Tata Nama Senyawa

Senyawa Ionik
Tujuan Pembelajaran:
Siswa mampu menggunakan aturan IUPAC dalam pemberian nama senyawa ionik biner
dengan benar melalui diskusi.
Siswa mampu menerapkan aturan IUPAC dalam pemberian nama senyawa-senyawa
poliatomik dengan benar melalui diskusi.

Tabel 1. Penamaan Senyawa Ionik Biner (Atom Logam yang memiliki satu bilangan
oksidasi)
Atom Logam Atom Non Logam
No +  Senyawa Ion
(Kation) (Anion)
Na+ Cl- NaCl
+ 
(Logam) (Non logam) (Senyawa ion)
1
Natrium + 
Klorin Natrium klorida
2Al3+ 3O2- Al2O3
+ 
(Logam) (Non logam) (Senyawa ion)
2
Aluminium + oksigen 
Aluminium oksida
Mg2+ 2Br- MgBr2
+ 
(Logam) (Non logam) (Senyawa ion)
3
Magnesium + Bromin 
Magnesium bromida

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Tata Nama |1
Senyawa
Tabel 2. Penamaan Senyawa Ionik Biner (Atom Logam yang memiliki bilangan oksidasi
lebih dari satu)
Atom Logam Atom Non Logam
No +  Senyawa Ion
(Kation) (Anion)
Fe2+ 2Cl- FeCl2
+ 
(Logam) (Non logam) (Senyawa ion)
1
Besi + 
Klorin Besi(II) klorida
2Fe3+ 3O2- Fe2O3
+ 
(Logam) (Non logam) (Senyawa ion)
2
Besi + Oksigen 
Besi(III) oksida
Cu2+ 2I- CuI2
+ 
(Logam) (Non logam) (Senyawa ion)
3
Tembaga + Iodin 
Tembaga(II) iodida

Tuliskan hasil Pengamatanmu!

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Rumusan masalah

Berdasarkan pengamatan yang sudah kalian lakukan, identifikasikan rumusan masalah yang
kalian temukan!

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Tata Nama |2
Senyawa
 Perhatikan tabel di bawah ini, isilah kolom yang kosong pada tabel dengan
jawaban yang tepat sesuai dengan data yang telah kalian kumpulkan!

Rumus Komponen Penyusun

No Nama Senyawa
Kimia Kation Jumlah Anion Jumlah
1 CaBr2 Ca2+ 1 Br- 2 Kalsium bromida
2 AlCl3 ........ ........ ........ ........ ................................
3 ........ ........ ........ ........ ........ Kalium oksida
4 Na2O ........ ........ ........ ........ ................................
5 AgCl Ag+ 1 Cl- 1 ................................
6 ........ ........ ........ ........ ........ Tembaga(II) oksida
7 PbS ........ ........ ........ ........ ................................
8 ........ Pb4+ 1 O2- 2 ................................

Diskusikanlah dengan kelompokmu, jawab pertanyaan di bawah ini dengan tepat!

1. Jelaskan aturan penamaan senyawa ionik biner menurut aturan IUPAC!
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2. Timah (Sn) merupakan unsur golongan utama. Salah satu senyawanya adalah SnCl 4
dengan nama IUPAC timah(IV) klorida. Mengapa senyawa SnCl 4 memiliki nama
Timah(IV) klorida tidak seperti halnya AlCl3 memiliki nama Aluminium klorida?
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3. Seng (Zn) merupakan unsur golongan transisi yang pada umumnya memiliki bilangan
oksidasi yang bermacam-macam. Salah satu senyawanya adalah ZnO dengan nama seng
oksida. Mengapa senyawa ZnO memiliki nama Seng oksida bukan Seng(II) oksida?
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Kesimpulan
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Tata Nama |3
Senyawa
 Tata Nama Senyawa
Senyawa Poliatomik

Tabel 3. Penamaan Senyawa Poliatomik

No Kation + Anion  Senyawa Ion
1 NH4+ + Cl-  NH4Cl

Amonium + klorin  Amonium klorida

2 2Na+ + SO42-  Na2SO4

Natrium + sulfat  Natrium sulfat

3 2Li+ + CO32-  Li2CO3

Litium + karbonat  Litium karbonat

Tuliskan hasil Pengamatanmu!

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Rumusan masalah

Berdasarkan pengamatan yang sudah kalian lakukan, identifikasikan rumusan masalah yang
kalian temukan!

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Tata Nama |4
Senyawa
 Perhatikan tabel di bawah ini, isilah kolom yang kosong dengan rumus senyawa
dan nama senyawa pada tabel dengan jawaban yang tepat sesuai dengan data
yang telah kalian kumpulkan!

Anion
Kation Cl- SO42- PO43- CO32- CN-

NH4Cl ....... ....... ....... .......

NH4+
Amonium klorida ....... ....... ....... .......
....... MgSO4 ....... ....... .......
Mg2+
....... Magnesium sulfat ....... ....... .......
....... ....... AlPO4 ....... .......
Al3+
....... ....... Aluminium fosfat ....... .......
....... ....... ....... CaCO3 .......
Ca2+
....... ....... ....... Kalsium karbonat .......
....... ....... ....... ....... KCN
K+
....... ....... ....... ....... Kalium sianida

Diskusikanlah dengan kelompokmu, jawab pertanyaan di bawah ini dengan tepat!

