Using the steady-state approximation, develop the rate expression for the following hypothetical mechanisms of formation of HBr: (a) Br2 2Br Br + H2 HBr + H (b) Br2 2Br Br + H2 HBr + H Br + HBr Br2 + H Jawab 1a: Reaksi pembentukan HBr: H2 + Br2 2 HBr
Br2 2Br Br + H2 HBr + H Br + HBr Br2 + H Hukum laju penguraian H2 dinyatakan sebagai:
2. Consider the following mechanisms for the decomposition of ozone into oxygen: (1) O3 O2 + O (2) O + O2 O3 (3) O3 + O 2O2 a) Derive the rate expression for O3 b) Under what condition will the reaction be first order with respect to ozone? Jawab: Reaksi disosiasi ozon menjadi oksigen mengikuti persamaan reaksi: 2 O3 3 O2
Jadi, reaksi akan berorde satu terhadap ozon apabila konsentrasi ozon sangat besar.
3. The mechanism proposed for the decomposition of N2O5 is: (1) N2O5 NO2 + NO3 (2) NO2 + NO3 N2O5 (3) NO2 + NO3 NO + O2 + NO2 (4) NO + NO3 2NO2 Derive the expression for the rate of disappearance of N2O5 based on the steady state approximation for the concentrations of NO3 and NO. Persamaan reaksi penguraian N2O5: 2 N2O5 4 NO2 + O2
(1) N2O5 NO2 + NO3 (2) NO2 + NO3 N2O5 (3) NO2 + NO3 NO + O2 + NO2 (4) NO + NO3 2NO2