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SMK PUTRAJAYA PRESINT 16(1)

UJIAN 1
KIMIA TINGKATAN 5
Nama : ______________________________________________________ Ting : _________

ANSWER ALL THE QUESTIONS.


JAWAB SEMUA SOALAN.

1. In which of the chemical reactions can the rate of reaction be determined by measuring
the change in the gas volume?
Antara tindak balas yang berikut, yang manakah mempunyai kadar tindak balas yang
boleh ditentukan dengan mengukur perubahan isipadu gas?

A. Acidified potassium dichromate(VI) solution with iron(II) sulphate solution


Larutan kalium dikromat(VI) berasid dengan larutan ferum(II) sulfat
B. Potassium hydroxide solution with dilute sulphuric acid
Larutan kalium hidroksida dengan asid sulfurik cair
C. Lead(II) nitrate solution with sodium iodide solution
Plumbum(II) nitrat dengan larutan kalium iodida
D. Magnesium ribbon with dilute nitric acid
Pita magnesium dengan asid nitrik

2. 10.0 g of iron powder reacts with dilute sulphuric acid. After 40 seconds, 3.50 g of iron
remains unreacted. What is the average rate of reaction?
10.0 g serbuk besi bertindak balas dengan asid sulfurik cair. Selepas 40 saat, 3.50 g
besi tertinggal tanpa bertindak balas. Berapakah kadar purata bagi tindak balas itu?

A. 0.0029 g s-1 C. 0. 1625 g s-1


B. 0.0875 g s-1 D. 0.2500 g s-1

3. Which of the following is not a characteristic of a catalyst?


Antara yang berikut, yang manakah tidak benar tentang sifat mangkin?

A. Catalyst increases the amount of products formed


Mangkin menambah kuantiti hasil tindak balas yang terbentuk
B. Catalyst alters the rate of chemical reaction
Mangkin mengubah kadar suatu tindak balas
C. The mass of catalyst used remains unchanged at the end of reaction
Jisim mangkin yang digunakan tidak berubah pada akhir tindak balas
D. The total surface area of a catalyst affects the rate of reaction
Jumlah luas permukaan suatu mangkin mempengaruhi kadar tindak balas
4. Diagram 1 shows a graph for the volume of hydrogen gas against time for a reaction
between zinc and excess hydrochloric acid.
Rajah 1 menunjukkan sebuah graf bagi isipadu gas hidrogen melawan masa bagi suatu
tindak balas antara zink dengan asid hidroklorik berlebihan.

Diagram 1 / Rajah 1

What is the average rate of reaction?


Berapakah kadar purata bagi tindak balas itu?

A. 2.0 cm3 s-1 C. 4.0 cm3 s-1


B. 2.5 cm3 s-1 D. 5.0 cm3 s-1

5. Diagram 2 shows a graph to study the effect of total surface area on the rate of reaction.
Rajah 2 menunjukkan suatu graf bagi mengkaji kesan jumlah luas permukaan ke atas
kadar tindak balas.

Diagram 2 / Rajah 2
What is represented by gradient of y/x?
Apakah yang diwakili oleh kecerunan y/x?

A. Average rate of reaction in the first 4 minutes


Kadar tindak balas purata dalam 4 minit pertama
B. Average rate of reaction in the 4th minute
Kadar tindak balas purata pada minit ke-4
C. Overall average rate of reaction
Kadar tindak balas purata keseluruhan
D. Rate of reaction at the 4th minute
Kadar tindak balas pada minit ke-4

6. Table 1 shows the result of an experiment.


Jadual 1 menunjukkan keputusan satu eksperimen.

Time (s) 0 30 60 90 120 150


Masa (s)
Volume of gas (cm3) 0.00 8.50 15.00 19.00 22.00 25.00
Isipadu gas (cm3)
Table 1/ Jadual 1

What is the average rate of reaction in the second minute?


Berapakah kadar tindak balas purata dalam minit kedua?

