NAMA : 1.

GENTA HUDA FAUZAN (I0520037)

2. TEGAR SATRIYO PRIBADI (I0520108)

NERACA MASSA PRARANCANGAN PABRIK AMIL ALKOHOL dari AMIL KLORIDA DAN SODIUM HIDR

KAPASITAS 40000 TON/TAHUN

Data Komponen
Komponnen Rumus Molekul TD BM (kgkmol)
Amil Klorida C5H11Cl 106.0 106.617
Sodium Hidroksida NaOH 135.0 39.910
Sodium Oleat NaC18H33O2 - 304.440
Air H2O 100.0 18.020
Amil Alkohol C5H11OH 137.9 88.174
Natrium Klorida NaCl - 58.353
Amilen C5H10 38.500 70.154

Perhitungan Laju Alir produk

Kapasitas 40000.000 ton/tahun
Hari kerja 350.000 hari/tahun
Jam kerja 24.000 jam/hari
Produksi 4761.905 kg/jam

Spesifikasi bahan baku %Berat

Amil Klorida
Kemurnian 0.980 Impuritas (air) 0.02
Sodium Hidroksida
Kemurnian 0.480 Impuritas (Air) 0.520

Rasio mol bahan baku masuk reaktor

Amil Klorida 1.000
Sodium hidroksida 1.000
Basis Perhitungan 7381.244 kg/jam amil klorida

Arus 1 (Bahan Baku Amil Klorida)

Komponen Fraksi berat kg/jam kmol/jam
Amil Klorida 0.980 7381.244 69.232
Air 0.020 150.638 8.359
Jumlah 1.000 7531.882 77.591

Arus 2 (Bahan baku katalis)

Komponen kg/jam kmol/jam Fraksi mol
Sodium Oleat 5269.227 17.308 1.000
jumlah 5269.227 17.308 1.000

Arus 3 (Hasil Mixing)

Komponen Fraksi berat kg/jam kmol/jam
Amil Klorida 0.577 7381.244 69.232
Sodium Oleat 0.412 5269.227 17.308
Air 0.012 150.638 8.359
Jumlah 1.000 12801.109 94.899

Arus 4 (Air pengencer NaOH)

Komponen kg/jam kmol/jam Fraksi mol
Air 34537.978 1916.647 1.000
jumlah 34537.978 1916.647 1.000

Arus 5 (Bahan Baku Sodium Hidroksida)

Komponen Fraksi berat kg/jam kmol/jam
Kemurnian 0.480 5526.076 138.463
Impuritas (Air) 0.520 5986.583 332.219
Jumlah 1.000 11512.659 470.682

Arus 6 (Hasil Pengenceran)

Komponen Fraksi Berat kg/jam kmol/jam
Sodium Hidroksida 0.120 5526.076 138.463
Air 0.880 40524.561 2248.866
Jumlah 1.000 46050.637 2387.329

1. Reaktor

Fresh Feed Reaktor

Komponen Fraksi berat kg/jam kmol/jam
Amil Klorida 0.125 7381.244 69.232
Sodium Hidroksida 0.094 5526.076 138.463
Air 0.691 40675.198 2257.225
Sodium Oleat 0.090 5269.227 17.308
Jumlah 1.000 58851.746 2482.228

Reaksi Reaktor 1 ;
Reaktan Pro
komponen
C5H11Cl NaOH C5H11OH
mula-mula 69.232 138.463 0.000
reaksi 47.339 47.339 47.339
sisa 21.893 91.125 47.339

Arus 7 produk dari Reaktor 1

komponen Fraksi Berat kg/jam kmol/jam
C5H11Cl 0.039 2299.139 21.565
NaOH 0.062 3623.680 90.796
C5H11OH 0.071 4174.024 47.339
NaCl 0.047 2781.522 47.667
C5H10 0.000 23.038 0.328
H2O 0.691 40681.116 2257.554
Sodium Oleat 0.090 5269.227 17.308
jumlah 1.000 58851.746 2482.557

Feed Reaktor 2
komponen Fraksi Berat kg/jam kmol/jam
C5H11Cl 0.039 2299.139 21.565
NaOH 0.062 3623.680 90.796
C5H11OH 0.071 4174.024 47.339
NaCl 0.047 2781.522 47.667
C5H10 0.000 23.038 0.328
H2O 0.691 40681.116 2257.554
Sodium Oleat 0.090 5269.227 17.308
jumlah 1.000 58851.746 2482.557

