SOLAF CHEMISTRY SPM 2014 QUALITATIVE ANALYSIS OF SALT

(B) QUALITATIVE ANALYSIS OF SALT

1 Which of the ions below will form green precipitate which is insoluble in excess sodium
hydroxide solution ?
Di antara ion-ion berikut, yang manakah membentuk mendakan hijau yang tidak larut dalam
larutan natrium hidroksida berlebihan ? KS D

A Lead (II) ion C Copper (II) ion

Ion plumbum(II) Ion kuprum (II)
B Magnesium ion D Iron (II) ion PS
Ion magnesium Ion ferum (II)

2 Salt X is decomposed by strong heating. The residue is brown when hot and yellow when
cold. What is X?
Garam X terurai apabila dipanaskan dengan kuat. Bakinya berwarna perang ketika
panas dan kuning ketika sejuk . Apakah X? KBAT

A Copper(II) nitrate B Zinc carbonate

Kuprum (II) nitrat Zink karbonat
C Zinc nitrate D Lead(II) nitrate
Zink nitrat Plumbum(II) nitrat

3 Which of the following ions will produce white precipitate that is insoluble in excess
aqueous ammonia solution?

Antara ion berikut, yang manakah akan menghasilkan mendakan putih yang tidak larut
dalam ammonia akueus berlebihan?

I Mg2+ II Ca2+ III Pb2+ IV Al3+

A I and II only
I dan II sahaja
B III and IV only
III dan IV sahaja
C I, III and IV only
I, III dan IV sahaja
D II, III and IV only
II, III dan IV sahaja

4 Which of the following ions form a white precipitate insoluble in excess sodium
hydroxide solution?
Antara ion-ion berikut, yang manakah membentuk mendakan putih yang larut
dalam larutan natrium hidroksida berlebihan?

A Al 3+ B Zn 2+ C Pb 2 D Mg 2+

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SOLAF CHEMISTRY SPM 2014 QUALITATIVE ANALYSIS OF SALT

5 Which of the following chemical substances can be use to verify the cation and anion in
a sample of ammonium chloride salt solution?
Antara berikut, bahan kimia yang manakah boleh digunakan untuk mengesahkan kation
dan anion dalam satu sampel larutan ammonium klorida?

Cation / Kation Anion / Anion

A Nessler reagent
Reagen Nessler
B Nessler reagent
Reagen Nessler
C Potassium thiocyanate
Kalium thiosianat
D Potassium thiocyanate
Kalium thiosianat
Dilute nitric acid and silver nitrate
Asid nitrik cair dan argentum nitrat
Dilute hydrochloric acid and barium chloride
Asid hidroklorik cair dan barium klorida
Dilute nitric acid acid silver nitrate
Asid nitrik cair dan argentum nitrat
Dilute hydrochloric acid and barium chloride
Asid nitrik cair dan barium klorida

6 The following statements show the steps taken in an experiment.

Pernyataan berikut menunjukkan langkah-langkah yang diambil dalam
satu eksperimen.

 Lead(II) nitrate solution is mixed with potassium iodide solution

Larutan Plumbum(II) nitrat dicampurkan dengan larutan kalium iodida

 The mixture is filtered

Campuran dituraskan

 The residue in the filter paper is lead(II) iodide

Baki turasan pada kertas turas ialah plumbum(II) iodida KBAT

The steps are related to

Langkah-langkah tersebut adalah berkaitan dengan
A Preparation of soluble salt
Penyediaan garam terlarut

B Preparation of insoluble salt

Penyediaan garam tak terlarut
C Purification of soluble salt
Penulenan garam terlarut

D Purification of insoluble salt

Penulenan garam tak terlarut

7 Lead(II) nitrate solution reacts with potassium iodide to form yellow precipitate and
a colourless solution.
Larutan plumbum(II) nitrat bertindak balas dengan kalium iodide untuk membentuk
mendakan kuning dan larutan tidak berwarna.
Which of the following ionic equations represents the reaction?
Antara persamaan ion berikut, yang manakah mewakili tindak balas tersebut?
KBAT

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SOLAF CHEMISTRY SPM 2014 QUALITATIVE ANALYSIS OF SALT

A K+ + I- KI
2+ -
B Pb + 2I PbI2
+
C K + NO3- KNO3-
D Pb2+ + NO3- Pb(NO3)2

8 Which of the following could be W, X.Y and Z?

Antara berikut yang manakah mungkin W, X, Y dan Z? KBAT

Solid W  Brown gas X + Colourless gas Y + Black solid Z

Pepejal W  Gas perang X + Gas tak berwarna Y + Pepejal hitam Z

W X Y Z
A Copper(II )oxide Nitrogen dioxide Oxygen Copper
Kuprum(II) oksida Nitrogen dioksida Oksigen Kuprum

B Copper(II) nitrate Nitrogen dioxide Oxygen Copper(II )oxide

Kuprum(II) nitrat Nitrogen dioksida Oksigen Kuprum(II) oksida

C Sodium nitrate Nitrogen dioxide Oxygen Sodium oxide

Natrium nitrat Nitrogen dioksida Oksigen Natrium oksida

D Potassium nitrate Nitrogen dioxide Oxygen Potassium

Kalium nitrat Nitrogen dioksida Oksigen Kalium

9 Which of the following substances can be used to differentiate between sodium

sulphate solution and sodium chloride solution?
Antara bahan berikut yang manakah boleh digunakan untuk membezakan larutan
natrium sulfat dan larutan natrium klorida?

