TUGAS KINETIKA KIMIA

Nama : Aloysius K. Kerans

NIM : 0806073154

Fak/Jur : FST / Kimia

REAKSI ORDER 3 TIPE I

3A P
d[A]
V= = k[A]3
dt
d[A]
V= = k[A]3
dt
d[A]
= kdt
[A]3
[A]3 d[A] = kdt
A t
[A]3 d[A] = kdt
AO 0
1 2 1
[A] [A]O 2 = kt
2 2
1 1
= kt (x2)
2[A] 2
2[A]O 2
1 1
= 2kt
[A]2 [A]O 2
1 1
= 2kt +
[A] 2
[A]O 2
Untuk mencari waktu paruh maka di buat persamaan pada saat t t1/2 maka [A] = [A]o
1 1
[A] 2 = 2kt
[A]2 O
1 1
1 2 [A] 2 = 2kt 1 1
( 2[A]0 ) O 2
1
[A]
1
= 2kt 1 [A]2
1 2 2
( 2[A]0 ) O 2 = 2
3
= 2kt 1
[A]O 2 2

3
t 1 =
2 2[A]O 2
1
[A]O 2
t

REAKSI ORDER 3 TIPE II

 REAKSI ORDER 3 TIPE II, model yang pertama dengan persamaan reaksi sebagai berikut :
A + B P
d[A]
V= = k[A]2 [B], dimana [A] = [B]
dt
d[A] = d[B]
A B
d[A] = d[B]
Ao Bo
[A] [A]O = [B] [B]O
[B] = [A] [A]O + [B]O . (1)
d[A]
= k[A]2 [B]
dt
d[A]
2 = kdt . (2)
[A] [B]
Persamaan (1) di subtitusikan ke persamaan (2)
d[A]
2 = kdt
[A] ([A] [A]O + [B]O )

Bentuk dekomposisi linear atau pecahan parsialnya:

1 x y z
= + + = kt . (3)
[A]2 ([A] [A]O + [B]O ) [A]2 [A] [A] [A]O + [B]O

Penyebutnya di samakan :
1 x([A] [A]O + [B]O ) + y[A]([A] [A]O + [B]O ) + z[A]2
=
[A]2 ([A] [A]O + [B]O ) [A]2 ([A] [A]O + [B]O )

Setelah peyebutnya dihilangkan :

1 = x([A] [A]O + [B]O ) + y[A]([A] [A]O + [B]O ) + z[A]2
1 = x[A] x[A]O + x[B]O + y[A]2 y[A][A]O + y[A][B]O + z[A]2
1 = [A]2 (y + z) + [A](x y[A]O + y[B]O ) + x[B]O x[A]O
[A]2 (y + z) = 0
y+z=0
y = z

[A](x y[A]O + y[B]O ) = 0

x y[A]O + y[B]O = 0
x + y([B]O [A]O ) = 0
y([B]O [A]O ) = x
x
y=
[B]O [A]O

x[B]O x[A]O = 1
1
x=
[B]O x[A]O
 1
y=
([B]O x[A]O )2

z = y
1
z=
([B]O x[A]O )2

nilai x, y, dan z dimasukan ke dalam persamaan (3) :

d[A} d[A] d[A]

+ = kdt
([B]O [A]O )[A]2 ([B]O [A]O )2 [A] ([B]O [A]O )2 ([A] [A]O + [B]O )
A t
1 d[A] 1 1
+ = kdt
[B]O [A]O Ao [A]2 ([B]O [A]O )2 ([B]O [A]O )2 0
1 1 1 1 [A] 1 ([A] [A]O + [B]O )
( + ) ln + ln = kt
[B]O [A]O [A] [A]0 ([B]O [A]O )2 [A]O ([B]O [A]O )2 [B]O
1 1 1 1 [A] 1 ([A] [A]O + [B]O )
( + )+ 2
ln 2
ln = kt
[B]O [A]O [A] [A]0 ([B]O [A]O ) [A]O ([B]O [A]O ) [B]O
[A]
1 1 1 1 [A]
O
( )+ ln = kt
[B]O [A]O [A] [A]0 ([B]O [A]O )2 [B]
[B]
O
1 1 1 1 [A][B]O
( )+ ln = kt
[B]O [A]O [A] [A]0 ([B]O [A]O )2 [A]O [B]

REAKSI ORDER 3 TIPE IIb

2A + B P
d[A]
= k[A]2 [B] [A] = 2[B]
dt
1
[A] = [B]
2
d[A] = 2d[B]
A B
d[A] = 2 d[B]
AO BO
[A] [A]o = 2[B] 2[B]o
[A] [A]o + 2[B]o
[B] = . (1)
2
d[A]
2 = kdt . (2)
[A] [B]
Persamaan (1) disubtitusikan ke persamaan (2)
d[A]
= kdt
2 [A] [A]o + 2[B]o
[A] ( )
2
Bentuk pecahan raionalnya:
 1 x y z
= + + = kt
2 [A] [A]o + 2[B]o [A] 2 [A] [A] [A]o + 2[B]o
[A] ( ) ( )
2 2
[A] [A]o + 2[B]o [A] [A]o + 2[B]o
1 x( ) + y[A] ( ) + y[A]2
2 2
=
2 [A] [A]o + 2[B]o [A] [A]o + 2[B]o
[A] ( ) [A]2 ( )
2 2
[A] [A]o + 2[B]o [A] [A]o + 2[B]o
1 = x( ) + y[A] ( ) + z[A]2 (x2)
2 2
2 = x([A] [A]o + 2[B]o ) + y[A]([A] [A]o + 2[B]o ) + 2z[A]2
2 = x[A] x[A]o + 2x[B]o + y[A]2 y[A][A]o + 2y[A][B]o + 2z[A]2
2 = y[A]2 + 2z[A]2 + x[A] y[A][A]o + 2y[A][B]o + 2x[B]o x[A]o
2 = [A]2 (y + 2z) + [A](x y[A]o + 2y[B]o ) + 2x[B]o x[A]o
[A]2 (y + 2z) = 0
y = 2z

