1000 lebih rendah dari logam Untuk pure resin, thermal conductivity 0.15-1.5 W/mK SPECIFIC HEAT CAPACITY
Specific heat capacity dari plastik: 0.4
2.7 kJ/kg K
Alat ukur specific heat capacity DSC
(differential scanning calorimetry), perilaku melting dan crystallization dari plastik
Informasi yang diperoleh dari DSC :
Melting temperature (Tm) Crystallization temperature (Tc) degree of crystallinity (XC) SKEMA UJI DSC DATA DSC SPECIFIC HEAT CAPACITY
Contoh data DSC dari nanokomposit yang
terdiri dari matrik 70% Polyamide 6 (PA6), 30% Polypropylene (PP), + clay
Informasi yang diperoleh dari DSC :
Melting temperature (Tm) Crystallization temperature (Tc) degree of crystallinity (XC) DEGREE OF CRYSTALLINITY (XC)
Di mana :
Hf (PP) : fusion enthalpy dari komponen PP
Hf0 (PP): fusion enthalpy dari PP dengan 100% crystallines = 209.2 J/g Hf (PA6) : fusion enthalpy dari komponen PA6 Hf0 (PA6): fusion enthalpy dari PA6 dengan 100% crystallines = 190.8 J/g wPP and wPA6 are the weight fractions of PP and PA6 DSC HEATING SCANS OF PA6/PP/CLAY NANOCOMPOSITES DSC COOLING SCANS OF PA6/PP/CLAY NANOCOMPOSITES DEGREE OF CRYSTALLINITY OF PA6/PP/CLAY NANOCOMPOSITES POLYMER CRYSTALLINITY POLYMER CRYSTALLINITY PEMBEKUAN TERMOPLASTIK SEMI-CRYSTALLINE
Ketika pembekuan
Spherulitic yang terdiri dari
crystalline dan amorphous regions tumbuh di sekitar inti kristalisasi
viscometer, rheometers, dan melt flow indexer SIFAT ALIR PLASTIK Shrinkage Reduction in linear size during cooling from molding to room temperature
Polymers have high thermal expansion coefficients, so
significant shrinkage occurs during cooling in mold Typical shrinkage values for selected polymers:
Plastic Shrinkage, mm/mm (in/in)
Nylon-6,6 0.020 Polyethylene 0.025 Polystyrene 0.004 PVC 0.005 Compensation for Shrinkage Dimensions of mold cavity must be larger than specified part dimensions:
Dc = Dp + DpS + DpS2
where Dc = dimension of cavity;
Dp = molded part dimension, and S = shrinkage value Shrinkage Compensation Factors Fillers in the plastic tend to reduce shrinkage
Injection pressure as pressure is increased, it forces
more material into the mold cavity, and shrinkage is reduced
Compaction time - similar effect - forces more material
into cavity during shrinkage
Molding temperature - higher temperature lowers the
polymer melt viscosity, allowing more material to be packed into mold and reducing shrinkage