kapasitas : 100000 Ton/Tahun

Basis Perhitungan : 1 Jam Operasi

Satu tahun produksi : 330 hari
satu hari 24 Jam Operasi
kapasitas Produksi : 12626.263 kg/jam

Spesifikasi produk :
Ammonium Sulfat 99.75% berat : 12594.69697 kg/jam
Asam Sulfat 0.1% berat : 12.62626263 kg/jam
Air 0.15% berat : 18.93939394 kg/jam

Mekanisme Reaksi :
2 NH3 + H2SO4 (NH4)2SO4
Dasar perhitungan :
1. kondisi Steady state
2. satuan neraca masa kg/jam

1. Rotary Dryer :
a. filtrat yang ingin dikeluarkan adalah air
b. kristal ZA yang terbawa aliran udara 2 % dari total
c. kadar air kristal 0.15 %
d. kadar H2SO4 2%
Neraca massa total : 12626.26 kg/jam

ZA : 257.0346 kg/jam 257.67367553

H2SO4 : 0.252525 kg/jam 0.0009800196 0.00098 0.00196
H2O : 0.386518 kg/jam 0.9975199504

11
ZA : 12851.732 kg/jam ZA : 12594.69697 kg/jam
H2SO4 : 12.883941 kg/jam 7 Rotary Dryer 10 H2SO4 12.626262626 kg/jam
H2O : 19.325912 kg/jam H2O: 18.939393939 kg/jam

2. Centrifuge :
a. perbandingan kristal ZA : larutan ZA = 1:1
b. cake mengandung 5 % cairan sehingga liquid terikut sebanyak =
5 / 95 x 12851.7316 = 676.4069264 kg/jam 262.2802

ZA : 13095.971 kg/jam 3 7 ZA : 12851.731602 kg/jam

H2SO4 : 13.562044 kg/jam Centrifuge H2SO4 : 12.883941455 kg/jam
H2O : 900.61686 kg/jam H2O : 663.52298495 kg/jam

8 13528.138528
0.049047619
ZA : 244.2399 kg/jam 0.000952381
H2SO4 : 0.678102 kg/jam
H2O : 237.0939 kg/jam

3. Cyclone :
 a. filtrat yang keluar dari cyclone 5%
ZA : 12.851732 kg/jam
H2SO4 : 0.0126263 kg/jam
H2O : 0.0289889 kg/jam

12

Cyclone

11 14
ZA : 257.03463 kg/jam ZA : 244.1829 kg/jam
H2SO4 : 0.2525253 kg/jam H2SO4 : 0.239899 kg/jam
H2O : 0.0289889 kg/jam

ammonium sulfat (3) : 13095.97147 kg/jam

ammonium sulfat (9) : 13108.766234 kg/jam
molekul relatif : 132.136 kg/kgmol
masa ammonium sulfat bereaksi : -12.79476413 kg/jam
-0.096830267 kmol/jam
Konversi reaksi : 98%
2 NH3 + H2SO4 (NH4)2SO4
-0.197613
-0.193661 -0.1936605
-0.1897873 -0.094894 -0.094893661
-0.0038732 0.979992

-0.0037957 -0.001898 -0.001897873

-7.746E-05

-7.591E-05 -3.8E-05 -3.79575E-05

-1.549E-06 -0.096829492 kmol/jam

kebutuhan ammonia : -3.29222907 kg/jam
ammonia reaksi : -3.22638449 kg/jam
As. Sulfat reaksi : -9.48929023 kg/jam
As.sulfat (9) + As. Sulfat(2) : -9.876687207 kg/jam
As. Sulfat out reaktor(3) : -0.387396982 kg/jam

masa air masuk reaktor (1) : masa amonia x (0.5% / 99.5%)

Air (1) : -0.01654386 kg/jam

masa air masuk reaktor (2) : masa As. Sulfat x (2% / 98%)
Air (2) : -0.22055744

-2.63378E-05
-0.06584458
4. Scrubber :
a. filtrat yang ingin discrub adalah air
b. kristal ZA dan asam sulfat yang terbawa menuju scrubber 100%