Reaksi Reaktor 2 ;
Reaktan Pro
komponen
C5H11Cl NaOH C5H11OH
mula-mula 21.565 90.796 47.339
reaksi 14.745 14.745 14.745
sisa 6.819 76.051 62.084
Produk dari Reaktor 2
komponen Fraksi Berat kg/jam kmol/jam
C5H11Cl 0.012 711.055 6.669
NaOH 0.051 3029.209 75.901
C5H11OH 0.093 5474.166 62.084
NaCl 0.062 3650.706 62.562
C5H10 0.001 33.563 0.478
H2O 0.691 40683.819 2257.704
Sodium Oleat 0.090 5269.227 17.308
jumlah 1.000 58851.746 2482.707

DEKANTER

Perbandingan Zat Organik Zat Anorganik

0.093 0.907

Top 75.778
Bottom 737.898
Amyl Alcohol (aquesous) Total 813.676

Tabel Input Dekanter Solubility Organic Material

Komponen Input Solubility (Organic)
Amylene 33.563 0.000
Amyl Chloride 711.055 0.000
Amyl Alcohol 5474.166 2%
Sodium Oleate 5269.227 (inorganic)
NaCl 3650.706 (inorganic)
NaOH 3029.209 (inorganic)
Water 40683.819 (inorganic)
Total 58851.746

Output Dekanter
Komponen Light Liquid Heavy Liquid
Amylene 33.563 0.000
Amyl Chloride 711.055 0.000
Amyl Alcohol 4736.267 737.898
Sodium Oleate 0.000 5269.227
NaCl 0.000 3650.706
NaOH 0.000 3029.209
Water 3788.900 36894.920
Total 5480.886 49581.960

Resume NM Dekanter
Output
Komponen Input 8 9
Amylene 33.563 33.563 0.000
Amyl Chloride 711.055 711.055 0.000
Amyl Alcohol 5474.166 4736.267 737.898
Sodium Oleate 5269.227 0.000 5269.227
NaCl 3650.706 0.000 3650.706
NaOH 3029.209 0.000 3029.209
Water 40683.819 3788.900 36894.920
Subtotal 58851.746 9269.786 49581.960
Total 58851.746

Menara Distilasi

Spesifikasi Produk 4761.905 kg/jam

Spesifikasi Produk (Sebagai Bottom)
Komponen Rasio (%)
Amyl Alcohol 0.985
Amyl Chloride 0.01
Water 0.005

Fraksi MD
Output
Komponen Input Distillate Bottom
Amylene 33.563 33.563 0.000
Amyl Chloride 711.055 663.436 47.619
Amyl Alcohol 4736.267 45.791 4690.476
Water 3788.900 3765.090 23.810
Subtotal 4507.881 4761.905
Total 9269.786 9269.786

OPTIMASI JUMLAH REAKTOR

Menghitung nilai Fv dan Cao

Komponen A B n
C5H11Cl 0.30284 0.2695 0.2804
NaOH 0.19975 0.09793 0.25382
C5H11OH 0.26923 0.2673 0.2506
NaCl 0.22127 0.10591 0.37527
C5H10 0.23787 0.26648 0.2905
H2O 0.3471 0.274 0.28571
Sodium Oleat
Total

Komponen Laju Alir Fraksi Rho

C5H11Cl 7381.244 0.112 0.328
NaOH 5526.076 0.084 2.040
C5H11OH 4174.024 0.063 1.007
NaCl 2781.522 0.042 0.728
C5H10 23.038 0.000 0.240
H2O 40681.116 0.618 0.393
Sodium Oleat 5269.227 0.080 0.000
Total 65836.248 1.000 4.737

1/rho 2.076
Rho Campuran 0.482 g/ml
481.765 kg/m3
FV Ft/Rhocampuran
2.278 m3/menit

Menghitung Cao
Cao Mol mula mula Amil Klorida/Fv
0.507 kmol/m3
506.612 mol/m3

Trial error optimasi reaktor

Xa 0.684
k1 0.03170 /menit k2
Fv 2.278 m3/menit
Cao 506.612 mol/m3
Untuk 1 Reaktor
Xa1 0.684
Ca1 Cao(1-Xa1)
160.205 mol/m3 t
Xa Total Ca0-Ca1/Ca0
0.684 sama

V1 Fv/(k1+k2)*(1-x)
221.613 m3
V Total 221.613 m3 V Overdesign

Penentuan Volume
Xa2 0.684
k1 0.03170 /menit k2
Fv 2.278 m3/menit
Cao 506.612 mol/m3
RIDA DAN SODIUM HIDROKSIDA

