Determinatioan of

concentration Ca in CaCO 3

10.8
Group members :
1) Dini Safitri
2) Livia Nurul
3) Peris Gultom
SMK SMAK

Base :
Calcium can be precipitation as calcium
oxalate in
pH a few of base. Because CaO unstable, ofter
candescance precipitation become CaSO4 .

Reaction :
CaCO3 + 2HCl CaCl2 + H2O + CO2
CaCl2 + (NH4)2C2O4 + H2O CaC2O4.H2O +
NH4Cl
CaC2O4.H2O CaC2O4 + H2O
CaC2O4
CaCO3 + CO
CaCO3
CaO + CO2
CaO + H2SO4 CaSO4 + H2O

Dasar
Kalsium dapat diendapkan senagai kalsium oksalat
pada pH sedikit basa. Karena CaO tidak stabil setelah
pemijaran endapan dijadikan kalsium sulfat ynag stabil.

Reaksi :
CaCO3 + 2HCl CaCl2 + H2O + CO2
CaCl2 + (NH4)2C2O4 + H2O CaC2O4.H2O +
NH4Cl
CaC2O4.H2O CaC2O4 + H2O
CaC2O4 CaCO3 + CO
CaCO3 CaO + CO2
CaO + H2SO4 CaSO4 + H2O

Teory :
Calcium ions can be precipitated as calcium oxalate in an atmosphere
slightly alkaline, as sedimentation can be used ammonium oxalate.
Used to adjust the pH near neutral indicator, namely MM and
ammonia solution.
Washing with a solution to reduce the solubility of settling.
Precipitated calcium oksalatsama like barium sulfate precipitate,
which is very smooth.
Deposition must be conducted in an aqueous and curing. By
regulating the temperature annealed precipitate can be calculated as:
CaC2O4.H2O in 100 C - 105 C
CaCO3 in 475 C - 525 C
CaO in 1200 C
Abu usually weighed as CaSO4 by adding H2SO4 to the rest flare. To
obtain the above three forms in a pure state is very difficult, what
else is very hygroscopic CaO

Teori :

Ion kalsium dapat diendapkan sebagai kalsium oksalat dalam

suasana sedikit basa, sebagai pengendap dapat dipakai
amonium oksalat. Untuk mengatur pH dipakai indikator yang
mendekati netral, yaitu MM dan larutan amonia.
Pencucian dengan larutan pengendap untuk mengurangi
kelarutan. Endapan kalsium oksalatsama seperti endapan
barium sulfat, yaitu sangat halus.
Pengendapan harus dalam keadaan encer dan dilakukan
pemeraman. Dengan mengatur suhu pemijaran endapan dapat
dihitung sebagai :
CaC2O4.H2O dalam 100C - 105C
CaCO3 dalam 475C - 525C
CaO dalam 1200C
Abu biasanya ditimbang sebagai CaSO4 dengan menambahkan H2SO4 pada sisa
pijar. Untuk mendapatkan ketiga bentuk di atas dalam keadaan murni sangat
sulit, apa lagi CaO sangat higroskopis

Materials :
CaCO3 sample
HCl 4N
(NH4)2C2O4 4% and 0.1%
NH4OH 4N
H2SO4 4N
Distillate Water
Methyl Red Indicator

Tools :

Analytical Balance
Watch Glass
Beaker Glass 800 and 400 ml
Dropper Pipette
Test Tube
Measuring Cylinder
Rubber Policemen
Stirring Rods
Tecklu Burner
Meker Burner
Wash Bottle
Thermometer
Glass Cover
Water Bath
Funnel
Funnel Holder
Oven
Crucible Porcelain
Tripod Stand
Porcelain Triangle
Wire Gauze
Fumehood

Steps :
1. Weigh about 0.5 grams sample CaCO3
2. Put CaCO3 into 400 mls Beaker Glass , pour about 25 mls
destilled water with it.
3. Dissolve with 8 mls Chloride Acid, heat till completely
dissove.
4. Dilute the solution with distilled water till volume 100 mls
5. Heat the solution till it shows 90C in Thermometer.
6. Add about 5 drops Methyl Red Indicator with pipette till it
becomes red.
7. Add ammonium oxalate 4% (calculate amount you need)
8. Netralize the solution with ammonium hydroxide 2N till it
becomes orange.

9. Keep in heating water place.

10. Solution upper precipitation added by (NH4)2C2O4
4%.
11. Filtrate precipitation with filtrated paper Whatman
brand number 42.
12. Wash the precipitation with ammonium oxalate 0.1%
until free of chloride.
13. Drain the precipitation in oven, annealed, charred
with Meker Burner
14. Chill in open air, added CaO precipitation some
drops of destilled water.
15. Added 2 mls of H2SO4 4N.
16. Fume crucible porcelain with the contain in
fumehood till it drain.
17. Get out crucible porselain from fumehood, glowing,
chill it in dessicator, and weigh.
18. Repeat the steps till you get absolute weight CaSO4.

Cara Kerja:
1. Sampel ditimbang sebanyak 0,5 gram
2. Dimasukkan ke dalam piala gelas 400 mL, dibubuhi
25 mL air suling
3. Dilarutkan dengan 15 mL HCL 4 N, dipanaskan
sampai larut sempurna
4. Larutan diencerkan dengan air suling samapai berisi
125 mL
5. Larutan dipanaskan hingga 90 C (termometer)
6. Ditambahkan 2-3 tetes indikator MM
7. Ditambahkan (NH4)2C2O4 4% (jumlah yang
diperlukan dihitung terlebih dahulu)

8. Larutan dinetralkan dalam piala gelas dengan

NH4OH 2N
9. Piala gelas beserta isinya disimpan di atas
penangas air mendidih 1 jam
10. Diuji pengendapan sempurna (cairan jernih di
atas endapan ditetesi (NH4)2C2O4 4% )
11. Bila pengendapan telah sempurna ditambahkan
lagi 10 mL (NH4)2C2O4 4%
12. Endapan disaring dengan kertas saring barit
(blue ribbon / Whatman 542)
13. Endapan dicuci dengan (NH4)2C2O4 0,1 %
sampai bebas klorida
14. Endapan dikeringkan di oven, diabukan sampai
karbon kertas sarign habis

15. Didinginkan (di udara terbuka), endapan CaO

dimatikan dengan beberapa tetes air suing
16. Ditambahkan H2SO4 4 N 2 mL
17. Cawan beserta isinya diuapkan di ruang asam
(dengan bantuan api teklu kecil) sampai kering
18. Cawan dan isinya dikeluarkan dari ruang asam,
dipijarkan, didinginkan di desikator, ditimbang
19. Dilakukan berulang-kali sampai bobot tetap
(CaSO4).

Calculation :
Practice Concentration: fk x weight of time incandescent

x 100%
weight sample
Theoretical Concentration

Ca

x 100%

CaCO3

% accuracy

% Practice

x 100%

%Theoretical

% mistake :

% Practice - % Theoretical
% Theoretical

x 100%

Fk :

Ca
CaSO4

Perhitungan:
Kadar Praktek : fk x bobot abu x 100%
bobot sampel
Kadar Teoritis :
Ca
x 100%
CaCO3
% ketelitian :
% Praktek
x 100%
%teoritis
% Kesalahan :
100%

% praktek - % Teoritis
% Teoritis