Neraca Massa Fix

NERACA MASSA PABRIK ACRYLAMIDE DARI ACRYLONITRIL DAN H2O DENGAN PROSES HIDRA
KAPASITAS 50.000 TON/TAHUN
I. NERACA MASSA BASIS
REAKTOR
1. Umpan Segar Acrylonitril (Kemurnian 95% berat)
Komponen BM Kmol/jam Kg/jam

C3H3N 53 100 5300
H2O 18 15.4971 278.9474
Total 115.4971 5578.9474
2. Umpan Segar H2O

Perbandingan
H20 18 184.5029 3321.05263
3. Total umpan masuk reaktor (Basis 100 Kmol/jam ; C3H3N / H2O = 1 : 2 )
Komponen BM Kmol/jam Kg/jam rho rho campuran

C3H3N 53 100 5300 0.7480 0.2493
H2O 18 200.0000 3600.0000 0.9777 0.6518
CU 1756.6050
Total 300.0000 10656.6050 0.9011
Rekasi
C3H3N + H2O -------------> C3H5NO
Konversi Xa = 0.99
(1-Xa) = 0.01
maka :
C3H3N = nAo (1-Xa)
= 100 0.01
= 1 Kmol/jam
H2O = nBo - nAo Xa

= 200.0000 - 100 0.99
= 101.0000 Kmol/jam
C3H5NO = nCo+nAo Xa
= 0+ 100 0.99
= 99 Kmol/jam
maka komposisi hasil reaksi
4. hasil reaksi
Komponen BM Kmol/jam Kg/jam rho Fraksi mol

C3H3N 53 1 53 0.7480 0.0050
H2O 18 101.0000 1818 0.9777 0.5025
C3H5NO 71 99 7029 0.8573 0.4925
CU 1756.60501
Total 201 10656.605 1.0000
CENTRIFUGE
1. Umpan masuk
C3H3N 53 1 53
H2O 18 101.0000 1818
C3H5NO 71 99 7029
CU 1756.60501
Total 201.0000 10656.6050
Kebutuhan air pencuci sebesar 20 % terhadap umpan
2. Umpan air pencuci
Komp BM Kmol/jam Kg/jam

H2O 18 118.4067 2131.3210 3949.3210
kadar air dalam CU sebesar 5%
3. Hasil penyaringan fase pada (cake) (recycle)
Komponen BM Kmol/jam Kg/jam fraksi mol in

Campuran 92.4529 12787.9260
C3H3N 53 0.0087 0.4600 0.0050
H2O 18 2.5809 46.4564 0.5025
C3H5NO 71 0.6414 45.5365 0.4925
CU 1756.6050
Total 1849.0579
4. Komposisi filtrat

C3H3N 53 0.9913 52.5400
H2O 18 216.8258 3902.8646
C3H5NO 71 98.3586 6983.4635
Total 316.1758 10938.8681
EVAPORATOR
1. UMPAN MASUK
Komponen BM Kmol/jam Kg/jam fraksi mol

C3H3N 53 0.9913 52.5400 0.0031
H2O 18 216.8258 3902.8646 0.6858
C3H5NO 71 98.3586 6983.4635 0.3111
Total 316.1758 10938.8681
Diharapkan C3H5NO keluar pada keadaan larutan jenuh

pada suhu 105 oC
C3H5NO
S= 2.3 T + 146.5
388 g/95,47 g H2O
H20 pelarut = 95.47 6983.4635

388
= 1718.32799 Kg/jam
H2O yg menguap = 3902.86457 - 1718.3280
= 2184.53658 Kg/jam
2. H2O yg menguap
H2O 18 121.3631 2184.53658
3. C3H3N yg menguap = 52.5400 Kg/jam

2237.0766
3. Komposisi hasil penguapan
Komponen BM Kmol/jam Kg/jam in

H2O 18 95.4627 1718.3280 10938.86811
C3H5NO 71 98.3586408 6983.4635
Total 193.8213 8701.7915
CRRSTALIZER
1. Umpan masuk

H2O 18 95.4627 1718.3280
C3H5NO 71 98.3586 6983.4635
Total 193.8213 8701.7915
Data kelarutan C3H5NO 30 0c

= 215.5 gr/99,54gr H2O
C3H5NO terlarut = 215.5 1718.32799

99.54
= 3720.10932 Kg/jam
C3H5NO padatan = 6983.4635 - 3720.1093

= 3263.35418 Kg/jam
2. Komposisi hasil kristalisasi

H20 18 95.4627 1718.3280
C3H5NO(aq) 71 52.3959 3720.1093
C3H5NO(s) 71 45.9627 3263.3542
Total 193.8213 8701.7915
CENTRIFUGE
1. Umpan masuk

H2O 18 95.4627 1718.3280 in
C3H5NO(aq) 71 52.3959 3720.1093 10442.14979
C3H5NO(s) 71 45.9627 3263.3542
Total 193.8213 8701.7915
2. Komposisi air pencuci sebesar 20% terhadap umpan

H2O 18 96.6866 1740.3583
3. Komposisi cake

H2O 18 1.8130 32.6335
C3H5NO(s) 71 45.5031 3230.7206
Total 47.3161 3263.3542
4. Komposisi filtrat 10442.14979

10442.14979
H2O 18 190.3363 3426.0527
C3H5NO(aq) 71 52.8555 3752.7429
Total 243.1918 7178.7956
Rotary Dryer
1. Umpan masuk dari CF

H2O 18 1.8130 32.6335
C3H5NO(s) 71 45.5031 3230.7206
Total 47.3161 3263.3542
Kadar air dalam produk akhir sebesar 0,5 %
2. Komposisi hasil akhir (produk)