AHUN

C 12.011
H 1.010
Cl 35.453
Na 22.900
O 16.000

,
 0.000

Fraksi mol
0.892
0.108
1.000

Fraksi mol
0.730
0.182
0.088
1.000
46050.637 40524.561
34537.978

0.120

Fraksi mol
0.294
0.706
1.000

Fraksi mol
0.058
0.942
1.000

fraksi mol
 0.028
0.056 58851.746
0.909
0.007
1.000

0.684
Produk Reaksi
NaCl
komponen
0.000
47.339 mula-mula
47.339 reaksi
sisa

fraksi mol
0.009
0.037
0.019
0.019
0.000
0.909
0.007
1.000

fraksi mol
0.009
0.037
0.019
0.019
0.000
0.909
0.007
1.000

Konversi : 0.684 Reaksi

Produk
komponen
NaCl
47.667 mula-mula
14.745 reaksi
62.412 sisa
 fraksi mol
0.003
0.031
0.025
0.025
0.000
0.909
0.007
1.000

ty Organic Material
LK in Bottom 0.01
HK in distilate 0.0101580509746698
 453.15 K

Tc Rho
568 0.328219284121485
2820 2.03972225058715
586.15 1.0072203516648
3400 0.728255655243185
464.78 0.240188466555152
647.13 0.393438943726063

4.737

Fraksi/Rho
0.342
0.041
0.063
0.058
0.001
1.571
#DIV/0!
2.076

0.00080 /menit
 Xa(Cao)/k1(Cao(1-X))+k2(Cao.Xa)
66.532 menit 1.109

243.774

entuan Volume dan Jumlah Reaktor Optimum

0.00080 /menit
t1
Xa1
-ra1
t2
Xa2
Ca1
-ra2
Ca2
Xa Total

V1
V2
Vtotal
dtau
dv

2014
Harga USD
Volume
2024

Jumlah Reaktor
1
2
3
 Rasio
Amil Klorida : Sodium Hidroksida
1.000 : 2.000
 Reaktan Produk
C5H11Cl NaOH C5H10 NaCl
21.893 91.125 0.000 0.000
0.328 0.328 0.328 0.328
21.565 90.796 0.328 0.328

klorid 21.893 2334.151

naoh 91.125 3636.786
amilen 0.000 0.000
nacl 0.000 0.000
air 0.000 0.000
5970.938

Reaktan Produk
C5H11Cl NaOH C5H10 NaCl
6.819 76.051 0.000 0.000
0.150 0.150 0.150 0.150
6.669 75.901 0.150 0.150
RESUME NERACA MASSA

Input
Komponen
1 2 4

C5H11Cl 7381.244 0 0
NaOH 0 0 0
NaC18H33O2 0 5269.227 0
H2O 150.638 0 34537.978
C5H11OH 0 0 0
NaCl 0 0 0
C5H10 0 0 0
Total 58851.746
 Dua Reaktor
21.039
0.684
16.465
21.039
0.684
160.205
5.207
50.661
0.900

47.919 52.711
47.919 52.711
105.422
0.000
0.000

576.1
$ 459,200.00
4000 gallons
738

V m3 V Total m3 Harga 1 Reaktor (USD) Harga Total Reaktor (USD)

243.774 243.774 $ 3,116,358.05 $ 3,116,358.05
52.711 105.422 $ 1,243,351.83 $ 1,884,568.96
19.400 58.199 $ 682,543.69 $ 1,319,481.32
 Jumlah vs harga total
$3,500,000.00

$3,000,000.00

$2,500,000.00

$2,000,000.00

$1,500,000.00

$1,000,000.00

$500,000.00

$-
0 2

Jumlah vs harga total

Rasio
Sodium Hidroksida : Sodium Oleat
2.000 0.25000
 0.015

0.000
H2O
0.000
0.328
0.328

21.565 2299.139
90.796 3623.680
0.328 23.038
0.328 19.163
0.328 5.918
5970.938

0.022

H2O
0.000
0.150
0.150
 Trial Tdew Point

Output

5 9 11 12

0 0 663.436 47.619
5526.076 3029.209 0 0
0 5269.227 0 0
5986.583 36894.920 3765.090 23.810
0 737.898 45.791 4690.476
0 3650.706 0 0
0 0 33.563 0.000
58851.746
 Tiga Reaktor
t1 7.743
Xa1 0.252
-ra1 16.465
t2 7.743
Xa2 0.252
Ca1 379.121
-ra2 12.321
Ca2 283.713
t3 7.743
Xa3 0.252
-ra3 9.221
Ca3 212.315

Xa Total 0.581

19.400 V1 17.636 V1-V2 0.000

19.400 V2 17.636 V2-V3 0.000
19.400 V3 17.636 T3-T2 0.000
V Total 58.199 T2-T1 0.000

V (gallons) V total (gallons)

