Kimia Alam
Ranno Marlany Rachman
Hubungan
antar sistem
lingkungan
dengan
manusia dan
kehidupan
Environmental
Chemistry
dalam triliun
liter/hari
Air
• Struktur terdiri atas 2 atom H
dan 1 atom O dalam setiap
molekulnya
• Struktur bersudut 105 o
moment dipol tidak nol (polar)
• Kemampuan sangat besar
membentuk ikatan hidrogen
(kelarutan molekul, logam,
suspensi)
• Pelarut yang universal
• Kapasitas panas tinggi
• Densitas terbesar pada 4 oC
(jaminan kelangsungan hidup)
Ikatan Hidrogen
26
Water Chemistry
The polarity of water causes it to be cohesive and
adhesive.
Polarity unequal charge distribution in a molecule resulting in a –
region and a + region
cohesion: water molecules stick to other water
molecules by hydrogen bonding
adhesion: water molecules stick to other polar
molecules by hydrogen bonding
27
Water Chemistry
cohesion
28
Water Chemistry
adhesion 29
Sifat
Air
Stratifikasi Air danau
Major Aquatic Chemical Process
Kesetimbangan CO2-CaCO3 di air
CO2 di Air
Kesetimbangan CO2 di Air
Oksidasi-Reduksi di Air
Properties of Water
1. Water has a high specific heat.
- A large amount of energy is required to change
the temperature of water.
37
Properties of Water
3. Solid water is less dense than liquid water.
- Bodies of water freeze from the top down.
38
39
Properties of Water
4. Water is a good solvent.
- Water dissolves
polar molecules and
ions.
40
Properties of Water
5. Water organizes nonpolar molecules.
- hydrophilic: “water-loving”
-hydrophobic: “water-fearing”
- Water causes hydrophobic molecules to
aggregate or assume specific shapes.
41
Ionization; happens spontaneously
KELOMPOK
1 pH - 6-9 pHmeter
2 TSS mg/L 100 Gravimetri
3 BOD mg/L O2 100 Winkler
4 Minyak & mg/L 10 Gravimetri
Lemak
AIR PERMUKAAN Stream Standar
Baku Mutu Air
No Parameter Satuan Hasil Analisa Metoda Analisa
Kelas I *)
A. FISIKA
o
1 Temperatur C deviasi 3 Termometer
2 Total Disolved Solid (TDS) mg/L 1000 Gravimetri
3 Padatan Tersuspensi (SS) mg/L 50 Gravimetri
B. KIMIA
1 pH - 6,0 - 9,0 pH meter
2 Barium mg/L Ba 1 AAS
3 Besi mg/L Fe 0.3 Spektropotometri
4 Boron mg/L B 1 AAS
5 Mangan mg/L Mn 0.1 Spektropotometri
6 Tembaga mg/L Cu 0.02 AAS
7 Seng mg/L Zn 0.05 AAS
6+
8 Krom Heksavalen mg/L Cr 0.05 AAS
9 Kadmium mg/L Cd 0.01 AAS
10 Raksa mg/L Hg 0.001 AAS
11 Timbal mg/L Pb 0.03 AAS
12 Arsen mg/L As 0.05 AAS
13 Selenium mg/L Se 0.0 AAS
14 Kobalt mg/L Co 0.2 AAS
15 Khlorida mg/L Cl - Argentometri
16 Sulfat mg/L SO4 400 Spektropotometri
17 Sianida mg/L CN 0.02 Spektropotometri
18 Sulfida mg/L H2S 0.002 Iodometri
19 Fluorida mg/L F 0.5 Spektropotometri
20 Sisa Khlor Bebas mg/L Cl2 0.03 Iodometri
21 Total Phospat mg/L PO4 -P 0.2 Spektropotometri
22 Nitrat mg/L NO3 -N 10 Spektropotometri
23 Nitrit mg/L NO2 -N 0.06 Spektropotometri
24 Amonia Bebas mg/L NH3-N 0.5 Spektropotometri
25 BOD mg/L O2 2 Winkler
26 COD mg/L O2 10 Reflux/Titrimetri
27 Disolved Oxygen (DO) mg/L O2 6 Iodometri
28 Detergent Anionik mg/L LAS 0.2 Spektropotometri
29 Fenol mg/L 0.001 Spektropotometri
30 Minyak & Lemak mg/L 1 Gravimetri
Sea water
Alkalinity
Buffering capacity –
resistance to pH changes.
In natural systems:
Limestone outcrop 50 – 150 mg/L as CaCO3.
Hardness
Reflects dissolved
carbonate minerals.
Create scale/hard
water deposits
From US EPA
http://www.epa.gov/glnpo/monitoring/limnology/SprNOx.html
Solutions??
Measures how
“murky” the water is
Estimates:
Mineral fraction
Organics
Inorganics
Soluble organic compounds
Plankton
Microscopic organisms