H2O 18 0.9019 16.2348 3263.354177
C3H5NO(s) 71 45.5031 3230.7206
Total 46.4050 3246.9554
3. Komposisi air menguap

H2O 18 0.9110 16.3988
Total 0.9110 16.3988
CRYLONITRIL DAN H2O DENGAN PROSES HIDRASI KATALITIK
AS 50.000 TON/TAHUN
3N / H2O = 1 : 2 )
fraksi mol Volume

0.3333 5881.4826
0.6667 3994.9693
1 9876.4519
1
rho campuran volume
0.0037 57.7811
0.4913 1981.9991 1871 3779.7713871052
0.4223 7663.0757 0.4950
0.9173 9702.8558 L
Katalis yang diperlukan = 1756605.01474222 gr

= 1756.6050147422 Kg/jam
konsentrasi katalis = 181.04 gr/L
out
12787.9260
RECYCLE
EVAPORATOR
1. UMPAN MASUK
Komponen BM Kmol/jam
C3H3N 53 0.991321
H2O 18 407.1621
C3H5NO 71 151.2142
559.3676

pada suhu 105 oC
C3H5NO
S= 2.3 T
388 g/100 g H2O
AC 15861.6472 H20 pelarut = 100

388
= 2767.063
H2O yg menguap = 7328.917
= 4561.854
2. H2O yg menguap
H2O 18 253.4363
3. C3H3N yg mengua= 159
out Komponen BM Kmol/jam

10938.8681074357 H2O 18 153.7257
C3H5NO 71 151.2142
304.9399
CRRSTALIZER
1. Umpan masuk
H2O 18 153.7257
C3H5NO 71 151.2142
in out 304.9399
8701.7914896143 8701.79149
Data kelarutan C3H5NO 30
= 388
C3H5NO terlarut = 388

100
= 6667.113
C3H5NO padatan = 10736.21

= 4069.094
H20 18 153.7257
C3H5NO(aq) 71 93.90299
C3H5NO(s) 71 57.31118
304.9399
CENTRIFUGE
1. Umpan masuk
out H2O 18 153.7257
10442.1497875371 C3H5NO(aq) 71 93.90299
C3H5NO(s) 71 57.31118
304.9399
3. Komposisi cake
H2O 18 11.77896
C3H5NO(s) 71 56.73807
68.51702
H2O 18 141.9468
C3H5NO(aq) 71 94.47611
236.4229
Rotary Dryer
H2O 18 11.77896
C3H5NO(s) 71 56.73807
68.51702
H2O 18 1.124624
C3H5NO(s) 71 56.73807
57.86269
H2O 18 10.65433
10.65433
Kg/jam
52.540035
7328.9173
10736.206
18117.664
da keadaan larutan jenuh
+ 146.5
g/100 g H2O
10736.206
Kg/jam
- 2767.063
Kg/jam
Kg/jam
4561.8538
Kg/jam
Kg/jam in out
2767.0635 18117.66 18224.12
10736.206
13503.27
Kg/jam
2767.0635
10736.206
13503.27 in out
13503.27 13503.27
0c
gr/100gr H2O
1718.3280
Kg/jam
- 6667.113
Kg/jam
Kg/jam
2767.0635
6667.1126
4069.0938
13503.27
Kg/jam
2767.0635 in out
6667.1126
4069.0938 13503.27 13503.27
13503.27
Kg/jam
212.0212
4028.4028
4240.424
13503.27
13503.27
Kg/jam
2555.0423
6707.8035
9262.8458
Kg/jam
212.0212
4028.4028
4240.424
sebesar 0,5 %
Kg/jam
20.24323 4240.424
4028.4028
4048.6461
Kg/jam
191.77797
191.77797
NERACA MASSA PABRIK ACRYLAMIDE DARI ACRYLONITRIL DAN H2O DENGAN PROS
REAKTOR
0.0000

H2O 18.0000 15.4971 278.9474
C3H3N 53.0000 100.0000 5300.0000
115.4971 5578.9474
2. Umpan Segar H2O

Perbandingan
H20 18.0000 184.5029 3321.0526

H2O 18.0000 200.0000 3600.0000
C3H3N 53.0000 100.0000 5300.0000
Cu 1756.6050
300.0000 10656.6050
Rekasi
C3H3N + H2O -------------> C3H5NO
Konversi Xa = 0.9900
(1-Xa) = 0.0100
maka :
C3H3N = nAo (1-Xa)
= 100.0000 0.0100
= 1.0000 Kmol/jam
H2O = nBo - nAo Xa

= 200.0000 - 100.0000 0.9900
= 101.0000 Kmol/jam
C3H5NO = nCo+nAo Xa
= 0.0000 + 100.0000 0.9900
= 99.0000 Kmol/jam

4. hasil reaksi

H2O 18.0000 101.0000 1818.0000 0.9777 0.5025
C3H3N 53.0000 1.0000 53.0000 0.7480 0.0050
C3H5NO 71.0000 99.0000 7029.0000 0.8573 0.4925
Cu 1756.6050
201.0000 10656.6050 1.0000
=
CENTRIFUGE
1. Umpan masuk
H2O 18.0000 101.0000 1818.0000
C3H3N 53.0000 1.0000 53.0000
C3H5NO 71.0000 99.0000 7029.0000
CU 1756.6050
201.0000 10656.6050

