LAPORAN PRAKTIKT]M KIMIA I}ASAR YAI{ORGAMK

PERCOBAAIT C-2
KONTROL KEASAMAN LARUTAN PEFIYANGGA (BUTFER)

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DISUSUN OLEH:
de

NamaAlIM : Jason Mandela Q0l4l36ffi7 6[PN16I.32)

an

Nama PartnerA[IM : Vinanda II S QOl4l365676lPN16I33)

Prodi : Kimia
M

Hari, tanggal : Jumat, 21 November 2014

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Asisten : Ika Septiana

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Kelompok .n
Ja

LABORATORITJM KIMIA DASAR

FAKULTAS MATEMATIKA I}AN ILMU PENGETAIIUAII ALAM
UNTVERSITAS GADJAII MAI}A
YOGYAKARTA
2014
 |{ootro I V"oso*on Lotuton l-boqon3qa

BujJet)
-\-r- r\
L) lu3uc,n l'ercobuo n
r) Memohomi me.^n{a"rt rn.ngontrol pH' terutqrora dato- 5is*ern
i
{isro\og n ni lc'i pH ]oruto/) da-
u) Me*pe\a \ur i tekni\'t nnemperdahon[/la

lo* kiboq"i oP\il',,asi

aisle,n tet5g[ul1
, Mu*r*ho* 't ,''tL- bt,Lffu" don Junqsi
lL). Doto,. Teor i

rt
XI) Teo.i Asar-Boso Arhenius
adc.t\crh 5ucrtu zut qunq al,ton te n ionisosi dolo-

po
Aro.n
*i. [.rU.rh o{o, snboqion) don mulghl';ll"n ion H* Io" H*

Re
bcososiosi den3on ptLt't doo 'nunghq'i\[^qn H:0"
HA -t Fl^O HrO* + A-
F
ab
ftdono\,ton bosa oda\,^h zq1- qc'nq crL-cn terionisasi c)a'
\o* u.i. [Su\r.uuh atau s"b*g,on1 dan *tlq\iosi \ttrn r0n Ol-l-
L
$+ HrO € BH** cH-
's

Teoci i terbc,tos \,no re^ q. p ulo.ut Urng olig,rnalao^ hrngo-

la

in

\oh 0ir (c h.i slian ' :.oo'r) '

de

a r) Bujje.
an

Lo.uton penyootga a{ota \.,.*trn buf}u. aUalcuh

lcrruton qonq tetbr''ot Qsqmlbo" Iern"h don gdr4rnoqa'
dori
M

Lorrton",nl me.,punrtrai lna,o* puon untuh . rnervrpettaht*nl'r'n

"don[i'u
niiai p H-ngo Lo.*tt. buJlc6 olibuot denS'"
n

:u::*.n"
so

.,,^rhon or.^.i /buru len,oh qdramnqq Lorutrn buiJe.

[,r*p,. n Iopcrsttas buffe ,- .lo"ton

Ja

1oi 3uu'*l .[:*'nnpuan

(Cho n3 10 ro )
br11.. Jr\, -' rnecn pn.i'honho ^ PH'
Untr\,n Iig bel,,n.ia' Suatu bu'[fer hqcus mqrnpu unt,al,t
menelcr.n\[r^11 0tsqrv'r lbor'o lrrrat qgnq d'tac,Tbhi,ron. flol ,ni qc,tq'
\oh gonl d,\u\,, Ion c\eL qscrn^ /br:" ]on1rn3os i do^ I/c''ni'r ponen
osorv-r / brrrnqo. Hnduqnqu o [,,on sr\inq- be"rp'1";
dcngu'^' Zqi

