TEKNIK METALURGI

Pb-Ag Anode Hidro-Elektro Metalurgi

Degredation During
Electrowinning
Zinc
M. Zuhdi Syihab (11)
Ninda Yuliayahya (18)
 TEKNIK METALURGI 2
Hidro-Elektro Metalurgi
OUTLINE
OUTLINE
PENDAHULUAN 01

ELEKTROWINNING ZINC 02
02
ASPEK TERMODINAMIKA 03

ASPEK KINETIKA 04

INTI PEMBAHASAN 05
APLIKASI INDUSTRI 06

KESIMPULAN 07

REFERENSI 08
 TEKNIK METALURGI 3

ZINC
Hidro-Elektro Metalurgi

APLIKASI KEHIDUPAN

2B, 4

GALVANIZING

https://www.lenntech.com/periodic/elements/zn.htm
 PROSES PENGOLAHAN TEKNIK METALURGI 4
Hidro-Elektro Metalurgi

Raw Material

Kominusi

FLOTASI Konsentrasi

Roasting ZnS + 1,5O2 ZnO + SO2

ZnO + H2SO4 ZnSO4 + H2O Leaching

Electrowinning

Melting dan Casting

Zinc Plate
Zabaleta, J. R. (2011).
Robertson, SW, Vercuil, A., van Staden, PJ, Craven, P., (2005)
 TEKNIK METALURGI 5
Hidro-Elektro Metalurgi
ELECTROWINNING Zn
e- e- Katoda Al
+ -

Endapan Zn

Pb-Ag Anoda
Zn2+
ZnSO4 (aq)

Konstantin Popov. (2002).

 TEKNIK METALURGI 6
Hidro-Elektro Metalurgi
ELECTROWINNING Zn
Battery
e- e-
+
-
ANODA 2H2O  4H++O2+4e

KATODA 2Zn2++4e  2Zn +

2Zn2+ + 2H2O  4H+ + O2+2Zn

Konstantin Popov. (2002).

 7
TEKNIK METALURGI
Hidro-Elektro Metalurgi
 TEKNIK METALURGI 8

ASPEK TERMODINAMIKA
ASPEK TERMODINAMIKA
Hidro-Elektro Metalurgi

Persamaan Nernst E = Eo – [RT/nF] lnK

Keterangan
E       = Energi Potensial Elektroda
Eo      = Potensial Standar Sel Elektroda
R       = Tetapan Gay Lussac Gas Ideal
T       = Temperatur
n       = Jumlah ion Walther Nernst
F      = Konstanta Faraday
K      = Konstanta Keseimbangan

Scott, a C., Pitblado, R. M., & Barton, G. W. (1987).

 TEKNIK METALURGI 9

ASPEK
ASPEKTERMODINAMIKA
Hidro-Elektro Metalurgi

TERMODINAMIKA
Zn / Zn2+

i
H2 / H +

– 0 +
E
Kurva Polarisasi Antara Rapat Arus dan Potensial Elektroda

Hua, Xiao-YU. Behavior of Arsenic in Zinc Electrowinning

 TEKNIK METALURGI 10
Hidro-Elektro Metalurgi
ASPEK KINETIKA
ASPEK KINETIKA

HUKUM FARADAY

Keterangan
W       = berat logam yang terambil dalam proses (gr)
I        = arus (Ampere)
t        = waktu (s)
Ar      = Atom Relatif (berat atom)
Michael Faraday
n       = jumlah atom
F      = konstanta Faraday (96.500 joule)

Kumar Guvta, Chiranjib. (2003).

 11

INTI PEMBAHASAN
 TEKNIK METALURGI 12
Inti Pembahasan
Inti Pembahasan Hidro-Elektro Metalurgi

PENGGUNAAN
PENGGUNAANANODA
ANODA
Mudah teroksidasi

-0,13V 0,8 V

sukar teroksidasi

Paduan Ag meningkatkan ketahanan korosi

Paduan Ag meningkatkan ketahanan korosi

Sorour, Nabil, Chaoran Su, Edward Ghali, and Georges Houlachi. (2017).
 TEKNIK METALURGI 13
Inti Pembahasan
Inti Pembahasan Hidro-Elektro Metalurgi

PENGGUNAAN
PENGGUNAANANODA
ANODA

Pengaruh penambahan Ag terhadap laju korosi Anoda paduan Pb.

Zhang, Wei, Sanae Haskouri, Georges Houlachi, and Edward Ghali. (2018).
 TEKNIK METALURGI 14
Inti Pembahasan
Inti Pembahasan Hidro-Elektro Metalurgi

DEGRADASI
DEGRADASIAnoda
AnodaPb-Ag
Pb-Ag

Tahap I
Pb -> Pb2+ + 2e-
 TEKNIK METALURGI 15
Inti Pembahasan
Inti Pembahasan Hidro-Elektro Metalurgi

DEGRADASI
DEGRADASIAnoda
AnodaPb-Ag
Pb-Ag

Tahap II
Pb2+ + 2e- -> Pb

Pb2+ + SO42- -> PbSO4

 TEKNIK METALURGI 16
Inti Pembahasan
Inti Pembahasan Hidro-Elektro Metalurgi

DEGRADASI
DEGRADASIAnoda
AnodaPb-Ag
Pb-Ag
Tahap III
Pb2+ + 2H2O ->
PbO2 + 4H+ + 2e-

PbSO4 + 2H2O -> PbO2

+ SO42- + 4H+ + 2e-
 TEKNIK METALURGI 17
Inti Pembahasan
Inti Pembahasan Hidro-Elektro Metalurgi

