TUGAS KIMIA ANORGANIK DASAR

Dosen Pembimbing :
Dr. Syahruddin Kasim, S.Si. M.Si.

Kelompok 1
H031201002 Rezky Aspiyana Wulandari
H031201003 Putri
H031201004 Dhea Faraditha Anggriani
H031201005 Rosari
H031201006 Muhammad Rizky Fadliansyah
H031201007 Melinda Yudistira
H031201008 Firman H
H031201009 Nurul Yasmin Syam
H031201010 Nurdiyanti

DEPARTEMEN KIMIA
FAKULTAS MATEMATIKA DAN ILMU PENGETAHUAN ALAM UNIVERSITAS
HASANUDDIN
MAKASSAR
2021
TUGAS PR
Cari pasangan asam atau basa (Keras dan lunak) untuk ligan dengan atom pusatdalam
suatu senyawa kompleks disertai pengelompokannya, sesuai teori HSBC.
Kelas Asam Basa

Keras H+, Li+, Na+, K+ H2O, NH3, N2H4

Be2+, Mg2+, Ca2+, Sr2+ F-, Cl-, OH-, ROH, R2O

Ti4+, Cr3+, Cr6+, Mn2+, Mn7+, Fe3+, Co3+ NO3-, ClO4-, CH3COO-

BF3, BCl3, Al3+, AlCl3, AlH3 O2-, CO32-, SO42-

CO2, Si4+ PO43-

HX (molekul ikatan hidrogen)

Daerah Fe2+, CO2+, Ni2+, Cu2+, Zn2+, Sn2+, Pb2+ C6H5NH2, N3-, N2, NO2-, Br-

batas C6H5+, NO+, Sb3+, Bi3+, SO2 SO32-

C6H5NH2, N3-, N2, NO2-, Br-

SO32-

Lunak Cu+, Ag+, CH3Hg+ H-, C2H4, C6H6, CO, SCN-

Hg22+, Hg2+, Cd2+, Pd2+, Pt2+, Pt4+ CN-, I-

2-
Br2, Br+, I2, I+, O, Cl, Br, I, N S2-, S2O3

Atom-atom logam
PR 5

1. Mg(OH)2 + H2O MgOH+H2O + OH

(Basa) (Asam) (Asam) (Basa)
2. H2CO3 + H2O HCO3- + H3O+
(Asam) (Basa) (Basa) (Asam)
3. NH3 + H2O NH4+ + OH-
(Basa) (Asam) (Asam) (Basa)
4. H2O + H2O H3O+ + OH
(Asam) (Basa) (Asam) (Basa)
5. NH3 + NH3 NH4+ + NH2-
(Basa) (Asam) (Asam) (Basa)
6. H3OCl + NaOH NaCl + 2H2O
(Asam) (Basa) (Basa) (Asam)
7. NH4Cl + NaNH2 NaCl + 2NH3
(Asam) (Basa) (Basa) (Asam)
8. SOCl2 + (NH4)2SO3 (NH4)2Cl + 2SO2
(Basa) (Asam) (Asam) (Basa)
9. CrCl3 + 6NH3 Cr(NH3)6Cl3
(Basa) (Asam) (Asam)
10. FeCl3 + 6KCN Fe(CN)6K3 + 3KCl
( Asam) (Basa) (Basa) (Asam)
11. [Co(NH3)6]3+ + 6H3O+ [Co(H2O)6]3+ + 6NH4+
(Asam) (Basa) (Basa) (Asam)
PR 6

1. 2PbO + PbS 3Pb + SO2

(Asam) (Basa) (Basa) (Asam)

2. HClO4 + CH3COOH ClO4 - + CH3COOH2+

(Basa) (Asam) (Asam) (Basa)

3. PbI2 + 2KNH2 PbNH + 2KI + NH3

( Basa) (Asam) (Asam) (Basa) (Asam)

4. HgCl2 + 2NH3 HgNH2Cl + NH4Cl

(Asam) (Basa) (Basa) (Asam)

5. HNO3 + 2H2SO4 NO2+ + H3O+ + 2HSO4-

(Basa) (Asam) (Asam) (Basa) (Asam)

6. BF3 + 2HF H2F+ + BF4-

(Basa) (Asam) (Asam) (Basa)

7. NH4Cl + CH3CN CH3Cl + NH4CN

(Asam) (Basa) (Basa) (Asam)
8. SO3 + H2O H2SO4
(Asam) (Basa) (Basa)

9. CaO + H2O Ca(OH)2

(Basa) (Asam) (Asam)

10. CaO + SO3 CaSO4

(Basa) (Asam) (Asam)
11. NH3 + CO(NH2)2 NH4+ + CONH2N
(Basa) (Asam) ( Asam) (Basa)