.
PDF Files. SNI 19-0232-2005 NAB Nilai Ambang Batas (NAB) zat kimia di udara tempat
kerja
ICS 13.040.30 Badan Standardisasi Nasional (BSN)
http://id.wikipedia.org/wiki/Asam_asetat
http://avogadro.chem.iastate.edu/MSDS/NaBr.htm
http://avogadro.chem.iastate.edu/MSDS/NaOH.htm
http://avogadro.chem.iastate.edu/MSDS/NH3aq.htm
http://avogadro.chem.iastate.edu/MSDS/NH4Cl.htm
http://mbingboo29.blogspot.com/2012/05/asam-asetat-msds.html

http://efamuniar.blogspot.co.id/2014/07/msds-bahan-kimia-garam.html

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