H2O 18.0000 118.4067 2131.3210
Komponen BM Kmol/jam Kg/jam Fraksi mol in

H2O 18.0000 5.1363 92.4529 12787.9260
H2O 18.0000 2.5809 46.4564 0.5025
C3H3N 53.0000 0.0087 0.4600 0.0050
C3H5NO 71.0000 0.6414 45.5365 0.4925
CU 1756.6050
1849.0579

H2O 18.0000 216.8258 3902.8646
C3H3N 53.0000 0.9913 52.5400
C3H5NO 71.0000 98.3586 6983.4635
316.1758 10938.8681
EVAPORATOR
1. UMPAN MASUK
H2O 18.0000 216.8258 3902.8646
C3H3N 53.0000 0.9913 52.5400
C3H5NO 71.0000 98.3586 6983.4635
10938.8681
2. Filtrat recycle
H2O 18.0000 411.4272 7405.6896 0.0000
C3H5NO 71.0000 114.2515 8111.8567 0.0000
Total 525.6787 15517.5463
3. TOTAL UMPAN MASUK

H2O 18.0000 628.2530 11308.5542
C3H3N 53.0000 0.9913 52.5400
C3H5NO 71.0000 212.6101 15095.3202
Total 841.8545 26456.4144

pada suhu 105.0000 oC
C3H5NO
S= 2.3000 T + 146.5000
388.0000 g/95,47 g H2O 97.7700
H20 pelarut = 95.4700 15095.3202

388.0000
= 3714.3047 Kg/jam
H2O yg menguap = 11308.5542 - 3714.3047
= 7594.2495 Kg/jam
2. H2O yg menguap 18809.6249

H2O 18.0000 421.9028 7594.2495

7646.7895

H2O 18.0000 206.3503 3714.3047 26456.4144
C3H5NO 71.0000 212.6101 15095.3202
Total 418.9604 18809.6249
CRRSTALIZER
1. Umpan masuk

H2O 18.0000 206.3503 3714.3047
C3H5NO 71.0000 212.6101 15095.3202
Total 418.9604 18809.6249
Data kelarutan C3H5NO 30.0000 0c

= 215.5000 gr/100gr H2O
C3H5NO terlarut = 215.5000 3714.3047

99.5400
= 8041.3167 Kg/jam
C3H5NO padatan = 15095.3202 - 8041.3167

= 7054.0035 Kg/jam

H20 18.0000 206.3503 3714.3047
C3H5NO(aq) 71.0000 113.2580 8041.3167
C3H5NO(s) 71.0000 99.3522 7054.0035
Total 418.9604 18809.6249
CENTRIFUGE
1. Umpan masuk

H2O 18.0000 206.3503 3714.3047 in
C3H5NO(aq) 71.0000 113.2580 8041.3167 18809.6249
C3H5NO(s) 71.0000 99.3522 7054.0035
Total 418.9604 18809.6249
2. Komposisi air pencuci sebesar 20% umpan 7476.2297

H2O 18.0000 208.9958 3761.9250 22571.5499
3. Komposisi cake

H2O 18.0000 3.9189 70.5400
C3H5NO(s) 71.0000 98.3586 6983.4635
Total 102.2775 7054.0035

22571.5499
H2O 18.0000 411.4272 7405.6896
C3H5NO(aq) 71.0000 114.2515 8111.8567
525.6787 15517.5463
Rotary Dryer

H2O 18.0000 3.9189 70.5400
C3H5NO(s) 71.0000 98.3586 6983.4635
Total 102.2775 7054.0035

H2O 18.0000 1.9496 35.0928 7054.0035
C3H5NO(s) 71.0000 98.3586 6983.4635
Total 100.3082 7018.5563

H2O 18.0000 1.9693 35.4473
Total 1.9693 35.4473
EVAPORATOR
RYLONITRIL DAN H2O DENGAN PROSES HIDRASI KATALITIK
50.000 TON/TAHUN
/ H2O = 1 : 2 )
1.0000
1.0000
rho campuran volume
0.4913 1981.9991
0.0037 57.7811
0.4223 7663.0757
0.9173 9702.8558 L

= 1756.6050 Kg/jam
2184.3210
out
12787.9260
RECYCLE
EVAPORATOR
1. UMPAN MASUK
C3H3N 53.0000 213.3689
H2O 18.0000 414.3461
C3H5NO 71.0000 326.8616
954.5767

pada suhu 105.0000 oC
C3H5NO
S= 2.3000 T
388.0000 g/100 g H2O
AC 213.5282 H20 pelarut = 100.0000

388.0000
= 5981.2312
= 1476.9985
2. H2O yg menguap
H2O 18.0000 82.0555
3. C3H3N yg mengua= 159.0000

26456.4144 H2O 18.0000 332.2906
C3H5NO 71.0000 326.8616
659.1523
CRRSTALIZER
1. Umpan masuk
H2O 18.0000 332.2906
C3H5NO 71.0000 326.8616
in out 659.1523
18809.6249 18809.6249
Data kelarutan C3H5NO 30.0000
= 215.5000
C3H5NO terlarut = 215.5000

