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SKOR A KIMIA 2014

TAJUK: SEBATIAN KARBON


SET 1

Diagram 7 shows a flow chart for a series of changes of organic


compounds from one homologous series to another homologous series.
Rajah 7 menunjukkan carta alir satu siri penukaran sebatian organic
daripada suatu siri homologus kepada suatu siri homologus yang lain.

Butan
e
Butan
a

+
H2

But-1ene
But-1ena

Process
I
Proses
I
+ H 2O

C4H10O

+ Ethanoic acid
Asidetanoik
Compound Q
Sebatian Q
Diagram 7 /
Rajah 7
(a) Both but-1-ene and butane are hydrocarbons. Which hydrocarbon
burn with sootier flames. Explain your answer.
Kedua-dua but-1-ena dan butana adalah hidrokarbon. Hidrokarbon
manakah terbakar dengan nyalaan lebih berjelaga? Terangkan
jawapan anda.

..
[4 marks]
(b) b) Butane undergoes complete combustion to produce carbon
dioxide and water.
Write the chemical equation for the combustion of butane and
3
calculate the volume of carbon dioxide produce when 600 cm of
butane is burnt at room condition. [1 mole of gas occupies
3
24dm at room condition]
Butana menjalani pembakaran lengkap menghasilkan karbon
dioksida dan air. Tuliskan persamaan kimia bagi pembakaran
butane dan hitung isipadu karbon dioksida yang dihasilkan apabila
3
600 cm butana dibakarpada keadaanbilik.
3
[1 mol gas menempati 24 dm pada keadaan bilik

[5 marks]

(c) In Process I,
Dalam Proses I,
(i)

state the name of Process I and what is the condition


needed for but-1-ene to form C4H10O?
Nyatakan nama Proses I dan apakah keadaan yang diperlukan
bagi but-1-ena membentuk C4H10O?

[4 marks]
(ii) C4H10O can form isomers. Draw two of the isomers in C4H10O
and
state the name of the isomer.
C4H10O boleh membentuk isomer.Lukiskan dua isomer dalam
C4H10O dan nyatakan nama bagi isomer itu.

[4 marks]
(d) Compound Q has sweet fruity smell. What are the homologous
series and
the name of compound Q? Draw the structural formula of
compound Q. Sebatian Q mempunyai bau manis buah-buahan.
Apakah siri homologus dan nama bagi sebatian Q? Lukiskan
formula strukturbagisebatian Q.

[3 marks]

SKOR A KIMIA 2014


TAJUK: SEBATIAN KARBON
SET 2

Diagram 6.1 shows a series of reactions involving compound P, C2H6O.

Diagram 6.1
/Rajah 6.1
(a) (i) State the name of compound P.
Nyatakan nama bagi sebatian P.
......
.....................................
[1 mark]
(ii) Draw the structural formula for compound P.
Lukis formula struktur bagi sebatian P.

[1 mark]

(b)

(c)

Write a chemical equation for the complete combustion of


compound P.
Tulis persamaan kimia bagi pembakaran lengkap sebatian P.

.
[2 marks]
(i) State the name of gas T that produced in reaction III.
Nyatakan nama gas T yang terhasil dalam tindak balas III.

....
[1 mark]

(ii) Draw the diagram of set-up of apparatus to carry out


reaction III in the laboratory.
Lukis gambarajah susunan radas untuk menjalankan tindak
balas III di dalam makmal.

[2 marks]
(d) State the change of colour of acidified potassium
manganate(VII) solution in reaction IV.
Nyatakan perubahan warna larutan kalium manganat(VII)
berasid di dalam tindak balas IV.

..
[1 mark]
(e) Diagram 6.2 shows the environment pollution from the
manufactured substance of polymer R.
Rajah 6.2 menunjukkan pencemaran alam sekitar daripada bahan
buatan
polimer R.
Uses
Polymer
Kegunaan
R
Polime
rR
Throw
Buang

Acidic gas
Gas berasid
Burning
Pembakaran

Toxic gas
Gas
beracun

Diagram 6.2 / Rajah 6.2


Based on diagram 6.2, describe the efect of pollution from
the manufactured substance of polymer R on the
environment. State one way to overcome the problem.
Berdasarkan rajah 6.2, huraikan kesan pencemaran bahan
buatan daripada polimer R ke atas alam sekitar. Nyatakan
satu cara mengatasi masalah ini.