64397.889 64397.889
13924.602 27849.203
5124.799 15374.398 1.000
harga total

2 4

h vs harga total
ga Reaktor
Kapasitas panas (Cp), J/mol.K
Formula =
Formula =
Formula =
dengan,
Cp
T
A,B,C,D

Heat Capacity Coefficient of Liquids

Komponen
Amil Klorida
Sodium Hidroksida
 Sodium Oleat
Air
Amil Alkohol
Natrium Klorida
Amilen

MIXER M-100
Panas Masuk
Arus 1 (Bahan baku amil klorida)
Q1 Q2 T umpan
Komponen
Amil Klorida
Sodium Hidroksida
Sodium Oleat
Air
M
Amil Alkohol
Natrium Klorida
Amilen
Total

Q3 Panas Keluar
Arus 3
T umpan
Komponen
Amil Klorida
Sodium Hidroksida
Sodium Oleat
Air
Amil Alkohol
Natrium Klorida
 Amilen
Total

Tabel Neraca Panas MIX-100

Komponen

Amil Klorida
Sodium Hidroksida
Sodium Oleat
Air
Amil Alkohol
Natrium Klorida
Amilen
Subtotal
Total

MIXER M-101
Panas Masuk
Arus 4 (Pengencer NaOH)
Q4 Q5
T umpan
Komponen
Amil Klorida
Sodium Hidroksida
Sodium Oleat
M Air
Amil Alkohol
Natrium Klorida
Amilen
Total

Q6 Panas Keluar
Arus 6
 T umpan
Komponen
Amil Klorida
Sodium Hidroksida
Sodium Oleat
Air
Amil Alkohol
Natrium Klorida
Amilen
Total

Tabel Neraca Panas MIX-100

Komponen

Amil Klorida
Sodium Hidroksida
Sodium Oleat
Air
Amil Alkohol
Natrium Klorida
Amilen
Subtotal
Total

REAKTOR R-100
a. Panas Input
Arus 3'
T umpan
Q3 Q6 Komponen
Amil Klorida
Sodium Hidroksida
Sodium Oleat

R
 Air
QReaksi Amil Alkohol
R QPendingin
Natrium Klorida
Amilen
Total

b. Panas reaksi
Q7 T reaksi
Komponen
Amil Klorida
Sodium Hidroksida
Sodium Oleat
Air
Amil Alkohol
Natrium Klorida
Amilen
Total

Reaksi utama

Keterangan

Mula - mula
reaksi
sisa

Reaksi
Komponen
Amil Klorida
Sodium Hidroksida
Sodium Oleat
Air
Amil Alkohol
Natrium Klorida
Amilen
Total

c. Panas output
T output
Komponen
Amil Klorida
Sodium Hidroksida
Sodium Oleat
Air
Amil Alkohol
Natrium Klorida
Amilen
Total
Panas masuk + panas reaksi
Beban pendingin

Tabel NP R-100

Komponen

Amil Klorida
Sodium Hidroksida
Sodium Oleat
Air
Amil Alkohol
Natrium Klorida
Amilen
Subtotal
Total

R-101
 a. Panas Input
Arus 7
Q7 Komponen
Amil Klorida
Sodium Hidroksida
Sodium Oleat
Air
Amil Alkohol
QReaksi R QPendingin
Natrium Klorida
Amilen
Total

b. Panas Reaksi
Q8 Keterangan

Mula - mula
reaksi
sisa

Panas Reaksi
Komponen
Amil Klorida
Sodium Hidroksida
Sodium Oleat
Air
Amil Alkohol
Natrium Klorida
Amilen
Total

Panas Keluar
Komponen
 Amil Klorida
Sodium Hidroksida
Sodium Oleat
Air
Amil Alkohol
Natrium Klorida
Amilen
Total
Panas masuk + panas reaksi
Beban pendingin

Tabel NP R-101
Komponen
Amil Klorida
Sodium Hidroksida
Sodium Oleat
Air
Amil Alkohol
Natrium Klorida
Amilen
Total

DEKANTER (S-100)
Input (Arus 8')
Q8 T
Komponen
Amil Klorida
Sodium Hidroksida
Sodium Oleat
Air
D
Amil Alkohol
Natrium Klorida
D

Amilen
Total

Q9 Output
Light Liquid (Arus 9)
T
Komponen
Amil Klorida
Sodium Hidroksida
Sodium Oleat
Air
Amil Alkohol
Natrium Klorida
Amilen
Total

Tabel NP S-100

Komponen

Amil Klorida
Sodium Hidroksida
Sodium Oleat
Air
Amil Alkohol
Natrium Klorida
Amilen
Subtotal
Total

