ANALISIS MINERAL
a. Polimorfisme
b. Homeomorfisme
MINERAL c. Psedomorfisme
d. Paramorfisme
e. Mineraloid
Fenomena suatu kristal yang memiliki bentuk lebih dari satu
(alotropi).
Kalsit Aragonit
CaCO3
Pirit Markasit
FeS2
Sfalerit Wurzit
ZnS
Rutil Zircon
bentuk luar kristal dipertahankan tetap tetapi struktur bagian
dalamnya berubah
Ex: pirit berubah jadi limonit tetapi bagian luarnya pirit.
SUBSTITUSI
materi semula diubah sedikit demi sedikit secara terus
menerus tanpa reaksi kimia diantara keduanya.
Ex: terbentuknya kuarsa setelah fluorit
Kuarsa Fluorit
PELAPISAN KERAK (INCRUSTATION) :
suatu kerak mineral dideposit ke kristal lain.
Ex : penutupan kuarsa oleh fluorit.
PERUBAHAN
perubahan terjadi pada sebagian materi
Ex: CaSO4 anhidrit → CaSO4 . 2 H2O
PbS (galena) → PbSO4 anglesit
Galena Anglesit
Fenomena suatu kristal yang struktur bagian dalamnya
berubah sehingga terbentuk suatu polimorfi tanpa
perubahan bagian luar.
Ex: aragonit menjadi kalsit, rutil menjadi brukit.
Proses terbentuknya suatu kristal karena memadatnya
larutan koloid di bawah keadaan tekanan dan temperatur
rendah.
Ex: limonit, opal, lekaterit.
Kristal yang rusak karena radiasi unsur-unsur radioaktif
nirbentuk
Mg1,14Fe0,87Mn0,01Si0,99O4
(Mg0,57Fe0,43)2SiO4
Analisis kualitatif unsur
Nyala Reduksi
Nyala tidak tampak (d) Arah tiupan
a
Nyala oksidasi
Unsur Warna dan keadaan percikan Keterangan
Au Kuning, lunak, tidak melapisi, Dapat diperoleh dengan mudah
warna terang. melalui reduksi mineral emas telurida
tanpa flux.
Ag Putih, lunak, tidak melapisi, warna Biasanya menggunakan campuran
terang. pereduksi.
Sn Putih, lunak, menjadi suram pada Percikan sulit terbentuk, walau
pendinginan. Lapisan tipis dengan tambahan campuran
oksida berwarna putih. pereduksi. Percikan logam
teroksidasi dalam asam nitrat.
Cu Merah, lunak, permukaan hitam
jika dingin, sulit melebur
Pb Abu-abu, lunak, melebur. Warna
dalam nyala reduksi
Komposisi Warna dan keadaan lapisan pada
Unsur Keterangan
lapisan arang
As As2O3 Putih dan mudah menguap, Biasanya
mengendap pada jarak tertentu menimbulkan bau
dari analit. bawang.
Sb Sb2O3 Putih, mudah menguap, Kurang mudah
Sb2O4 mengendap dekat dengan analat. menguap dibanding
As2O3
Se SeO2 Menguap putih
Te TeO2 Putih gigi, mudah menguap. Dalam nyala
Bagian luar berwarna abu-abu reduksi membentuk
sampai coklat. lapisan.
Mineral Criteria
– 1. Crystalline solid – atoms have specific
arrangement or crystal structure
Kuarsa
(putih)
malasit ( hijau)
Ametis
(ungu)
pirit (kuning)
Warna goresan
Serbuk Pelat
gores Skala Mosh < 7
Melalui penghancuran,
pengikiran atau
penggarukan
Warna Mineral bervariasi Warna goresan tetap
Mungkin warna
Warna yang sama dari Beberapa Mineral goresan beda
(Hematit, gutit, magnetit = HITAM) (coklat hitam, coklat
kuning, hitam)
Varieties of Hematite – all same color streak
Daya tahan mineral terhadap pengikiran atau goresan
Skala 6,5
Tidak mudah
Mineral mengubah bentuk
mineral melalui
penekanan →
mineral pecah
Penentuan Kekerasan dipengaruhi :
1. Kerapuhan
2. Ada tidaknya pecahan
3. Arah penentuan kekerasan
4. Struktur kristal
5. Tidak sebandingnya material dengan alat
Sejajar dengan bidang Tidak pada bidang muka
muka kristal kristal
Biasanya material
nirbentuk
Cleavage – due to weak bonds in
the crystal structure
Halite (NaCl)
Fluorite (CaF2)
HALITE
FLUORITE
Cleavage
MUSCOVITE
BIOTITE
sifat mineral karena perlakuan pemecahan, pemotongan,
pembengkokan, penghancuran dan lain-lain.