..
[3 marks]

SKOR A KIMIA 2014


TAJUK: SEBATIAN KARBON
SET 3
Table 4 shows the molecular formulae and observations for three compounds when they react
with bromine water.
Jadual 4 menunjukkan formula molekul dan pemerhatian bagi tiga sebatian apabila
bertindakbals dengan air bromin.
Compound
Sebatian
P

Molecular Formula
Formula Molekul
C2H4

Observation
Pemerhatian
Brown colour is decolourised
Warna perang menjadi tidak berwarna

C2H6

Brown colour remains


Warna perang tidak berubah

C4H10

a) i)

.
Table 4
Jadual 4
Name the homologous series for these compounds.
Namakan siri homolog bagi sebatian-sebatian ini.
P : ......................................................

Q : ......................................................
ii) Write the general formula for the homologous series of compounds Q and R?
Apakah formula am bagi siri homolog sebatian Q dan R?
...........................................................................................................................................
[ 1 mark ]
iii) In Table 4, complete the observation when compound R reacts with bromine water.
Dalam Jadual 4, lengkapkan pemerhatian yang berlaku apabila sebatian R
bertindakbalas dengan air bromin.
[ 1 mark ]
iv)

v)

Name another substance that can replace bromine water.


Namakan bahan lain yang boleh menggantikan air bromin.
...........................................................................................................................................
[ 1 mark]
Explain why compound P is chemically more reactive than compound Q.
Jelaskan mengapa sebatian P lebih reaktif secara kimia berbanding sebatian Q.
...........................................................................................................................................

...........................................................................................................................................
[ 1 mark ]
b) One mole of compound P and Q undergo complete combustion to form gas X and
water.
Satu mol sebatian P dan Q mengalami pembakaran lengkap untuk menghasilkan gas X
dan air.
i)
Name gas X.
Namakan gas X.
.................................
[ 1 mark ]

ii)

iii)

Write a balanced chemical equation when compound P or Q reacts with oxygen.


Tulis persamaan kimia yang seimbang apabila sebatian P atau Q bertindak balas
dengan oksigen.
..
[ 1 mark ]
Explain why the compound P burns with more soot compared to compound Q.
Jelaskan mengapa sebatian P terbakar dengan penghasilan jelaga yang lebih
banyak daripada sebatian Q.

.
[2 marks ]

SKOR A KIMIA 2014


TAJUK: SEBATIAN KARBON
SET 4

The flow chart in Diagram 6 shows the relationship between four organic compounds.
Carta alir pada Rajah 6 menunjukkan perkaitan antara empat sebatian organik.

Diagram 6 /
Rajah 6
(a) Alcohol Q can be changed into an alkene C4H8, through process I. Draw the
apparatus setup for the process.
Alkohol Q boleh ditukar kepada suatu alkena C4H8, melalui Proses 1. Lukiskan
susunan alat radas untuk melakukan proses tersebut.

[2 marks / 2 markah]
(b) (i) Name the alcohol Q.
Namakan alkohol Q.

1mrk
(ii) Name the Process I
Namakan Proses 1

(c) (i) What is meant by isomerism?.


Apakah maksud isomerism

.
(ii) Draw and name two isomers of alcohol Q
Lukis dan namakan dua isomer bagi alkohol Q.

(d) Through oxidation process, alcohol Q is changed to butanoic acid.


Explain a chemical test to differentiate between alkane,C4H10 and butanoic
acid.
In the description, you should include : apparatus and materials used, procedures
and
observati
ons

Melalui proses pengoksidaan, alcohol Q ditukarkan kepada asid butanoik.


