Appendix E.

Kapasitas Panas (Cp) untuk Organik / Anor

Cp = a + b(T) + c(T)2 + d
Cp = J/gmol, Kelvin (K) dan C
Konversi = cal/gmol, Kelvin (K) dan Celcius (C) = Btu/lbmol, Rankine (R) da

Komponen

Rumus Kimia

Mr

Kondisi

Form

Aseton
Asetilen
Udara

CH3COCH3
C2H2

58.08
26.04
29

Amonia
Amonium Sulfat
Benzena

NH3
(NH4)2SO4
C6H6

17.03
132.15
78.11

C4H10
C4H10
C4H8
CaC2
CaCO3
Ca(OH)2
CaO
C
CO2
CO
CCl4
Cl2
Cu
C6H5CH(CH3)2
C6H12
C5H10
C2H6
C2H5OH

58.12
58.12
56.104
64.1
100.09
74.1
56.08
12.01
44.01
28.01
153.838
70.91
63.54
120.19
84.16
70.13
30.07
46.068

g
g
g
g
g
c
l
g
g
g
g
c
c
c
c
c
g
g
l
g
c
g
g
g
g
l

1
1
1
1
1
1
1
1
1
1
1
2
2
1
2
2
1
1
1
1
1
1
1
1
1
1
1
1
2
1
1
1
1
1
1
1

Isobutana
n-Butana
Isobutena
Kalsium Carbit
Kalsium Karbonat
Kalsium Hidroksida
Kalsium Oksida
Karbon
Karbondioksida
Karbonmonoksida
Karbon tetraklorid
Klorin
Tembaga
Cumin(Isopropilbenzena)
Kloroheksana
Kloropentana
Etana
Etil Alkohol

Etilena
Besi (III) Oksida
Formadehida
Helium
n-Heksana
Hidrogen
Asam Bromin
Asam Klorida

C2H4
Fe2O3
H2CO
He
C6H14

28.052
159.7
30.026
4
86.17

H2
HBr
HCl

2.016
80.924
36.465

g
c
g
g
l
g
g
g
g

Asam Sianida
Asam sulfida
Magnesium Klorida
Magnesium Oksida
Metana

HCN
H2S
MgCl2
MgO
CH4

27.026
34.082
95.23
40.32
16.041

Metil Alkohol

CH3OH

-32.042

Metil Sikloheksana
Metil Siklopentana
Asam Nitrat
Nitrit Oksida
Nitrogen Oksida
Nitrogen Tetraoksida
Nitrogen (II) Oksida

C7H14
C6H12
HNO3
NO
NO2
N2O4
N2O

98.182
84.156
63.02
30.01
46.01
92.02
44.02

Oksigen
n-Pentana

O2
C5H12

32
72.15

Propana
Propilena
Natrium Karbonat
Natrium Karbonat
Belerang

C3H8
C3H6
Na2CO3
Na2CO3.10H2O
S

44.09
42.078
105.99
286.15
32.07

Asam Sulfat
Belerang Dioksida
Belerang Trioksida
Toluena

H2SO4
SO2
SO3
C6H5CH3

98.08
64.066
80.066
-92.13

H2O

18.016

Air

g
g
c
c
g
g
l
g
l
l
l
g
g
g
g
g
g
l
g
g
g
c
c
c++
c*
l
g
g
l
g
l
g

1
1
1
2
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

k Organik / Anorganik (pada tekanan rendah)

= a + b(T) + c(T)2 + d(T)3

mol, Kelvin (K) dan Celcius (C)
bmol, Rankine (R) dan Fahrenheit (F) dikali 0,2390

T
C
C
C
K
C
K
K
C
C
C
C
K
K
K
K
K
C
C
K
C
K
C
C
C
C
K
C
C
K
C
C
K
C
C
C
C

a
71.96
42.43
28.94
28.09
35.15
215.9
-7.27329
74.06
89.46
92.3
82.88
68.62
82.34
89.5
41.84
11.18
36.11
28.95
12.285
33.6
22.76
139.2
94.14
73.39
49.37
-325.137
61.34
40.75
103.4
34.28
20.8
31.421
137.44
28.84
29.1
29.13

