2019

Optimisasi Kondisi Operasi dan Desain Plantwide

Control Pada CO2 Absorption & Regeneration Plant
Aditya Damar Jati Dosen Pembimbing
02311640000100 Totok Ruki Biyanto
OUTLINE

Pendahuluan Tinjauan Pustaka Metodologi Jadwal Kegiatan

 PENDAHULUAN

SEMINAR PROPOSAL Plantwide CO2 Adsorber & Regeneration

Latar Belakang 2025

51,2% Gas Alam

20,3%
 korosi

CO2 pada
natural gas Plugging

Mengurangi Kalor
Pembakaran
Rumusan Masalah

• Bagaimana Optimisasi Kondisi Operasi dan

Plantwide Control pada Proses CO2 Absorption
and Regeneration ?

• Bagaimana dampak penerapan Optimisasi

Kondisi Operasi dan Plantwide Control pada
Proses CO2 Absorption and Regeneration
terhadap kuantitas dan kualitas produk,
penggunaan energi, serta sisi ekonomi yang
lain?
Tujuan

• Melakukan Optimisasi Kondisi Operasi dan

Plantwide Control pada Proses CO2 Absorption
and Regeneration ?

• Mengetahui dampak penerapan Optimisasi

Kondisi Operasi dan Plantwide Control pada
Proses CO2 Absorption and Regeneration
terhadap kuantitas dan kualitas produk,
penggunaan energi, serta sisi ekonomi yang
lain?
 LINGKUP KERJA

PENGUMPULAN DATA
PFD, P&ID, dan datasheet komponen yang diperoleh

PERMODELAN PADA ASPEN HYSYS 8.8

Memodelkan data yang telah diperoleh menggunakan
ASPEN HYSYS 8.8

KOMPONEN
Komponen yang digunakan antara lain main CO2
Absorber, OVHD Cooler, OVHD ACC, Regenerator
Kolom. Reboiler
 TINJAUAN PUSTAKA

SEMINAR PROPOSAL Plantwide CO2 Adsorber & Regeneration

 Proses di Plant ini memiliki fungsi untuk memurnikan feed gas
alam dari kandungan CO2 sampai kadar maksimum yang
diizinkan, yaitu 50 ppmv.

Dengan menggunakan larutan aMDEA (activated Methyl Diethanol

Amine) yang sebagai absorben, senyawa CO2 dipisahkan dari feed gas
alam pada Plant-1 ini.

SEMINAR PROPOSAL Plantwide CO2 Adsorber & Regeneration

SEMINAR PROPOSAL Plantwide CO2 Adsorber & Regeneration
 PLANTWIDE
CONTROL
SKOGESTAD

Top Down
Mengoptimasi proses demi tujuan meningkatkan profit atau
menurunkan cost
Material Recycle
Integrasi Panas
Bottom Up
Beragam Komponen Kimia
Mempertahankan stabilitas dari sistem
 Neraca Kesetimbangan Massa dan
Energi

𝒎𝒊 = laju massa input fluida kerja (kg/s)

𝒎𝒆
𝑸
= laju massa output fluida kerja (kg/s)
= laju kalor pada sistem (kJ/s)
𝑸 − 𝑾 + Ʃ𝒎𝒊 𝒉𝒊 − Ʃ𝒎𝒆 𝒉𝒆 = 𝟎
𝑾 = kerja pada sistem (kJ/s)
𝒉𝒊 = entalpi dari fluida kerja input (kJ/kg)
𝒉𝒆 = entalpi dari fluida kerja output (kJ/kg)
 METODOLOGI

SEMINAR PROPOSAL Plantwide CO2 Adsorber & Regeneration

METODOLOGI________________.
Start

A
Pengambilan Data PFD, Datasheet, P&ID

Perancangan PWC

Pemodelan Plant menggunakan HYSYS

Pengujian Performansi Sistem

Validasi Pemodelan

Hasil
Optimal?
Pemodelan Tidak
Valid?
Tidak Ya

Ya Analisis hasil dan pembahasan

Finish
A
JADAWAL KEGIATAN
Daftar Pustaka
[1] S. Mokhatab, W. A. Poe, and J. Y. Mak, Natural Gas Transmission and Processing, Third. Oxford, UK: Gulf Professional Publihing, 2015.

[2] T. Nejad, G. Borhani, M. Afkhamipour, A. Azarpour, and V. Akbari, “Journal of Industrial and Engineering Chemistry Modeling study on CO 2 and H 2 S simultaneous removal using MDEA solution,”
J. Ind. Eng. Chem., vol. 34, pp. 344–355, 2016.

[3] Y. Al-naumani, “MPC for Upstream Oil & Gas Fields a practical view,” no. July, 2017.

[4] C. H. Twu, V. Tassone, W. D. Sim, and S. Watanasiri, “Advanced equation of state method for modeling TEG-water for glycol gas dehydration,” Fluid Phase Equilib., vol. 228–229, pp. 213–221, 2005.

