NO. Order : 33.10.

23
Nama Alat : BOMB CALORI METER
No. Seri/Kode : B612007003
No. Asset :
Tipe/Model : IKA KV 600 DIGITAL
Merk/Pembuat : KOEHLER

Temp. Ruang (oC) : 29,1333333333333

Kelembaban Udara (%) : 66,6666666666667

NST (Nilai skala terkecil) : 1,00

Petugas : Dedy Rahman A, S.Si

NPP : 04.77.07419

A. Standar Bom Kalorimeter

Standar of Benzoic acid 26452,202 IT cal/g

Rererence 1 : Cert. Of Analysis SRM 39j Benzoic acid ; National Institute of Standard and Technology (NIST)
Reference 2 : Cert. Of Analysis Part No. B2281 Benzoic acid Calorimeteric Std.
Elemental Microanalysis Limited
Okehampton Business Park
Exeter Road ; Okehampton
Devon EX20 1UB

B. Data kalibrasi

BOMB I.
Serial No. 940085
No. Parameter Unit
1
1 Bobot wadah kosong g 10,3137
2 Bobot wadah + Benzoic acid g 11,322
3 Bobot Benzoic acid g 1,0080
4 Penunjukan alat cal/g 26688,0
Correction factor cal/g 235,80
Average cal/g 26685,40
Stdev cal/g 7,2664
RSD % 0,0272
 Correction between True Value (S-A) -235,80
Avg -235,80
min -241,80
max -221,80
max-min 20,00
Stdev 10,2632
U1 Type A (Repeatibility) 5,9255
U2 Type B (CRM) 5,0000
Uc 7,7531
Ue 15,5063

Avg 20136,78
C. Uncertainty Budget
Data Cylinder Vessel 1
940085
NST alat : 0,288675134594813
Uc (Ulangan) Type A : 5,9255
Uc (Standard CRM) Type B u1 : 5,000000000
(U Anal. Balance 120g) u2 : 0,000092376
U combine : 7,758507875
Ue (uncertainty at 95% CL) : 15,52

min 20135,47
max 20137,68
max-min 2,21
 Thermometer :
No. Sertifikat :
No. Seri/Kode :

Barometer :
No. Sertifikat :
C
o

% Thermohygrograph : Thermohygrometer

cal/g No. Sertifikat : Cal. 6842017

No. Seri/Kode : KAL-1

± 10 IT cal/g

Penunjukan alat
2 3 4 5
10,3183 10,3861 10,3821 10,3873
11,3106 11,3987 11,3815 11,3957
0,9923 1,0126 0,9994 1,0084
26674,0 26694,0 26686,0 26685,0
221,80 241,80 233,80 232,80
 -221,80 -241,80 -233,80 -232,80

Cylinder Vessel 2
BOMB 4
0,288675134594813
0,7669
5,000000000
0,000092376
5,066703175
10,13
 UNCERTAINTY BUDGET ( untuk penetapan nilai BMC )

Bidang kalibrasi / besaran ukur : BOMB CALORI METER

Jenis alat ukur yang dilkalibrasi : Bomb Calorimeter
Alat/Standar yang digunakan : - CRM Benzoic Acid
- Analytical Balance
Metode : ASTM D 5865-04 ; Buku Manual Kalorimeter
Model matematis pengukuran : Calorie/g = delta T * EE / w
EE = Hm + e1 + e2 + e3 / T
dimana, delta T : Suhu akhir - suhu awal
EE : Energi ekivalen
w: bobot std benzoic acid dalam gram
H: Panas pembakaran benzoic acid dalam calorie per gram
m: bobot std benzoic acid dalam gram
T: Suhu e yang dicapai dalam Celcius
e1 : koreksi panas
e2 : koreksi sulfur
e3 : koreksi kawat
Rentang ukur : -
Resolusi : 0,1 cal/g

Tabel kontribusi Uncertainty :

