Pra-rancangan Pabrik Diphenylamine dari Aniline Kapasitas 10.000 Ton/Tahun 16.1.

2020

E.2 Sifat Termodinamika Bahan Baku dan Produk

1. Kapasitas Panas pada Gas (Cp = J/mol.K)
Komponen Formula A B C D E Tmin (K) Tmax (K)
Aniline C6H7N -22,062 0,57313 -4,5651E-04 1,841E07 -2,9867E-11 200 1500
Nitrobenzene C6H5NO2 -16,202 0,56182 -3,9302E-04 1,004E-07 -1,2252E-12 200 1500
Diphenylamine C12H11N -119,40 1,30600 1,2200E-03 5,876E-07 -1,1447E-10 298 1500
Amoniak NH3 33,573 -1,2581E-02 8,8906E-05 -7,1783E-08 1,8569E-11 100 1500
Cp= A+ ( B ×T ) + ( C × T ) + ( D ×T ) +( E ×T )
2 3 4

Sumber : (Yaws, 1999)

2. Kapasitas Panas pada Padatan (Cp = J/mol.K)

Cp= A+ ( B ×T ) + ( C × T )
2

Komponen Formula A B C Tmin Tmax Cp at TMin Cp at TMax

Aniline C6H7N 12,511 0,36035 3,4393E-04 40 267 133,24 267
Nitrobenzene C6H5NO2 38,83 0,22390 5,8770E-04 70 279 147,05 279
Diphenylamine C12H11N -58,807 0,99421 - 269 299 237,62 298,15
Amoniak NH3 15,849 1,4204E-01 -9,4648E-05 120 190 31,531 39,42
Sumber : (Yaws, 1999)

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3. Kapasitas Panas pada Cairan (Cp = J/mol.K)

Komponen Formula A B C D Tmin (K) Tmax (K) T Cp at T
Aniline C6H7N 46,948 0,9896 -2,3583E-03 2,3296E-06 268 629 298,15 194,1

Nitrobenzene C6H5NO2 39, 473 0,9128 -2,1098E-03 2,0093E-06 280 647 298,15 177, 32
153,83 346,15 326,57
Diphenylamine C12H11N 0,9490 -1,9014E-03 1,7374E-06 336 696
5
Amoniak NH3 -182,15 3,3618 -1,4398E-02 2,0371E-05 195 385 298,15 80,16
Cp= A+ ( B ×T ) + ( C × T ) + ( D ×T )
2 3

Sumber : (Yaws, 1999)

4. Enthalpy of Combustion

Komponen Formula Phase ∆Hc 77°F ∆Hc 77°F ∆Hc 77°F

(kJ/mol) (kJ/kg) (Btu/lb)
Aniline C6H7N Liquid 2688,4 28868 12411,2
Nitrobenzene C6H5NO2 Liquid 2436 19787,1 8507,1
Diphenylamine C12H11N Solid 4513,5 26671,1 11466,7
Amoniak NH3 liquid - - -
Sumber : (Yaws, 1999)

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5. Entalpi Pembentukan (kJ/mol)

∆ H f = A+ ( B ×T )+ ( C ×T 2 )

Komponen Formula MW A B C T min T max Hf 298 K Hf 500 K

93,129 102,9 -0,064834 0,000037033 298,1 1000 86,86 79,74
Aniline C6H7N
5
Nitrobenzene C6H5NO2 123,112 80,959 -0,054226 3,1598E-05 298,1 1000 67,6 61,745
5
169,226 229,92 -0,1139 0,000067899 298,1 1000 202 189,95
Diphenylamine C12H11N
5
Sumber : (Yaws, 1999)

Komponen Formula MW Hf at 298,15 K (Kj/mol) Uf at 298,15 K (Kj/mol) S at 298,15 K (Kj/mol)

Amoniak NH3 17,031 -45,90 -43,42 192,80
Sumber : (Yaws, 1999)

6. Entalpi Fusion

Komponen Formula MW Tfreeze H fusion H fusion H fusion

(kJ/mol) (kJ/kg) (Btu/lb)
Aniline C6H7N 93,129 267,13 10,54 113,177 48,658
Diphenylamine C12H11N 169,226 326,15 18,5 109,321 47
Nitrobenzene C6H5NO2 123,112 278,8 12,121 98,455 42,329
Amoniak NH3 17,031 195,41 5,657 332,159 142,828
Sumber : (Yaws, 1999)

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7. Viskositas Cairan : μ liq (cP) = T (K)

log 10( μ liq)= A+ ( B ÷ T ) + ( C × T )+ ( D× T 2 )
Komponen Formula MW A B C D Tmin Tmax T (K) liq μ at
T
Aniline C6H7N 93,129 -13,863 2,51E+03 0,0257 -1,83E-05 268 699 298,15 3,8979
Nitrobenzene C6H5NO2 123,112 -7,771 1,40E+03 0,0147 -1,15E-05 279 719 298,15 1,8899
Diphenylamine C12H11N 169,226 -16,08 3,23E+03 0,0266 -1,63E-05 328 817 572,5 0,2719
Amoniak NH3 17,031 -8,591 8,764E+02 2,681E-2 -3,612E-05 195 406 298,15 0,135
Sumber : (Yaws, 1999)

8. Viskositas Gas : µgas (µP) = T (K)

log 10( μ liq)= A+ ( B ×T ) + ( C × T 2 )