\rnt
olrlqrr'tohLran l,; da\q* brly:. snhi1,1, pun pll
tot^ bcrubrh s€csrct sr3n,{i i^*n '[btoclq, 2-o I z)
 T 3) Ap\i\,r*r L*,ton BufJur Dolo* Huhrdvpon o.hc'ri-hanr
Lo.u5n bulyt sotgot pen{'1 dalann sts&nn brolo3i

don !t, cn, i o. $onqo!, si stenn tersnbr-t scrn3at snn slrJ den
3o
n pH.
Contoh ngo odo"\oh do.of,. Bilo pH )o\o, fls'ah adq

di JenJont 7,55 5ctMFi 1'1 rntho Monusta

b''o hictup 'te-
t pi" i,\rJ PH dmah cli \'or ienionl te'sebut ' nanusia a-
H dar"h
u^{ m o}i, Sirtenn brf3n. rrrenrpertahoni,on p
\o;" Iong,-l-\,CCu
dan HcOr- [b.od3, ]0rr)
[uitu

rt
u

\,,,, **',*' i J I l i::. u, |;l*' ; :il, .,1,*' T,,1 ".'

po
^, t+onrron
^iffi;
HPOu'- dun Hr PCq- pHt nu'ic1r, brsq diper-fahonl,,,o.

Re
\,(.oro*on [p H ) u\anq bor\rr unt,,,[n 0utr,'r, ton<r." rn adaloh
seilito.. 5,& - d, st Ap\,'\,tar, ini bir,rsonSca .J;\c,lou\,,on dolar"l
{c,nu*^ }ipu hiotropn{\t (5*po.o*odu,
L ab }oro)

UJ Mebae E..oboq n
$
's
rl A\ot dsn Bohon
la

o) Alat
de

A\ul Uqnq d,quna\,on do\qrn pPrt'obaon rAr oda [q h ts bur,h

tobunqu.Jhr,lseb,,,t', prpel goncloir s*L,tAurh ptoprpet , z buoh

an

sebu qh ylos p[e1 50 m L , se-

lc,bu dr^o. Sornl , sobuqh p,pui fntut,

buoh r*1, tobung reofrsi, rebuoh hh1 pengudurh , drn p,tu ,ndtl,roto,
M

p l{ r.tnt vorsa I "

n

b) Boh*n
so

l5ohrn \anq dtqunol,ron dalc{rn peocohoo in; adqlah 1-]Cl lA4,'

NuoF\ ir,,i\i ttct o,t M;NorC,H o,t M, lhPOq o,gp; r'tc,zHPo.
Ja

o,s M i ClltCooH \M i CHs@Na lM; Nt-\q0H I Mr; NFlqCt

\M , don c,r.l,ruud.s.

][ r ). Pncs"d,rr 11e.3c,,.
o) Pg*bq*tun Luutan t-\Cl orc.ool fl
frba*lol,r 5 .n He t o, I L M drmosul,tl,ton 1,io drrlqr, Iqhrr
tot^o."'Joo*L " i"t* al^tradas chtarnbahhon sCImpai qqrs batrs
Lolu r r^L larut*n HCt nonX baru dibrrqt d,qdBil ol"an
dimosu[,,]^4.', lae da.la, \rbu- hkqr 5o rvrL l,tt*boli - Lalta
otfiuodr. ditq"nbrh l^Rn sao^pq ) qort s bafo s " La \u ioroton br-
sebni CHC\ o,mot M) clibug, l,,eu dqla,n {rqa buqh ta}:ung reahsi -
 Lo\u se bcrnga\,t 5sfetes H,C\ \M NqCF\ I A4 drfe&s ho"
,

*ctS\nl - rno S\nr rX lrn dot** {y6t tubunl reahsi Lo\" l,t"trqo,n go di-
op6ol\ n ri nUCn
b) P"rbuoton \-orrton Nc,cH c,clect M
Snbrn r'u 5 nnL NoOH O,\ M o\rrnasui',t,ls6 he daiq* Ic"bt', to-
il a\nr.,odes sannpaf qrrrs s Lo[u
iror So..^L La\u "lrta*hhlaon ba+"

\o.utonte'snbutdi'tosutnlton\nc*bo\lt,neflqlavriqb'^{'al'rqr5orvrL sarvr p<i tori5

sebonrol, s rvrL Lalu drlot'looh [oo Le'loo\' al'ruoc{es
.iff;:11"\-,,'''\'0,'
utan No qt-l o' u'o i te.rubut drb'g I '"
'+ 'l'o\,5' Tr,b"1 'ut I tr ' tabuol IT dr'
\r, g" fob;';

rt
i'l'''['to xI
rta*ly.h t'^n
\*o n *;lu l-\sc\ I M , dan tob uo-1
f

po
{o*\oo\^
setebes tr\a0 H \ M" Lcrl( p H ['ro{gan.1 a Pun
oiqrnct'tt '
- do^ ]iPo"-
Pe* buotr n Loru-[o n BufJen H' Pc.