Terangkan satu ujian kimia untuk membezakan antara alkana, C4H10 dan
asid butanoik. Di dalam penerangan, anda mesti menyatakan : susunan
alat radas dan bahan, prosedur dan pemerhatian.
[10 markah]

SKOR A KIMIA 2014


TAJUK: SEBATIAN KARBON
SET 5
Table 5 shows the formulae of three organic compounds.
Jadual 5 menunjukkan formula bagi tiga sebatian organik

Organic compound
Sebatian organik

Formula
Formula

Butan-1-ol
Butan-1-ol
Butanoic acid
Asid Butanoik
But-1-ene
But-1-ena

C4H10O
C4H8O2
C4H8
TABLE / JADUAL 5

Use the information in Table 5 to answer the following questions.


Gunakan maklumat dalam Jadual 5 untuk menjawab soalan berikut.
(a)

Name the homologous series for butan-1-ol.


Namakan siri homolog bagi butan-1-ol
..
[ 1 mark ]

(b)

(i)

Draw the structural formula of butan-1-ol


Lukiskan formula struktur bagi butan-1-ol

[ 1 mark ]
(ii)

The following structural formula is isomer of butanol.


Formula struktur berikut ialah isomer bagi butanol
CH3
CH3 -

- CH3

OH
Name the isomer.
Namakan isomer itu.
.................
.....................................
1 mrk

(c )

Butan-1-ol can react with butanoic acid to form compound X and water.
Butan-1-ol boleh bertindak balas dengan asid butanoik untuk menghasilkan
sebatian X dan air.
(i)

(ii)

What is the name of this reaction?


Apakah nama tindak balas ini.
.
[ 1 mark ]
Write the chemical equation for the reaction.
Tuliskan persamaan kimia bagi tindak balas itu.
.
[ 1 mark ]

(iii)

State one physical property of compound X.


Nyatakan satu sifat fizik bagi sebatian X.
.
[ 1 mark ]

(d)

Dehydration of butan-1-ol using porous pot chips produce but-1-ene.


Draw the set up of apparatus used in the dehydration.
Pengdehidratan butan-1-ol menggunakan serpihan pasu berliang menghasilkan
but-1-ena. Lukiskan susunan radas yang digunakan dalam pengdehidratan itu.

2 mrk

SKOR A KIMIA 2014


TAJUK: SEBATIAN KARBON
SET 6

(a) Diagram 10.1 shows the structural formulae of compound A and compound B.
Rajah 10.1 menunjukkan formula struktur bagi sebatian A dan sebatian B.

Compound A

Compound B

Sebatian A

Sebatian B

Diagram 10.1
Rajah 10.1

Compound A and compound B are burnt completely in oxygen to produce


carbon dioxide gas and water.
Sebatian A dan sebatian B terbakar lengkap dalam oksigen menghasilkan gas
karbon dioksida dan air.

(i)

Name compound B.
Namakan sebatian B.

..

(ii)

Compound B produced more soot than compound A when burnt in oxygen.


Explain why.
Sebatian B menghasilkan lebih jelaga daripada sebatian A apabila terbakar
dalam oksigen. Terangkan mengapa.

[Relative molecular mass of: A = 86, B = 84]

[Jisim molekul relatif: A = 86, B = 84]

.
4 mrk.

(b)

Diagram 10.2 shows the structural formulae of compound J and compound K.


Rajah 10.2 menunjukkan formula struktur bagi sebatian J dan sebatian K.

Compound J

Compound K

Sebatian J

Sebatian K

Diagram 10.2
Rajah 10.2

State one physical property of compound K . Describe briefly a chemical


test to differentiate between compound J and compound K.
Nyatakan satu sifat fizik Sebatian K. Huraikan secara ringkas satu ujian
kimia untuk membezakan antara sebatian J dan sebatian K.

[6 marks]

(c)
Alcohols undergo dehydration reaction to produce alkenes and water.
Describe how to prepare an alkene from a named alcohol through dehydration
process. In your description, include the diagram of the apparatus set-up and
balanced chemical equation for the reaction.
Alkohol mengalami tindak balas pendehidratan untuk menghasilkan alkena dan air.
Huraikan bagaimana satu alkena disediakan daripada alkohol yang dinamakan melalui
proses pendehidratan. Dalam huraian anda, sertakan gambar rajah bagi susunan radas
dan persamaan kimia seimbang bagi tindak balas itu.

[10 marks]

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