100.0000
= 12889.5531

= 10317.6237
H20 18.0000 332.2906
C3H5NO(aq) 71.0000 181.5430
C3H5NO(s) 71.0000 145.3186
659.1523
CENTRIFUGE
1. Umpan masuk
out H2O 18.0000 332.2906
22571.5499 C3H5NO(aq) 71.0000 181.5430
C3H5NO(s) 71.0000 145.3186
659.1523
3. Komposisi cake
H2O 18.0000 29.8668
C3H5NO(s) 71.0000 143.8655
173.7323
H2O 18.0000 302.4238
C3H5NO(aq) 71.0000 182.9962
485.4200
Rotary Dryer
H2O 18.0000 29.8668
C3H5NO(s) 71.0000 143.8655
173.7323
H2O 18.0000 2.8516
C3H5NO(s) 71.0000 143.8655
146.7171
H2O 18.0000 27.0152
27.0152
Kg/jam
11308.5542
7458.2297
23207.1769
41973.9608
keadaan larutan jenuh
+ 146.5000
/100 g H2O
23207.1769
Kg/jam
- 5981.2312
Kg/jam
Kg/jam
1476.9985
Kg/jam
Kg/jam in out
5981.2312 41973.9608 30824.4066
23207.1769
29188.4080
Kg/jam
5981.2312
23207.1769
29188.4080 in out
29188.4080 29188.4080
0c
gr/100gr H2O
5981.2312
Kg/jam
- 12889.5531
Kg/jam
Kg/jam
5981.2312
12889.5531
10317.6237
29188.4080
Kg/jam
5981.2312 in out
12889.5531
10317.6237 29188.4080 29188.4080
29188.4080
Kg/jam
537.6025
10214.4475
10752.0500
29188.4080
29188.4080
Kg/jam
5443.6287
12992.7294
18436.3580
Kg/jam
537.6025
10214.4475
10752.0500
Kg/jam
51.3289 10752.0500
10214.4475
10265.7764
Kg/jam
486.2736
486.2736
NERACA MASSA PABRIK ACRYLAMIDE DARI ACRYLONITRIL DAN H2O DENGAN PROSES HIDRASI KATALITIK
Neraca massa kapasitas = 50000 ton/tahun

= 5707.762557 kg/jam
Produk C3H5NO = 6887 kg/jam
faktor pengali = 0.828773422
REAKTOR

H2O 18 12.843565 231.18417
C3H3N 53 82.877342 4392.4991
95.720907 4623.6833
2. Umpan Segar H2O

Perbandingan
H20 18 165.75468 2983.5843
Komponen BM Kmol/jam Kg/jam Densitas Volume

H2O 18 178.59825 3214.7685 0.97777 3287.858
C3H3N 53 82.877342 4392.4991 0.748 5872.325
Cu 1564.5576
261.47559 9171.8253 9160.183
Rekasi
C3H3N + H2O -------------> C3H5NO
Konversi Xa = 0.97
(1-Xa) = 0.03
maka :
C3H3N = nAo (1-Xa)
= 82.877342 0.03
= 2.4863203 Kmol/jam
H2O = nBo - nAo Xa

= 178.59825 - 82.8773422 0.97 1
= 98.207227 Kmol/jam
C3H5NO = nCo+nAo Xa
= 0+ 82.8773422 0.97 1
= 80.391022 Kmol/jam

4. hasil reaksi
Komponen BM Kmol/jam Kg/jam Fraksi massa Densitas volume

H2O 18 98.207227 1767.7301 0.19273482 0.9777 1808.05
C3H3N 53 2.4863203 131.77497 0.014367366 0.748 176.1698
C3H5NO 71 80.391022 5707.7626 0.622314794 0.8573 6657.836
Cu 1564.5576 0.170583019
181.08457 9171.8253 8642.055 L
RDVF
Katalis yang diperlukan
1. Umpan masuk
H2O 18 98.207227 1767.7301 konsentrasi katalis
C3H3N 53 2.4863203 131.77497
C3H5NO 71 80.391022 5707.7626
CU 1564.5576
181.08457 9171.8253

1966.14

H2O 18 101.90917 1834.3651
Komponen BM Kmol/jam Kg/jam in out

H2O 18 4.57473 82.345139 11006.19
CU 1564.5576 11006.19
1646.9028

H2O 18 195.54167 3519.75
C3H3N 53 2.4863203 131.77497
C3H5NO 71 80.391022 5707.7626
9359.2875
EVAPORATOR
1. UMPAN MASUK
H2O 18 195.54167 3519.75
C3H3N 53 2.4863203 131.77497
C3H5NO 71 80.391022 5707.7626
9359.2875
2. Filtrat recycle
H2O 18 182.47869 3284.6164 0
C3H5NO 71 102.257 7260.2472 0
284.73569 10544.864

H2O 18 378.02036 6804.3664
C3H3N 53 2.4863203 131.77497
C3H5NO 71 182.64803 12968.01
563.1547 19904.151

pada suhu 105 oC
C3H5NO
S= 2.3 T + 146.5
388 g/100 g H2O
H20 pelarut = 100 12968.01 AC 511.2869
388
= 3342.2706 Kg/jam
H2O yg menguap = 6804.3664 - 3342.270565
= 3462.0958 Kg/jam
2. H2O yg menguap
H2O 18 192.33866 3462.0958

H2O 18 185.6817 3342.2706 19904.15 19904.15
C3H5NO 71 182.64803 12968.01
368.32972 16310.28
CRRSTALIZER
1. Umpan masuk

H2O 18 185.6817 3342.2706
C3H5NO 71 182.64803 12968.01
368.32972 16310.28 in out
16310.28 16310.28
= 215.5 gr/100gr H2O
C3H5NO terlarut = 215.5 3342.2706

100
= 7202.5931 Kg/jam
C3H5NO padatan = 12968.01 - 7202.593067

= 5765.4167 Kg/jam

H20 18 185.6817 3342.2706
C3H5NO(aq) 71 101.44497 7202.5931
C3H5NO(s) 71 81.203052 5765.4167
368.32972 16310.28
CENTRIFUGE
1. Umpan masuk

H2O 18 185.6817 3342.2706 in out
C3H5NO(aq) 71 101.44497 7202.5931 16310.28 16310.28
C3H5NO(s) 71 81.203052 5765.4167
368.32972 16310.28
3. Komposisi cake