Re
") nnL \crrutc'n NqH"PCq ,O',t ry d1o'npu'l'.t'n
Sebongo\,r {o
denoon lo r,,r L \orutun Nc{.r HPOq O, s M Laiu d;adntt hrngXq lo-
;:; Lo., ton ! i b'g"satetes
b;, l_ drfclas[un HCt M
L ab
' la e d' la "'rI z drn trbun3
ta bun3.
'=*
ll1 ot"" t"
TI'
f
dtteteslt"n
.#+n. NaCH I M Lc,ta i,toduangu dlles pHnqa
's

d). Pe*buoton Loru{rn Buffe. CHsCDoH I M cJ,n"Cl-lsCgoNq lU

la

5etnn,,rl,r tOnnL lc,rutop C1-lrCgOH \M dica-pu.l,1an det4on l0rnL

l^rrnry* Lala lc'tuton d;-
\o*+r.- Cur(coor1* \ M Lo \,,t di'd..,rI f 'nt.o
de

*rr i,re dalqnn dua tobunq reoLsi Tobunq I dltan Lthtaqn Sele-
int HCI lM don {olrrXq I ditannbor}r.an setetus Noot-\ lA't
an

Lo\u Isduon.{u dttes pHngir

-ru-brotonu
e) Lq.uLn
'BuJiu. NH4eI-l IH daa NH+CI 1q (r' t)
M

Sebnual,r lo m L \orut,n NH'rOH 144 dicannpul\'ton denqan toa'

loruton Nni,Cr I M Lalrr d,qd,,[i hinqqq lurnqan ual,r \oruton' diba-
q a lsL{ l,tsl ,o]di.,l t?;
n

dolqrn du O tobuog t u uv(tq 1

g' he
he Uatg1,1 TaUutt3 reeL,,, )-
_^ol+1;,i Klii,_,
tut", HCI I M do n tobuiS
,
I.
d'to"'6ahl'tJon setetes Na O l-\ l14
so

Lc,)u [eduongo di tPs PHng.^

Pu*br"ton Loiut'n Buff'" Ni+uou rq dor $\f-lq C[ tM [t ''i)
Ja

j)
Sebon,r, i, s m L laruton NH"'' CH M di'o 'p'tl'ron
I d enqan

lorrton" (u,J-CI lM *bonqrl,t lcsn,,L L,l' dtadrth !';nc11a !'Tg:"

Lalq laruton dto,ra, lrn dilo, i(rc'+abuol rea[''si fabu^q a dl-
" dt\aulqlnlno se'belos
+r-U,l;5st4?r ffit lM don labunq I
NaOH lA,1 Lal, l,,edrttu)ttra dites" pHngo.
 r
JVf. Hosi
-\
r

l don Pembohoron

I l) Ho,il
Perub,hqn
Pe.lohuon Loct. Non Lart
Bu4fei pH Bu{.}er pll
6 L 5 o
HCI o,r M diL,nnbhllon l,re luruton osavl
NcoHo'tM drh*bhl,lon lae loubn osao 6 I 5 o
HCI o,lM drb.v,hhh* \,te lon,{rn b,sa I 3 q I

