4.

DATA DAN PERHITUNGAN

a) Pembuatan dapar sitrat pH= 5,6 dengan kapasitas dapar = 0.01 sebanyak 250ml :

[]
pH =pKa3 + log
[]
[]
5,6 = 6,4 + log
[]
[]
log = - 0,8
[]
[G] = 0,1584893192[A]

pH =-log [H3O+]
5,6 = - log [H3O+]
[H3O+] = 2,511886432 x 10-6 M

pKa = -log Ka
6,4 = - log ka
Ka = 3,981071706 x 10-7M

= 2,303. C .Ka. [H3O+]

Ka+ [H3O+]2
0,01 = 2.303.C [ 3.981071706 . 10-7 x 2,511886432. 10-6]
[( 3.981071706 . 10-7 x 2,511886432. 10-6)]2
C = 0,03676970372

[G]+[A] =C
0,1584893192 [A]+[A] = 0,03676970372
1,1584893192 [A] = 0,03676970372
[A] = 0,03173935496 M
[G] = 0,00503034876 M

Reaksinya :
H3. Sitrat + NaOH NaH2 Sitrat + H2O
Mula : 0,03676970372 0,03676970372
Bereaksi : 0,03676970372 0,03676970372 0,03676970372
Sisa : - - 0,03676970372

NaH2. Sitrat + NaOH Na2H Sitrat + H2O

Mula : 0,03676970372 0,03676970372
Bereaksi : 0,03676970372 0,03676970372 0,03676970372
Sisa : - - 0,03676970372
 Na2H. Sitrat + NaOH Na3. Sitrat + H2O
Mula : 0,03676970372 0,00503034876
Bereaksi : 0,00503034876 0,00503034876 0,00503034876
Sisa : 0,03173935496 - 0,00503034876

H3. Sitrat = 0.03676970372 M

X 250 ml

= 9,19242593 mmol/250 ml

X Mr ( 210,14)

= 1.931,696385 mg = 1,9316 g

NaOH = (0,03676970372) + (0,03676970372) + ( 0,00503034876 )

= 0,078569756 M

X 250 ml

= 19,64243905 mmol/250 ml

X Mr ( 40)

= 785,697562 mg = 0,7857 g

b) Penimbangan :
Berat botol timbang + asam sitrat =
Berat botol timbang =
Berat asam sitrat =

Berat botol timbang + NaOH =

Berat botol timbang =
Berat NaOH =

Berat botol timabng + vitamin C =

Berat botol timbang =
Berat vitamin C =

c) Hasil Pengamatan Absorban

Berat vitamin C yang ditimbang = 0,048 g
Dalam 100ml terdapat 48 mg vitamin C, jadi dalam 1000ml atau 1 L terdapat 480 mg vitamin C
 2
Hitung BPJ-nya = x 480 = 9,6 BPJ
100
Kadar
8
Kadar t8 = x BPJ
15

15
Kadar t15 = x BPJ
8

0,3485
- 40OC > t8 = x 9,6 = 9,633
0,3473
0,3473
> t15 = x 9,6 = 9,567
0,3485
0,3555
- 45OC > t8 = x 9,6 = 9,033
0,3778
0,3778
> t15 = x 9,6 = 10,202
0,3555
0,3790
- 50OC > t8 = x 9,6 = 10,506
0,3463
0,3463
> t15 = x 9,6 = 8,772
0,3790
0,3751
- 55OC > t8 = x 9,6 = 10,514
0,3425
0,3425
> t15 = x 9,6 = 8,766
0,3751

d) Penentuan Orde Reaksi

Orde O

K40OC > t8 =

9,69,633
= = - 4,125 x 10-3 = -0,004125
8
9,69,567
> t15 = = 2,2 x 10-3 = 0,0022
15

