Tugas Kelompok ke-4

(Minggu 9, Sesi 13)

Chemical Energy and Chemical Kinetics

Gunakan angka penting dan dibulatkan sampai 3 angka decimal di belakang koma

1. Diketahui :
ΔHf° C2H5OH(l) = -277,69 kJ/mol

ΔHf° CO2(g) = -393,51 kJ/mol

ΔHf° O2(g) = 0

ΔHf° H2O(l) = -285,83 kJ/mol

a. Tentukan ΔH reaksi pembakaran C2H5OH sesuai reaksi:

C2H5OH (l) + 3 O2(g) → 2 CO2(g) + 3 H2O(l)

b. Tentukan jumlah kalor yang dibebaskan pada pembakaran 11,5 gram etanol
(C2H5OH) (Ar C = 12, O = 16, dan H = 1) !

2. Diketahui :

C(s) + O2(g) → CO2(g) ΔH = –94 kJ (reaksi 1)

2 H2(g) + O2(g) → 2 H2O(g) ΔH = –136 kJ (reaksi 2)

3 C(s) + 4 H2(g) → C3H8(g) ΔH = –24 kJ (reaksi 3)

C3H8(g) + 5 O2(g) → 3 CO2(g) + 4 H2O(g)

Tentukan ΔH pada Persamaan reaksi tersebut !

SCIE6057 – Chemistry and Biology

3. Pada suhu 273°C gas bromine dapat bereaksi dengan gas nitrogen monoksida menurut
persamaan reaksi : 2NO (g) + Br2 (g)  2NOBr (g). Berdasarkan reaksi tersebut di
peroleh data sebagai berikut.

Konsentrasi awal Laju reaksi

Percobaan
NO(mol/L) Br2(mol/L) (M/detik)
1 0,1 0,05 6

2 0,1 0,1 12

3 0.2 0,1 24

laju reaksi bila konsentrasi gas NO= 0,01M dan gas Br 2 = 0,03M adalah ?

4. Berikut di berikan data percobaan laju reaksi :

Q (g) + 2T (g)  T2Q (g) pada beberapa kodisi

Percobaan [Q](M) [T](M) V (M/detik)

1 0,1 0,1 0,0125

2 0,2 0,1 0,05

3 0,1 0,2 0,1

jika [Q] dan [T] masing-masing diubah menjadi 0,5M maka laju reaksi (v) pada saat itu
ada0.lah?

SCIE6057 – Chemistry and Biology

1. 𝛥𝐻f° 𝐶2 𝐻5 𝑂𝐻(𝑙) = −277.69 kJ/mol

𝛥𝐻f° CO2 (𝑔) = −393.51 kJ/mol

𝛥𝐻f° 𝑂2 = 0 kJ/mol

ΔHf° H2O(l) = -285,83 kJ/mol

a. 𝛥𝐻𝑟𝑒𝑎𝑘𝑠𝑖 𝐶2 𝐻5 𝑂𝐻 =?

𝐶2 𝐻5 𝑂𝐻(𝑙) + 3𝑂2 (𝑔) → 2 𝐶𝑂2 (𝑔) + 3 𝐻2 𝑂(𝑙)

𝛥𝐻𝑟𝑒𝑎𝑘𝑠𝑖 = 𝛥𝐻𝑝𝑟𝑜𝑑𝑢𝑘 − 𝛥𝐻𝑟𝑒𝑎𝑘𝑡𝑎𝑛

𝛥𝐻𝑟𝑒𝑎𝑘𝑠𝑖 = (2 × 𝛥𝐻f° CO2 (𝑔) + 3 × 𝛥𝐻f° 𝐻2 𝑂(𝑙) ) − (𝛥𝐻f° 𝐶2 𝐻5 𝑂𝐻(𝑙) + 3 × 𝛥𝐻f° 𝑂2 )

𝛥𝐻𝑟𝑒𝑎𝑘𝑠𝑖 = (2 × (−393.51) + 3 × (−285,83)) − (−277.69 + 3 × 0)

𝛥𝐻𝑟𝑒𝑎𝑘𝑠𝑖 = (−787.02 + −857.49) − (−277.69 + 0)