A Dilute nitric acid B Barium nitrate solution

Asid nitrik cair Larutan barium nitrat
C Potassium iodide solution D Magnesium nitrate solution
Larutan kalium iodida Larutan magnesium nitrat

10 Reaction between a soluble salt A and sodium iodide solution will produce an
insoluble salt, lead(II) iodide

Tindak balas antara garam terlarutkan A dan larutan natrium iodida akan
menghasilkan garam tak larut, plumbum (II) iodida.

A Sodium iodide solution Lead(II) iodide

+ Larutan natrium iodida Plumbum(II) iodida
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SOLAF CHEMISTRY SPM 2014 QUALITATIVE ANALYSIS OF SALT

Which of the following substance is A?

Yang manakah antara berikut adalah A? KBAT

A Lead(II) nitrate B Lead(II) chloride

Plumbum(II) nitrat Plumbum(II) klorida

C Lead(II) carbonate D Lead(II) sulphate

Plumbum(II) karbonat Plumbum(II) sulfat

12 A series of test is carried out on solution Y and the results are shown in the Table
below:

Satu siri ujian dijalankan ke atas larutan Y dan keputusannya ditunjukkan dalam
Jadual di bawah:

Test 1 Addition of NaOH until excess. White precipitate formed. Precipitate

Ujian 1 Penambahan NaOH sehingga
berlebihan
Test 2 Addition of ammonia solution until
Ujian 2 excess.
Penambahan larutan ammonia
sehingga berlebihan
Test 3 Addition of dilute nitric acid followed by White precipitate formed.
Ujian 3 barium nitrate solution.
Penambahan larutan asid nitric diikuti
dengan larutan barium nitrat.
The substance present in solution Y is
Bahan yang hadir dalam larutan Y adalah
dissolve in excess NaOH
Mendakan putih terbentuk. Mendakan
larut dalam NaOH berlebihan
White precipitate formed. Precipitate
dissolve in excess ammonia
Mendakan putih terbentuk. Mendakan
larut dalam ammonia berlebihan.
Mendakan putih terbentuk.
KBAT

A Zinc sulphate C Lead(II)nitrate

Zink sulfat Plumbum(II)nitrat
B Aluminium chloride D Aluminium sulphate
Aluminium klorida Aluminium sulfat

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SOLAF CHEMISTRY SPM 2014 QUALITATIVE ANALYSIS OF SALT

(B) QUALITATIVE ANALYSIS OF SALT- STRUCTURED

1 Table below shows an experiment to investigate the effect of heat on copper(II)

carbonate.

Diagram Procedure Observation

Gambar rajah Prosedur Pemerhatian

Copper(II)carbonate is Green solid turns

CuCO3
heated and the gas black.
produced is passed The lime water turns
Heat through lime water. milky.
Panaskan
Lime water
Air kapur Kuprum(II) karbonat Pepejal hijau menjadi
dipanaskan dan gas yang hitam.
terhasil dialirkan melalui Air kapur menjadi
air kapur. keruh.

Based on the experiment :

(i) state the name of the products formed.

………………………………………………………………………………………
[1 mark]
(ii) write a chemical equation for the reaction.

……………………………………………………………………………………
[1 mark]

2 Diagram shows two chemical reactions involving salt J.

Rajah menunjukkan dua tindak balas kimia melibatkan garam J.

larut dalam air

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SOLAF CHEMISTRY SPM 2014 QUALITATIVE ANALYSIS OF SALT

Use the information in the Diagram to answer the following questions.

Gunakan maklumat dalam Rajah itu untuk menjawab soalan-soalan berikut.

(a) State the name of salt J.

Nyatakan nama garam J.

…………………………………………………………………………………….
[1 mark]

(b) Explain how you would carry out a simple test to confirm oxygen gas is produced
when salt J is heated in a test tube.
Terangkan bagaimana anda boleh menjalankan satu ujian ringkas untuk
mengesahkan gas oksigen terhasil apabila garam J dipanaskan.

................................................................................................................................. ..

.....................................................................................................................................
[2 marks] KBAT
(c) State two observations when salt J is heated in a test tube?
Nyatakan dua pemerhatian apabila garam J dipanaskan dalam sebuah tabung uji.?

……………………………………………………………………………………….

……………………………………………………………………………………….
[2 marks]
(d) Write a chemical equation for the decomposition of salt J by heat
Tuliskan persamaan kimia bagi penguraian garam J oleh haba.

.....................................................................................................................................
[2 marks]
(e) (i) Name aqueous solution T / Namakan larutan akueus T.

