1.

DATA PEN
PENUGASAN
Laju Gas 14000
%w/w Solut dalam Gas 0.11
%v/v solut dalam Cairan Penyerap Umpan 800
Konstanta Henry 11700
Temperatur Operasi 54
Tekanan Operasi 7.5
Jenis Packing Metal Raschig
Recovery 0.9

2. PENENTUAN
DATAFISIK
Mr Udara 28.96 g/mol Mr Gas 26.88805657
Mr air 18.02 g/mol
Mr NH3 17.03 g/mol
densitas NH3 0.769 kg/m3 0.000769 g/mL
densitas air 986.2 kg/m3 0.9862 g/mL

3. PENENTUAN PER
ALIRAN GAS
Laju molar gas total (Gm)
Laju molar solut dalam gas
Laju molar gas inert
Fraksi mol solut (y1)
INLET Perbandingan mol solut (Y1)
Perbandingan mol solut (Y2)
OUTLET
Fraksi mol solut (y2)

4. PEMBUATAN KURVA KE
Yi yi xi Xi
Y2 0.0210 0.0206 0.0111 0.0112
0.0310 0.0300 0.0161 0.0164
0.0409 0.0393 0.0211 0.0216
0.0509 0.0484 0.0260 0.0267
0.0608 0.0574 0.0308 0.0318
0.0708 0.0661 0.0355 0.0368
0.0808 0.0747 0.0401 0.0418
0.0907 0.0832 0.0447 0.0467
0.1007 0.0915 0.0491 0.0516
 0.1106 0.0996 0.0535 0.0565
0.1206 0.1076 0.0578 0.0613
0.1305 0.1155 0.0620 0.0661
0.1405 0.1232 0.0661 0.0708
0.1504 0.1308 0.0702 0.0755
0.1604 0.1382 0.0742 0.0802
0.1704 0.1456 0.0782 0.0848
0.1803 0.1528 0.0820 0.0894
0.1903 0.1599 0.0858 0.0939
0.2002 0.1668 0.0896 0.0984
Y1 0.2102 0.1737 0.0933 0.1029
0.0099557847

5. PENENTUAN NUMBER O

y1/y2 8.436924486
𝒎
𝑮_𝒎 0.6 0.65 0.7 0.75
/𝑳_𝒎
NOG Hitung 3.4499170827 3.66213033912 3.909385417383 4.202211
DNOG Hitung 0.2122132564 0.24725507826 0.292825582833 0.353948582

Pemilihan NOG
𝐦
𝐆_𝐦 x1 NOG
/𝐋_𝐦
0.6 0.0459 3.450
0.65 0.0498 3.662
0.7 0.0536 3.909
0.75 0.0574 4.202
0.8 0.0612 4.556
0.85 0.0651 4.995
Max 0.0612
0.8 4.556

mGm/Lm optimum 0.8 5.000

0.4
kriteria X1 terbesar
rentang optimum 0,7-0,8
Lm/Gm 2.5

mGm/Lm optimum 0.8

6. Penentuan D
Parameter simbol Nilai
Berat Molekul gas MrV 26.888056569
Densitas gas rV 8.336
Densitas cair rL 985.3
Viskositas gas mV 0.00001821
Viskositas cair mL 0.0005091
Laju alir molar gas Gm 0.1446325761
Laju alir massa gas Vw 3.8888888889
Laju alir molar cair Lm 0.3615814403
Laju alir massa cair Lw 6.515697555
Liquid Vapor flow fraction FLV 0.1541097066
K4 pressure drop K4p 1.25
K4 flooding line K4f 2.888
Percentage flooding %f 0.6578947368
Packing factor Fp 190
Packing size dp 51
Laju alir massa gas per luas Vw* 4.1706040521
Luas penampang kolom A 0.9324521917
Diameter kolom Dc 1.0896031406
Diameter kolom baru Dc baru 1.092
Luas penampang kolom baru A baru 0.9365590355
Packing size to Dc ratio 21.411764706
Flooding percentage baru %f baru 0.6550098456

7. Metode
Parameter Simbol Nilai
Association Parameter j 2.6
Volume molar solut VM 0.0258
Difusivitas cairan DL,AB 4.6284429E-06
Structural volume increment NH3 SvA 14.9
Structural volume increment udara SvB 20.1
Difusivitas gas Dv,AB 3.464735E-06
Laju alir massa superfisial cair L w* 6.9570601617
Gas Schmidt number ScV 0.630495823
Liquid Schmidt number ScL 0.1491298524
HG factor y 105
HL factor f 0.082
Faktor koreksi f1*f2*f3 0.8095241431
Percentage flooding correction factor K3 0.875
HOG tebakan HOG tebak 1.9903133941
Height of a gas-phase transfer unit HG 1.9823525349
Height of a liq-phase transfer unit HL 0.0099514673
Overall height of gas-phase HOG hitung 1.9903137088
Galat HOG Galat Hog 1.5808877E-05
Tinggi kolom hitungan Zhitung 9.0681854428
Z/D 8.3224663228