Komponen Formula MW A B C Tmin Tmax µ gas 25 °C µ gas µ gas
Tmin Tmax
Aniline C6H7N 93,129 -19,148 0,3067 -5,3256E-05 250 1000 67,559 54,197 234,29
Nitrobenzene C6H5NO2 123,112 -19,512 0,2958 -5,1687E-05 250 1000 64,095 51,215 224,63
Diphenylamin C12H11N 169,226 -21,162 0,2544 -4,5847E-05 250 1000 50,605 39,567 187,37
e
Amoniak NH3 17,031 -7,874 3,67E-01 -4,47E-06 195 1000 101,28 63,61 355,10
Sumber : (Yaws, 1999)

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9. Entropi (J/mol K)
S= A + ( B × T ) + ( C ×T )
2

Komponen Formula MW A B C Tmin Tma S gas 298 K S gas 500 K

(K) x (K)

Aniline C6H7N 93,129 201,22 0,4229 -8,3564E-05 273,15 1500 319,87 391,77
Nitrobenzene C6H5NO2 123,112 233,53 0,4487 -9,4533E-05 273,15 1500 358,89 434,22
Diphenylamine C12H11N 169,22 203,02 0,7131 -1,3294E-04 273,15 1500 403,8 526,31
Sumber : (Yaws, 1999)

Komponen Formula MW Entropi (S) at 298 Entropi of Formation (Sf) at 298

Amoniak NH3 17,031 192,67 -98,940
Sumber : (Yaws, 1999)

10. Energi Gibbs (kJ/mol)

∆ Gf = A+ ( B ×T ) + ( C × T 2 )
Komponen Formula MW A B C T min T max ∆Gf 298 ∆Gf 500 K
K
84,583 0,27 1,4124E-05 298,1 1000 166,69 223,7
Aniline C6H7N 93,129
5
65,379 0,31 1,0601E-05 298,1 1000 158 221,8
Nitrobenzene C6H5NO2 123,112
5
197,38 0,49 2,1238E-05 298,1 1000 345 447,1
Diphenylamine C12H11N 169,226
5
Sumber : (Yaws, 1999)

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Komponen Formula MW Gf at 298,15 K Af at 298,15 K Sf at 298,15 K

Amoniak NH3 17,031 -16,40 -13,92 -0,0969
Sumber : (Yaws, 1999)

11. Energi Helmholtz (kJ/mol)

∆ Af = A+ ( B ×T ) + ( C × T )
2

Komponen Formula MW A B C T min T max ∆Af 298 K ∆Af 500 K

Aniline C6H7N 93,129 84,583 0,2961 1,4124E-05 298,15 1000 174,13 236,17
Nitrobenzene C6H5NO2 123,112 65,379 0,3324 1,0601E-05 298,15 1000 165,44 234,25
Diphenylamine C12H11N 169,226 197,38 0,5304 2,1238E-05 298,15 1000 357,39 467,87
Sumber : (Yaws, 1999)

Komponen Formula MW Gf at 298,15 K Af at 298,15 K Sf at 298,15 K

Amoniak NH3 17,031 -16,40 -13,92 -0,0969
Sumber : (Yaws, 1999)

12. Energi Dalam (kJ/mol)

∆ Uf = A+ ( B ×T ) + ( C × T )
2

Komponen Formula MW A B C Tmin Tmax ∆Uf 298 K ∆Uf 500 K

Aniline C6H7N 93,129 102,9 -0,0399 3,7033E-05 298,15 1000 94,296 92,211
Diphenylamine C12H11N 169,226 229,92 -0,0723 6,7899E-05 298,15 1000 214,39 210,73
Nitrobenzene C6H5NO2 123,112 80,959 -0,0293 3,1598E-05 298,15 1000 75,036 74,216
Amoniak NH3 17,031 72,29 -0,0224 1,4206E-05 298,15 1000 66,879 64,649

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Sumber : (Yaws, 1999)

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13. Konduktivitas Termal Gas (W/mK)

K= A + ( B × T ) + ( C ×T )
2

Komponen Formula MW A B C Tmin Tmax K 25°C K Tmax K Tmin

Aniline C6H7N 93,129 -1,2794E-02 7,1020E-05 2,1005E-08 250 1000 0,0102 0,0063 0,0792
Nitrobenzene C6H5NO2 123,112 -1,0283E-02 5,7531E-05 1,0851E-08 250 1000 0,0078 0,0048 0,0581
Diphenyamine C6H5NO2 - - - - - - - - -
Amoniak NH3 17,031 0,00457 2,3239E-05 1,4810E-07 200 700 0,02466 0,01514 0,09341
Sumber : (Yaws, 1999)

B.14 Konduktivitas Termal Liquid (W/m.K) K= A + ( B × T ) + ( C ×T 2)

Komponen Formula MW A B C T min T K 25°C K Tmin K Tmax
max
Aniline C6H7N 93,129 1,9620E-01 -5,2139E-07 -2,4460E-07 267 664 0,1742 0,1786 0,088
Nitrobenzene C6H5NO2 123,112 1,6330E-01 8,5964E-06 -1,9810E-07 279 683 0,1483 0,1503 0,0768
Diphenylamine C12H11N 169,226 1,4790E-01 -3,1662E-05 -1,3395E-07 356,15 747 0,1196 0,0495
Amoniak NH3 17,031 1,1606 -2,2840E-03 3,1245E-18 220 400 0,480 0,658 0,247
Sumber : (Yaws, 1999)

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