Isolat senyawa diisolasi dari kulit batang

Artocarpus integer

SPEKTRUM 1H NMR
(Acetone-d6, 500 MHz)
 H Chemical Shifts
1

C H
C C
O
C
CH3 CH3
X
O O C CH2
C H
C C
OH H Aromatic H O H CH
C C Ar CH3
TMS
H C C H

12 11 10 9 8 7 6 5 4 3 2 1 0
1H Chemical shift ( )

downfield upfield
 Kopling aromatik
Jorto = 6-9 Hz

Ha

R Ho
Jmeta = 1-3 Hz
Kopling alifatik :
Hm
1. Kopling geminal (umumnya 8 - 18 Hz)
Jpara = 0-1 Hz 14,1 H
Hp 9,0
H H
O
H O
H Jgeminal (2JHH)
Ar Ar
H H
H

2. Kopling visinal (umumnya 0 - 18 Hz)

H Heq
H 5,3 H
O
H O Hax
H 8,5 Jvisinal (3JHH) Hax
Ar Ar
6,8 6,4
H H
Jae = 1-6 Hz
H

Hax
Heq
Heq
Jaa = 8-13 Hz
Jee = 0-5 Hz
 6.4238
δH H
ΣH m J (Hz) estimasi
(ppm) 7.3021
H
12,155 1H s - H dari OH aromatik

7,3021 1H d 8,35 H aromatik

H 6.4617
6,4617 1H d 2,2 H aromatik
6,4238 1H dd 2,2 8,4 H aromatik
6.0406
H
6,0406 1H d 2,15 H aromatik
6,0174 1H d 2,15 H aromatik

5,717 1H dd 2,75 13,2 H-C-OR

3,1869 2H dd 13,2 17,1 H-C-C=O H 6.0174
2,7368 1H dd 2,85 17,15 H-C-C=O

3,8378 3H s - H metoksi
6.4238
H
7,9741 4H s -
7.3021
3,314 3H s - H OR
6.0406
2,9766 5H s - H
5.717
H
RO O
H
6.4617
3,8378
H
OR
H 3,8378
H H
6.0174 2.7368
O H H
3,8378 12,155 3.1869
O O O
H
H
12,155
 SPEKTRUM 13C NMR
(Acetone-d6, 125 MHz)

CH-R

C=C aroamtik CH2-R

C=O C=C CH3-R

alkena
220 200 180 160 140 120 100 80 60 40 20 0
1 198,04
2 168,66
79,1
3 164,95
75,42
4 164,59
56,14
5 159,52
42,6
6 156,28
7 128,9
8 117,21
9 107,8
10 103,42
11 95,31
12 94,4
 δC
ƩC estimasi
(ppm)
sp2 6.4238
1 198,04 C=O H
2 168,66 C=C, aromatik
7.3021
3 164,95 C=C, aromatik H OR
6.0406
4 164,59 C=C, aromatik H
5 159,52 C=C, aromatik 5.717
H
6 156,28 C=C, aromatik RO O
7 128,9 C=C, aromatik
H
8 117,21 C=C, aromatik 6.4617
9 107,8 C=C, aromatik
10 103,66 OR
198,04
11 103,42 C=C, aromatik H H
6.0174 2.7368
12 95,31 C=C, aromatik H
3.1869
13 94,4 C=C, aromatik O O
H
12,155
sp3
14 75,42 CH-O
15 56,14 C-metoksi
3,8378
16 42,6 C-alkil H
H 3,8378
56,14 C
17 79,1 C-O O H
3,8378