DAMPAK
DAMPAKLapisan
LapisanPbO
PbO2 2

Positif
Positif
Meningkatkan ketahan korosi
Meningkatkan ketahan korosi
2

-Ag
Negatif
Negatif
Meningkatkan konsumsi energi, 60%
Meningkatkan konsumsi energi, 60%
energi untuk reaksi anodik
energi untuk reaksi anodik
Ivanov I, Stefanov Y. (2002).
Nakisa. (2014)
 TEKNIK METALURGI 18
Inti Pembahasan
Inti Pembahasan Hidro-Elektro Metalurgi

SOLUSI
SOLUSIDAMPAK
DAMPAKLapisan
LapisanPbO
PbO2 2
Reaksi Evolusi Gas

Reaksi Pembentukan PbSO4 dan PbO2

Sorour, Nabil, Chaoran Su, Edward Ghali, and Georges Houlachi. (2017)
 TEKNIK METALURGI 19
APLIKASI INDUSTRI
APLIKASI INDUSTRI
Hidro-Elektro Metalurgi

Korean zinc
Korean zinc
Korea,1100kt of Zinc
Switzerland,1001kt of Zinc

China, 519kt of Zinc

International Zinc Association. (2003)

 TEKNIK METALURGI 20
APLIKASI INDUSTRI
APLIKASI INDUSTRI
Hidro-Elektro Metalurgi

Produk: SHG Zinc, Zinc Alloy,

Sulphuric Acid Switzerland,1001kt of Zinc

http://www.nyrstar.com/Pages/default.aspx
 TEKNIK METALURGI 21
KESIMPULAN
KESIMPULAN
Hidro-Elektro Metalurgi

Dampak Lapisan PbO2

Paduan Ag pada Anoda Pb Positif : Meningkatkan ketahan korosi

berfungsi menurunkan laju korosi Negatif : Meningkatkan konsumsi energy

(Solusi : overpotensial)

Degradasi Anoda Pb-Ag:

1. Terbentuk lapisan PbO2

2. Dekomposisi Pb pada Katoda

 TEKNIK METALURGI 22
REFERENSI
REFERENSI
Hidro-Elektro Metalurgi

G.W. Barton, A.C. Scott, A validated mathematical model for a zinc electro- winning cell, J. Appl. Electrochem. 22 (2) (1992) 104e115.
Ivanov I, Stefanov Y. Electroextraction of zinc from sulfate electrolytes containing antimony ions and hydroxyethylated- butyne-2-diol-1,4: part 3. The
influence of manganese ions and a divided cell. Hydrometallurgy 2002; 64: 181–186.
Konstantin Popov. (2002). Fundamental Aspects of Electrometallurgy. Kluwer Academic Publisher.
Kumar Guvta, Chiranjib. 2003. Chemical Metallurgy, Principles and Practice. India:Wiley-VCH Verlag GmbH & Co.
Lai, Yanqing et al. 2010. “A Novel Porous Pb-Ag Anode for Energy-Saving in Zinc Electro-Winning. Part I: Laboratory Preparation and Properties.”
Hydrometallurgy 102(1–4): 73–80.
Lashgari, Mohsen, and Farzaneh Hosseini. 2013. “Lead-Silver Anode Degradation during Zinc Electrorecovery Process: Chloride Effect and Localized
Damage.” Journal of Chemistry 2013: 1–5.
Liangxing, Jiang et al. 2010. “A Novel Porous Pb–Ag Anode for Energy-Saving in Zinc Electrowinning.” Hydrometallurgy 102(1–4): 81–86.
Nakisa, Sh., N. Parvini Ahmadi, and J. Moghaddam. 2014. “Electrochemical Study of Pb Anodes for Zinc Electrowinning Industry.” Surface Engineering
30(9): 650–55.
Robertson, SW, Vercuil, A., van Staden, PJ, Craven, P., (2005), A Bacterial Heap Leaching Approach for the Treatment of Low Grade Primary Copper
Sulphide Ore, 3rd S. African Conf. on Base Metals,SAIMM Symp. Series S39, ISBN 1–919783–74–1, pp 471-484
Scott, a C., Pitblado, R. M., & Barton, G. W. (1987). A Mathematical Model of a Zinc Electrowinning Cell. Twentieth International Symposium on the
Application of Computers and Mathematics in the Mineral Industries, 2(February), 51–62.
Sorour, Nabil, Chaoran Su, Edward Ghali, and Georges Houlachi. 2017. “Electrochimica Acta Effect of Ionic Liquid Additives on Oxygen Evolution
Reaction and Corrosion Behavior of Pb-Ag Anode in Zinc Electrowinning.” Electrochimica Acta 258: 631–38..
Zabaleta, J. R. (2011). ZINC AIR FUEL CELL VEHICLES: REVIEW OF DIFFERENT TECHNOLOGIES TO OBTAIN ZINC FROM ZINC OXIDE. ILLINOIS
INSTITUTE OF TECHNOLOGY
Zhang, Wei, Sanae Haskouri, Georges Houlachi, and Edward Ghali. 2018. “Lead-Silver Anode Behavior for Zinc Electrowinning in Sulfuric Acid Solution.”
Corrosion Reviews: 1–22.
Hua, Xiao-YU. Behavior of Arsenic in Zinc Electrowinning
International Zinc Association. (2003)
http://www.nyrstar.com/Pages/default.aspx
https://www.lenntech.com/periodic/elements/zn
 TEKNIK METALURGI 23
Hidro-Elektro Metalurgi

Terima kasih.