2x[B]o x[A]o = 2
x([B]o [A]o ) = 2
2
x=
(2[B]o [A]o )

[A](x y[A]o + 2y[B]o ) = 0

x + 2y[B]o y[A]o = 0
x + y(2[B]o [A]o ) = 0
y(2[B]o [A]o ) = x
x
y=
(2[B]o [A]o )
2
y=
(2[B]o [A]o )2

1 1 2
z = y = ( )
2 2 (2[B]o [A]o )2
1
z=
(2[B]o [A]o )2

d[A]
= kdt
[A] [A]o + 2[B]o
[A]2 ( )
2
2d[A] 2d[A] 2d[A]
+ = kdt
(2[B]o [A]o )[A]2 (2[B]o [A]o )2 [A] (2[B]o [A]o )2 ([A] [A]o + 2[B]o )
A A A t
2 d[A] 2 d[A] 2 d[A]
+ = kdt
(2[B]o [A]o ) AO [A] (2[B]o [A]o )2 AO [A]2 (2[B]o [A]o )2 AO [A] [A]o + 2[B]o 0
2 1 1 2 [A] 2 [B]
( + ) ln + ln = kt
(2[B]o [A]o ) [A] [A]o (2[B]o [A]o )2 [A]o (2[B]o [A]o )2 [B]o
 2 1 1 2 [A] 2 [B]
( )+ 2
ln 2
ln = kt
(2[B]o [A]o ) [A] [A]o (2[B]o [A]o ) [A]o (2[B]o [A]o ) [B]o
[A]
2 1 1 2 [A]
o
( )+ ln = kt
(2[B]o [A]o ) [A] [A]o (2[B]o [A]o )2 [B]
[B]o
2 1 1 2 [A][B]o
( )+ 2
ln = kt
(2[B]o [A]o ) [A] [A]o (2[B]o [A]o ) [A]o [B]

REAKSI ORDER 3 TIPE III

d[A]
= k[A][B][C] [A] = [B] = [C]
dt
d{A] = d[B] = d[C]
A B C
d{A] = d[B] = d[C]
AO BO CO
[A] [A]O = [B] [B]O = [C] [C]O
[B] = [A] [A]O + [B]O
[C] = [A] [A]O + [C]O
d[A]
= kdt
[A][B][C]
d[A]
= kdt
[A]([A] [A]O + [B]O )([A] [A]O + [C]O )
1 x y
= +
[A]([A] [A]O + [B]O )([A] [A]O + [C]O ) A ([A] [A]O + [B]O )([A] [A]O + [C]O )
1 x([A] [A]O + [B]O )([A] [A]O + [C]O ) + y[A]
=
[A]([A] [A]O + [B]O )([A] [A]O + [C]O ) [A]([A] [A]O + [B]O )([A] [A]O + [C]O )

1 = x([A] [A]O + [B]O )([A] [A]O + [C]O ) + y[A]

1 = x([A]2 [A][A]O + [A][C]O [A][A]O + [A]2 [A]O [C]O + [A][B]O [A]O [B]O + [B]O [C]O )
1 = x[A]2 + x[A]o 2 x[A][A]O + x[A][C]o x[A][A]O + x[A][B]O x[A]O [C]o + x[B]O [C]o + y[A]
1 = (x[A]2 + x[A]o 2 ) [A](x[A]O x[C]o + x[A]O x[B]O + y) (x[A]O [C]o x[B]O [C]o )
x[A]O [C]o + x[B]O [C]o = 1
x([A]O [C]o + [B]O [C]o ) = 1
1
x=
[A]O [C]o + [B]O [C]o

[A](x[A]O x[C]O + x[A]O x[B]O y) = 0

x[A]O x[C]o + x[A]O y = 0

x(2[A]O [C]o [B]O ) y = 0
x(2[A]O [C]o [B]O ) = y
2[A]O [C]o [B]O
y=
[A]O [C]o + [B]O [C]o
 d[A] d[A](2[A]O [C]o [B]O )
+ = kdt
([A]O [C]o + [B]O [C]o )[A] ([A] [A]O + [B]O )([A] [A]O + [C]O )([A]O [C]o + [B]O [C]o )
A
1 d[A] (2[A]O [C]o [B]O ) A d[A] t
+ = kdt
([A]O [C]o + [B]O [C]o ) AO [A] ([A]O [C]o + [B]O [C]o ) AO ([A] [A]O + [B]O )([A] [A]O + [C]O ) 0
1 [A] (2[A]O [C]o [B]O ) ([A] [A]O + [B]O )([A] [A]O + [C]O )
ln + ln = kt
([A]O [C]o + [B]O [C]o ) [A]O ([A]O [C]o + [B]O [C]o ) [B]O [C]O
1 [A] (2[A]O [C]o [B]O ) [B][C]O
ln + ln = kt
([A]O [C]o + [B]O [C]o ) [A]O ([A]O [C]o + [B]O [C]o ) [B]O [C]O
1 [A] (2[A]O [C]o [B]O ) [B] (2[A]O [C]o [B]O ) [C]
ln + ln + ln = kt
([A]O [C]o + [B]O [C]o ) [A]O ([A]O [C]o + [B]O [C]o ) [B]O ([A]O [C]o + [B]O [C]o ) [C]O