Untuk satuan SI
b. 10^2
c.10^5
0.01
0.00001
0.201
-0.0001278
0.06053
-0.00005033
0.004147
0.000003191
0.001965
0.000004799
0.02954
0.000004421

d.10^9
0.000000001
3.476E-008
1.82E-008
-0.000000002
-0.000000002
-6.686E-009

0.77054
0.3295
0.3013
0.2788
0.2564
0.0119
0.04975

-0.0016482
-0.000252
-0.0001891
-0.0001547
-0.0001727
-866000
-1287000

1.8979E-006
-7.757E-008
4.987E-008
0.000000035
5.05E-008
-

0.0203
0.01095
0.04233
0.00411
0.0001095
0.01367
0.0006117
0.5376
0.4962
0.3928
0.1392
0.00041379
0.1572
0.1147
0.06711
0.04206
0.0097606
0.4085
0.0000765
-0.000227
-0.001341

-452000
-489100
-0.00002887
0.000003548
-0.0031826
-0.00001607
-0.0003979
-0.000319
-0.0002554
-0.00005816
-0.014031
-0.00008749
-0.00006891
-1772000
0
-0.0023537
-0.0002392
0.000003288
0.000009887
0.000009715

7.464E-009
-2.22E-009
3.4252E-006
6.473E-009
1.205E-007
8.063E-008
6.866E-008
7.28E-009
0.000017035
1.938E-008
1.766E-008
-8.694E-009
3.0927E-006
5.766E-008
-8.698E-010
-4.858E-009
-4.335E-009

C
C
K
K
C
K
K
C
C
C
C
C
C
C
C
C
C
K
C
C
C
K
K
K
K
C
C
C
K
C
K
C

35.3
33.51
72.4
45.44
34.31
19.87
-259.25
42.93
121.3
98.83
110
29.5
29
36.07
75.7
37.66
29.1
33.24
114.8
68.032
59.58
121
535.6
15.2
18.5
139.1
38.91
48.5
1.8083
94.18
-18.2964
33.46

0.02908
0.01547
0.0158
0.005008
0.05469
0.05021
0.0003358
0.08301
0.5653
0.45857
0.008188
0.002199
0.0397
0.125
0.04151
0.01158
1.9241
0.3409
0.2259
0.1771
0.0268
0.0184
0.1559
0.03904
0.09188
0.81222
0.38
0.47212
0.00688

0.00001092
0.000003012
-873200
-0.000003661
-0.00001268
-0.000011639
-0.0000187
-0.0003772
-0.0003044
-0.000002925
0.000005723
-0.0000288
-0.000113
-0.00002694
-0.000006076
-0.0023687
-0.0001899
-0.0001311
-0.0001017
-0.00003104
-0.0000854
-0.0015127
-0.0002786
-0.0013388
0.000007604

-3.292E-009
-0.000000011
-0.000000011
0.000014052
-0.000000008
1.008E-007
8.391E-008
3.652E-010
-2.871E-009
7.87E-009
1.057E-008
1.311E-009
0.000017944
4.226E-008
3.171E-008
2.46E-008
8.606E-009
3.24E-008
0.00000163
8.033E-008
1.3142E-006
-3.593E-009

konversi =

0.239

Untuk satuan British

b. 10^2
c.10^5
0.00239
0.00000239
0.00048039
-3.05442E-010
0.0001446667
-1.202887E-010
9.91133E-006
7.62649E-012
4.69635E-006
1.146961E-011
7.06006E-005
1.056619E-011

d.10^9
2.39E-010
8.30764E-018
4.3498E-018
-4.69635E-019
-4.69635E-019
-1.597954E-018

-1.73831631
17.70034
21.38094
22.0597
19.80832
16.40018
19.67926

0.0018415906
0.000787505
0.000720107
0.000666332
0.000612796
0.000028441
0.0001189025

-3.939198E-009
-6.0228E-010
-4.51949E-010
-3.69733E-010
-4.12753E-010
-2.06974
-3.07593

4.535981E-016
-1.853923E-017
1.191893E-017
8.36022E-018
1.20695E-017
-

9.99976
2.67202
8.63029
6.91905
2.936115
8.0304
5.43964
33.2688
22.49946
17.54021
11.79943
-77.707743
14.66026
9.73925
24.7126
8.19292
4.9712
7.509619
32.84816
6.89276
6.9549
6.96207