Piknometer
(C - A)
massa jenis =
(B + C) - (A - D)
A= massa piknometer kosong
B = massa piknometer terisi air
C = mass piknometer dalam keadaan kering dan
terisi serbuk mineral
D = massa piknometer terisi mineral dan air
sampai penuh
Ditunjukkan oleh mineral yang mengandung besi
PEMBENTUKAN LARUTAN
MINERAL
UAP
Material lebur
Magma
Komposisi kimia
Mineral
(Mineral primer) magnetit,ilmenit, kromit,
pirotit, kalkopirit
Contact metamorphism: Mineralogical and textural changes and
deformation of rock resulting from the head and pressure of an igneous
intrusion in the near vicinity.
Penguapan Garam Pengendapan air tanah
Air laut/danau yang Kerak bumi memiliki banyak patahan
mengandung garam (kecil dan besar) yang berisi air tanah
MINERAL
Mineral mengkristal dan terendapkan di
dinding celah batuan
Konsentrasi, suhu, komposisi
MINERAL URAT
Penguapan larutan
Ex: penguapan air laut dan danau
Pengeluaran gas yang dapat bekerja sebagai pelarut
Air yang mengandung gas CO2 kontak dengan batu kapur
Gas CO2 Mineral
Melarutkan CaCO3 P dan T
dalam mengendap
menghasilkan
larutan
bikarbonat
keluar
Ex: stalagtit dan stalagmit
PEMBENTUKAN
MINERAL DARI Penurunan suhu dan tekanan
LARUTAN Air magmatis P dan T rendah Mineral hidrotermal
Air tanah mengendap
P dan T tinggi
Interaksi larutan-larutan
Ex: larutan CaSO4 +larutan BaCO3
Interaksi larutan dengan bahan padat
Larutan melarutkan sesuatu dari mineral, dan mengendapkan
mineral lain ditempatnya
Interaksi gas dengan larutan
Ex: air mengandung gas H2S mengendapkan Zn, Cu, Fe
Pengaruh kegiatan makhluk hidup
Moluska → aragonit atau kalsit
SUBLIMASI ….. Tidak hanya terjadi pada mineral yang
langsung mengkristal dari uap, tetapi..
hasil interaksi gas atau gas dengan batuan
PNEUMATOLITIS / PNEUMATOLISIS.
Mineral yang terbentuk dari reaksi gas, dengan batuan
yang berdekatan
Pembentukan kasierit (SnO2) bersama-sama fluorit
SnF4 + 2H2O → SnO2 + 4 HF
4 HF + 2CaCO3 → 2CaF2 + 2 H2O + 2 CO2
BATUAN BEKU
BATUAN SEDIMEN
BATUAN MALIHAN /
METAMORF
- dari pendinginan & pemadatan magma
- Mineral mengkristal sesuai “DERET BOWEN”
olivin bitownit
Mg-piroksen labradorit
Mg-Ca-piroksen anelsin
ampibol oligoklas
biotit
albit
K- felspar
muskovit
kuarsa
Jumlah Silisium Berlebih: kuarsa
Kurang: fekspatoit
PENGGOLONGAN
Macam2 felspar dan kandungan
BATUAN BEKU masing2 jenis
(P dan T rendah)
• Mineral bijih primer adalah mineral yang pertama terbentuk,
diendapkan dari larutan yang naik ke permukaan bumi
• Mineral sekunder adalah mineral yang berasal dari mineral primer
yang telah mengalami perubahan karena pengaruh oksidasi akibat
kandungan oksigen dalam air
• Naturally Occurring
• Crystalline Solid
• Specific Chemical Composition
• Inorganic
Review of Minerals
What mineral is this?