A. 0.06 cm3 s-1 C. 0.37 cm3 s-1


B. 0.12 cm3 s-1 D. 0.07 cm3 s-1

7. When excess marble chips are added to dilute hydrochloric acid, the reaction gradually
becomes slower and finally stops. Which of the following statements best explains why
this happens?
Apabila serpihan marmar berlebihan ditambahkan kepada asid hidroklorik cair ,
tindak balas menjadi semakin perlahan dan akhirnya berhenti. Antara pernyataan
berikut, yang manakah paling baik menerangkan sebab keadaan ini berlaku?

A. The total surface area of the marble chips gradually increases.


Jumlah luas permukaan serpihan marmar bertambah secara beransur-ansur
B. The concentration of dilute hydrochloric acid gradually decreases.
Kepekatan asid hidroklorik cair berkurangan secara beransur-ansur
C. The temperature of dilute hydrochloric acid decreases
Suhu asid hidroklorik cair berkurangan
D. An insoluble layer of calcium chloride is formed on the surface of the marble chips
Satu lapisan kalsium klorida yang tak larut terbentuk pada permukaan serpihan
marmar
8. Diagram 3 shows the energy profile for the reaction between Sulphur dioxide and
oxygen to produce sulphur trioxide.
Rajah 3 menunjukkan profil tenaga bagi tindak balas antara sulfur dioksida dan
oksigen untuk menghasilkan sulfur trioksida.

Diagram 3 / Rajah 3

Which change must be done to get curve Y from curve X?


Apakah perubahan yang mesti dilakukan untuk mendapatkan lengkung Y daripada
lengkung X?

A. The mixture of sulphur dioxide and oxygen is heated to 500oC.


Campuran sulfur dioksida dan oksigen dipanaskan ke suhu 500oC.
B. The mixture of sulphur dioxide and oxygen is compressed to a pressure of 5 atm.
Campuran sulfur dioksida dan oksigen dimampatkan ke tekanan 5 atm.
C. The mixture of sulphur dioxide and oxygen is passed over vanadium(V) oxide
Campuran sulfur dioksida dan oksigen dialirkan melalui vanadium(V) oksida
D. Sulphur trioxide gas is constantly removed from the mixture
Gas sulfur trioksida sentiasa disingkirkan daripada campuran itu

9. Table 2 shows the total volume of oxygen, collected in the decomposition of hydrogen
peroxide catalyzed by manganese(IV) oxide.
Jadual 2 menunjukkan jumlah isipadu oksigen yang dikumpul dalam penguraian
hidrogen peroksida yang dimangkinkan oleh mangan(IV) oksida.

Time (min) 0 1 2 3 4 5
Masa (min)
Volume of gas (cm3) 0.00 11.20 23.60 29.70 31.40 31.40
Isipadu gas (cm3)
Table 2/ Jadual 2
What is the average rate of reaction?
Berapakah kadar tindak balas purata?

A. 6.28 cm3 min-1 C. 9.90 cm3 min-1


B. 7.85 cm3 min-1 D. 11.80 cm3 min-1

10. Table 3 shows the volume of hydrogen gas collected at a regular time intervals for the
reaction between zinc powder with hydrochloric acid.
Jadual 3 menunjukkan isipadu gas hidrogen yang dikumpul pada sela masa tertentu
bagi tindak balas antara serbuk zink dengan asid hidroklorik.

Time (min) 0 0.5 1.0 1.5 2.0 2.5


Masa (min)
Volume of gas (cm3) 0.00 7.50 14.80 20.40 25.00 30.50
Isipadu gas (cm3)
Table 3/ Jadual 3

What is the average rate of reaction between the first minute and the second minute?
Apakah kadar tindak balas purata antara minit pertama dengan minit kedua?

A. 7.50 cm3 min-1 C. 12.50 cm3 min-1


B. 10.20 cm3 min-1 D. 14.80 cm3 min-1

11. If you want to cook 100 potatoes within a short time, which is the most suitable method?
Sekiranya anda ingin memasak 100 biji kentang dalam masa yang singkat, apakah
langkah yang paling sesuai dilakukan?