N*OH o,tM drh'v'bhlaon he laru-["n h'a I O

? I

6
HCI o, lM ditonnbahlton he lotu*'n net'o[ 7 I

rt
Noou o,tM di+dMbqhlmo ire lorubn netrol 6 o

po
I
7
\n
IV ,2j,Pe"r,bohoson

Re
Podo pur*brn *onq r.e\rba{tirn 1o.utun non h,11.t olilo -

[*[on Penqenco*n Tujuon danr [Pn3eCIae,,-an in; crdolah unf{l'(

ab
tnervrpermudah, dr\rr* r.,ejartnlti perulralnon PH grt Leladi
L
bilo dita*boh sedih,t ctsarn ataq basa cui,rup 7rekaI
Uong
's
$ ila tCIl,t di\nl,tulaon peryen @rd bo ho p H al,tax cul,tup
^,-Fru ^
la

I,ru",l soh,nqqo sultl diamq{1. So*ohin e.ntcct mo[r, perot-

de

bohrn pH *tr^ samq[rin :i1n i];[rc,n dolr. hal in i.

'

'bertuluon ur,tul,
Puno*bohrn osorn dqn barq
an

o€rn-
ryr\ hati,run perubahan p\-1 qunq teriadi" Setnlo h ri.rcoorn
bohL,on asqrn , bo*, otl, oY,uoJn.; ml[oo harvs d,lrihrlron
M

Wnry duf,,.,n Ha\ rn i brtrrivon untula membuaf larufo., Iur-

n

s€b; hornoqen ion lx.utoii^u n p H $u T d rolap-[ pr^ brsq

so

5e aiaur-at ilrngln in .

Pqdo pi..oho n rynentuon PH dntq* ioruton n0n

Ja

buf&. di lutt u l,tmn p.**hho n osctM do n

Pe
n'r rn,ba hu n

b";; padcx otauacles Dalonn \'r'u, ini

,lonq ter';u{' ada'
\ah peoqenoeftT^. l,{eoro*qn otl'ruodps ot Jn bt.t"-t'Lr [ptl
tr.u.l) .l,ot di'Lorrbah denqan Qsam Hal ini ter'1udi se-
Stlo r taor i poda hasf l pu..dorrn \6a\uuprn
scsuci , letc/Pi
n,16 pHnua {idal,t t!*oi denqan '\qt,.,(ton
teonitr's. Hcrl inr bisq
dise hnUo, J,tarrn, ,terusuttqn (),rilr^ osqrr' . I'{e.u,soh
e/n driebqbladn oteh tor linXl,,uoqan ,x yrti : or'n sli udo-
fat
 fa uanq
( n rnOnq l,rontornrnas,' lolutoo 0sctm te nsebrf - La'
btohrn bat a ni )ur p' l-] a\"uod's alaan
'lu podo Pen00^ r r^ ,l' \r).,1^,.^,,^
^^^-.h^.^^ \"Jalaupun
,l.,ni'-,1cli ,^, sesuqi dengan hasi,i Percolwon
O
l-\ ho.i\ pefco brJn tida[ 5&{na fng"" f ',
be,r,tu, ptH"i
,.H; ;, dlsubobrro,-., o le h l,re rrtr lzon ,pud,, Iarut
J'"t"1'l'tan o\eh {al'r lot )'ng ln'ng"n '

ar, bso Uant

osCIrn al'on
Pn**behon Qsqrvl poda lorut'on. ^e'
nqebqhl^an penu;r;;
-dan n,lo, l+ol pp to'' drperlih't[''un oleh

il. L Dpr.6'boon I
hast -Leonitls walau,p,un ,nrlar p
Fl

rt
ttarena'
;; Hi;r;t bei bedq Hal inr Pu ^ disebqbl"tan
qsqo. oh ib"{ i c(in di

po
+e.lzontqrninas
i,r.,jr-,rrn \oruton n osam a'
udcrno Lolu p;;;;bahan
bos' P'f1 ,lar^L

Re
\,,0n ine.r,b*t ftf \oruton
nai["'Hal in' borbetu 1:t"'
l^nsli percoboan t3on( , *u,n':lu['t['ro
n P'[',til'i",|]]
L ab :i ^

Iri^i",."' Uo[* puno']b'h#^ lorut'n Iv* ferhradop

's

io*tr^ , tecjcrdi real'tsi

0sqo^
la

'