9,69,033
K45OC > t8 = = 0,070875
8
 9,610,202
> t15 = = -0,04013
15

9,610,506
K50OC > t8 = = -0,11325
8

9,68,772
> t15 = = 0,0552
15

9,610,514
K55OC > t8 = = -0,11425
8

9,68,766
> t15 = = 0,0556
15

Orde 1
2,303
K40OC > t8 = log

2,303 9,6
= log
8 9,633

= 0,287875 . log 0,9965

= 0,287875 . 1,523 x 10-3

= 0,4384 x 10-3 = 0,0004384

2,303 9,6
> t15 = log
8 9,567

= 0,1535 . log 1,003

= 0,1535. 1,301 x 10-3

= 0,199 x 10-3 = 0,000199

2,303 9,6
K45OC > t8 = log
8 9,033

= 0,287875 . log 1,063

= 0,287875 . 0,0265

= 7,63 x 10-3 = 0,00763

 2,303 9,6
> t15 = log
8 10,202

= 0,1535 . log 0,94099

= 0,1535. -0,02641499

= -0,0040547

2,303 9,6
K50OC > t8 = log
8 10,506

= 0,287875 . log 0,9137

= 0,287875 . -0,0392

= -0,01128

2,303 9,6
> t15 = log
8 8,772

= 0,1535 . log 1,094

= 0,1535. 0,039

= 5,9865 x 10-3 = 0,0059865

2,303 9,6
K55OC > t8 = log
8 10,514

= 0,287875 . log 0,91306

= 0,287875 . -0,0395

= -0,01137

2,303 9,6
> t15 = log
8 8,766

= 0,1535 . log 1,096

= 0,1535. 0,0394

= 6,0479 x 10-3 = 0,0060479

 Orde 2

K40OC > t8 =
(.).

9,69,633 0,023
= = = 0,0000446
(9,6.9,633).8 739,8144

9,69,567 0,033
> t15 = = = 0,00002379
(9,6.9,567).15 1387,152

9,69,033 0,567
K45OC > t8 = = = 0,00081732
(9,6.9,033).8 693,7344

9,610,202 0,602
> t15 = = = -0,00040978
(9,6.10,202).15 1469,088

9,610,506 0,906
K50OC > t8 = = = -0,00112287
(9,6.10,506).8 806,8608

9,68,772 0,828
> t15 = = = 0,00065549
(9,6.8,772).15 1263,168

9,610,514 0,914
K55OC > t8 = = = -0,00113192
(9,6.10,514).8 807,4752

9,68,766 0,834
> t15 = = = 0,0006607
(9,6.8,766).15 1262,304

K rata-rata orde 0
t8 = -0,004125+0,070875+(-0,11325)+(-0,11425) = -0,16075
t15 = 0,0022+(-0,04013)+0,0552+0,0556 = 0,07287
15 0,07287
K rata-rata = x 100% = x 100% = -45,33%
8 0,16075
K rata-rata orde 1
t8 = 0,0004384+0,00763+(-0,01128)+(-0,01137) = -0,0145816
t15 = 0,000199 +(-0,0041248)+(-0,0040547)+0,0060479 = -0,0018552
15 0,0018552
K rata-rata = x 100% = x 100% = 12,772%
8 0,0145816
K rata-rata orde 2
t8 = -0,0000446+0,00081732+(-0,00112287)+(-0,00113192) = -0,00148207
t15 = 0,00002379+(-0,00040978)+0,00065549+0,0006607= 0,0009302
15 0,0009302
K rata-rata = x 100% = x 100% = -62,763%
8 0,00148207
Tabel
Orde t K40OC K45OC K50OC K55OC K Rata-rata
8 -0,004125 0,070875 -0,11325 -0,11425 -0,0401875
Nol
15 0,0022 -0,04013 -0,0552 0,0556 0,0182175
8 0,0004384 0,00763 -0,01128 -0,01137 -0,0036454
Satu
15 0,000199 -0,0040547 0,0059865 0,0060479 -0,0004638
8 0,0000446 0,00081732 -0,00112287 -0,00113192 -0,00037052
Dua
15 0,00002379 -0,00040978 0,00065549 0,0006607 0,00023255

Kurva
T(OC) T(OK) 1/T K log K log K+5
8 0,0000446 -4,350665 0,649335
40 40+273=313 1/313=0,00319488
15 0,00002379 -4,623605 0,376395
8 0,00081732 -3,0876078 1,9123922
45 45+273=318 1/318=0,003144654
15 -0,00040978 0,999056891 5,99056891
8 -0,00112287 0,997417835 5,997417835
50 50+273=323 1/323=0,0003095975
15 0,00065549 -3,183433929 1,816566
8 -0,00113192 0,997397 5,997397
55 55+273=328 1/328=0,00304878
15 0,0006607 -3,1799956 1,8200044