..........................................................................................................................
[1 mark]
(ii) What is the name for the type of reaction between solution J with solution T?
Apakah nama bagi jenis tindakbalas antara larutan J dengan larutan T?

……………………………………………………………………………….
[1 mark]
(f) What is observed when an acidified solution of salt J is shaken with iron(II) sulphate
solution in a test tube and then concentrated sulphuric acid is added slowly down the
side of the test tube.
Apakah yang diperhatikan apabila larutan garam J berasid ditambahkan larutan
ferum(II) sulfat dalam sebuah tabung uji dan kemudian asid sulfurik pekat
ditambahkan dengan perlahan ke bawah melalui sisi tabung uji itu.

……………………………………………………………………………………….
[1 mark]

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SOLAF CHEMISTRY SPM 2014 QUALITATIVE ANALYSIS OF SALT

(B) QUALITATIVE ANALYSIS OF SALT- ESSAY

1 (a) Diagram shows a series of chemical tests carried out by a student to identify the
cation and anion present in a salt, P.

Rajah 9 menunjukkan satu siri ujian kimia yang dijalankan oleh seorang murid bagi
tujuan mengenalpasti kation dan anion dalam suatu garam, P.

Salt P
Garam P

Testing for cation Testing for anion

Ujian kation Ujian anion

Dissolved in water
Testing for cation
Larutkan dalam air
Ujian kation

Heated strongly
Sodium Aqueous Panaskan
hydroxide ammonia is dengan kuat
solution is added until
added until excess A brown gas that Dissolved in water
excess. Ammonia turns moist blue Larutkan dalam air
Larutan akues litmus paper red is
natrium ditambah liberated
sehingga D
Gas perang yang
hidroksida
ditambah berlebihan menukarkan Confirmatory test
sehingga kertas litmus biru for anion
berlebihan lembab ke merah Ujian pengesahan
terbebas bagi anion

Based on the Diagram / Berdasarkan Rajah ,

(i) Name a salt that can possibly be P.

Namakan satu garam yang mungkin bagi P.
[1 mark] KBAT

(ii) Describe a confirmatory test for the anion present in salt P.

Terangkan satu ujian pengesahan bagi anion yang hadir dalam garam P.

[5 marks] KBAT

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SOLAF CHEMISTRY SPM 2014 QUALITATIVE ANALYSIS OF SALT

(iii) For the salt named in (a)(i), describe the observations you would obtain, when
testing for the cation, using sodium hydroxide solution and aqueous ammonia,
separately.
Bagi garam yang dinamakan di (a)(i), jelaskan pemerhatian yang anda
perolehi apabila menguji kation dengan larutan natrium hidroksida dan
ammonia akues secara berasingan.
[4 marks] KBAT

2 Diagram shows a series of reaction starting from lead(II) carbonate, PbCO 3.

Rajah menunjukkan suatu siri tindak balas bermula darpada
plumbum(ll) karbonat, PbCO3.

Solution X Gas Y
PbCO3 + HNO3 + + H2O
Larutan X

Heat Crystallisation
panaskan Penghabluran

PbO + Gas Y Solid X

Pepejal X

Based on the Diagram :

 Identify gas Y. Describe a chemical test to verify gas Y.

 Describe a chemical test to determine the presence of anion in the
solution X.
 Compare and contrast the observation when solid X and lead(II)
carbonate, PbCO3 are heated.

Berdasarkan Rajah
 Kenal pasti gas Y. Huraikan ujian kimia untuk mengesahkan gas Y
 Huraikan ujian kimia untuk menentukan kehadiran anion dakam
larutan X
 Banding dan bezakan pemerhatian apabila pepejal X dan
plumbum(ll) karbonat dipanaskan

[8 marks] KBAT

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SOLAF CHEMISTRY SPM 2014 QUALITATIVE ANALYSIS OF SALT

3 Diagram shows conversion of salt X when it heated strongly and dissolved in

water.
The solution formed is tested with sodium hydroxide, NaOH solution.
Rajah menunjukkan penukaran bagi garam X apabila dipanaskan dengan kuat
dan dilarutkan dalam air. Larutan yang terbentuk diuji dengan larutan natrium
hidroksida, NaOH.

Salt X solid Metal oxide Brown gas Colourless gas

Pepejal garam Oksida + Gas perang + Gas tanpa warna
X ∆ logam

H2O

Salt X solution A white precipitate soluble in excess NaOH.

Larutan garam X Mendakan putih larut dalam NaOH
NaOH solution
Larutan NaOH berlebihan.

Based on the information in the diagram :

Berdasarkan maklumat dalam Rajah :

(i) Identify an anion that is present in salt X. Describe a chemical test to verify
the anion.
Kenal pasti satu anion yang hadir dalam garam X. Huraikan satu ujian
kimia untuk menentusahkan anion itu.
[4 marks] KBAT

(ii) Identify three cations that are possible present in salt X solution.
Describe chemical test to verify the cations.
Kenalpasti tiga kation yang mungkin hadir dalam larutan garam X.
Huraikan ujian kimia untuk menentusahkan kation itu.
[6 marks] KBAT