HC\ + NuCH NaCl t HrC

de

Lr\u Doda [0Futon bosq pun d'lal'tula'" {)emm'

b,hon osool' dan basa Pena n rbqhq 6 bato ter I uc)op
an

\oru{on bqs"( qLon meulwqt lotu fo o *wqhin

brrsa
M

";;- -ban ttrdq dttq,rrb,h[z'n lebih

hn.rno pel'tof dari lc'r.i,. t-
;; tu,*dutu ll't t0t pl'n he,.la ku' poda larutan a-
n

CI-" Puclo haril percoboan lrh dtdop:all:..o" perul'^hsn

so

pH Hol rnr bisq'dtsebqbl,,an oloh {,t,.t,r )'n1 I,run3"'

Lr\, opnocnhhqn asorn terhodrp }on,lto o W'i" altan

Ja

*u*UJot pH lorutq^, turcrn Ho,l ini scsiro, g:trn 1a1l

"oljql,thon
W,\uuptrn ugll-; qonq clido
d{ :llll.pn
oat tak *rrol ienqon' ntlt" P't Po','t''' H'iin) puo
l;oq I'ru'f F{pa l'tsr rcric/dr
h,snhoblron olah 'iatr+ir '1 3on1
Sar'rl se pe-l
'HC\realnsi di atot, quitk :

+ NrrOH [\a C) + H"O

-'
Dala, percobqqn ini sernuq lorutrn dtporlalrulron sornq G-
gp:, hasrl perubahrn pH
, Wldld.rpt biv,, semra i/alid
H t ho.'U lnqlnJrn.
 sotnua recphsi e-
Dolonn percobrrn lorufon n0n butfo t
\*\,^* pend*loql*rn c{sqn4 abu b,i=q adala[r rea1lsi ioniscsi
qsam cbr,r bnsa \c'rr,ton Calam at r' i-eafis1 ferJe''ri't ialah
ItCl l-.1*+cl"
No,CH J? = Na* + OH
Ton H" drn OH- terseb.,t lah, '-,Jal,rqo
uarta
,:1"
(neM paryaruhi ntlai
(- u
oH,
Ir
Lo\u podo t)prcoboon penoruiu\ron
zat sien is ler[nocla'1
,
Ioruton seJenls tu , urt i reo lrs i peno ,u)oa h an iurvrlah mol
q
zu)

rt
I e'sebut Re, [,,r, \p,.,"b" t iala{n
+ H*+cl- 2i-l++2c\-

po
l-1 Ct
(Lo.utrn l-tcl ol,tor'&h aser'a HCI)

Re
NaOH+ Nr++ot-l 2Nc,++zOt-l-
(Lorulrn trrlc,^OH dtto,.'rloqh [r(t, NaOii )

ab
Lo\, pada percobc-ron petuba hoo p H PoC" lq'uton n,un
bu{f e. ter'1ud i pencam puncn osq m / be su denqon ,ny ltrntq
L
[,rcrnSunrlasinga. Se.,nua lqrulcrn buffer tnasin - ditq'nb"h'
's
'it':?
l,rrn" .u+n+J, HCI lM dan setetes NoCpl lhlo'u bi'fJer
la

asarn , \anutrn Hc t olr,on bereql,tsi deor4an bysa l"n'1 unqas\

-
de

ngc(- 5eclr.oqiaot n da\qm buf baso, Ia.rtrn hCl otnr" bereql.tst

fer
./iryn boJr"g^. Hrl in,, drtun; ii kkrn ol ph rectk si Ar\ terSadt,
an

Llui{,u,
" ') Bulf r cts..rn No r H POq dan Nc{ t-!po q
M

Nq,- HPCq + H c t -> N' H" Poq + Nac I

") Bu{Jn. ctsarv'\ CHuCoon\a clon CllcCOol-1

n

+ !*\C\ --+ Ct-lgcOOH + I\acl

CHsCccNa
so

') Bufler basa NHq oll dan

NH'* C\
N\lqOH +l-lcl NHqCI + HzO
Ja

i,lr\o^ buf fer qsom , lorutun NaCH ohun bercqh, i deoclan qsa$o*u.
kdurqlzrao dula r'^ buJJe,. ,hr:" iurutan N oiCl-1 olion Lpcpql.{s, dd
nqn^ i.o- I,toniu^qasinqc{. Hcll 'o, bi.a c{'trnjul,tqn olph rpq[,ls;
t BuJJe. ,;J url HPo. oton Na H.Poq
,

