JURNAL KEGIATAN

PRAKTIKUM KIMIA DASAR

NAMA :

NIM :

KELOMPOK :

JUR./ FAK. :

LABORATORIUM KIMIA DASAR UPT MKU

UNIVERSITAS HASANUDDIN
 KEGIATAN 5
PERCOBAAN KECEPATAN REAKSI

Nama Praktikan : Nurul Aulia Pirdaus (G031231037)

Nama TemanKerja : 1. Alya Ayu Shalsabilla (G031231015)
2. Nurul Maghfirah (G031231004)
3. Kylarissa Piergiana (G031231010)
4. Prameshvira Dewantari (G031231008)
5. Rana Anindya Shahira (G031231018)
6. Nur Atiqah Salam (G031231052)
7. Sulis Sri Wirdani (G031231016)
8. Muhammad Dzaky Abdillah (G031231035)
Asisten dosen : Imega Eka Pertiwi (H031201094)
A. PENGAMATAN
1. Hasil Pengamatan
1.1 Pengaruh Konsentrasi Na2S2O3
Reaksi berlangsung pada suhu 29 ˚C
[Na2S2O3] (M) [H2SO4] (M) dt (s) 1/dt (s-1)
0,1 0.1 24 4,4642
0,08 0,1 40 0,025
0,06 0,1 57 0,0175
0,04 0,1 68 0,0147
0,02 0,1 117 0,0085
1.2 Pengaruh Konsentrasi H2SO4
Reaksi berlangsung pada suhu 32 ˚C

[H2SO4] (M) [Na2S2O3] (M) dt (s) 1/dt (s-1)

0,1 0,1 20,99 0,0476
0,08 0,1 19,96 0,0501
0,06 0,1 26,71 0,0374
0,04 0,1 29,79 0,0335
0,02 0,1 36,43 0,0274

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1.3 Pengaruh Suhu

[Na2S2O3] (M) [H2SO4] (M) Suhu (oC) Waktu (s)

0,1 0,1 80 5
0,1 0,1 32 20
0,1 0,1 21 35

Konsentrasi yang digunakan:

H2SO4 = Na2S2O3 =

2. Grafik

2.1 Pengaruh Konsentrasi Na2S2O3

No. [Na2S2O3] (M) v (M/s) Log [Na2S2O3] Log v Y regresi

1. 0,1 0,0020 -1 -2,6989 -0,3014
2. 0,08 0,001 -1,0969 -3 -0,3426
3. 0,06 0,0005 -1,2218 -3.3010 -0,3837
4. 0,04 0,00029 -1,3979 -3,5376 -0,4249
5. 0,02 0,00004 -1,6990 -3,3979 -0,4660

3
 Log Na2S2O3 vs Log V
0
-1 -1.0969 -1.2218 -1.3979 -1.699
-1

Log V
-2
-3
-4
-5
Log Na2S2O3

2.2 Pengaruh Konsentrasi H2SO4

No. [H2SO4] (M) v (M/s) Log [H2SO4] Log v Y regresi

1. 0,1 0,0023 -1 -2,6383 -0,9218
2. 0,08 0,0020 -1,0969 -2,6989 -0,9525
3. 0,06 0,0011 -1,2218 -2,9586 -0,9832
4. 0,04 0,0006 -1,3979 -3,2218 -1,0139
5. 0,02 0,0002 -1,6990 -3,6989 -1,0446

Log H2SO4 vs Log V

0
-1.8 -1.7 -1.6 -1.5 -1.4 -1.3 -1.2 -1.1 -1 -0.9
-0.5
-1
-1.5
Log v

-2
-2.5
-3
-3.5
-4
Log H2SO4

2.3 Pengaruh Suhu

Tabel 2.3 Pengaruh Suhu

No. v (M/s) T(oC) ln v 1/T Y regresi

4
 1. 0,01 80 -4,6052 0,0125 -5,7111

2. 0,0025 32 -5,9915 0,0312 -5,7282

3. 0,0014 21 -6,5713 0,0476 -5,7223

B. Reaksi
Na2S2O3 (aq) + H2SO4(aq) Na2SO4 + SO4 + S + H2O
C.Pembahasan

D. Kesimpulan

E. Sumber Acuan

Lampiran perhitungan

1. Pengenceran Na2S2O3
Untuk V1 = 5 mL

5
 V1M1= V2M2

5 mL × 0,1 M = 5 mL × M2

M2= 0,1 M

Untuk V1 = 4 mL

V1M1= V2M2

4 mL × 0,1 M = 5 mL ×M2

M2 = 0,08 M

Untuk V1 = 3 mL

V1M1= V2M2

3 mL × 0,1 M = 5 mL ×M2

M2 = 0,06 M

Untuk V1 = 2 mL

V1M1= V2M2

2 mL × 0,1 M = 5 mL ×M2

M2 = 0,04 M

Untuk V1 = 1 mL

V1M1= V2M2

1 mL × 0,1 M = 5 mL ×M2

M2 = 0,02 M

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2. Pengenceran H2SO4
Untuk V1 = 5 mL