DOLOMITE
Review of Minerals
What mineral is this?
QUARTZ
Review of Minerals
What mineral is this?
GALENA
Review of Minerals
What mineral is this?
OLIVINE
Review of Minerals
What mineral is this?
ORTHOCLASE
FELDSPAR
Review of Minerals
What mineral is this?
HEMATITE
Review of Minerals
What mineral is this?
FLOURITE
Review of Minerals
What mineral is this?
GYPSUM
Review of Minerals
What mineral is this?
PYROXENE - AUGITE
Review of Minerals
What mineral is this?
PYRITE
Review of Minerals
What mineral is this?
MAGNETITE
Review of Minerals
What mineral is this?
MUSCOVITE
Review of Minerals
What mineral is this?
CALCITE
Review of Minerals
What mineral is this?
HALITE
Review of Minerals
What mineral is this?
GARNET
Review of Minerals
What mineral is this?
AMPHIBOLE
-
HORNBLENDE
Review of Minerals
What mineral is this?
BIOTITE
Goals for this lab
Learn the basics of rock identification
Learn how to distinguish between 3 rock
types
Observe hand samples and infer how
they might have been formed
*Solid aggregate of mineral grains, mineral
crystals, or other rocks
*Some exceptions
**Obsidian is made of volcanic glass
**Coal is made of plant fragments
Vesicular
Pyroclastic/Fragmental
What minerals are present also determine
what kind of Igneous Rock forms.
Chemistry changes
influence rock type
Minerals in Igneous Rocks Cont.
Chemistry changes influence rock type
Felsic rocks
Mineralogy cont.
• dominated by K-feldspar, Na Plagioclase, quartz, and biotite
• usually light in color
• typical of continental crust (Granite and Rhyolite)
Intermediate rocks
• dominated by plagiocase, amphibole, pyroxene, biotite, quartz
• intermediate color
• Andesite and diorite
Mafic rocks
• Dominated by Ca-Plagioclase, pyroxene, olivine, amphibole
• Usually dark in color
• Typical of oceanic crusts (and the Moon, Mars, and Venus!) (Basalt,
• Gabbro)
Ultramafic rocks
• Dominated by olivine, minor amounts of pyroxene and Ca-plagioclase
• Rarely seen on Earth’s surface
• Major constituent of Earth’s Mantle
• Peridotite
Sedimentary Rocks…
Type of rock
and Rock-forming
source material process
SEDIMENTARY
Weathering and Deposition,
erosion of burial, and
Exposed rocks lithification
Sediments
Grain Size
Gravel >2mm
Sand 1/16-2mm
Silt 1/256-1/16mm
Clay <1/256
Sediments cont.
How are size and angularity affected by transport?
Sediments cont.
Grain Sorting
Sedimentary Rocks
Formed by surface processes
Sediments are formed from weathering
and erosion
• Weathering = chemical and physical processes
that break up rocks into fragments of various
sizes
• Erosion = set of processes that loosen soil and
rock and move them
Sedimentary Rocks
Loose sediments form sedimentary rocks through
the process of lithification
Lithification = converts sediment into solid rock
by
• Compaction = grains are squeezed together by weight
of overlying sediment into a mass denser than original
• Cementation = minerals precipitate around deposited
particles and bind them together
The sedimentary stages of the rock cycle
Weathering Erosion carries
breaks down away particles.
rocks. Transportation moves
particles downhill.
Glacier
Delta
Desert
Playa Deposition occurs
lake when particles
settle out or
precipitate.
Diagenesis lithifies
the sediment to make
sedimentary rocks.
Sedimentary Rock Texture
Step 1 in identifying a Sedimentary Rock
• 3 types
Detrital/Siliclastic – rock made of fragments of other
rocks
Pressure
Heat to Heat to
90° - 120° C 90° - 120° C
Evaporation Precipitation
Breccia Chert
Hematite
Coal-Anthracite Conglomerate
Limestone Rocksalt
Siltstone
Sandstone Shale
Metamorphic Rocks…
Metamorphism
Metamorphism is the solid-state
transformation of a protolith (parent or
pre-existing rock) into texturally or
mineralogically distinct new rock as the
result of high temperature, high
pressure, or both.