𝛥𝐻𝑟𝑒𝑎𝑘𝑠𝑖 = −787.02 − 857.49 + 277.69

𝛥𝐻𝑟𝑒𝑎𝑘𝑠𝑖 = −1366.82 𝑘𝐽/𝑚𝑜𝑙

b. 𝑀𝑎𝑠𝑠𝑎 𝐶2 𝐻5 𝑂𝐻 = 11.5gram
𝐴𝑟 𝐶 = 12, 𝐴𝑟 𝑂 = 16 𝐴𝑟 𝐻 = 1
𝛥𝐻 = ?
𝑀𝑟 𝐶2 𝐻5 𝑂𝐻 = 𝐴𝑟 𝐶 × 2 + 𝐴𝑟 𝐻 × 6 + 𝐴𝑟 𝑂
𝑀𝑟 𝐶2 𝐻5 𝑂𝐻 = 12 × 2 + 6 × 6 + 16
𝑀𝑟 𝐶2 𝐻5 𝑂𝐻 = 46 𝑔𝑟/𝑚𝑜𝑙

𝑀𝑎𝑠𝑠𝑎 𝐶2 𝐻5 𝑂𝐻
𝑛 𝐶2 𝐻5 𝑂𝐻 =
𝑀𝑟 𝐶2 𝐻5 𝑂𝐻
11.5 𝑔𝑟
𝑛 𝐶2 𝐻5 𝑂𝐻 =
46 𝑔𝑟/𝑚𝑜𝑙
𝑛 𝐶2 𝐻5 𝑂𝐻 = 0.25 𝑚𝑜𝑙

𝛥𝐻 = 𝛥𝐻𝐶2 𝐻5 𝑂𝐻 × 𝑛𝐶2 𝐻5 𝑂𝐻

𝛥𝐻 = −1366.82 𝑘𝐽/𝑚𝑜𝑙 × 0.25 𝑚𝑜𝑙

𝛥𝐻 = −341.705 𝑘𝐽

SCIE6057 – Chemistry and Biology

2. 𝐶(𝑠) + 𝑂2 (𝑔) → 𝐶𝑂2 (𝑔) 𝛥𝐻 = −94 kJ

2𝐻2 (𝑔) + 𝑂2 (𝑔) → 2𝐻2 𝑂 (𝑔) 𝛥𝐻 = −136 kJ

3𝐶(𝑠) + 4𝐻2 (𝑔) → 𝐶3 𝐻8 (𝑔) 𝛥𝐻 = −24 kJ

𝐶3 𝐻8 (𝑔) + 5𝑂2 (𝑔) → 3𝐶𝑂2 (𝑔) + 4𝐻2 𝑂 (𝑔) 𝛥𝐻 =?

𝐶(𝑠) + 𝑂2 (𝑔) → 𝐶𝑂2 (𝑔) 𝛥𝐻 = −94 kJ × 3

2𝐻2 (𝑔) + 𝑂2 (𝑔) → 2𝐻2 𝑂 (𝑔) 𝛥𝐻 = −136 kJ × 2
3𝐶(𝑠) + 4𝐻2 (𝑔) → 𝐶3 𝐻8 (𝑔) 𝛥𝐻 = −24 kJ 𝑑𝑖𝑏𝑎𝑙𝑖𝑘

3 𝐶(𝑠) + 3 𝑂2 (𝑔) → 3𝐶𝑂2 (𝑔) 𝛥𝐻 = −282 kJ

4𝐻2 (𝑔) + 2𝑂2 (𝑔) → 4𝐻2 𝑂 (𝑔) 𝛥𝐻 = −272 kJ
𝐶3 𝐻8 (𝑔) → 3𝐶(𝑠) + 4𝐻2 (𝑔) 𝛥𝐻 = +24 kJ
+
𝐶3 𝐻8 (𝑔) + 5𝑂2 (𝑔) → 3𝐶𝑂2 (𝑔) + 4𝐻2 𝑂 (𝑔) 𝛥𝐻 = −530kJ

3. 2𝑁𝑂(𝑔) + 𝐵𝑟 (𝑔) → 2𝑁𝑂𝐵𝑟(𝑔)

[𝑁𝑂] = 0.01M
[𝐵𝑟] = 0.03M
𝑣 =?

Percobaan Konsentrasi awal Laju reaksi

NO(mol/L) Br2(mol/L) (M/detik)
1 0,1 0,05 6

2 0,1 0,1 12

3 0.2 0,1 24

Orde 𝑁𝑂(𝑔) ?
Percobaan Konsentrasi awal Laju reaksi
NO(mol/L) Br2(mol/L) (M/detik)
2 0,1 0,1 12

3 0.2 0,1 24

SCIE6057 – Chemistry and Biology

𝑣2 𝑘[𝑁𝑂]𝑎 [𝐵𝑟]𝑏
=
𝑣3 𝑘[𝑁𝑂]𝑎 [𝐵𝑟]𝑏
12 [0.1]𝑎 [0.1]𝑏
=
24 [0.2]𝑎 [0.1]𝑏
12 [0.1]𝑎
=
24 [0.2]𝑎
1 [1]𝑎
=
2 [2]𝑎
𝑎=1