0.000048517
2.61705E-005
0.0001011687
9.8229E-006
2.61705E-007
3.26713E-005
0.000001462
0.001284864
0.001185918
0.000938792
0.000332688
0.000000989
0.000375708
0.000274133
0.0001603929
0.0001005234
2.3327834E-005
0.000976315
1.82835E-007
-5.4253E-007
-0.000003205

-1.08028
-1.168949
-6.89993E-011
8.47972E-012
-7.606414E-009
-3.84073E-011
-0.000000001
-7.6241E-010
-6.10406E-010
-1.390024E-010
-3.353409E-008
-2.091011E-010
-1.646949E-010
-4.23508
0
-5.625343E-009
-5.71688E-010
7.85832E-012
2.362993E-011
2.321885E-011

1.783896E-018
-5.3058E-019
8.186228E-016
1.547047E-018
2.87995E-017
1.927057E-017
1.640974E-017
1.73992E-018
4.071365E-015
4.63182E-018
4.22074E-018
-2.077866E-018
7.391553E-016
1.378074E-017
-2.078822E-019
-1.161062E-018
-1.036065E-018

a
0.239
17.19844
10.14077
6.91666
6.71351
8.40085

8.4367
8.00889
17.3036
10.86016
8.20009
4.74893
-61.96075
10.26027
28.9907
23.62037
26.29
7.0505
6.931
8.62073
18.0923
9.00074
6.9549
7.94436
27.4372
16.259648
14.23962
28.919
128.0084
3.6328
4.4215
33.2449
9.29949
11.5915
0.4321837
22.50902
-4.3728396
7.99694

6.95012E-005
3.69733E-005
0.000037762
1.196912E-005
0.0001307091
0.0001200019
8.02562E-007
0.0001983939
0.001351067
0.0010959823
1.956932E-005
5.25561E-006
0.000094883
0.00029875
9.92089E-005
2.76762E-005
0.004598599
0.000814751
0.000539901
0.000423269
0.000064052
0.000043976
0.000372601
9.33056E-005
0.0002195932
0.0019412058
0.0009082
0.0011283668
1.64432E-005

2.60988E-011
7.19868E-012
-2.086948
-8.74979E-012
-3.03052E-011
-2.781721E-011
-4.4693E-011
-9.01508E-010
-7.27516E-010
-6.99075E-012
1.367797E-011
-6.8832E-011
-2.7007E-010
-6.43866E-011
-1.452164E-011
-5.661193E-009
-4.53861E-010
-3.13329E-010
-2.43063E-010
-7.41856E-011
-2.04106E-010
-3.615353E-009
-6.65854E-010
-3.199732E-009
1.817356E-011

-7.86788E-019
-2.629E-018
-2.629E-018
3.358428E-015
-1.91917E-018
2.40912E-017
2.005449E-017
8.72828E-020
-6.86169E-019
1.88093E-018
2.52623E-018
3.13329E-019
4.288616E-015
1.010014E-017
7.57869E-018
5.8794E-018
2.056834E-018
7.7436E-018
3.8957E-016
1.919887E-017
3.140938E-016
-8.58727E-019

Appendix F

Hf untuk semua komponen pada 25o

Komponen

Rumus Kimia

Mr

Kondisi

Asam Asetat

CH3COOH

60.05

Asetaldehida
Aseton

CH3CHO
C3H6O

40.052
58.08

C2H2
NH3

26.04
17.032

(NH4)2CO3

96.09

NH4Cl
NH4OH
NH4NO3

53.5
35.05
80.05

Amonium Sulfat

(NH4)2SO4

132.15

Benzaldehid

C6H5CHO

106.12

Benzena

C6H6

78.11

Boron Oksida

B2O3

69.64

Br2

159.832

n-Butana

C4H10

58.12

Isobutana

C4H10

58.12

C4H8
Ca3(AsO4)2
CaC2
CaCO3
CaCl2
CaCN2
Ca(OH)2
CaO
Ca3(PO4)2
CaSiO3
CaSO4

56.104
398.06
64.1
100.09
110.99
80.11
74.1
56.08
310.19
116.17
136.15

l
g
g
aq, 200
g
g
l
g
c
aq
c
aq
c
aq
c
aq
l
g
l
g
c
l
l
g
l
g
l
g
g
c
c
c
c
c
c
c
c
c
c
aq