A. Boil the potatoes in a pan


Merebus kentang dalam kuali leper
B. Boil the potatoes in a pressure cooker
Merebus kentang dalam periuk tekanan
C. Steam the potatoes in a steamer
Mengukus kentang dalam pengukus
D. Fry the potatoes in a wok
Menggoreng kentang dalam kuali

12. Which statement is correct about propene and propane?


Pernyataan yang manakah adalah betul tentang propena dan propana?

A. Propane decolourises the purple colour of acidified potassium manganite(VII)


solution but propene does not.
Propana menyahwarnakan warna ungu larutan kalium manganat(VII) berasid
tetapi propena tidak.
B. The percentage of carbon by mass in propane molecule is higher.
Peratus karbon mengikut jisim bagi propana lebih tinggi.
C. Propene decolourises the brown colour of bromine water but propane does not.
Propena menyahwarnakan warna perang air bromin tetapi propana tidak.
D. Propene is soluble in water but propane does not.
Propena larut di dalam air tetapi propana tidak.

13. Which compound is unsaturated hydrocarbon?


Sebatian manakah ialah hidrokarbon tak tepu?

A. CH3CH2CH2CH2CH3 C. CH3CH2CHCHCH3
B. CH3CH2CH2CH3 D. CH3CH2CH2CH2CH2CH2CH3

14. Which of the following are saturated hydrocarbon?


Antara berikut yang manakah merupakah hidrokarbon tepu?

A. I and/dan II B. I and/dan III C. II and/dan IV D. III and/dan IV

15. Cyclohexane, C6H12 is an organic solvent. Which substance is soluble in cyclohexane?


Sikloheksana, C6H12 merupakan suatu pelarut organik. Bahan manakah yang larut
dalam sikloheksana?

A. Limestone C. Sodium sulphate


Batu kapur Natrium sulfat
B. Naphtalene D. Aluminium oxide
Naftalena Aluminium oksida
16. Which statement is correct about alkanes?
Pernyataan manakah yang betul tentang alkana?

A. Undergo polymerization reaction


Mengalami tindak balas pempolimeran
B. Undergo hydrogenation reaction
Mengalami tindak balas penghidrogenan
C. Undergo substitution reaction
Mengalami tindak balas penukargantian
D. Undergo hydration reaction
Mengalami tindak balas penghidratan

17. Which observation is correct when hexane is burnt in air?


Pemerhatian manakah yang betul apabila heksena dibakar dalam udara?

A. No flame
Tiada nyalaan
B. Blue flame produced
Nyalaan biru terhasil
C. Yellow flame and little soot produced
Nyalaan kuning dan sedikit jelaga terhasil
D. Yellow flame and lots soot produced
Nyalaan kuning dan banyak jelaga terhasil

18. Ethene reacts with steam at the temperature of 300oC to produce compound M.
Concentrated phosphoric acid is used as a catalyst in this reaction. What is M?
Etena bertindak balas dengan stim pada suhu 300oC untuk menghasilkan sebatian M.
Asid fosforik pekat digunakan sebagai mangkin dalam tindak balas ini. Apakah M?

A. C2H4 B. C2H6 C. C2H5OH D. C2H5COOH

19. What is the product formed when hydrogen and propene are passed over a nickel
catalyst at temperature 180oC?
Apakah hasil yang terbentuk apabila hidrogen dan propena dilalukan ke atas mangkin
nikel pada suhu 180oC?

A. Propane
Propana
B. Propanol
Propanol
C. Propanoic acid
Asid propanoik
D. Propyl propanoate
Propil propanoat
20. What is the product formed when ethane is burned in air?
Apakah hasil yang terbentuk apabila etena dibakar dalam udara?