H2O 18 3.2030093 57.654167
C3H5NO(s) 71 80.391022 5707.7626
83.594031 5765.4167

16310.28
H2O 18 182.47869 3284.6164
C3H5NO(aq) 71 102.257 7260.2472
284.73569 10544.864
Rotary Dryer

H2O 18 3.2030093 57.654167
C3H5NO(s) 71 80.391022 5707.7626
83.594031 5765.4167

H2O 18 1.5934569 28.682224 5765.417
C3H5NO(s) 71 80.391022 5707.7626
81.984479 5736.4448

H2O 18 1.6095524 28.971943
1.6095524 28.971943
EVAPORATOR
SES HIDRASI KATALITIK
= 1564557.64810095 gr
= 1564.557648101 Kg/jam
= 181.04 gr/L
RECYCLE
EVAPORATOR
1. UMPAN MASUK

C3H3N 53 128.3843 6804.366
H2O 18 189.7995 3416.391
C3H5NO 71 284.905 20228.26
603.0888 30449.01

pada suhu 105 oC
C3H5NO
S= 2.3 T + 146.5
388 g/100 g H2O
H20 pelarut = 100 20228.26
388
= 5213.468 Kg/jam
H2O yg menguap = 3416.391 - 5213.468
= -1797.08 Kg/jam
2. H2O yg menguap
H2O 18 -99.8376 -1797.08
3. C3H3N yg mengua= 159 Kg/jam

H2O 18 289.6371 5213.468 30449.01 23803.65
C3H5NO 71 284.905 20228.26
574.5422 25441.73
CRRSTALIZER
1. Umpan masuk

H2O 18 289.6371 5213.468
C3H5NO 71 284.905 20228.26
574.5422 25441.73 in out
25441.73 25441.73
= 215.5 gr/100gr H2O
C3H5NO terlarut = 215.5 5213.468

100
= 11235.02 Kg/jam
C3H5NO padatan = 20228.26 - 11235.02

= 8993.233 Kg/jam

H20 18 289.6371 5213.468
C3H5NO(aq) 71 158.2398 11235.02
C3H5NO(s) 71 126.6653 8993.233
574.5422 25441.73
CENTRIFUGE
1. Umpan masuk

H2O 18 289.6371 5213.468 in out
C3H5NO(aq) 71 158.2398 11235.02
C3H5NO(s) 71 126.6653 8993.233 25441.73 25441.73
574.5422 25441.73
3. Komposisi cake

H2O 18 26.03304 468.5948
C3H5NO(s) 71 125.3986 8903.3
151.4316 9371.895

25441.73
H2O 18 263.6041 4744.874
C3H5NO(aq) 71 159.5064 11324.96
423.1105 16069.83
Rotary Dryer

H2O 18 26.03304 468.5948
C3H5NO(s) 71 125.3986 8903.3
151.4316 9371.895

H2O 18 2.485567 44.7402 9371.895
C3H5NO(s) 71 125.3986 8903.3
127.8842 8948.041

H2O 18 23.54748 423.8546
23.54748 423.8546
NERACA MASSA PABRIK ACRYLAMIDE DARI ACRYLONITRIL DAN H2O DENGAN PROSES
REAKTOR
0

H2O 18 12.6662 227.9908
C3H3N 53 81.7325465754 4331.82497
94.3987 4559.8158
2. Umpan Segar H2O

Perbandingan
H20 18 150.798938272 2714.38089

H2O 18 163.4651 2942.3717
C3H3N 53 81.7325465754 4331.82497
Cu 1435.7180
245.1976 8709.9147
Rekasi
C3H3N + H2O -------------> C3H5NO
Konversi Xa = 0.99
(1-Xa) = 0.01
maka :
C3H3N = nAo (1-Xa)
= 81.7325465754 0.01
= 0.8173254658 Kmol/jam
H2O = nBo - nAo Xa

= 163.4651 - 81.73254658 0.99
= 82.5499 Kmol/jam
C3H5NO = nCo+nAo Xa
= 0+ 81.73254658 0.99
= 80.9152211096 Kmol/jam

4. hasil reaksi

H2O 18 82.5499 1485.8977 0.9777 0.5025
C3H3N 53 0.8173 43.3182 0.7480 0.0050
C3H5NO 71 80.9152 5744.9807 0.8573 0.4925
Cu 1435.7180
164.2824 8709.9147 1.0000
=
RDVF
1. Umpan masuk
H2O 18 82.5498720411 1485.8977
C3H3N 53 0.8173254658 43.3182497
C3H5NO 71 80.9152211096 5744.9807
CU 1435.71801
164.282418616 8709.91466

10451.897588
Komp BM Kmol/jam Kg/jam 3227.8806281
H2O 18 96.7768 1741.98293

H2O 18 4.1980 75.5641 10451.897588
CU 1435.71801
1511.28212

H2O 18 175.1287 3152.31652
C3H3N 53 0.8173254658 43.3182497
C3H5NO 71 80.9152211096 5744.9807
Total 256.8612 8940.6155
EVAPORATOR
1. UMPAN MASUK
H2O 18 175.1287 3152.31652
C3H3N 53 0.8173 43.3182497
C3H5NO 71 80.9152 5744.9807
Total 256.8612 8940.6155
2. Filtrat recycle
H2O 18 336.269929166 6052.85872 -18.2590
C3H5NO 71 93.3806626857 6630.02705 -20.000121101
Total 429.650591852 12682.8858