")

") Bu{{e'- asdrn CHg@oNq dan CHtCooH

6i{j cooH + Nq0[ -i CHgOONoT + HrC
,) Bu{{e, bura NHqo H drn NHqC\
'"
Nl4qct + NoOH NHq0H + Nc{C\
 )oci reo[s i Ltonq teri, d, , b,,q d'irln'* hqoiuota q'rt't
nai' bahon dsclM a-
\r,r{r" bufter rneo^,pc,cJ{ur,Jan;rl nrlai p linq,
"foclo
Pe

to, bo.o \o,.ulan bu{Jer c{Uon ,Jng hasiIi'ro.'' , o,toY /boto

a*ou GSqM /bas,^ [9nirnqa, t
nrr. l\eduo p'od'['t terrtb' * ahao rne a
br,,a-t pH telo p tlodi I i'ru"eun, '6r\r^il rr00qe i *tbanXlaa,n satc'
Sorna Ioin. Zut Nr.^L\ Con FtrLr qo^q d'has,-t[,lrn {tdah alnan
rneulpsnflaruh, ptl bu{}e. lno*no tfatvigo netnot'
UrnS
Hrr,\ uunq d,d,pot dor' percoloaa0 sesuai denq'n teor;'
[ci,t
u penon4ilrn*^ o iu* /bosu' \/u d''\o' lar u,t,ur, bufJer
rl"-

sorqot sedrh,t metubqh' ntl511 Pf tetfl'"fi?S

rt
Ar;a o\.,ran
"*o=,no-,*r.,
i);, .n kapus;los loaJfer-ngo Pt'\'ed,ain,PFl

po
-te0r,'1,t :

L*t.r ha.,1t percobrr'n denqan p l1 u:t"*I_ P0n cul.tuyt ,vte.ll

hrl t\ ro\ vu L bv iso
lrur tersebut d'ia hu l'tu n,

Re
suh,nglo rvv
bgllll)qqu
JJ '
I,,e dq\c,.n lcnrt"n
l-
f
buJJer 1a ;:]"lil-
[ar.' leladi
^,
,

asq* / looso
?enan^balna^
\no*n, otrll, perulo,h, n lon':'t,f1n L 1:': I t"T, . :+::,^l::{:C
ab
nr" Purrirnl" {..tub, t sor qat We"il es\tn1Qu bts' dtancXy2
j+rf ,t nriar pHnq, Pa.boior.., T0sro a,affifbr'ro ,don Xara^'
L
.*"- "t^rn *ur.rb,h' pH ouol buiJer dqn L'opos;Ls bu{Je'ng"
's
tato pada larlpir-
Hll ,n, di urho s c{a\an^ 1ar^urMn lapot'n setnen
la

00.
de

f) l{n'i rnpulrtn
r) l\on{{rt menqon*rol pH adalr h un fu h M?A gqot Veslri',lrn ni -
an