1. Jelaskan aturan penamaan senyawa poliatomik menurut aturan IUPAC!
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2. Timbal (Pb) merupakan unsur golongan utama. Salah satu senyawanya adalah PbSO 4
dengan nama IUPAC timbal(II) sulfat. Mengapa senyawa PbSO 4memiliki nama
timbal(II) sulfat tidak seperti halnya BaSO4 memiliki nama barium sulfat?
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Kesimpulan
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Tata Nama |5
Senyawa
 Tata Nama Senyawa
Senyawa Kovalen Biner, Asam Basa, Hidrat, dan Senyawa organik
sederhana
Tujuan Pembelajaran:
Siswa mampu menggunakan aturan IUPAC dalam pemberian nama senyawa-senyawa
kovalen biner dengan benar melalui diskusi.
Siswa mampu menggunakan aturan IUPAC dalam pemberian nama senyawa-senyawa
asam-basa anorganik dengan benar melalui diskusi.
Siswa mampu menggunakan aturan IUPAC dalam pemberian nama senyawa-senyawa
hidrat dengan benar melalui diskusi.
Siswa mampu menggunakan aturan IUPAC dalam pemberian nama senyawa-senyawa
hidrokarbon dengan benar melalui diskusi

NO2 N2O3
Nitrogen di nitrogen trioksida
di oksida

Tuliskan hasil Pengamatanmu!

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Berdasarkan senyawa dan nama senyawa yang diamati diatas, rumusan

pertanyaan yang kalian temukan!

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Tata Nama Senyawa Kovalen biner

Tata Nama | 6
 1. Perhatikan contoh berikut, kemudian lengkapi titik-titik dalam tabel di bawah ini!

Rumus
No Komposisi atom dalam senyawa Nama senyawa
Kimia
1 CO 1 atom C 1 atom O Karbon monoksida
2 N2O3 2 atom N 3 atom O Dinitrogen trioksida
3 CCl4 .............................. ............................ .................................................
4 NO2 .............................. ............................ .................................................
5 .................. 2 atom P 5 atom O .................................................
6 .................. 1 atom P 5 atom Cl .................................................
7 .................. .............................. ............................ Karbon disulfida
8 .................. .............................. ............................ Karbon dioksida

Catatan!
Awalan Yunani untuk menyatakan jumlah atom pada senyawa kovalen biner:
1 = mono6 = heksa2 = di7 = hepta3 = tri8 = okta4 = tetra9 = nona5 = penta10
= deka
Awalan mono tidak digunakan untuk menuliskan nama atom nonlogam pertama.

2. Tentukan nama senyawa dan rumus senyawa berikut ini:

a. N2O5 = ………………………………
b. N2O = ………………………………
c. Karbon tetraflorida = ………………………………
d. Sulfur dioksida = ………………………………

3. Berdasarkan penulisan nama senyawa kovalen di atas, simpulkan aturan tata nama senyawa
kovalen biner!

Tata Nama Asam Basa

CATAT Cermati Penamaan Senyawa Asam dan Senyawa Basa berikut!

HCl NaOH Tata Nama | 7

asam klorida natrium hidroksida

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Berdasarkan senyawa dan nama senyawa yang diamati diatas, rumusan

pertanyaan yang kalian temukan!

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Catatan!
Asam adalah zat yang apabila dilarutkan dalam air akan menghasilkan ion H+

Basa adalah zat yang apabila dilarutkan dalam air akan menghasilkan ion OH-

1. Perhatikan contoh penamaan senyawa asam berikut dan lengkapi titik-titik dalam tabel!

Rumus Ion Penyusun

No Kimia Jumlah Nama Nama Senyawa
Kation Anion
Senyawa kation anion
1 HCl H+ 1 Cl- klorida Asamklorida
2 H2SO4 H+ 1 SO42- sulfat Asam sulfat
3 HNO3 ................. ................ NO3- nitrat ................................
4 HClO3 H+ .................. ClO3- ................... .................................
5 .................. H+ 3 ................... pospat ................................
6 ................... ................ 1 CN- ................ Asam sianida
7 ................... ................ 2 ................. dikromat Asam dikromat
2. Perhatikan contoh penamaan senyawa basa berikut dan lengkapi titik-titik dalam tabel!

Rumus Ion Penyusun

No Kimia Jumlah Jumlah Nama Senyawa
Kation Anion
Senyawa kation anion
1 KOH K+ 1 OH- 1 Kalium hidroksida

Tata Nama | 8
 2 Mg(OH)2 Mg2+ 1 OH- 2 Magnesium hidroksida
3 Fe(OH)2 Fe2+ 1 OH- 2 Besi(II) hidroksida
4 Ca(OH)2 .............. .............. .............. .............. ........................................
5 Al(OH)3 .............. .............. .............. .............. ........................................
6 Fe(OH)3 .............. .............. .............. .............. ........................................
7 .......................... .............. .............. .............. .............. Tembaga(II) hidroksida
8 .......................... .............. .............. .............. .............. Natrium hidroksida

3. Berdasarkan penulisan nama senyawa asam basa di atas, simpulkan aturan tata nama senyawa
asam basa!

Asam :

Basa :

Tata Nama | 9