V1M1= V2M2

5 mL × 0,1 M = 5 mL × M2

M2= 0,1 M

Untuk V1 = 4 mL

V1M1= V2M2

4 mL × 0,1 M = 5 mL ×M2

M2 = 0,08 M

Untuk V1 = 3 mL

V1M1= V2M2

3 mL × 0,1 M = 5 mL ×M2

M2 = 0,06 M

Untuk V1 = 2 mL

V1M1= V2M2

2 mL × 0,1 M = 5 mL ×M2

M2 = 0,04 M

Untuk V1 = 1 mL

V1M1= V2M2

7
 1 mL × 0,1 M = 5 mL ×M2

M2 = 0,02 M

3. Grafik Pengaruh Konsentrasi Na2S2O3

−d n [ Na2 S 2 O3 ]
Vn =
dt
a. [Na2S2O3] awal = 0,1 M
Vawal
[Na2S2O3] akhir = [Na2S2O3] ×
Vakhir
5 mL
= 0,1 M ×
10 mL
= 0,05 M
d1 = [Na2S2O3] akhir − [Na2S2O3] awal
= 0,05 M – 0,1 M
= − 0.05 M
−(−0 ,05)
V1 =
dt
−(−0 , 05 ) M
=
24 s
= 0,002 M/s

b. [Na2S2O3] awal = 0,08 M

V awal
[Na2S2O3] akhir = [Na2S2O3] ×
V akhir
5 mL
= 0,08 M ×
10 mL
= 0,04 M
d2 = [Na2S2O3] akhir − [Na2S2O3] awal
= 0,04 M – 0,08 M
= − 0.04 M

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 −(−0 ,04 )
V2 =
dt
−(−0 , 04 ) M
=
40 s
= 0,001 M/s

c. [Na2S2O3] awal = 0,06 M

V awal
[Na2S2O3] akhir = [Na2S2O3] ×
V akhir
5 mL
= 0,06 M ×
10 mL
= 0,03 M
d3 = [Na2S2O3] akhir − [Na2S2O3] awal
= 0,03 M – 0,06 M
= − 0.03 M
−(−0 ,03)
V3 =
dt
−(−0 , 03 ) M
=
57 s
= 0,0005 M/s

d. [Na2S2O3] awal = 0,04 M

V awal
[Na2S2O3] akhir = [Na2S2O3] ×
V akhir
5 mL
= 0,04 M ×
10 mL
= 0,02 M
d3 = [Na2S2O3] akhir − [Na2S2O3] awal
= 0,02 M – 0,04 M
= −¿0,02 M

9
 −(−0 ,02)
V3 =
dt
−(−0 , 02 ) M
=
68 s
= 0,00029 M/s

e. [Na2S2O3] awal = 0,02 M

V awal
[Na2S2O3] akhir = [Na2S2O3] ×
V akhir
5 mL
= 0,02 M ×
10 mL
= 0,01 M
d3 = [Na2S2O3] akhir − [Na2S2O3] awal
= 0,01 M – 0,02 M
= − 0.01 M
−(−0 ,01)
V3 =
dt
−(−0 , 01 ) M
=
117 s
= 0,0004 M/s
Perhitungan Y regresi
No. X (log [Na2S2O3]) Y (log V) X×Y X2
1 -1 -2,6989 2,6989 1
2 -1,0969 -3 3,2907 1,2028
3 -1,2218 -3,3010 4,0331 1,4927
4 -1,3979 -3,5376 4,9452 1,9541
5 -1,6990 -3,3979 5,7730 2,8866
∑ -6,4156 -15,9354 20,7409 8,5362
Y = ax+b

a = n¿¿
5 (20,7409 )−(−6,4156)(−15,9354)
=
5 ( 8,5362 ) −( 41,1599)

10
 1,4693
=
1,5211
= 0,9659

b = ¿¿
(−15,9354 ) ( 8,5362 )−(−6,4156)(20,7409)
=
5 ( 8,5362 )−( 41,1599 )
−2,9624
=
1,5211
= −¿ 1,9476

