Nov 2013
POLYPLASTICS
Pusat Solusi Teknis ASEAN
Urutan Material
Special PA
PP
PET
PBT
POM
PA
PE
Crystalline
s
na
Pa
PEEK PAI
LCP PEI
PSF
PPS
PES
an
Tah
PI
Thermo plastics
COC
Plastik super
berkinerja tinggi
over 150 degC
Plastik Biasa
berkinerja tinggi
PC
PPE
PMMA
ABS
AS
Amorphous
(
Oven
Broken
Damage
Soft
Weak
Gas
Weight
By overheat
By force on heat
a) Degradasi Thermal
Saat spesimen terpapar pada temperatur
yang tinggi, akan melepaskan reaksi
oksidasi dengan sendirinya. Reaksi ini
berlangsung pada temperatur yang sangat
lebih rendah daripada deformasi thermal
dan dekomposisi thermal.
b) Dekomposisi Thermal
Pada temperatur yang lebih tinggi, polymer
terurai dan proses depolimerisasi
berlangsung dengan energi panas.
c) Deformasi Thermal
Saat dipanaskan, sebuah spesimen
mengalami perubahan fisik kepadatannya.
Deformasi temperatur thermal adalah
sebuah temperatur yang meningkat pada
sebuah beban tertentu pada deformasi
plastik yang berubah-ubah.
Gas
By overheat
a) Degradasi Thermal
Indeks Thermal Relatif menurut UL (Underwriters Laboratories, Inc.)
RTI (relative temperature Index) : The life to keep 50% original for 40,000hrs in air
c) Deformasi Thermal
Metode tes DTUL (ISO 75)
0.45 MPa
Weight
Micrometer
1.80 MPa
Bak Pemanasan
DTUL curve
120 degC
up /hr
Sample
Alat percobaan
0.34mm
DTUL point
UL-index (deg C)
250
PPS
PPS
200
PES
PEI
150
PBT
PBT
PC PC-G
PAR
PBT-G
PBT-G PA-66-G
M-PPO
PPE
100
PA-6-G
POM
POM
POM-G
POM-G
Unfilled
Reinforced
50 50
100
150
200
DTUL/1.82MPa deg C
ASTM
250
300
Amorphous
Crystalline
Clear trance point
: MeltSolid
Melting points
Crystalline temp
Advantage
Disadvantage
Opacity
Large mold shrinkage
Changing structure by cooling
Transparency
Impact strength
Small molding shrinkage
Creep property
Weathering property
Disadvantage
Chemical property
Poor durability
Sliding property
Crystalline / Amorphous
HH
C-C
HH n
PE
Mencair
Padat
Crystalline
Solidification
Amorphous
Melt
Melt
Menunjukkan
perubahan
volume yg
besar
PVT curve
Pressure Velocity
Temperature
PBT
PA66
PC
DURACON DURANEX
PET
FR-PET
DURAFIDE VECTRA
Crystalline
Crystalline
Kecepatan memadat
middle
fast
fast
Slow
Slow
Slow
fast
Kestabilan mencair
Flowability
Big
Big
Big
Small
Big
Big
Tipe Resin
Penyusutan cetakan
Barrel temp
Crystalline Amorphous
PPS
Small
Temperatur cetakan 60 80
Predrying
better
60 80
necessary
necessary
necessary
necessary
better
necessary
Mold corrosion
Dimension accuracy
Mold release
Excellent Good
Poor
DURACON is a registered trademark of Polyplastics Co., Ltd. in Japan and other countries.
DURANEX is a registered trademark of Polyplastics Co., Ltd. in Japan and other countries and is used by WinTech Polymer Ltd. under
license.
FR-PET is a registered trademark of Teijin Limited in Japan and other countries and is used under license by WinTech Polymer Ltd.
DURAFIDE is a registered trademark of Polyplastics Co., Ltd. in Japan and other countries.
VECTRA is a registered trademark of CNA Holdings LLC or its affiliates and is manufactured and sold by Polyplastics Co., Ltd. under license.