H2O 18 511.3986 9205.17525
C3H3N 53 0.8173254658 43.3182497
C3H5NO 71 174.295883795 12375.0077
Total 686.5118 21623.5012

pada suhu 105 oC
C3H5NO
S= 2.3 T + 146.5
388 g/95,47 g H2O 97.77
H20 pelarut = 95.47 12375.0077

388
= 3044.9536 Kg/jam
H2O yg menguap = 9205.1752 - 3044.9536
= 6160.2217 Kg/jam
2. H2O yg menguap
H2O 18 342.2345 6160.22167

6203.53991487

H2O 18 169.1641 3044.9536 21623.501246
C3H5NO 71 174.295883795 12375.0077
Total 343.4600 15419.9613
CRRSTALIZER
1. Umpan masuk

H2O 18 169.1641 3044.9536
C3H5NO 71 174.295883795 12375.0077
Total 343.4600 15419.9613

= 215.5 gr/100gr H2O
C3H5NO terlarut = 215.5 3044.95358

99.54
= 6592.1991 Kg/jam
C3H5NO padatan = 12375.0077495 - 6592.1991

= 5782.8087 Kg/jam

H20 18 169.1641 3044.9536
C3H5NO(aq) 71 92.8479 6592.1991
C3H5NO(s) 71 81.4480 5782.8087
Total 343.4600 15419.9613
CENTRIFUGE
1. Umpan masuk

H2O 18 169.1641 3044.9536 in
C3H5NO(aq) 71 92.8479 6592.1991 15419.961332
C3H5NO(s) 71 81.4480 5782.8087
Total 343.4600 15419.9613
18503.9536
2. Komposisi air pencuci sebesar 20% umpan
H2O 18 171.3329 3083.9923 6128.9458
3. Komposisi cake

H2O 18 3.2127 57.8281
C3H5NO(s) 71 80.6335 5724.9806
Total 83.8462 5782.8087
18503.953598
H2O 18 337.2843 6071.1178
C3H5NO(aq) 71 93.6624 6650.0272
Total 430.9467 12721.1449
18503.9536
Rotary Dryer

H2O 18 3.2127 57.8281
C3H5NO(s) 71 80.6335 5724.9806
Total 83.8462 5782.8087

H2O 18 1.5982637012 28.7687466 5782.8086643
C3H5NO(s) 71 80.6335292631 5724.98058
Total 82.2317929643 5753.74932

H2O 18 1.614407779 29.05934
Total 1.614407779 29.05934
EVAPORATOR
YLONITRIL DAN H2O DENGAN PROSES HIDRASI KATALITIK
50.000 TON/TAHUN
Neraca massa kapasitas = 50000 ton/tahun

= 5707.7625570776 kg/jam
Produk C3H5NO = 6983.4634992251 kg/jam
faktor pengali = 0.8173254658
/ H2O = 1 : 2 )
1
rho campuran volume
0.4913 1619.9383
0.0037 47.2259
0.4223 6263.2269
0.9173 7930.3911 L

= 1435.7180 Kg/jam
1785.3011810903
out
10451.897588432
RECYCLE
EVAPORATOR
1. UMPAN MASUK
C3H3N 53 173.6826
H2O 18 339.6909
C3H5NO 71 267.9582
781.3317

pada suhu 105 oC
C3H5NO
S= 2.3 T
388 g/100 g H2O
AC 176.0498678 H20 pelarut = 100

388
= 4903.36
= 1211.076
2. H2O yg menguap
H2O 18 67.28203
3. C3H3N yg mengua= 159

21623.5012464046 H2O 18 272.4089
C3H5NO 71 267.9582
540.3671
CRRSTALIZER
1. Umpan masuk
H2O 18 272.4089
C3H5NO 71 267.9582
in out 540.3671
15419.961331536 15419.96133
Data kelarutan C3H5NO 30
= 215.5
C3H5NO terlarut = 215.5

100
= 10566.74

= 8458.295
H20 18 272.4089
C3H5NO(aq) 71 148.8273
C3H5NO(s) 71 119.1309
540.3671
CENTRIFUGE
1. Umpan masuk
out H2O 18 272.4089
18503.9535978432 C3H5NO(aq) 71 148.8273
C3H5NO(s) 71 119.1309
540.3671
3. Komposisi cake
H2O 18 24.48454
C3H5NO(s) 71 117.9396
142.4241
H2O 18 247.9243
C3H5NO(aq) 71 150.0186
397.943
Rotary Dryer
H2O 18 24.48454
C3H5NO(s) 71 117.9396
142.4241
H2O 18 2.33772
C3H5NO(s) 71 117.9396
120.2773
H2O 18 22.14682
22.14682
Kg/jam
9205.175
6114.436
19025.03
34344.65
da keadaan larutan jenuh
+ 146.5
g/100 g H2O
19025.03
Kg/jam
- 4903.36
Kg/jam
Kg/jam
1211.076
Kg/jam
Kg/jam in out
4903.36 34344.65 25298.47
19025.03
23928.39
Kg/jam
4903.36
19025.03
23928.39 in out
23928.39 23928.39
0c
gr/100gr H2O
4903.36
Kg/jam
- 10566.74
Kg/jam
Kg/jam
4903.36
10566.74
8458.295
23928.39
Kg/jam
4903.36 in out
10566.74
8458.295 23928.39 23928.39
23928.39
Kg/jam
440.7217
8373.712
8814.434
23928.39
23928.39
Kg/jam
4462.638
10651.32
15113.96
Kg/jam
440.7217
8373.712
8814.434
sebesar 0,5 %
Kg/jam
42.07896 8814.434
8373.712
8415.791
Kg/jam
398.6427
398.6427
CU =
H2O = 4942.8713
C3H3N = 3767.2027 H2O = 6298.1699
8710.0740
H2O = 19604.6203
H2O = 3295.2476 CO(NH2)2 = 1235.7178
NH4NO3 = 4942.8713
3295.2476 CH6N4O3 = 8753.9207
34537.1302
R RDVF
H2O = 13469.0449
SiO2 = 3089.2946 H2O = 8325.7681
CO(NH2)2 = 1235.7178 CO(NH2)2 = 1235.7178
NH4NO3 = 4942.8713 NH4NO3 = 4942.8713
CH6N4O3 = 8753.9207 CH6N4O3 = 8753.9207
31490.8493 23258.2779
H2O = 162.5945
SiO2 = 3089.2946
3251.8890
Total massa masuk = 8710.0740 + 3295.2476 + 6298.17 +