MENARA DISTILASI (T-100)

Menentukan suhu input (Arus 9')
P
 T trial
Q9 Vapor Pressure
Komponen
Amilen
Air
Amil Klorida
Amil Alkohol
MD
Total

Arus 9
Suhu
Komponen
Q10 Amil Klorida
Sodium Hidroksida
Sodium Oleat
Air
Amil Alkohol
Natrium Klorida
Amilen
Total

Output
Menentukan suhu Distilat (Arus 11)
P
T trial
Vapor Pressure
Komponen
Amilen
Air
Amil Klorida
Amil Alkohol
Total
Arus 11 (Distilat)
Suhu
Komponen
Amil Klorida
Sodium Hidroksida
Sodium Oleat
Air
Amil Alkohol
Natrium Klorida
Amilen
Total

Menentukan suhu Bottom (Arus 12)

P
T trial
Vapor Pressure
Komponen
Amilen
Air
Amil Klorida
Amil Alkohol
Total

Arus 12 (Bottom)
Suhu
Komponen
Amil Klorida
Sodium Hidroksida
Sodium Oleat
Air
Amil Alkohol
Natrium Klorida
Amilen
Total

NP Menara Distilasi (T-100)

Komponen

Amil Klorida
Sodium Hidroksida
Sodium Oleat
Air
Amil Alkohol
Natrium Klorida
Amilen
Subtotal
Total

Kebutuhan pendingin
Cp = A + BT + CT^2 + DT^3 Cairan
Cp = A + BT + CT^2 + DT^3 + ET^4 Gas
Cp = A + BT + CT^2 Padat

kapasitas panas cairan, J/mol K

suhu, K
konstanta

Cp=A+B*T+C*(T^2)+D*(T^3)
A B C D BM
99.612 0.6341 -0.0019117 0.0000026022 106.617
87.639 -0.00048368 -0.0000045423 0.0000000011863 39.910
 304.440
92.053 -0.039953 -0.00021103 0.00000053469 18.020
105.748 0.7462 -0.0021694 0.0000027315 88.174
95.016 -0.031081 0.00000096789 0.0000000055116 58.353
74.305 0.5838 -0.0021386 0.0000035676 70.154
T reff 25 C 298.15 K

(Pencampuran bahan baku amil klorida dan katalis sodium oleat)

Arus 2
30 C 303.15 K T umpan
molar flow (kmol/jam ∫Cp dT (kJ/mol) delta H (kJ/jam) Komponen
69.232 940.863887980165 65137.6319367438 Amil Klorida
0 435.576163524757 0 Sodium Hidroksida
0 0 0 Sodium Oleat
8.359 377.486381588157 3155.58591659917 Air
0 1041.15789078699 0 Amil Alkohol
0 429.543901461057 0 Natrium Klorida
0 767.3521606393 0 Amilen
77.591 Total 68293.217853343 Total

30 C 303.15 K
molar flow (kmol/jam ∫Cp dT (kJ/mol) delta H (kJ/jam)
69.232 940.863887980165 65137.6319367438
0 435.576163524757 0
17.308 0 0
8.359 377.486381588157 3155.58591659917
0 1041.15789078699 0
0 429.543901461057 0
 0 767.3521606393 0
94.899 Total 68293.217853343

Input Output
Arus 1 Arus 2 Arus 3
65137.6319367438 0 65137.6319367438
0 0 0
0 0 0
3155.58591659917 0 3155.58591659917
0 0 0
0 0 0
0 0 0
68293.217853343 0
68293.217853343
68293.217853343

(Pengenceran bahan baku sodium hidroksida)

Arus 5 (Bahan baku NaOH)

30 C 303.15 K T umpan
molar flow (kmol/jam ∫Cp dT (kJ/mol) delta H (kJ/jam) Komponen
0 940.863887980165 0 Amil Klorida
0 435.576163524757 0 Sodium Hidroksida
0 0 0 Sodium Oleat
1916.647 377.486381588157 723508.118190215 Air
0 1041.15789078699 0 Amil Alkohol
0 429.543901461057 0 Natrium Klorida
0 767.3521606393 0 Amilen
1916.64694007312 Total 723508.118190215 Total
 30 C 303.15 K
molar flow (kmol/jam ∫Cp dT (kJ/mol) delta H (kJ/jam)
0 940.863887980165 0
138.463 435.576163524757 60311.3801742441
0 0 0
2248.866 377.486381588157 848916.192009852
0 1041.15789078699 0
0 429.543901461057 0
0 767.3521606393 0
2387.32919723157 Total 909227.572184096