Asetilen
Amonia
Amonium Karbonat
Amonium Klorida
Amonium Hidroksida
Amonium Nitrat

Bromin

1-Butena
Kalsium Arsenat
Kalsium Carbit
Kalsium Karbonat
Kalsium Klorida
Kalsium Sianida
Kalsium Hidroksida
Kalsium Oksida
Kalsium Pospat
Kalsium Silikat
Kalsium Sulfat

Kalsium Sulfat (gypsum)

Karbon

CaSO4.2H2O
C

Karbondioksida

CO2

Karbon disulfat

CS2

Karbonmonoksida
Karbon tetraklorid

CO
CCl4

Kloroetana
Cumin(Isopropilbenzena)

C2H5Cl
C6H5CH(CH3)2

Tembaga Sulfat

CuSO4

Kloroheksana
Kloropentana

C6H12
C5H10

Etana
Etil Asetat
Etil Alkohol

C2H6
CH3CO2C2H5
C2H5OH

Etil Benzena

C6H5

Etil Klorida
Etilena
Etilena Klorid
3-Etil Heksana

C2H5Cl
C2H4
C2H3Cl
C8H18

Besi (III) Klorida

Besi (III) Oksida
Besi (II) Sulfit
Besi (IV) Oksida
Besi (II) Klorida
Besi Oksida
Besi Sulfit
Formadehida
n-Heptana

FeCl3
Fe2O3
FeS2
Fe3O4
FeCl2
FeO
FeS
H2CO
C7H16

n-Heksana

C6H14

Hidrogen
Asam Bromin
Asam Klorida
Asam Sianida

H2
HBr
HCl
HCN

172.18
12.01

c
c
grafit ()
44.01
g
l
76.14
l
g
28.01
g
153.838
l
g
64.52
g
l
120.19
g
l
159.61
aq
c
84.16
g
70.13
l
g
30.07
g
88.1
l
46.068
l
g
106.16
l
g
64.52
g
28.052
g
62.5
g
114.22
l
g
c
159.7
c
Lihat di Besi (Iron) Sulfida
231.55
c
c
71.85
c
87.92
c
30.026
g
100.2
l
g
86.17
l
g
2.016
g
80.924
g
36.465
g
27.026
g

Asam sulfida
Besi (Iron) Sulfida
Timbal Oksida
Magnesium Klorida
Magnesium Hidroksida
Magnesium Oksida
Metana
Metil Alkohol

H2S
FeS2
PbO
MgCl2
Mg(OH)2
MgO
CH4
CH3OH

34.082
119.98
223.21
95.23
58.34
40.32
16.041
-32.042

Metil Klorida
Metil Sikloheksana

CH3Cl
C7H14

50.49
98.182

Metil Siklopentana

C6H12

84.156

Asam Nitrat

HNO3

63.02

Nitrit Oksida
Nitrogen Oksida
Nitrogen (II) Oksida
n-Pentana

NO
NO2
N2O
C5H12

30.01
46.01
44.02
72.15

Asam Fospat

H3PO4

98

Fosfor
Fosfor Pentoksida
Propana

P4
P2O5
C3H8

123.9
141.95
44.09

Propena
n-Propil Alkohol
n-Propil Benzena

C3H6
C3H8O
C6H5.CH2.C2H5

42.078
60.09
120.19

SiO2
NaHCO3
NaHSO4
Na2CO3
NaCl
NaCN
NaNO3
NaNO2
Na2SO4
Na2S
Na2SO3
Na2S2O3
S

60.09
84.01
120.07
105.99
58.45
49.01
85
69
142.05
78.05
126.05
158.11
32.07

Silikon Dioksida
Natrium Bikarbonat
Natrium Bisulfat
Natrium Karbonat
Natrium Klorida
Natrium Sianida
Natrium Nitrat
Natrium Nitrit
Natrium Sulfat
Natrium Sulfida
Natrium Sulfit
Natrium Tiosulfat
Belerang

g
c
c
c
c
c
g
l
g
g
l
g
l
g
l
aq
g
g
g
l
g
c
aq (1 H2O)
c
c
l
g
g
c
l
g
c
c
c
c
c
c
c
c
c
c
c
c
c
S4 (rombic)
c

