Reaksi-reaksi Pemisahan dan Identifikasi Golongan Tembaga (Golongan 2)

Gol 2a
HgS, CuS, Cds, PbS, dan BiS3:
3CuS(s) + 2NO3- + 8H+ 2Cu2+ + 2NO + 3S(s) + 4H2O
3CdS(s) + 2NO3- + 8H+ 2Cd2+ + 2NO + 3S(s) + 4H2O
3PbS(s) + 2NO3- + 8H+ 2Pb2+ + 2NO + 3S(s) + 4H2O
Bi2S3(s) + 2NO3- + 8H+ 2Bi3+ + 2NO + 3S(s) + 4H2O

(Hg):
3HgS(s) + 2NO3- + 12Cl- + 8H+ 3HgCl42- + 2NO + 3S(s) + 4H2O
3HgCl42- + 2Sn2+ Hg2Cl2(s) + SnC162HgCl42+ + Cu Hg(s) + CuCl42Cu + HgS Amalgam
(Pb):
2Pb2+ + SO42- PbSO4(s)
PbSO4(s) + 2CH3COO- (CH3COO)2Pb + SO42(CH3COO)2Pb + CrO42- PbCrO4(s) + 2CH3COOPbCrO4(s) + 3OH- HpbO2- + CrO42- + H2O
Cu2+ + 4NH3 Cu(NH3)42+
Cd2+ + 4NH3 Cd(NH3)42+
(Bi):
Bi3+ + 3OH- Bi(OH)3(s)
Sn2+ + 3OH- Sn(OH)2(s)
Sn(OH)2(s) + OH- HsnO2- + H2O
Bi(OH)3(s) + 3HsnO2- 2Bi(s) + 3HsnO32- + 3H2O
Bi3+ + Chinchonine-KI (Bil3, Chinchonine, HI)
(Jingga)

(Cu):
Cu(NH3)42+ + 4H+ Cu2+ + 4NH4+
2Cu2+ + K4Fe(CN)6 Cu2 Fe(CN)6(s) + 2K2SO4
Cu2+ benzoinoxim Cu(C14H11O2N)
(hijau)
(Cd):
Cu(NH3)42+ + 4CN- Cu(CN)42- + 4NH3
2Cu(CN)42- stabil
Cd(NH3)42+ + 4CN- Cd(CN)42- + 4NH3
Cd(CN)42- Cd2+ + 4CNCd2+ + H2S CdS(s) + 2H+

Reaksi Pemisahan Golongan 2b

As3+, Sb3+, dan Sn2+
(As3+)

(Sb3+)

(Sn2+)