Metamorphism is Described by
Texture, Index minerals, Grade, and
Facies
Identifying Metamorphic Rocks
Step 1
• Determine the rock texture
Foliated textures – rocks exhibit
foliation…layering or parallel alignment of
platy or flat mineral crystals (if the rock
appears layered, it is foliated) due to
pressure and recrystallization
Nonfoliated textures – rocks exhibit no
layering, yet they may exhibit stretched
fossils or long, prismatic crystals that have
grown parallel to the pressure field
Foliation
Slate
Phyllite Schist
You end up with something that is really Gneiss!
Low
Grade
Slate
Intermediate
Pressure (kilobars)
Phyllite Grade
Depth (km)
High
Grade
Schist
Blueschist Gneiss
Migmatite
Temperature (°C)
Metamorphic Rock Textures
(Unfoliated Textures)
- Crystalline Texture – medium to coarse grained aggregate
of intergrown, equigranular, visible crystals (example:
Marble)
- Microcrystalline Texture – fine grained aggregate of
intergrown microscopic crystals (example: hornfels)
- Sandy Texture – medium to coarse grained aggregate of
fused, sand-sized grains that resemble sandstone (example:
quartzite)
- Glassy Texture – homogeneous texture with no visible
grains or other structures and breaks along glossy surfaces
(anthracite coal)
Identifying Metamorphic Rocks
Step 2
• Determine the rock’s mineralogical composition
and/or other distinctive properties
Other Distinctive Features to Note
Stretched or Sheared Grains – deformed
pebbles, fossils, mineral crystals, that have been
stretched, shortened, or sheared
Porphyroblastic Texture – arrangement of large
crystals (PORPHYROBLASTS) set in a finer-
grained groundmass (sort of sounds like
porphyritic texture)
Hydrothermal Veins – fractures filled by minerals
that precipitated from hydrothermal fluids
With increasing metamorphic
Mineral suites define
grade, mineral composition
metamorphic facies.
changes.
Identifying Metamorphic Rocks
Step 3
• Use Five Step Chart for Metamorphic Rock
Analysis to determine the name of the rock you
are identifying
Step 4
• Based on the name of the identified
metamorphic rock, name the rock it was before
metamorphism (this is the metamorphic rocks
“parent” rock or protolith)
Metamorphism of Sedimentary Rocks
Protolith
Examples: metabasalt
metarhyolite
-Amphibolite
Mineral Classification
Minerals are classified by
chemical composition
1. Minerals with the same anion or anionic
group have unmistakable family
resemblances. For example, the carbonates
resemble each other more closely than say
the minerals of Cu.
2. They occur together in nature, for
example, it is very common to find both
calcite and dolomite in the same rocks.
3. It agrees with the naming of inorganic
compounds in chemistry.
And at the next level
Once minerals have been grouped by
chemical composition, they can be
further separated into groups on the
basis of internal structure.
Native Elements
Metals
Semi Metals
Non Metals
Sulfides
Including sulfarsenides; arsenides and
tellurides
Sulfosalts
In these minerals, As and Sb play a role
more akin to metals than anions. Many
important Ag minerals are sulfosalts.
Oxides
a) simple and multiple where O
combines with one or metals (cations)
Simple
Multiple
b) hydroxides with OH- group and H2O
molecules
Halides
these minerals have Cl, Br, F, and I as
anions
Carbonates
Based on the carbonate radical
Hexagonal; orthorhombic; and
monoclinic
You have examples of all three!
Nitrates
NO3 radical
Only 7 known minerals
Borates
(BO3)-3 can form polymers--about 100
known minerals
So are they iso, meso, or aniso desmic?
Phosphates
(PO4)-3 are usually hydrous as well
Sulfates
(SO4)-2 can be hydrous or anhydrous
Tungstates (WO4)-2
scheelite and wolframite are both ore
minerals for W
Silicates (SiO4) -4
1. Cabochon
POLA BATUMULIA UNTUK PERHIASAN
2. Berbidang muka