Orde 𝐵𝑟(𝑔) ?
Percobaan Konsentrasi awal Laju reaksi
NO(mol/L) Br2(mol/L) (M/detik)
1 0,1 0,05 6

2 0,1 0,1 12

𝑣1 𝑘[𝑁𝑂]𝑎 [𝐵𝑟]𝑏
=
𝑣2 𝑘[𝑁𝑂]𝑎 [𝐵𝑟]𝑏
6 [0.1]𝑎 [0.05]𝑏
=
12 [0.1]𝑎 [0.1]𝑏
6 [0.05]𝑏
=
12 [0.1]𝑏
1 1𝑏
=
2 2𝑏
𝑏=1

𝑘 =?
𝑣 = 𝑘[𝑁𝑂]𝑎 [𝐵𝑟]𝑏
𝑣 = 𝑘[𝑁𝑂]1 [𝐵𝑟]1
𝑣 = 𝑘[𝑁𝑂][𝐵𝑟]
𝑣
=𝑘
[𝑁𝑂][𝐵𝑟]
𝑣
𝑘=
[𝑁𝑂][𝐵𝑟]

SCIE6057 – Chemistry and Biology

 12 M det −1
𝑘=
0.1M ∙ 0.1M
𝑘 = 1200 M−1 det −1

[𝑁𝑂] = 0.01M [𝐵𝑟] = 0.03M, 𝑣 =?

𝑣 = 𝑘[𝑁𝑂][𝐵𝑟]
𝑣 = 1200 M −1 det −1 ∙ 0.01M ∙ 0.03M
𝑣 = 0.36 M det −1

4. 𝑄(𝑔) + 2𝑇 (𝑔) → 𝑇2 𝑄(𝑔)

[𝑄] = 0.5M
[𝑇] = 0.5M
𝑣 =?
Percobaan [Q](M) [T](M) V (M/detik)
1 0,1 0,1 0,0125
2 0,2 0,1 0,05
3 0,1 0,2 0,1

Orde 𝑄?
Percobaan [Q](M) [T](M) V (M/detik)
1 0,1 0,1 0,0125
2 0,2 0,1 0,05

𝑣1 𝑘[𝑄]𝑎 [𝑇]𝑏
=
𝑣2 𝑘[𝑄]𝑎 [𝑇]𝑏
0,0125 [0,1]𝑎 [0,1]𝑏
=
0,05 [0,2]𝑎 [0,1]𝑏
0,0125 [0,1]𝑎
=
0,05 [0,2]𝑎
1 1𝑎
=
4 2𝑎
𝑎=2

SCIE6057 – Chemistry and Biology

Orde 𝑇?
Percobaan [Q](M) [T](M) V (M/detik)
1 0,1 0,1 0,0125
3 0,1 0,2 0,1

𝑣2 𝑘[𝑄]𝑎 [𝑇]𝑏
=
𝑣3 𝑘[𝑄]𝑎 [𝑇]𝑏
0,0125 [0,1]𝑎 [0,1]𝑏
=
0,1 [01]𝑎 [0,2]𝑏
0,0125 [0,1]𝑏
=
0,1 [0,2]𝑏
1 1𝑏
=
8 2𝑏
𝑏=3

𝑘 =?
𝑣 = 𝑘[𝑄]𝑎 [𝑇]𝑏
𝑣 = 𝑘[𝑄]2 [𝑇]3
𝑣
=𝑘
[𝑄] [𝑇]3
2

𝑣
𝑘=
[𝑄 ]2 [𝑇 ]3
0.1 M det −1
𝑘=
(0.1M)2 ∙ (0.2M)3
𝑘 = 1250 M−5 det −1

[𝑄] = 0.5M [𝑇] = 0.5M, 𝑣 =?

𝑣 = 𝑘[𝑄][𝑇]3
𝑣 = 1250 M −5 det −1 ∙ (0.5M)2 ∙ (0.5M)3
𝑣 = 39.0625M det −1
𝑣 ≈ 39.063M det −1

SCIE6057 – Chemistry and Biology

Team 5 Member :

RIFKY RIZALDY M. RIVALDI SUDRAJAT

NIM: 2502053571 NIM: 2502048514

CLAUDIA VIVIAN NISA BIJAK SETYO UTOMO

NIM: 2502043702 NIM: 2502043715

YOPPI SANDI PUTRA

NIM: 2502057292

SCIE6057 – Chemistry and Biology