Input Output
Arus 1 Arus 2 Arus 3
0 0 0
0 60311.3801742441 60311.3801742441
0 0 0
723508.118190215 125408.073819637 848916.192009852
0 0 0
0 0 0
0 0 0
723508.118190215 185719.453993881
909227.572184096
909227.572184096

Arus 6'
180 C 453.15 K T umpan
molar flow (kmol/jam ∫Cp dT (kJ/mol) delta H (kJ/jam) Komponen
69.232 32244.6680784515 2232354.06103813 Amil Klorida
0.000 13465.2833122244 0 Sodium Hidroksida
17.308 0 0 Sodium Oleat
 8.359 11840.9007858373 98983.6496946847 Air
0.000 35113.9402716019 0 Amil Alkohol
0.000 12986.4490495247 0 Natrium Klorida
0.000 28629.7809181145 0 Amilen
Total 2331337.71073281 Total

180 C 453.15 K
molar flow (kmol/jam ∫Cp dT (kJ/mol) delta H (kJ/jam)
69.232 32244.6680784515 2232354.06103813
138.463 13465.2833122244 1864449.63935982
17.308 0 0
2257.225 11840.9007858373 26727579.7934525
0.000 35113.9402716019 0
0.000 12986.4490495247 0
0.000 28629.7809181145 0
Total 30824383.4938504

Konversi 68%
Reaktan Produk
C5H11Cl NaOH C5H11OH NaCl
69.232 138.463 0.000 0.000
47.339 47.339 47.339 47.339
21.893 91.125 47.339 47.339

molar flow (kmol/jam delta Hf 298 (kJ/mol) delta H (kJ/jam)

47.339 -174890 -8279076.15249229 (Coulson, 2005)
47.339 -425600 -20147377.2685729 (Perry, 2007)
0 0 0
0 -249000 0
47.339 -300160 -14209202.9157304 (Coulson, 2005)
 47.339 -411200 -19465699.0903129 (Coulson, 2005)
0 -40800 0 (Coulson, 2005)
Total -5248448.5849781

180 C 453.15 K
molar flow (kmol/jam ∫Cp dT (kJ/mol) delta H (kJ/jam)
21.565 32244.668 695342.410
90.796 13465.283 1222597.868
17.308 0.000 0.000
2257.554 11840.901 26731468.280
47.339 35113.940 1662250.475
47.667 12986.449 619027.104
0.328 28629.781 9401.862
30940087.998
= Panas keluar + beban pendingin
= -5397160.017 kJ/jam

Input (kJ/jam) Output (kJ/jam)

Arus 3' Arus 6' Arus 7
2232354.061 0.000 695342.410
0.000 138.463 1222597.868
0.000 0.000 0.000
98983.650 2248.866 26731468.280
0.000 0.000 1662250.475
0.000 0.000 619027.104
0.000 0.000 9401.862
2331337.711 2387.329
2333725.040 30940087.998
 180 C 453.15 K
molar flow (kmol/jam ∫Cp dT (kJ/mol) delta H (kJ/jam)
21.565 32244.6680784515 695342.410164087
90.796 13465.2833122244 1222597.86768537
17.308 0 0
2257.554 11840.9007858373 26731468.2798011
47.339 35113.9402716019 1662250.47471358
47.667 12986.4490495247 619027.103769155
0.328 28629.7809181145 9401.86175675537
Total 30940087.99789

Konversi 68%
Reaktan Produk
C5H11Cl NaOH C5H11OH NaCl
21.565 90.796 47.339 47.667
14.745 14.745 14.745 14.745
6.819 76.051 62.084 62.412

molar flow (kmol/jam delta Hf 298 (kJ/mol) delta H (kJ/jam)

14.745 -174890 -2578799.15479396
14.745 -425600 -6275584.19738299
0 0 0
0 -249000 0
14.745 -300160 -4425938.32868063
14.745 -411200 -6063252.40123093
0 -40800 0
Total -1634807.37773462

180 C 453.15 K
molar flow (kmol/jam ∫Cp dT (kJ/mol) delta H (kJ/jam)
 6.6692818885234 32244.6680784515 215048.780817065
75.9010089947475 13465.283 1022028.58979797
0 0.000 0
2257.70363179704 11840.901 26733244.7079334
62.0840260008362 35113.9402716019 2180014.78081395
62.5624452177007 12986.449 812464.007233349
0.478419216864481 28629.781 13697.037365846
Total 30976497.9039616
= Panas keluar + beban pendingin
= -1671217.28380615 kJ/jam

Input Arus 7 (kJ/jam) Output Arus 8 (kJ/jam)