Kode Cylinder : 940085
Komponen Satuan Tipe Distribusi U Pembagi vi ui Ci uiCi ( ui.Ci )^2 ( ui.Ci )^4 / vi
CRM Std Benzoic Acid cal/g B Rectangular 5,7735 2,24 60 2,5819889 1 2,5819889 6,6666667 0,740740740740741
Analytical Balance g A Normal 0,00126 2 60 0,0006364 1 0,0006364 0,0000004 2,733192177219E-15
Repeatability cal/g A Normal 7,2664 2 60 3,6331804 1 3,6331804 13,2000000 2,904
Resolution cal/g A Rectangular 0,5774 1,73 60 0,3333333 1 0,3333333 0,1111111 0,000205761316872
Sums 19,9777782 3,64494650205761
Combined Standard Uncertainty, uc (cal/g) 4,4697
Degree of fredom Effective, "V eff" 109,5
Coverage factor, k for "V eff" & at CL 95 % 1,982
Expanded uncertainty, U = k . uc (cal/g) 8,858

Tabel kontribusi Uncertainty :

Kode Cylinder : BOMB 4
Komponen Satuan Tipe Distribusi U Pembagi vi ui Ci uiCi ( ui.Ci )^2 ( ui.Ci )^4 / vi
CRM Std Benzoic Acid cal/g B Rectangular 5,7735 1,73 60 3,33333333333 1 3,33333333333 11,1111111111111 2,05761316872428
Analytical Balance g A Normal 0,00126 2 60 0,00063636364 1 0,00063636364 4,049586777E-07 2,733192177219E-15
Repeatability cal/g A Normal 1,3039 2 60 0,65193890473 1 6,52E-01 0,4250243355001 0,003010761429455
Resolution cal/g A Rectangular 0,5774 1,73 60 0,33333333333 1 0,33333333333 0,1111111111111 0,000205761316872
Drift Alat cal/g A Rectangular - 1,73 60 0,0000000 1 0,0000000 0,0000000 0
Sums 11,647246962681 2,06082969147061
Combined Standard Uncertainty, uc (cal/g) 3,4128
Degree of fredom Effective, "V eff" 65,8
Coverage factor, k for "V eff" & at CL 95 % 1,997
Expanded uncertainty, U = k . uc (cal/g) 6,814

note : ci = koefisien sensitivitas

vi = derajat bebas (untuk masing-masing sumber ketidakpastian)
drift alat = ditentukan dari 6 kali data dan diambil nilai maksimumnya
Certificate No. : Issuing Office
Date : April 5, 2019 JL. ARTERI TOL CIBITUNG, BEKASI 17520
Phone / Facs : +62 21 88321176 / 88321166
Email : jum.cbt@sucofindo.co.id

CERTIFICATE OF CALIBRATION

CLIENT : 2010.1604/5
ADDRESS :

NAME OF EQUIPMENT : BOMB CALORI METER

SERIAL NO. / CODE : B612007003

TYPE/MODEL : IKA KV 600 DIGITAL

RANGE / DIVISION (J/g) : -/1

MANUFACTURER : KOEHLER
INVENTORY NO. : 3.08.01.41.027.4

The Attachment available is an integral part of this certificate

This calibration result (s) related to the sample (s) submitted only and the certificate cannot be reproduced in any way, except
in full context and with the prior approval in writing from Sucofindo Laboratory.
This Certificate is issued under our General Terms and Conditions,copy of which is available upon request or may be
accessed at www.sucofindo.co.id

SBU General Services

CBT. TRI SUROWIDODO

Attachment Issuing Office
To Certificate No : JL. ARTERI TOL CIBITUNG, BEKASI 17520
Date : April 5, 2019 Phone / Facs : +62 21 88321176 / 88321166
Email : jum.cbt@sucofindo.co.id

CERTIFICATE OF CALIBRATION
TESTING CONDITION,

- TEMPERATURE : 28,7 ± 0,6 °C

- HUMIDITY : 45 ± 4 %

STANDARD & SOLUTION : THERMOHYGROMETER

Serial No. KAL-1
Certificate of Calibration S.1800051
: BENZOID ACID
Part. No. 3285.02

The measurement is traceable to International System of

Units (SI) through P2M-LIPI and PARR INSTRUMENT CO.

CALIBRATION METHOD : PO/KI/02

RECEIVED ON : -

DATE OF CALIBRATION : Oktober 5, 2018

RESULTS
BOMB CALORI METER ,SERIAL/CODE NO. : B612007003

Cylinder Benzoic Acid Equipment Correction Uncertainty of measurement

No. Standard Reading (at 95 % CL, k = 2)
J/g J/g J/g J/g

940085 26452,2 26685 -233 8,9