H2O : 0.028989 kg/jam

13
17
Scrubber H2O : 0.386518 kg/jam

12 15
ZA : 12.85173 kg/jam ZA : 12.85173 kg/jam
H2SO4 : 0.012626 kg/jam H2SO4 : 0.012626 kg/jam
H2O : 0.028989 kg/jam H2O : 0.386518 kg/jam

5. Disoluting Drum :

ZA : 12.85173 kg/jam
ZA : 244.1829 kg/jam 14 15 H2SO4 : 0.012626 kg/jam
Disoluting
H2SO4 : 0.239899 kg/jam Drum H2O : 0.386518 kg/jam

16
ZA : 257.0346 kg/jam
H2SO4 : 0.252525 kg/jam
H2O : 0.386518 kg/jam

6. Mother Liquor Tank :

a. perbandingan kristal : mother liquor = 50 : 50
b. kelarutan ammonium sulfat 103.3 bagian ammonium sulfat/100 bagian air
 ZA : 12851.73 kg/jam
H2SO4 : 0.678102 kg/jam
H2O : 237.0939 kg/jam
8

ZA : 13108.77 kg/jam 9 16 ZA : 257.0346 kg/jam

H2SO4 : 0.930627 kg/jam mother liquor H2SO4 : 0.252525 kg/jam
H2O : 237.4804 kg/jam tank H2O : 0.386518 kg/jam

7. Reaktor Slurry Bubble Column :

a. konversi reaksi 98 %
b. recycle dari mother liquor tank terdiri dari ammonium sulfat, asam sulfat, dan air

NH3 : -0.065845 kg/jam

H2O : kg/jam
-663.3736
4
NH3 : -3.292229 kg/jam
H2O : -0.016544 kg/jam
1
ZA : 13095.97 kg/jam
H2O : kg/jam Reaktor Slurry 3 H2SO4 : -0.387397 kg/jam
5 Bubble Column H2O : 900.6169 kg/jam

H2SO4 : -10.80731 kg/jam

H2O : -0.220557 kg/jam
2

9
ZA : 13108.77 kg/jam 55.19936
H2SO4 : 0.930627 kg/jam 244.6048
H2O : 237.4804 kg/jam

8. Kondensor :
total
masuk : 13332.84
keluar : 13996.14

NH3: -0.065845 kg/jam 5 Kondensor

H2O : -663.3736

4
NH3 : -0.065845 kg/jam
H2O : -663.3736 kg/jam
13275.84
 6539.822
6520.829
13060.65

asumsi :
* perbandingan kristal ZA : mother liquor = 1 : 1
* kelarutan ZA = 103 gram / 100 gram H2O
untuk melarutkan ZA sebanyak 12851.7316 kg air yang dibutuhkan :

H2O = 100 x 12851.7316

103
H2O : 12477.41 kg/jam
kristal : 13237.28 kg/jam
25714.69 kg/jam

237.2433
-9.876687
227.3666 13996.2

464.6099
 reaktor masuk keluar
H2SO4 = 9716.647 190.7751
NH3 = 3377.799 64.88177 0 348.2718
H2O = 13000.76 13244.85
ZA = 13108.77 25703.46
39203.97 39203.97

213.763628 667.6825
0.055 Condensor

NH3 : 64.8817723 kg/jam

H2O : 148.881855 kg/jam 213.763628

NH3 : 3312.918 kg/jam 13519.41

H2O : 16.64783 kg/jam
0.975981
3329.565 Reaktor Slurry ZA : 25703.4632 kg/jam
NH3 : 64.88177 kg/jam Bubble Column H2SO4 : 190.775113 kg/jam Centrifuge
H2O : 13095.9715 kg/jam
3394.447
H2SO4 : 9538.756 kg/jam ZA :
0.348741 H2O : 194.6685 kg/jam 38990.21 H2SO4 :
H2O :

9733.424
211.3163 ZA : 13108.7662 kg/jam
H2SO4 : 177.891171 kg/jam
99.20362 H2O : 12789.4447 kg/jam Mother Liquor
Tank