lo' pH |er,rtario d"o\a n ,i rt,r, {,sioloqt gr."3''"utrrg, sonsil;-J

pda than
M

peru pH

4 Te\^n r \,n *r, pur*ahrnl,on pH oda['h deoSrn rnervtanfoat[.t*, lorrt-

'denqo"
dn louf{e. \'tapsttos don DH U0.v4 sesuai
n

3) Siste,n bu{*er brfunq.' ,6tu{,t *rn1r[^u l,ro.k, b,[o"' P H rLan

so

5i stenn bu.ffer oot'\ah cdrnPu{'a^ ctsc,l"tlt / bo tra dayo,t Ja ranr\$a

Ja

\1) Do{to, P,,{o[o

I

8."d3,J, ,utz, Chomt:lrg The Molehulor' Notrre o{ A4c,tte., lsh.,

qnd\ Sons Ltd.,

\li\o$ t"o.,
Choq, R , rolo , Che.nistrg loth Edllion ' ThB McGr.aw - Hl)l Compasfe":
{
-rnc.) Nl-
r\ruou Vo"i,t
Chrrsiron, 6o"q , :.ooir Ana\3{ital Chemistr.g ,]ohn Vl ;leg uni,t fons Ltol'
'
3n.,**lE
Sq*"rmodu . l. 5 r f,o ro, A l.ou, f,i1s1 N'.r{rient For mula'[ion w, Lh a Bir f ]er
' &,. Si*p\i,{icd Hgolro pon,cs Sgstem r, Jounnal of Ho,- }' cu\lure qnd
"E.osf
.,r, "tiol z l S
 P".hitun3oo
P"nnntuon pH dolo* \orutoo nDn buffer
") ') Lorr{on l, o.\,tuades
') PH a*ot = 7
r). pH setetqh peno.nbohoo Qsarn

MrVl = MrVz * I tetns =o,osmL

SmL,A = lA.o,osmL
& = o,ot M = tt-l-]
pH = -log LH'l
--
-L

rt
*). pH ,nlnloh *bohrn baro
peno

po
fl'V' ' A'lr\i r
SmL.M. lM.o,osrnL

Re
M : oror M. [OH-J
pOlr . - log tot-t- J

pH .
=z
12
L ab
').Lon,rtoo z, HCt o,o0or M
's

') pH awai =
Ll
la

d.pH seteiqh ptna*Lhon asqm

de

[l-)*i*o*"t = [H*] r V, * [H*Jr. Vz

=to,ooor
. s)+[ I. o'oE)
Vi +Vz 5+ O,O5
an

pH " -1og LH*J ' O'O I

M

-\og lo-a = 2
:) pH ss{"\a"in pet)a(nbahan bota
n

HCI + NqC H _) No Cl +
so

HrO
Vuct 5mL n HCI srsq = O
=
n NqOH stsq , Oro 5 mmo\
Ja

VS,OH : g,g5 rnL - o, 005 ryrmo I

Mr+cr.o,wolM
:
Or 04qS rnrnO I

l4uoou . iM
MnaOH alrhir o,oqqs firho I
'
5 rn L r Or09rvr L
n H C\ : O, Ooo5 mrno I
n NqoH : o,os rnmol , !,8 lo-3 = [ot-t'J
, p0l-l ' g-'log q,B
pll . lt +lq g,s
= ll,9?

'). Lo.ul"n s' NaCH o,ooo t M

aura\ . 14 - a{ = lO
').pH
 ,) PH eete\ah Penarnbahan ctsarn
[4noot-t ,o,ooot M
Vrtoou : e mL
/Vu.t = \M
Vrrt . o, os rn L
NcrOH + HCt J) NoCl + HeO
ftl1 smL
O:@O11.,!. lM o,oSnl
o,ooo5 mmo\ o,os nvnoI
C: -C,0OOErnn'ol -O,00osrnnol +o,mSmqoi +O,@5'ra,rrol *
5. o or o4 Q5 mrnol o,Nosn,l.ol o'o@5 umol

rt
MHrr ,tihrr = o^olg1i:il;i , g,B lo-3 M , LH*J

po
BmL +Or0S rnL

pH=s-\og?,0 =2,o1
i) pH setnlah Peno*boh'n I'osa

Re
MnrroFl,= o,ooo I Muoou trbohon ' I M
\UooU : !mL VNooH tonabohor, :orosrnL

[O1-l-] = to,ooorM- s*u)