Belerang Klorida
Belerang Dioksida
Belerang Trioksida
Asam Sulfat

S2Cl2
SO2
SO3
H2SO4

135.05
64.066
80.066
98.08

C6H5CH3

-92.13

H2O

18.016

m-Xilena

C6H4(CH3)2

106.16

o-Xylene

C6H4(CH3)3

106.16

C6H4(CH3)4

106.16

ZnSO4

161.45

Toluena
Air

Seng Sulfat

(Monosiklik)
l
g
g
l
aq
l
l
g
l
g
l
g
l
g
c
aq

n pada 25oC

Untuk konversi ke Btu/lb mol dikali =

Kondisi

Hf (kJ/gmol)spesifik

Hc (kJ/gmol)spesifik

l
g
g
aq, 200
g
g
l
g
c
aq
c
aq
c
aq
c
aq
l
g
l
g
c
l
l
g
l
g
l
g
g
c
c
c
c
c
c
c
c
c
c
aq

-486.2
-166.4
-410.03
-216.69
226.75
-67.2
-46.191
-941.86
-315.4
-366.5
-366.1
-339.4
-1179.3
-1173.1
-88.83
-40
48.66
82.927
-1263
-1245.2
0
30.7
-147.6
-124.73
-158.5
-134.5
1.172
-3330.5
-62.7
-1206.9
-749.9
-352
-986.56
-635.6
-4137.6
-1584
-1432.7
-1450.5

-871.69
-919.73
-1192.36
-1821.38
-1299.61
-382.58
-3267.6
-3301.5

-2855.6
-2878.52
-2849
-2868.8
-2718.9
-

c
c
grafit ()
g
l
l
g
g
l
g
g
l
g
l
aq
c
g
l
g
g
l
l
g
l
g
g
g
g
l
g
c
c
Iron) Sulfida
c
c
c
c
g
l
g
l
g
g
g
g
g

-2021.1
0

-393.51

-393.51
-412.92
87.86
115.3
-110.52
-139.5
-106.69
-105
-41.2
3.93
-769.86
-843.12
-751.4
-123.1
-105.8
-77.23
-84.667
-442.92
-277.63
-235.31
-12.46
29.79
-105
52.283
31.38
-250.5
-210.9
-403.34
-822.156

-1075.2
-1102.6
-282.99
-352.2
-384.9
-1421.1
-5215.44
-5260.59
3953
-3290.9
-3319.5
-1559.9
-2274.48
-1366.91
-1409.25
-4564.87
-4607.13
1410.99
-1271.5
-5470.12
-5509.78
Lihat di Besi (Iron) Sulfida

-1116.7
-342.67
-267
-95.06
-115.89
-224.4
-187.8
-198.8
167.2
0
-36.23
-92.311
130.54

-563.46
-4816.91
-4853.48
-4163.1
-4194.753
-285.84
-

g
c
c
c
c
c
g
l
g
g
l
g
l
g
l
aq
g
g
g
l
g
c
aq (1 H2O)
c
c
l
g
g
c
l
g
c
c
c
c
c
c
c
c
c
c
c
c
c
S4 (rombic)
c

-20.15
-177.9
-219.2
-641.83
-924.66
601.83
-74.84
-238.64
-201.25
-81.923
-190.2
-154.8
-138.4
-106.7
-173.23
-206.57
90.374
33.85
81.55
-173.1
-146.4
-1281
-1278
0
1506
-119.84
-103.85
20.41
-255
-38.4
7.824
-851
-945.6
-1126
-1130
-411
-89.79
-466.68
-359
-1384.5
-373
-1090
-1117
0
0.297

-562.589
-890.4
-726.55
-763.96
-766.63
-4565.29
-4600.68
-3937.7
-3969.4
-3509.5
-3536.15
-2204
-2220
-2058.47
-2068.6
-5218.2
-5264.5
-

(Monosiklik)
l
g
g
l
aq
l
l
g
l
g
l
g
l
g
c
aq

-60.3
-296.9
-395.18
-811.32
-907.51
11.99
50
-285.84
-241.826
-25.42
17.24
-24.44
19
-24.43
17.95
-987.55
-1059.93

-3909.9
-3947.9
-4551.86
-4594.53
-4552.86
-4596.29
-4552.86
-4595.25
-

430.6