A. Ethane and water C. Carbon dioxide and water


Etana dan air Karbon dioksida dan air
B. Carbon and hydrogen D. Carbon dioxide and hydrogen
Karbon dan hidrogen Karbon dioksida dan hidrogen

ANSWERS SPACE
RUANG JAWAPAN
[20 marks / markah]

1. D 6. B 11. B 16. C

2. C 7. B 12. C 17. D

3. A 8. C 13. C 18. C

4. C 9. B 14. B 19. A

5. C 10. B 15. B 20. C

21. Two sets of experiments are carried out to investigate one of the factors that affects the
rate of reaction between 100 cm3 of 0.5 mol dm-3 nitric acid and 2 g of zinc.
Dua set eksperimen telah dijalankan untuk menyiasat salah satu faktor yang
mempengaruhi kadar tindak balas antara 100 cm3 asid nitrik 0.5 mol dm-3 dengan 2 g
zink.

Diagram 4 shows the curves of the graph of volume of gas against time obtained from
two sets of experiments, Set I and Set II.
Rajah 4 menunjukkan lengkung graf isipadu gas melawan masa yang diperoleh
daripada dua set eksperimen itu, Set I dan Set II.

Diagram 4 / Rajah 4
(a) State the meaning of rate of reaction.
Nyatakan maksud kadar tindak balas.

Rate of reaction is the change in volume of gas collected during a reaction per
unit time (second)
[1 mark / markah]

(b) State the name of the gas released in this experiment.


Nyatakan nama gas yang terbebas dalam eksperimen ini.

Hydrogen gas
[1 mark / markah]

(c) State one observable change in this experiment that can be used to determine the rate
of reaction.
Nyatakan satu perubahan yang dapat diperhatikan dalam eksperimen ini yang boleh
digunakan untuk menentukan kadar tindak balas.

The volume of hydrogen gas // mass of zinc


[1 mark / markah]

(d) By referring to Diagram 4, identify one factor that affects the rate of reaction in the
experiment.
Dengan merujuk Rajah 4, kenal pasti satu faktor yang mempengaruhi kadar tindak
balas dalam eksperimen ini.

Total surface area of zinc // temperature // the presence of catalyst


[1 mark / markah]

(e) Diagram 5 shows two situations of grilling 500 g of meat.


Rajah 5 menunjukkan dua situasi memanggang 500 g daging.

Diagram 5 / Rajah 5
In which situation will the meat cook faster? Explain.
Dalam situasi manakah daging akan masak dengan lebih cepat? Terangkan.

P1 : Situation A
P2 : The size of the meat in Situation A is smaller // Because the meat in Situation
A has a higher total surface area exposed to heat compared to Situation B.
P3 : More heat energy is absorbed.
[3 marks / markah]

22. In an experiment to investigate the rate of reaction, 50.0 cm3 of 0.2 mol dm-3 sodium
thiosulphate solution and 5.0 cm3 of 1.0 mol dm-3 of sulphuric acid, are used. The
sulphur formed can be used to measure the rate of reaction.
Dalam satu eksperimen untuk mengkaji kadar tindak balas, 50.0 cm3 larutan natrium
tiosulfat 0.2 mol dm-3 dan 5.0 cm3 asid sulfurik 1.0 mol dm-3, digunakan. Sulfur yang
terbentuk boleh digunakan untuk mengukur kadar tindak balas itu.

The equation for the reaction is given below.


Persamaan tindak balas itu diberi di bawah.

Na2S2O3 + H2SO4 à Na2SO4 + SO2 + S + H2O

(a) What is the colour of sulphur?


Apakah warna sulfur?

Yellow
[1 mark / markah]

(b) Calculate the number of moles of sodium thiosulphate in the solution.


Hitung bilangan mol bagi natrium tiosulfat dalam larutan itu.

n = MV /1000
= 0.01 mol

[1 mark / markah]

(c) Calculate the number of moles of sulphuric acid.


Hitung bilangan mol bagi asid sulfurik.

n = MV /1000
= 0.005 mol

[1 mark / markah]
(d) Based on the answers in (b) and (c), name the reactant which determines the
quantity of sulphur formed at the end of the reaction.
Berdasarkan jawapan di (b) dan (c), namakan bahan tindak balas yang
menentukan kuantiti sulfur yang terbentuk pada akhir tindak balas itu.