= 22955.1471
Total massa keluar = 0.0000 + 11278.852 + 239.2344 +
= 16568.5917
H2O = 12712.9367
CO(NH2)2 = 1235.7178
NH4NO3 = 4942.8713
CH6N4O3 (aq) = 3728.6682
22620.1940
H2O = 11278.85 H2O = 4651.65559
EV SWC CF I
H2O = 8325.7681
CO(NH2)2 = 1235.7178
NH4NO3 = 4942.8713
CH6N4O3 (aq) = 3677.9080
CH6N4O3 (s) = 5076.0127
23258.2779
DR
H2O = 264.4870
CH6N4O3 (s) = 5025.2525
5289.7395
4651.6556
5050.5051
H2O = 239.23445
H2O = 25.2525
CH6N4O3 (s) = 5025.2525
5050.5051
k1 = 0.000472 L/gr.jam
k2 = 0.000454 L/gr.jam
CU = 181.04 gr/L
AN = 1.85 mol/L
H2O = 4.032 mol/L
VH2O = 3214.768 kg = 3288.092 kg/L
VAN = 4392.499 kg = 5872.325 kg/L
rho H2O = 0.9777 kg/L
RHO AN = 0.748 kg/L
fao = 82.87734 kmol/jam
ra = k1[Cu][AN]V(H2O) + K2[Cu][H2O]V(AN)
V(H2O) + V(AN)
0.000472 L/gr.jam 181.04 gr/L 1.85 mol/L 3288.092
3288.092
0.269188 mol/L jam 0.000269 kmol/Lj
V = Fao Xa 298642.4 kmol/jam

ra kmol/Lj
298642.4 L
78893.01 gal
39446.51 gal
L + 0.000454 L/gr.jam 181.04 gr/L 4.032 mol/L 5872.325 L
+ 5872.325 L
V = faox(xa1-xa0)
ra
(xa1-xa0) = fao
ra
xa1 - fao = xao
ra
0.97 82.87734 = 0
0.000269
-307878
T = 100 BM AN = 53 ra
m AN = 0.1 kg BM H2O = 18
m H2O = 0.1 kg xa = 0.99 debit
Ca = 0.001887 mol/L M = 2.944444
Cb = 0.005556 mol/L M-x = 1.954444 ra
M(1-x) = 0.029444
fao - fa1 -(-ra) v = 0 ln = 4.195356
fao - (fao - Faoxa) - (-ra) v = 0
fao xa - k cao(1-xa) (cbo-ca0xa) v = 0
k= ca0xa
cao(1-xa) (cbo-caoxa) k = 1 x ln M-x
(M-1) Cao t M(1-X)
k = 0.365075 L 1/(M-1)Ca = 68.14286
mol jam = 285.8835 lt/kgmol jam
v fao xa Volume = Fv . Xa
ra Cao.k(1-Xa) (M-Xa)
82000 0.99 811545.9
2.54E-08
3.2E+12 0.010542 8555.585
811545.9
= k ca ca ca = 1.886792E-05
= 2.54012E-08 cb = 0.003687631
= 8642.005
0.001810098
V 8918.086815
Data
m AN = 0.007 kg rho AN = 0.748
m H2O = 0.093 kg rho H2O = 0.9777
BM AN = 53 kg/kmol V AN = 0.009358
BM H2O = 18 kg/kmol V H2O = 0.095121
T = 110 C 0.104479 L
t tinggal = 8 jam
xa = 0.99
perhitungan
Fao = 0.000132 kmol
Fbo = 0.005167 kmol
Ftotal
V AN = 0.009358 L
V H2O = 0.095121 L
V TOT = 0.104479 L
Cao = 0.001264
Cbo = 0.049451
M = 39.11905
k = 1 x ln (M-X)
(M-1) Cao t M(1-X)
= 1 ln 38.1290476
38.11905 0.001264 8 0.39119048
= 2.594041 x 4.57953708
= 11.87951 lt
kgmol jam
keluar reaktor
Data massa rho volume mol fraksi mol rho campuran

AN 4392.5 0.748 5872.326 82.8773585 0.31696 0.237086
H2O 3214.768 0.9777 3288.092 178.598222 0.68304 0.667808
9160.419 261.475581 0.904894
Cao = massa = 0.00904733 0.009047