695342.410 215048.781
1222597.868 1022028.590
0.000 0.000
26731468.280 26733244.708
1662250.475 2180014.781
619027.104 812464.007
9401.862 13697.037
30940087.998 30976497.904

115 C 388.15
Molar flow (kmol/jam) ∫Cp dT (kJ/mol) delta H (kJ/jam)
6.669 17798.478 118703.065
75.901 7828.547 594194.601
0.000 0.000 0.000
2257.704 6779.523 15306152.901
62.084 19544.380 1213393.795
62.562 7622.254 476866.864
 0.478 15120.152 7233.771
17716544.996

Heavy Liquid (Arus 10)

115 C 388.15 T
Molar flow (kmol/jam) ∫Cp dT (kJ/mol) delta H (kJ/jam) Komponen
6.669 17798.478 118703.065 Amil Klorida
0.000 7828.547 0.000 Sodium Hidroksida
0.000 0.000 0.000 Sodium Oleat
210.261 6779.523 1425467.909 Air
53.715 19544.380 1049832.560 Amil Alkohol
0.000 7622.254 0.000 Natrium Klorida
0.478 15120.152 7233.771 Amilen
Total 2601237.30507172 Total

Input (kJ/jam) Output (kJ/jam)

Arus 8' Arus 9 Arus 10
118703.065 118703.065 0.000
594194.601 0.000 594194.601
0.000 0.000 0.000
15306152.901 1425467.909 13880684.992
1213393.795 1049832.560 163561.235
476866.864 0.000 476866.864
7233.771 7233.771 0.000
2601237.305 15115307.691
17716544.996
17716544.996

1.5 bar 1125.093 mmHg

 126.399 C 399.549 K
log10(P)=A+B/T+C*log10(T)+D*T+E*T^2
mass flow (kg/jam) Zi A B C
33.563 0.004 33.754 -2426.000 -9.443
3788.900 0.409 29.861 -3152.200 -7.304
711.055 0.077 -4.489 -2260.400 7.809
4736.267 0.511 71.253 -5497.700 -21.366
9269.786 1.000 VAPOR PRESSURE CONSTANT (YAWS)

126.399 C 399.549 K
Molar flow (kmol/jam) ∫Cp dT (kJ/mol) delta H (kJ/jam)
6.669 20212.843612539 134805.151820662
0.000 8818.1779463857 0
0.000 0 0
210.261 7648.74566728794 1608231.44396808
53.715 22166.3349074415 1190671.69858326
0.000 8571.36542527274 0
0.478 17291.4342878372 8272.55445045072
Total 2941980.84882245

1.3 bar 975.0806 mmHg

109.278 C 382.428 K
log10(P)=A+B/T+C*log10(T)+D*T+E*T^2
mass flow (kg/jam) Zi A B C
33.563 0.007 33.754 -2426.000 -9.443
3765.090 0.835 29.861 -3152.200 -7.304
663.436 0.147 -4.489 -2260.400 7.809
45.791 0.010 71.253 -5497.700 -21.366
4507.881 1.000 VAPOR PRESSURE CONSTANT (YAWS)
 109.278 C 382.428 K
Molar flow (kmol/jam) ∫Cp dT (kJ/mol) delta H (kJ/jam)
6.223 16602.640 103312.305
0.000 7331.573 0.000
0.000 0.000 0.000
208.940 6345.100 1325742.105
0.519 18242.866 9474.096
0.000 7144.430 0.000
0.478 14056.796 6725.041
Total 1445253.547

1.7 bar 1275.105 mmHg

154.121 C 427.271 K
log10(P)=A+B/T+C*log10(T)+D*T+E*T^2
mass flow (kg/jam) Zi A B C
0.000 0.000 33.754 -2426.000 -9.443
23.810 0.005 29.861 -3152.200 -7.304
47.619 0.010 -4.489 -2260.400 7.809
4690.476 0.985 71.253 -5497.700 -21.366
4761.905 1.000 VAPOR PRESSURE CONSTANT (YAWS)

154.121 C 427.271 K
Molar flow (kmol/jam) ∫Cp dT (kJ/mol) delta H (kJ/jam)
0.447 26283.208 11739.096
0.000 11222.953 0.000
0.000 0.000 0.000
1.321 9791.007 12936.694
53.196 28723.656 1527983.197
 0.000 10864.581 0.000
0.000 22901.394 0.000
Total 1552658.98647027

Input (kJ/jam) Output (kJ/jam)

Arus 9' Arus 11 Arus 12
134805.151820662 103312.305 11739.096
0 0.000 0.000
0 0.000 0.000
1608231.44396808 1325742.105 12936.694
1190671.69858326 9474.096 1527983.197
0 0.000 0.000
8272.55445045072 6725.041 0.000
1445253.547 1552658.986
2941980.84882245
2997912.533