[5] A. Bahadori and H. B. Vuthaluru, “Rapid estimation of equilibrium water dew point of natural gas in TEG dehydration systems,” J. Nat. Gas Sci. Eng., vol. 1, no. 3, pp. 68–71, 2009.

[6] S. A. Affandy, Renanto, Juwari, and I. L. Chien, “Simulation and optimization of structured packing replacement in absorption column of natural gas dehydration unit using triethylene glycol (TEG),”
2017 6th Int. Symp. Adv. Control Ind. Process. AdCONIP 2017, pp. 275–281, 2017.

[7] S. Moioli, A. Giuffrida, M. C. Romano, L. A. Pellegrini, and G. Lozza, “Assessment of MDEA absorption process for sequential H 2 S removal and CO 2 capture in air-blown IGCC plants,” Appl.
Energy, vol. 183, pp. 1452–1470, 2016.

[8] W. L. Luyben, B. D. Tyréus, and M. L. Luyben, Plantwide process control. 1999.

[9] V. Minasidis and J. Johannes, “Economic plantwide control : Automated controlled variable selection for a reactor-separator-recycle process,” 2013.

[10] J. D. le Roux, S. Skogestad, and I. K. Craig, “Plant-wide control of grinding mill circuits: Top-down analysis,” IFAC-PapersOnLine, vol. 49, no. 20, pp. 72–77, 2016.

[11] F. Hao and Q. Gu, “Optimization and control for thermal power plant based on plantwide control,” 2011 Int. Conf. Adv. Power Syst. Autom. Prot., vol. 2, pp. 1483–1487, 2011.

[12] Y. Ivanov, O. Pyatnichko, H. Zhuk, and L. Onopa, “ScienceDirect ScienceDirect Extraction of carbon dioxide from gas mixtures with amines absorbing process,” Energy Procedia, vol. 128, pp. 240–247,
2017.

[13] J. P. Nivargi, D. F. Gupta, S. J. Shaikh, and K. T. Shah, “TEG contactor for gas dehydration,” Chem. Eng. World, vol. 40, no. 9, pp. 77–80, 2005.

[14] J. S. Lopez-echeverry, S. Reif-acherman, and E. Araujo-lopez, “Fluid Phase Equilibria Peng-Robinson equation of state : 40 years through cubics,” Fluid Phase Equilib., vol. 447, pp. 39–71, 2017.

[15] Ahmed and D. Fares, “Process Simulation Using Aspen HYSYS V8.”
T h a n k y o u
1. Fungsi obyektif
2. Tentukan derajat kebebasan (DOF),
3. Identifikasi variabel proses yang akan dijadikan sebagai
objek pengukuran, lalu dari variabel proses tersebut dipilih
variabel kendali utama (controlled variable 1/CV1) guna
meminimalisir kerugian proses ditinjau dari segi ekonomi.
4. Tentukan lokasi Througput Manipulator (TPM) yang
menjadi pengatur besar laju produk per satuan waktu.

Analisa Bottom-up
1. Pilih struktur pada tingkat pengendalian regulatory dengan
menentukan variabel kendali kedua (Controlled Variable
2/CV2) PROPOSAL
SEMINAR yang fokus pada stabilisasi proses dan juga
Plantwide CO2 Adsorber & Regeneration
pemilihan pasangan variabel proses – variabel manipulasi.
2. Pilih struktur pada tingkat pengawasan atau supervisory
Equation of State: Peng Robinson

𝑅𝑇 𝑎𝛼
𝑝= − 2
𝑉𝑚 − 𝑏 𝑉𝑚 + 2𝑏𝑉𝑚 − 𝑏 2
Dimana :
𝑅2 𝑇𝑐 2 P = tekanan (mutlak)
𝑎 = 0,45724
𝑃𝑐 V = volume
𝑅𝑇𝑐 n = jumlah mole pada zat
𝑏 = 0,07780 𝑉𝑚 =
𝑉
= volume molar, volume dari 1
𝑃𝑐 𝑛
𝑘 = 0,37464 + 1,5422𝜔 − 0,26922𝜔2 mole gas atau cair
T = temperatur mutlak
𝛼 = (1 + 𝜅 1 − 𝑇𝑟 0,5 )2 R = gas konstan ideal (8,3144621 J/molK)
𝑃𝑐 = tekanan pada titik kritis
𝑇 𝑇𝑐 = temperatur mutlak pada titik kritis.
𝑇𝑟 =
𝑇𝑐
Degrees of Freedom

DOF = Jumlah variabel – Jumlah persamaan independen

First Order Plus Death Time

𝐾𝑒 −𝜃𝑠
𝐺 𝑠
𝜏𝑠 + 1

∆𝑀𝑒𝑎𝑠𝑢𝑟𝑒𝑑 𝑃𝑟𝑜𝑐𝑒𝑠𝑠 𝑉𝑎𝑟𝑖𝑎𝑏𝑙𝑒

𝐾𝑝 =
∆𝑀𝑎𝑛𝑖𝑝𝑢𝑙𝑎𝑡𝑒𝑑 𝑉𝑎𝑟𝑖𝑎𝑏𝑙𝑒
METODOLOGI

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