Fv
Cbo = massa 0.019497
Fv
M baru = 2.15497
v = Fv Xa = 9160.41867 0.99
k Cao (1-Xa) (M-Xa) 146.071 0.009047
= 589048.686
V = Cao Xa Fv
k Ca02 (1-Xa) M-xa
= 0.009047 0.99 9160.419
2337 8.185424E-05 0.01 2.15497
= 36816.74
0.01 1.16497
REAKTOR
1. Menentukan Harga k
Data yg diketahui :
m H2O = 0.093 kg
m AN = 0.007 kg
BM H2O = 18 kg/kmol
BM AN = 53 kg/kmol
Xa = 0.99
rho H2O = 0.9777 kg/L
rho AN = 0.748 kg/L
Data yg dihitung :
V AN = 0.009358289
V H2O = 0.095121203
V total = 0.104479492
Cao = 0.001264128
Cbo = 0.049451491
M = 39.11904762
- ra = - dca = k
dt
Cao dXa = k
dt
Cao dXa = k
dt
dXa = k
dt
k = 1
Cao
Dengan menggunakan penyelesaian simson 1/3
beda = delta x/n 0.2475
iterasi Xa faktor i I
0 0 1 0.025563 0.0255629945
1 0.2475 4 0.034187 0.1367482116
2 0.495 2 0.051269 0.1025370536
3 0.7425 4 0.101194 0.4047779581
4 0.99 2 2.622672 5.2453447565
5.9149709742
k = 1x
Cao x
= 1
0.0012641
= 772.05003
Menghitung Optimasi reaktor
Umpan Masuk Reaktor

Komponen BM Kmol/jam Kg/jam Densitas Volume (L/jam)
H2O 18 178.59825 3214.769 0.97777 3287.857573867
C2H3N 53 82.877342 4392.499 0.748 5872.325034759
Cu 1564.558
Jumlah 261.475592 7607.268 9160.182608626
Cao = 0.009047564 M = 2.1549708

Cbo = 0.019497237
Vl = Fv x Xa
Cao x k x (1-Xa) x (M-Xa)
= 9160.183 0.95
0.009047564 772.05 0.01 2.1334210682
= 58394.78075 L
Optimasi 2 reaktor
Xa1 = Xa2 - k Cao (1-Xa2)

Fv
Xa0 = Xa1 - k Cao (1-Xa1)

Fv
ca cb
Cao(1-Xa) (Cbo-Cao Xa)
Cao^2(1-Xa) (M-Xa)
Cao(1-Xa) (M-Xa)
dXa
(1-Xa) (M-Xa) dt
Ix delta X
t
5.9149709742 0.2475
0.5 3
liter
kmol jam
(M-Xa2) V
(M-Xa1) V

Neraca Massa Fix

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NERACA MASSA PABRIK ACRYLAMIDE DARI ACRYLONITRIL DAN H2O DENGAN PROSES HIDRA

KAPASITAS 50.000 TON/TAHUN

I. NERACA MASSA BASIS

1. Umpan Segar Acrylonitril (Kemurnian 95% berat)

Komponen BM Kmol/jam Kg/jam

2. Umpan Segar H2O

3. Total umpan masuk reaktor (Basis 100 Kmol/jam ; C3H3N / H2O = 1 : 2 )

Komponen BM Kmol/jam Kg/jam rho rho campuran

C3H3N + H2O -------------> C3H5NO

H2O = nBo - nAo Xa

Komponen BM Kmol/jam Kg/jam rho Fraksi mol

Kebutuhan air pencuci sebesar 20 % terhadap umpan

2. Umpan air pencuci

Komp BM Kmol/jam Kg/jam

kadar air dalam CU sebesar 5%

3. Hasil penyaringan fase pada (cake) (recycle)

Komponen BM Kmol/jam Kg/jam fraksi mol in

Komponen BM Kmol/jam Kg/jam

Komponen BM Kmol/jam Kg/jam fraksi mol

Diharapkan C3H5NO keluar pada keadaan larutan jenuh

H20 pelarut = 95.47 6983.4635

3. C3H3N yg menguap = 52.5400 Kg/jam

3. Komposisi hasil penguapan

Komponen BM Kmol/jam Kg/jam in

Komponen BM Kmol/jam Kg/jam

Data kelarutan C3H5NO 30 0c

C3H5NO terlarut = 215.5 1718.32799

C3H5NO padatan = 6983.4635 - 3720.1093

2. Komposisi hasil kristalisasi

Komponen BM Kmol/jam Kg/jam

Komponen BM Kmol/jam Kg/jam

2. Komposisi air pencuci sebesar 20% terhadap umpan

Komponen BM Kmol/jam Kg/jam

4. Komposisi filtrat 10442.14979

1. Umpan masuk dari CF

Komponen BM Kmol/jam Kg/jam

Kadar air dalam produk akhir sebesar 0,5 %

2. Komposisi hasil akhir (produk)

Komponen BM Kmol/jam Kg/jam

3. Komposisi air menguap

Komponen BM Kmol/jam Kg/jam

fraksi mol Volume

Katalis yang diperlukan = 1756605.01474222 gr

konsentrasi katalis = 181.04 gr/L

Diharapkan C3H5NO keluar pada keadaan larutan jenuh

AC 15861.6472 H20 pelarut = 100

3. C3H3N yg mengua= 159

3. Komposisi hasil penguapan

out Komponen BM Kmol/jam

C3H5NO terlarut = 388

C3H5NO padatan = 10736.21

2. Komposisi hasil kristalisasi

1. Umpan masuk dari CF

Kadar air dalam produk akhir sebesar 0,5 %

2. Komposisi hasil akhir (produk)

3. Komposisi air menguap

da keadaan larutan jenuh

I. NERACA MASSA BASIS

Komponen BM Kmol/jam Kg/jam

2. Umpan Segar H2O

3. Total umpan masuk reaktor (Basis 100 Kmol/jam ; C3H3N / H2O = 1 : 2 )

Komponen BM Kmol/jam Kg/jam

C3H3N + H2O -------------> C3H5NO

H2O = nBo - nAo Xa