39139.09 39139.09
26076.1021
0.006822
5.19625 0.247849
6.064283
7.410269

97.33424
kapasitas : 100000 Ton/Tahun
Basis Perhitungan : 1 Jam Operasi
Satu tahun produksi : 330 hari
satu hari 24 Jam Operasi
kapasitas Produksi : 12626.2626 kg/jam

Spesifikasi produk :
BM 132.14 Ammonium Sulfat 99.75% berat : 12594.7
BM 98.08 Asam Sulfat 0.1% berat : 12.62626
Air 0.15% berat : 18.93939
 ammonium sulfat (3) : 25703.4632 kg/jam
18.71635 ammonium sulfat (9) : 13108.7662 kg/jam
32.07868 molekul relatif : 132.136 kg/kgmol
13.38732 2 NH3 + H2SO4 (NH4)2SO4

0.031173 190.8287
187.0122 93.5060836
3.816575

3.740243 1.87012167
0.076331

0.074805 0.03740243
0.001527

ammonium sulfat bereaksi : 12594.7

kebutuhan asam sulfat = 3 kali kebutuhan amonia :
BM 17.03 kebutuhan amonia : 3244.08861
asam sulfat keluar reaktor = total kebutuhan asam sulfat - asam sulfa

neraca masa total :

centrifuge : rotary dryer : BF

masuk : 38990.21 13519.41 893.1515
keluar : 38990.21 13519.41 893.1515

Neraca Masa Total :

Masuk : 119288.157
Keluar 119288.157
 H2O : #VALUE! kg/jam
213.7636
cp 1.64E+06 J/kmol.K
69
1.21E+10 H2O : 635.8592 kg/jam
H2SO4 : 0.257679 kg/jam
ZA : 257.034632 kg/jam
Bag Filter
893.1515
38990.21 0.000289
ZA : 257.0346 kg/jam
H2O : 635.8592 kg/jam
689.261656 H2SO4 : 0.257679 kg/jam

ZA : 12851.7316 kg/jam ZA : 12594.697 kg/jam

Centrifuge H2SO4 : 12.8839415 kg/jam Rotary Dryer H2SO4 : 12.6262626 kg/jam
H2O : 654.798573 kg/jam H2O : 18.9393939 kg/jam

12851.732 kg/jam 12626.2626

177.89117 kg/jam 13519.4141 0.00250627
12441.173 kg/jam 667.682515 13087.53
25470.796 0.04938694 257.6788 12626.2626 0.9975
0.4954327 0.257679 0.001
0.386518 0.0015
ZA : 257.0346 kg/jam
H2O : 348.2718 kg/jam Disoluting Drum
H2O : 348.2718 kg/jam
893.1515
2088.521
605.3064 0.855296 1044.2605 kg/m^3
38990.21 25703.46 1352.81385
65.922865 25703.46
0.4892898
33.587846

kebutuhan ammonia : 3244.089 kg/jam

Ton/Tahun ammonia reaksi : 3179.207 kg/jam
Jam Operasi As. Sulfat reaksi : 9350.608 kg/jam
As.sulfat (9) + As. Sulfat(2) : 9732.26584 kg/jam
Jam Operasi As. Sulfat out reaktor(3) : 381.657484 kg/jam

masa air masuk reaktor (1) : masa amonia x (0.5% / 99.5%)

Air (1) : 16.30195 kg/jam
kg/jam
kg/jam masa air masuk reaktor (2) : masa As. Sulfat x (2% / 98%)
kg/jam Air (2) : 0
 ammonium sulfat (3) : 25703.4632 kg/jam
ammonium sulfat (9) : kg/jam
molekul relatif : kg/kgmol
masa ammonium sulfat bereaksi : kg/jam
(NH4)2SO4 kmol/jam
Konversi reaksi : 98%

93.506084 air yang diperlukan untuk dapat melarutkan kristal ZA masuk ke mother liquo
kelarutan ZA = 103.3 bagian ZA / 100 bagian H2O
H2O = 12613.38
1.8701217

