F7= H3PO4 2M

F3 = Ca(OH)2

F9 = CaHPO4.2H2O
REAKTOR

Basis Kg/jam = 100

KONVERSI 95% neraca massa mixer

IN OUT
KOMPONEN
KOMPONEN MR F5 F6 F7
H20 18 H20 15 71.51531 86.51531
H3PO4 98 H3PO4 85 85
Ca(OH)2 74 TOTAL 171.515305465414 171.5153
CaHPO4.2H2O 172

H3PO4 + Ca(OH)2 CaHPO4.2H2O

m 0.86734693878 0.867347
r 0.82397959184 0.82398 0.823979591836735
s 0.04336734694 0.043367 0.823979591836735

IN OUT
KOMPONEN
F3 F7 F9
Ca(OH)2 64.18367 3.209184
H3PO4 85 4.25
CaHPO4.2H2O 141.7245
H2O 86.51531 86.51531
TOTAL 235.698978934802 235.699
 PEMBUATAN H3PO4 2M
F7= H3PO4 2M H3PO4 = 85%
M = Massa jenis x 10 x %/BM
M= 14.83163
F9 = CaHPO4.2H2OM1 X V1 = M2 X V2
14.83163 X V1 = 2 X 100
V1 = 13.48469 L

kmol/jam
kmol/jam
kmol/jam
REAKTOR

Reaktor yang digunakan adalah reaktor tangki berpengaduk Mereaksikan soda ash dengan asam phosphate membentuk disod
Kondisi operasi : * Tekanan operasi = 1 atm (tekanan atmosfer)
* Suhu operasi = 35oC
* Waktu tinggal = 60 menit

F3 = Ca(OH)2

REAKTOR

H3PO4 + Ca(OH)2
Tref 298 K m 867.34693878 867.346939
Tin 303 K r 823.97959184 823.979592
Tout 308 K s 43.367346939 43.3673469

KOMPONEN MR mol/jam A B C D
H20 18 4806.406 1.83E+01 4.72E-01 -1.34E-03 1.31E-06
H3PO4 98 867.3469 0.7024
CaHPO4.2H2O 172 823.9796
Ca(OH)2 74 867.3469 19.07 10080

Cp(g T°K) = A + BT + CT2 + DT3 [ J/mol K ]

NE masuk NE keluar
komponen ∫Cp dT
(kkal/kmo ∆H masuk ∫Cp dT ∆H keluar
l) (kkal/jam) (kkal/kmol) (kkal/jam)
H2O 1.96E+02 9.44E+05 3.84E+02 1.85E+06
H3PO4 3.51E+00 3.05E+03 7.02E+00 6.09E+03
Ca(OH)2 1.51E+07 1.31E+10 3.05E+07 2.65E+10
Total 946854.6 1852966.8197
 Panas Reaksi

Panas reaksi pada suhu 85C (358,15 K) :

ΔHR,358,15K = ΔHR,Tref + (ΔHProduk - ΔHReaktan)
ΔHReaktan = Entalpi bahan masuk
ΔHProduk = Entalpi bahan keluar
ΔHR,Tref = Panas reaksi pada suhu reference

ΔHR,298,15K =

Data Hf komponen

komponen Hf
(kkal/mol)
Ca(OH)2 -235.8
H3PO4 -309.32
CaHPO4.2H2O -574.46
H2O -68.32

ΔHR,298,15K =
-80469.85+ Eksoterm
ΔHR,358,15K = ΔHR,Tref (ΔHProduk - ΔHReaktan)

825642.4

∆H masuk + ∆H reaksi = ∆H keluar + Qserap

946854.621139 + 825642.4 = 1852966.8197 + Qserap
1772497 = 1852966.8197 + Qserap
Qserap = 80469.846939

∆H Masuk ∆H Keluar
Komponen (kkal/jam) (kkal/jam)

F3 F7 F9
H2O 9.44E+05 1.85E+06
H3PO4 3.05E+03 6.09E+03
Ca(OH)2 1.31E+10 2.65E+10
CaHPO4.2H2O
ΔHReaksi 825642.351624305
Q serap 80469.84693878
Total 13137998055.6462 26492955982.585
m phosphate membentuk disodium phosphate.

F7 = H3PO4

OR F9 = CaHPO4.2H2O

CaHPO4.2H2O
mol/jam
823.979591836735 mol/jam
823.979591836735 mol/jam