L ab
+CtAo'c,,snnLl
5mL + oro5rnL
= O,QllM
's

PoH '['953
la

P
H '- 12,o37
de

b) p H da\arn^, \aruton bu-!{e r

'). Lo.u{on 4 . - dan \-lPoq t -
an

HzPoq
V" |iPOq'- = 6,2 . lo-B
-l
M

[ ]\.Po,, ' o'5 M

I H Po*t-1 = o,5 M
n

pH=pHa*lo$ffi
so

. s_ log 6,a t tog H = 7,L\

"). Lo.u{c,n 5, HC"H.Or. dq^ CrHsOr-
Ja

}{aChlrCC0!-l = \ t0-s
tctt.cco\-ll = lM
[Cttrao-] = I M
pF\ = pllo + log ffiffi
: s + loq + =5
.) Lo.rt n 6 , NHqoPi don NHq C I Ct ,i)
Hb ttHrOH . 1. \o-s mol NHqol-t = lo.,,rmoi
[NHqorlJ = lM mol NHqcl .l0rnrno\
[Nl-hcl] = \M
I = lornL
 pcr-l -pHb+ 1.gffi
, . I /zb('^L
b -r- iOq ToE-
*'/za^L
J
:5
PH =?
')Lon,ton 7 , NHqCH don NFi4 Cl [t . t)
l,ib Nl-lqOH = lO'5 r-rNHqoH
nNt]acl
= ernrnol
=2ornrnol
[NH.,OHJ=tM
[NHqc\] ' \M
\lto{c"rl -x*L
poH = pKb * r.g
ffi

rt
:5+\q3ffi*=s,6

po
PH
, \Ll - s,6 :$. q

Re
L ab
's
la
de
an
M
n
so
Ja
 PertonXaon Lopo*n Ser''entorct
]ooohn
,ikao hosi\ pu.Jboon' Perubqhan ,PJl $on,1, P1\,'ng.
,O,u*' ,fedacli
scra{ Denar\,^ brhan *sen^ k, do l"* NrOFI Hul ini diseb,b [,rrn

h;:r"r'tu.1odl reoIsi on{unq fredqa ,at {pcsebul i-olL( v@rc{

stoil,rrs11ptci5 mo\ hesa tatr

hrsrta sehingSa [mngo ::^l "i,:
,v'ifl
qs-c{^ tt,n-gaq,'-lJ'uh di
{ersisa. Hc,l tni dtLaccnatarn
;,on'.4trosi u'n?
il*3,. nno[ teHrso ' nilqi
utr,. br*ng*i oi;h, [no"no "o*" 3'X1
P
Fl Pun rnenurun flos sti s
z) Peruboh an p' H poda \ar u"Loo non buflen cul'lup tingq r sedonq -

\uruton buf ler *icls tr ioe rubo h atau lnrnto beru-

rt
\/lc,n Dqdc,o
'.udiln il . Lc,-utrn bu{Jer rnerniltlai laopost"["s fular^ (necn-

po
brh
pertuhan[,on nilc{1 pH nga.

Re
don€1raT
t'
3).Secoro, p.ol,rti. dan {eonilir, psrbrndn3r^ P
brr.[do alta o mecnPPn.laruh i , uriic; E ]1 lal ;i I dispb'b-
Uont berbeda ''5e*a\'nt6 ba'3''h X"'
Lr.,
ko,en, rnol'
iur'\'n $'! ab
Farrr .trnqr di."-p"tft'n 'Jolnuo PH lc'r'tat' Pun'ho''
L sermc't'

lnin .'Jnr.urn. Hal'ini berlah^ stboli[an'1*

da\a-
\arwtan
buttu. b";; Se\c'tir itu \"po''tosnga pUn
bi" beruh'h lergtn
's

;;Jl":r"r.* g. r, darann buJJer J,ro., l,tonsentcasi hrsa r,tonlurua-

"'\o*r,i
la

:llil IHI^ffi,;' ;,;; re..,eh,r )\,^^ iukh *uhan,e,t^i,

de

b;\^ d,i;*;ir';;" U'i ,.,i k'\'uln' seb'ti|,ng* d'r'el"l"*

buf{e' b'* '
an
M
n
so
Ja