Sulphuric acid
[1 mark / markah]

(e) State three factors that can affect the rate of reaction in this experiment.
Nyatakan tiga faktor yang boleh mempengaruhi kadar tindak balas itu dalam
eksperimen ini.

1. Temperature

2. Catalyst

3. Concentration
[3 marks / markah]

(f) Using the Collision Theory, explain how any one of the factors in (e) increases the
rate of reaction.
Menggunakan Teori Perlanggaran, terangkan bagaimana mana-mana satu
daripada faktor di (e) meningkatkan kadar tindak balas itu.

When the concentration of sodium thiosulphate solution is increases, the


number of thiosulphate ions per unit volume also increases. The frequency of
collision between thiosulphate ion and hydrogen ion increases. Hence, the
frequency of effective collision also increases.
[2 marks / markah]

23. Table 4 shows the molecular formula and boiling points for three compounds, which
are members of a homologous series.
Jadual 4 menunjukkan formula molekul dan takat didih bagi bagi tiga sebatian, ahli
suatu siri homolog.

Compound Molecular formula Boiling point (oC)


Sebatian Formula molekul Takat didih (oC)
P C2H4 -103
Q C3H6 -48
R C4H8 -6
Table 4/ Jadual 4
(a) Name the homologous series for these compounds.
Namakan siri homolog bagi sebatian-sebatian ini.

Alkene
[1 mark / markah]

(b) Write the general formula for this homologous series.


Tulis formula am bagi siri homolog ini.

CnH2n
[1 mark / markah]

(c) Explain why the boiling point for the members of this homologous series increases
when the number of carbon atoms per molecule increases.
Jelaskan mengapa takat didih bagi ahli-ahli dalam siri homolog ini meningkat
apabila bilangan atom karbon per molekul bertambah.

As the number of carbon atoms in a molecule increases, the molecular size of


alkene increases, the Van der Waals forces between molecules (intermolecular
forces) stronger/increases, more heat energy is needed to overcome this forces,
hence, boiling point increases.
[3 marks / markah]

(d) Write the chemical equation when compound P react with the steam in the presence
of phosphoric acid at the temperature of 300oC and 60 atm pressure.
Tulis persamaan kimia apabila sebatian P bertindak balas dengan stim dengan
kehadiran asid fosforik pada suhu 300oC dan tekanan 60 atm.

C2H4 + H2O ----à C2H5OH

[2 marks / markah]

(e) Compound P undergoes polymerization. The structural formula for compound P is


given below.
Sebatian P menjalani proses pempolimeran. Formula struktur bagi sebatian P
diberikan di bawah.
Write the equation for the polymerization of compound P.
Tulis persamaan bagi proses pempolimeran sebatian P.

[2 marks / markah]

(f) Draw the structural formula for Q.


Lukis formula struktur bagi Q.

[1 mark / markah]

24. Diagram 6 shows alkene P, C4H8 undergoes a reaction to form compound Q.


Rajah 6 menunjukkan alkena P, C4H8 melalui satu tindak balas bagi membentuk
sebatian Q.

Diagram 6 / Rajah 6
(a) State the name for alkene P, C4H8.
Nyatakan nama bagi alkena P, C4H8.

Butene
[1 mark / markah]

(b) State the name of compound Q.


Nyatakan nama bagi sebatian Q.

Butanol
[1 mark / markah]

(c) Write the balanced chemical equation for the conversion of alkene P to compound
Q.
Tulis persamaan kimia seimbang bagi penukaran alkena P kepada sebatian Q.

[2 marks / markah]

END OF QUESTIONS
KERTAS SOALAN TAMAT

Disediakan oleh,

…………………………………………..
(CIKGU SH. FATIMATUL ZAHRAH BINTI SYED YUSOF)
Penyelaras Kimia
SMK Putrajaya Presint 16(1)

Disemak dan disahkan oleh,

……………………………………………….
(CIKGU NIK AIDA BINTI NIK YUSUF)
GKMP Sains dan Matematik,
SMK Putrajaya Presint 16(1)

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