8. METOD
Parameter simbol Nilai
Packing surface area a 102
critical surface tension of packing σc 0.075
tegangan permukaan cairan σL 0.06702

laju alir massa superfisial cairan Lw* 6.9570601617

viskositas cairan μL 5.09E-04
densitas cairan ρL 985.3
tetapan gravitasi g 9.81
difusivitas cairan DL 4.63E-06
ukuran packing dp 0.051
laju alir massa superfisial gas Vw* 4.1706040521
viskositas gas μV 1.82E-05
difusivitas gas Dv 3.46E-06
tetapan gas universal R 0.08206
temperatur T 327
denitas gas ρV 8.336
laju alir molar superfisial Gm 0.1446325761
tekanan P 8.2588026316
laju alir molar superfisial gas Lm 0.3615814403
kosentrasi total Ct 54.738888889
 parameter simbol Nilai
aw/a 7.54E-01

effective interfacial area of packing per unit volume aw 76.859

koefisien transfer massa liquid kL 1.60E-02
koefisien transfer massa gas kG 4.84E-04
height of gas transfer unit HG 4.71E-01
height of liquid transfer unit HL 5.36E-03
height of overall gas phase transfer unit HOG 0.475018113
column height (tinggi kolom) Z 2.164258329
packing height to diameter ratio Z/D 1.9819215463
 1. DATA PENUGASAN PC

kg/jam volum (L) 1690.538900

NH3 Fraksi Mol 0.173675
ppb Molar 0.000103
mmHg/fraksi mol ppm 1.749552
o
C TEKANAN
kg/cm (gauge)
2
8.368 kg/cm2 (abs)
Metal Raschig Ring 836.8 kPa
0.9 8.2585739 atm (abs)
6282.6944 mmHg
2. PENENTUAN DATA FISIK

g/mol Laju Gas 520.677274 kmol/jam

STP (101.32 kPa dan 0 Celcius) Gases - Densities (engineeringtoolbox.com)

3. PENENTUAN PERBANDINGAN MOL

ALIRAN CAIRAN SOLVENT
0.1446325761385 kmol/s
0.0251
0.1195
kmol/s
kmol/s INPUT ALIRAN SOLV
0.1737
0.2102 Mol solut
0.0210 Mol larutan inert (air)
0.0206 Perbandingan mol solut (X2)

4. PEMBUATAN KURVA KESETIMBANGAN (HENRY)

X Y
0.0112 0.0210
0.0164 0.0310 Kurva Kese
0.0216 0.0409 0.2500
0.0267 0.0509
0.0318 0.0608
0.0368 0.0708 0.2000 f(x) = 2.00006248495485 x
0.0418 0.0808 R² = 0.99967011067618
0.0467 0.0907
0.0516 0.1007 0.1500
Y

0.1000
 0.2000 f(x) = 2.00006248495485 x
R² = 0.99967011067618

0.1500
0.0565 0.1106
0.0613 0.1206

Y
0.0661 0.1305 0.1000
0.0708 0.1405
0.0755 0.1504
0.0802 0.1604 0.0500
0.0848 0.1704
0.0894 0.1803
0.0939 0.1903 0.0000
0.0984 0.2002 0.0000 0.0200 0.0400

0.1029 0.2102

m (slope) = 2

5. PENENTUAN NUMBER OF TRANSFER UNIT (NTU)

0.8 0.85 0.9 0.95

4.5561595824977 4.99539647833346 5.5600496166 6.32314883

0.4392368958358 0.564653138238223 0.7630992156

N_OG=1/(1−((mG_m)/L_m ))
ln⁡[(1−(mG_m)/L_m ) y_1/y_2 +(mG_m)/L_m ]

𝑥_1=𝑚/𝑠𝑙𝑜𝑝𝑒 𝐺_𝑚/𝐿_𝑚
(𝑦_1−𝑦_2)
 6. Penentuan Diamter Kolom
Satuan keterangan tambahan
kg/kmol MrG=y1*(Mr Cl₂)+(1-y1)*(Mr udara)
kg/m 3
berdasarkan HYSYS
kg/m3 berdasarkan HYSYS
Pa.s berdasarkan HYSYS
Pa.s berdasarkan HYSYS (dekat dengan nilai milik air)
kmol/s Penugasan, ubah satuan
kg/s Penugasan, ubah satuan
kmol/s mGm/Lm ® Lm=mGm/(mGm/Lm)
kg/s ubah satuan, pake Mr air karena SOLUT SANGAT KECIL

Figure 11.44, (pressure drop 42 mm)

Figure 11.44, di flooding line
Eq 11.112, antara 50 - 90%
m-1 Table 11.2
mm Table 11.2
kg/m2s Eq 11.118
m 2
Vw*=Vw/A
m akar (4A/pi)
m ASME/ANSI B36.10M dengan 44 inch 1100 mm, XS ketebalan 12,7 mm
m2 berdasarkan diameter baru