Y1 = ax1 + b
= 0,9659 (0,1) + (-1,9476)
= -1,8510
Y2 = ax2 + b
= 0,9659 (0,08) + (-1,9476)
= -1,8703
Y3 = ax3 + b
= 2,0574 (0,06) + (-0,5072)
= -1,8896
Y4 = ax4 + b
= 2,0574 (0,04) + (-0,5072)
= -0,4249
Y5 = ax5 + b
= 2,0574 (0,1) + (-0,5072)
= -0,4660

4. Grafik Pengaruh Konsentrasi H2SO4

a. [H2SO4] awal = 0,1 M
Vawal
[H2SO4] akhir = [H2SO4] x
Vakhir

11
 5 mL
= 0,1 M x
10 mL
= 0,05 M
d1 = [H2SO4] akhir-[H2SO4] awal
= 0,05 M – 0,1 M
= -0,05 M
−(−0 ,05)
v1=
dt
−(−0 ,05) M
=
20 , 99 s
= 0,0023 M/s
b. [H2SO4] awal = 0,08 M
Vawal
[H2SO4] akhir = [H2SO4] x
Vakhir
5 mL
= 0,08 M x
10 mL
= 0,04 M
d2 = [H2SO4] akhir-[H2SO4] awal
= 0,04 M – 0,08 M
= -0,04 M
−(−0 ,04 )
v2=
dt
−(−0 ,04 )M
=
19 , 96 s
= 0,0020 M/s
c. [H2SO4] awal = 0,06 M
Vawal
[H2SO4] akhir = [H2SO4] x
Vakhir
5 mL
= 0,06 M x
10 mL

12
 = 0,03 M
d3 = [H2SO4] akhir-[H2SO4] awal
= 0,03 M – 0,06 M
= -0,03 M
−(−0 ,03)
v3=
dt
−(−0 ,03) M
=
26 , 71 s
= 0,0011 M/s
d. [H2SO4] awal = 0,04 M
Vawal
[H2SO4] akhir = [H2SO4] x
Vakhir
5 mL
= 0,04 M x
10 mL
= 0,02 M
d4 = [H2SO4] akhir-[H2SO4] awal
= 0,02 M – 0,04 M
= -0,02 M
−(−0 ,02)
v4=
dt
−(−0 ,02) M
=
29 ,79 s
= 0,0006 M/s
e. [H2SO4] awal = 0,02 M
Vawal
[H2SO4] akhir = [H2SO4] x
Vakhir
5 mL
= 0,02 M x
10 mL
= 0,01 M
d5 = [H2SO4] akhir-[H2SO4] awal

13
 = 0,01 M – 0,02 M
= -0,01 M
−(−0 ,01)
v5=
dt
−(−0 ,01) M
=
36 , 43 s
= 0,0002 M/s
Perhitungan Y regresi

No. x ( log [H2SO4]) y (log v) x.y x2

1. -1 -2,6383 2,6383 1
2. -1,0969 -2,6989 2,9604 1,2032
3. -1,2218 -2,9586 3,6148 1,4928
4. -1,3979 -3,2218 4,5037 1,9541
5. -1,6990 -3,6989 6,2844 2,8866
Σ -6,4056 -15,2165 20.0016 8,5367
Y=ax+b
n ( Σ x . y ) −(Σ x)(Σ y)
a=
n ( Σ x2 ) −(Σ x)2
5 (20,0016 )−(−6,4056)(−15,2165)
=
5 ( 8,5367 ) −( 41,0317)
2,5371
=
1,6518
= 1,5359 M

( Σ y ) ( Σ x 2 ) −(Σ x) ( Σ x . y )
b=
n ( Σ x 2 )−(Σ x )2
(−15,2165 ) ( 8,5367 )−(−6,4056) ( 20,0016 )
=
5 ( 8,5367 )−(41,0317)
−1,7764
=
1,6518
= 1,0754 M
Y1 = ax1+b

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 = 1,5359 (0,1) + (-1,0754)
= –0,9218

Y2 = ax2+b
= 1,5359 (0,08) + (-1,0754)
= –0,9525

Y3 = ax3+b
= 1,5359 (0,06) + (-1,0754)
= –0,9832

Y4 = ax4+b
= 1,5359 (0,04) + (-1,0754)
= –1,0139

Y5 = ax5+b
= 1,5359 (0,02) + (-1,0754)
= –1,0446

5. Grafik Pengaruh Suhu

a. [H2SO
Perhitungan Y regresi

No. x ( 1/T) y (In v) x.y x2

1. 0,0125 -4,6052 -0,0576 0,0002

2. 0,0312 -5,9915 -0,1869 0,0973

3. 0,0476 -6,5713 -0,3128 0,0023

Σ 0,0913 -17,168 -0,5573 0,0998

Y = ax + b

15