-55931.685 kJ/jam
(Katalis sodium oleat)
30 C 303.15
molar flow (kmol/jam ∫Cp dT (kJ/mol) delta H (kJ/jam)
0.000 940.863887980165 0
0 435.576163524757 0
17.308 0 0
0.000 377.486381588157 0
0 1041.15789078699 0
0 429.543901461057 0
0 767.3521606393 0
17.308 Total 0
 30 C 303.15
molar flow (kmol/jam ∫Cp dT (kJ/mol) delta H (kJ/jam)
0.000 940.863887980165 0
138.463 435.576163524757 60311.3801742441
0 0 0
332.219 377.486381588157 125408.073819637
0 1041.15789078699 0
0 429.543901461057 0
0 767.3521606393 0
470.682 Total 185719.453993881
 180 C 453.15 K
molar flow (kmol/jam ∫Cp dT (kJ/mol) delta H (kJ/jam)
0 32244.6680784515 0
138.463 13465.2833122244 1864449.63935982
0 0 0
 2248.866 11840.9007858373 26628596.1437578
0 35113.9402716019 0
0 12986.4490495247 0
0 28629.7809181145 0
Total 28493045.7831176

Reaksi samping 1.5% Konversi

Reaktan Produk
Keterangan
C5H11Cl NaOH C5H10 NaCl H2O
mula - mula 21.893 91.125 0.000 0.000 0.000
reaksi 0.328 0.328 0.328 0.328 0.328
sisa 21.565 90.796 0.328 0.328 0.328

Reaksi
Komponen molar flow (kmol/jam delta Hf 298 (kJ/mol) delta H (kJ/jam)
Amil Klorida 0.328 -174890 -57432.9090167287
Sodium Hidroksida 0.328 -425600 -139764.686817541
Sodium Oleat 0 0 0
Air 0.328 -249000 -81770.2232555632
Amil Alkohol 0 -300160 0
Natrium Klorida 0.328 -411200 -135035.806436496
Amilen 0.328 -40800 -13398.4944129598
Total -33006.9282707496
Reaksi 2 Konversi 2.20%
Reaktan Produk
Keterangan
C5H11Cl NaOH C5H10 NaCl H2O
Mula - mula 6.819 76.051 0.000 0.000 0.000
reaksi 0.150 0.150 0.150 0.150 0.150
sisa 6.669 75.901 0.150 0.150 0.150

Komponen molar flow (kmol/jam delta Hf 298 (kJ/mol) delta H (kJ/jam)

Amil Klorida 0.150 -174890 -26237.8278207003
Sodium Hidroksida 0.150 -425600 -63850.5318799819
Sodium Oleat 0 0 0
Air 0.150 -249000 -37356.1617436924
Amil Alkohol 0 -300160 0
Natrium Klorida 0.150 -411200 -61690.175538178
Amilen 0.150 -40800 -6121.00963511105
Total -15078.9872162993
 115 C 388.15 K
Molar flow (kmol/jam) ∫Cp dT (kJ/mol) delta H (kJ/jam)
0.000 17798.478 0.000
75.901 7828.547 594194.601
17.308 0.000 0.000
2047.443 6779.523 13880684.992
8.369 19544.380 163561.235
62.562 7622.254 476866.864
0.000 15120.152 0.000
Total 15115307.691
 D E log Psat Psat Ki Yi
9.85E-11 4.72E-06 3.869 7388.988 6.567 0.024
2.42E-09 1.81E-06 3.259 1814.713 1.613 0.659
-2.37E-02 1.49E-05 3.086 1218.746 1.083 0.083
3.81E-10 5.03E-06 2.712 514.874 0.458 0.234
CONSTANT (YAWS) Total 1.000

D E log Psat Psat Ki Xi

9.85E-11 4.72E-06 3.713 5166.799 5.299 0.001
2.42E-09 1.81E-06 3.020 1047.845 1.075 0.777
-2.37E-02 1.49E-05 2.890 776.556 0.796 0.185
3.81E-10 5.03E-06 2.435 272.064 0.279 0.036
CONSTANT (YAWS) Total 1.000
 D E log Psat Psat Ki Yi
9.85E-11 4.72E-06 4.096 12460.002 9.772 0.000
2.42E-09 1.81E-06 3.599 3975.262 3.118 0.016
-2.37E-02 1.49E-05 3.365 2319.037 1.819 0.018
3.81E-10 5.03E-06 3.097 1251.334 0.981 0.967
CONSTANT (YAWS) Total 1.000