%f lama *(Dlama/Dbaru)

7. Metode Cornell
Satuan Keterangan tambahan
2.6 untuk air
m3/kmol Tabel 8.6 Sinott
m2/s Persamaan 8.22 Sinott
Tabel 8.5 Sinott
Tabel 8.5 Sinott
m2/s Persamaan 8.21 Sinott
kg/m2s 5130.541 lb/hr.ft2
Miu/rho. Difusivitas
Miu/rho. Difusivitas
Figure 13.46 Wallas
Figure 13.45 Wallas
Dikoreksi terhadap air 20derajat, P operasi
Figure 13.46a Wallas
m Asumsi
m Eq 11.110 sinnott
m Eq 11.111 sinnott
m Eq 11.105
%
m Eq 11.99a

1.15633445E-07

8. METODE ONDA
Satuan Keterangan data koefisien wet area
m /m
2 3
Tabel 11.2 σc/σL
N/m Lw*/a.μL
N/m hysys (Lw*2.a)/(ρL2.g)
kg/m2.s (Lw*)2/(ρL.σL..a)
Pa.s data koefisien transfer liquid
kg/m3 μL/(ρL.DL)
m/s a.dp
m /s
2
ρL/μL.g
m D: 1m ; Dp: 2in =51mm Lw*/aw.μL
kg/m .s2
data koefisien transfer gas
Pa.s a.Dv/R.T
m /s
2
Vw*/a.μV
atm.m /kmol.K
3
μV/ρV.DV
K K5
kg/m 3

kmol/m2.s
atm
kmol/m2.s
kmol/m3
Satuan keterangan
eq 11.113

m2/m3 eq 11.113
eq 11.114
eq 11.115
eq 11.116
eq 11.117
eq 11.105
m eq 11.99a
LIRAN CAIRAN SOLVENT

ALIRAN SOLVENT
l solut 3.6E-02
an inert (air) 5.5E+04
n mol solut (X2) 6.6E-07

Kurva Kesetimbangan

= 2.00006248495485 x
= 0.99967011067618
 = 2.00006248495485 x
= 0.99967011067618

0.0200 0.0400 0.0600 0.0800 0.1000 0.1200

X
n

mm 23456.5111981

25.4190770141

paramete r nilai
Densitas air 20 1011
Viskositas air 20 0.00102
 Surface tension 2 0.07296
f1*f2*f3 0.8095241430699
f1 0.9683261471155
f2 0.8947721704589
f3 0.9343200712384

3.58032786885246
4.11959295629189

ta koefisien wet area keterangan

1.119068934646 eq 11.113
1.34E+02 eq 11.113
0.000518376991 eq 11.113
0.00718585484 eq 11.113
koefisien transfer liquid
0.111634826766 eq 11.114
5.202 eq 11.114
197286.0503565 eq 11.114
1.78E+02 eq 11.114
koefisien transfer gas 1092.4
1.32E-05 eq 11.115
2245.374795189 eq 11.115
0.630495823009 eq 11.115
5.23
0.00001981
 800 ppb
0.0008 0.0008
0.08

0.144633 520.6773
520.6773
0.350879 1263.163

1263.163
 packec section rating result
Section Starting Stage 1__Main Tower
Section Ending Stage 4__Main Tower
Column Diameter [m] 1.15356292785
Packed Height Per Stage [m] 0.875
Section Height [m] 3.5
Maximum % Capacity (Constant L/V) [%] 65.78
Maximum Capacity Factor [m/s] 4.14E-02
Section Pressure Drop [mbar] 24.2299704216
Average Pressure Drop / Height [mbar/m] 6.92284869188
Average Pressure Drop / Height (Frictional) [mbar/m] 6.08345907245
Maximum Stage Liquid Holdup [m3] 3.37E-02
Maximum Liquid Superficial Velocity [m 3/h-m2] 23.7298650503
Surface area [m /m ]
2 3
110
Void Fraction 0.95
1st Stichlmair Constant 40
2nd Stichlmair Constant 1
3rd Stichlmair Constant 6
Name solvent in @COL1 air in @COL1 air out @COL1 solvent out @COL1
Vapour 0.000 1.000 1.000 0.000
Temperature [C] 54.000 54.000 55.163 66.971
Pressure [kPa] 836.824 836.824 836.824 836.824
Molar Flow [kgmole/h] 1266.336 506.534 460.042 1312.828
Mass Flow [kg/h] 2.281.E+04 1.400.E+04 1.322.E+04 2.360.E+04
Std Ideal Liq Vol Flow [m3/h] 22.860 16.378 15.005 24.233
Molar Enthalpy [kJ/kgmole] -2.839.E+05 -4.251.E+03 -4.007.E+03 -2.741.E+05
Molar Entropy [kJ/kgmole-C] 60.917 111.837 105.208 65.663
Heat Flow [kJ/h] -3.596.E+08 -2.153.E+06 -1.843.E+06 -3.599.E+08