0.0374024

95.414371 kmol/jam
kg/jam
uhan amonia : 9732.266 kmol/jam

butuhan asam sulfat - asam sulfat reaksi

Disoluting Drum : Mother Liquor Tank : Reaktor Slurry Bubble Column :

605.3064 26076.1 39203.97
605.3064 26076.1 39203.97
 56.02 - 18.0152 0.014303 0.001694108 0.03052
19.4064310898999 - 98.0734 6.483503 0.7679114833 75.31169
13.6946358 - 132.136 1.945228 0.2303944087 30.4434
- kmol/m^3 8.443034 1 105.7856

12626.2626262626

13087.5257663785
235.794164646899
13087.5257663785

0.5% / 99.5%)

x (2% / 98%)
ristal ZA masuk ke mother liquor = larutan kristal / kelarutan ZA
an ZA / 100 bagian H2O
 PERHITUNGAN NERACA MASSA

1. Neraca Masa di Reaktor

Arus (kg/jam)
Komponen Input Output
1 2 16 14 3
Ammonia 3312.918 64.882
Asam Sulfat 9538.756 177.891 190.775
Air 16.648 194.668 12789.445 13095.971
ZA 13108.766 25703.463
3329.565 9733.424 64.882 26076.102 38990.210
Total
39203.973 39203.973

2. Neraca Masa di Centrifuge

Arus (kg/jam)
Komponen Input Output
3 5 6
Asam Sulfat 190.775 177.891 12.884
Air 13095.971 12441.173 654.799
ZA 25703.463 12851.732 ###
38990.210 25470.796 ###
Total
38990.210 38990.210

5. Neraca Massa di Bag Filter

Arus (kg/jam)
Komponen Input Output
9 10 11
Asam Sulfat 0.258 0.258
Air 25881.657 25881.657
ZA 257.035 257.035
Udara 141699.780 141699.780
167838.729 167581.695 257.035
Total
167838.729 167838.729

6. Neraca Massa di Disoluting Drum

Arus (kg/jam)
Komponen Input Output
11 12 13
Asam Sulfat
Air 348.272 348.272
ZA 257.035 257.035
257.035 348.272 605.306
Total
605.306 605.306

8. Neraca Massa di Condensor

Arus (kg/jam) 9. Neraca Massa di Separator
Komponen Input Output
4 15 Komponen
Amonia 64.882 64.882
Air 148.882 148.882 Amonia
Total 213.764 213.764 Air
Total

Arus (kg/jam)
Komponen
Input Output
Udara 0.0000 0.0000
Asam Sulfat 12.8839 12.8839
Air ### 654.7986
ZA ### ###
Total ### ###
 2. Neraca Massa di Kondensor
Arus (kg/jam)
Output Komponen Input Output
4 4 5
64.882 Ammonia 64.88177 64.88177
Asam Sulfat
148.882 Air 200.9213
ZA
213.764 265.80
Total
39203.973

4. Neraca Massa di Rotary Drier

Arus (kg/jam)
Komponen Input Output
6 8 7 9
Asam Sulfat 12.884 12.626 0.258
Air 654.799 25226.858 18.939 25881.657
ZA 12851.732 12594.697 257.035
Udara 141699.780 141699.780
13519.414 166926.638 12626.263 167838.729
Total
180446.053 180464.992

6. Neraca Massa di Scrubber

Arus (kg/jam)
Komponen Input Output
12 13 15
Asam Sulfat 0.012884 0.012884
Air 0.19326 12.47235 12.66561
ZA 12.85173 12.85173
13.057874 12.47235 25.530224
Total
25.530224 25.530224

7. Neraca Massa di Mother Liquor Tank

Arus (kg/jam)
Komponen Input Output
6 13 14
 Asam Sulfat 12.884 12.884
Air 654.799 348.272 1003.070
ZA 12851.732 257.035 13108.766
13519.414 605.306 14124.721
Total
14124.721 14124.721

9. Neraca Massa di Separator

Arus (kg/jam)
Input Output
15 16 17
64.882 64.882
148.882 148.882
213.764 64.882 148.882
213.764 213.764