GH-25
Standard
GF reinforced
>POM<
>POMGF25<
Tensile strength
MPa
Strain at break
62
35
87
2,500
6
95
136
2.8
200
7,900
8
162
Coefficient of thermal
expansion (Flow)
Coefficient of thermal
expansion (Transverse)
x10-5/
12
x10-5/
12
2.04
2.12
0.5
1.34
Flexural strength
MPa
Flexural modulus
MPa
kJ/m
DTUL (1.8MPa)
Unfilled
Soft, tough
GF reinforced
Hard, Strong, Brittle
GF reinforced
Unfilled
Mechanical properties
Fatigue resistance
Creep resistance
Wear coefficient
High sliding
Chemical resistance
Secondary processing
disadvantages
Adhesiveness
Hot water resistance
Mold shrinkage factor
Weather resistance
Homopolymer
157 161
degC
169 173
degC
Temperatur
degradasi
panas
280 degC
RTI :
Index UL
95 100
degC
258 degC
85 95 degC
DURACON M90-44
1000
Life (months)
Titik Cair
DURACON
(Co-polymer)
M90-44
100
M90-44
Homo polymer
10
1
0.1
140
120
100
80
60
Temp. (deg-C))
Sangat
licin
Sangat
membal
Sedikit
melenting
VOC
Rendah
GH-25
KT-20
NW-02
AW-01
SW-01
TF-10LV
SF-15
GB-25R
TR-20
M90LV
M9045LV
M90
M270
Sangat
lentur
Sangat
Kaku
M25
ES-05
EB-10
EB-08
Tahan
Cuaca
Konduktif
antistatik
POM :
M90-71
WR-01
Daya
tahan
tinggi
U10-01
FP15X
Extrusion
Blow
molding
HP90X
HP25X
CP15X
Hasil sangat
baik
Polymer
pot
ong
!
Terbagi 2 rantai
yg pendek
Flow weight at
10 minutes
Unit: g/10min
Kecepatan putar
: 80 to 150 rpm
Dimension variation
After shrinkage
Cylinder
temperature
Mold Temperature
Warpage
Injection speed
Holding Pressure
Mold deposit
Holding time
Cooling time
Screw speed
Mold temperature : 60 to 80 degC
Holding time
: Keep gate sealing ti
me
2.2
2.1
2.0
1.9
1.8
10
15
Time (h)
20
MT40
23
40
90
MT80
23
40
90
0.02%
<0.01%
0.08%
0.03%
0.29%
0.12%
DURACON
POM M90-44
40degC
60degC
80degC
t
in
Po
on
M
et
er
in
si
ti
VP
Po
on
C
us
hi
Holding
Injection
Back Pressure
Screw
Until resin at gate become complete solidify
Tekanan
Tinggi
Tekanan
Rendah
Check Weight
Weight
Cycle time Setting (sec) of
Run
molded
Inj/Hold Cooling Total part
Time
Time
(g/shot)
1
12
16
28
5.10
2
3
4
5
6
7
14
16
18
20
22
24
14
12
10
8
6
4
28
28
28
28
28
28
5.32
5.46
5.55
5.58
5.60
5.60
2
3
4
5
(kgfcm/cm 2)
Tensile impact
500
MAX
400
core cooling
300
MIN
200
100
0
less
holding time
(mm)
10
Holding time
15
Material: POM
COOCH24O
n
Hard
Soft
(High heat stability (Tuff )
Karakter kimia
Stabil terhadap panas
Resistor listrik
High flowability
Permukaan yang bagus
Possible Flame retardant
Kekurangan
Menyusut, melenting
Hidrolisis
Lengket
Property change over
Tg
2016
CN7000
Ko
so
ng
3316
CN7015
CN7030
Standar
CRN7030
Sedikit melentin
g
702MS
Flame retardant
Tampilan bagus
Gas
3306
Di
t
rendah
pe
pa
HB V-0,
e
rc
c
HR/HS
ep
531HS
er
p
Non-halogen
a
330HR
t Resist.
Di
FR
HB
Tampilan bagus
Anti-Hydrolysis
3105
Anti shock krn p
Kosong
3300
anas
Standar
Film
700FP
201AC
2002
Kecepatan putar
: 80 to 150 rpm
120
100
Tensile strength
Flexural strength
80
60
Waktu pra-pengeringan vs
kelembaban
40
20
0
6 8 10 12 14 16
Waktu prapengeringan (jam)
O
+ H2O
C-O-CH2-CH2-CH2-CH2- -PBT
H
O
PBT-O-C
O
C-OH + HO-CH2-CH2-CH2-CH2- PBT
O
PBT-O-C
O+
C O CH2
CH2-CH2-CH2- PBT
O-H
H
Polymer
Pot
ong
!
Memendek
Polymer
pot
ong
!
Terbagi 2 rantai
yg pendek
Flow weight at
10 minutes
Unit: g/10min
120
100
80
60
No-dry CT250
40
No-dry CT270
Dry
20
CT250
Dry CT270
0
0
20
40
60